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Abundance of the chemical elements

The abundance of the chemical elements is a measure of the occurrence of the chemical elements relative to all other elements in a given environment. Abundance is measured in one of three ways: by mass fraction (in commercial contexts often called weight fraction), by mole fraction (fraction of atoms by numerical count, or sometimes fraction of molecules in gases), or by volume fraction. Volume fraction is a common abundance measure in mixed gases such as planetary atmospheres, and is similar in value to molecular mole fraction for gas mixtures at relatively low densities and pressures, and ideal gas mixtures. Most abundance values in this article are given as mass fractions.

For example, the abundance of oxygen in pure water can be measured in two ways: the mass fraction is about 89%, because that is the fraction of water's mass which is oxygen. However, the mole fraction is about 33% because only 1 atom of 3 in water, H2O, is oxygen. As another example, looking at the mass fraction abundance of hydrogen and helium in both the universe as a whole and in the atmospheres of gas-giant planets such as Jupiter, it is 74% for hydrogen and 23–25% for helium; while the (atomic) mole fraction for hydrogen is 92%, and for helium is 8%, in these environments. Changing the given environment to Jupiter's outer atmosphere, where hydrogen is diatomic while helium is not, changes the molecular mole fraction (fraction of total gas molecules), as well as the fraction of atmosphere by volume, of hydrogen to about 86%, and of helium to 13%.[Note 1]

The abundance of chemical elements in the universe is dominated by the large amounts of hydrogen and helium which were produced during the Big Bang. Remaining elements, making up only about 2% of the universe, were largely produced by supernovae and certain red giant stars. Lithium, beryllium, and boron, despite their low atomic number, are rare because, although they are produced by nuclear fusion, they are destroyed by other reactions in the stars.[1][2] Their natural occurrence is the result of cosmic ray spallation of carbon, nitrogen and oxygen in a type of nuclear fission reaction. The elements from carbon to iron are relatively more abundant in the universe because of the ease of making them in supernova nucleosynthesis. Elements of higher atomic numbers than iron (element 26) become progressively rarer in the universe, because they increasingly absorb stellar energy in their production. Also, elements with even atomic numbers are generally more common than their neighbors in the periodic table, due to favorable energetics of formation (see Oddo-Harkins rule), and among the lightest nuclides helium through sulfur the most abundant isotopes of equal number of protons and neutrons.

The abundance of elements in the Sun and outer planets is similar to that in the universe. Due to solar heating, the elements of Earth and the inner rocky planets of the Solar System have undergone an additional depletion of volatile hydrogen, helium, neon, nitrogen, and carbon (which volatilizes as methane). The crust, mantle, and core of the Earth show evidence of chemical segregation plus some sequestration by density. Lighter silicates of aluminium are found in the crust, with more magnesium silicate in the mantle, while metallic iron and nickel compose the core. The abundance of elements in specialized environments, such as atmospheres, oceans, or the human body, are primarily a product of chemical interactions with the medium in which they reside.

Universe edit

Ten most common elements in the Milky Way Galaxy estimated spectroscopically[3]
Z Element Mass fraction
(ppm)
1 Hydrogen 739,000
2 Helium 240,000
8 Oxygen 10,400
6 Carbon 4,600
10 Neon 1,340
26 Iron 1,090
7 Nitrogen 960
14 Silicon 650
12 Magnesium 580
16 Sulfur 440
Total 999,060

The elements – that is, ordinary (baryonic) matter made of protons, neutrons, and electrons, are only a small part of the content of the Universe. Cosmological observations suggest that only 4.6% of the universe's energy (including the mass contributed by energy, E = mc2m = E / c2) comprises the visible baryonic matter that constitutes stars, planets, and living beings. The rest is thought to be made up of dark energy (68%) and dark matter (27%).[4] These are forms of matter and energy believed to exist on the basis of scientific theory and inductive reasoning based on observations, but they have not been directly observed and their nature is not well understood.

Most ordinary (baryonic) matter is found in intergalactic gas, stars, and interstellar clouds, in the form of atoms or ions (plasma), although it can be found in degenerate forms in extreme astrophysical settings, such as the high densities inside white dwarfs and neutron stars.

Hydrogen is the most abundant element in the Universe; helium is second. However, after this, the rank of abundance does not continue to correspond to the atomic number; oxygen has abundance rank 3, but atomic number 8. All others are substantially less common.

 
The most abundant isotopes -Isotopes with equal numbers of protons and neutrons are unusually abundant. Relative abundance is proportional to the area.   (large blue circle) comprises 74% of the ordinary matter of the universe. Color=nucleosynthetic process: Blue=Big Bang, Green=dying low-mass stars, Yellow=exploding massive stars.

There are 80 known stable elements, and the lightest 16 comprise 99.9% of the ordinary matter of the universe. These same 16 elements, hydrogen through sulfur, fall on the initial linear portion of the Table of Nuclides (also called the Segrè plot), a plot of the proton versus neutron numbers of all matter both ordinary and exotic, containing hundreds of stable isotopes and thousands more that are unstable. The Segrè plot is initially linear because (aside from hydrogen) the vast majority of ordinary matter (99.4% in the Solar System[5]) contains an equal number of protons and neutrons (Z=N). To be sure, 74% ordinary matter exists as mononucleonic protons (hydrogen). But when nucleons combine to form stable nuclides, they combine in a ratio of one part proton to one part neutron in 99.4% of ordinary matter. The structural basis of the equality of nucleon numbers in baryonic matter is one of the simplest and most profound unsolved mysteries of the atomic nucleus.

The abundance of the lightest elements is well predicted by the standard cosmological model, since they were mostly produced shortly (i.e., within a few hundred seconds) after the Big Bang, in a process known as Big Bang nucleosynthesis. Heavier elements were mostly produced much later, inside of stars.

Hydrogen and helium are estimated to make up roughly 74% and 24% of all baryonic matter in the universe respectively. Despite comprising only a very small fraction of the universe, the remaining "heavy elements" can greatly influence astronomical phenomena. Only about 2% (by mass) of the Milky Way galaxy's disk is composed of heavy elements.

These other elements are generated by stellar processes.[6][7][8] In astronomy, a "metal" is any element other than hydrogen or helium. This distinction is significant because hydrogen and helium are the only elements that were produced in significant quantities in the Big Bang. Thus, the metallicity of a galaxy or other object is an indication of stellar activity after the Big Bang.

In general, elements up to iron are made by large stars in the process of becoming supernovae, or by smaller stars in the process of dying. One type of Iron, Iron-56, is particularly common, since it is the most stable nuclide (in that it has the highest nuclear binding energy per nucleon) and can easily be made from alpha particles (being a product of decay of radioactive nickel-56, ultimately made from 14 helium nuclei). Elements heavier than iron are made in energy-absorbing processes in large stars, and their abundance in the universe (and on Earth) generally decreases with increasing atomic number.

The table shows the ten most common elements in our galaxy (estimated spectroscopically), as measured in parts per million, by mass.[3] Nearby galaxies that have evolved along similar lines have a corresponding enrichment of elements heavier than hydrogen and helium. The more distant galaxies are being viewed as they appeared in the past, so their abundances of elements appear closer to the primordial mixture. Since physical laws and processes are apparently uniform throughout the universe, however, it is expected that these galaxies will likewise have evolved similar abundances of elements.

As shown in the periodic table, the abundance of elements is in keeping with their origin. Very abundant hydrogen and helium are products of the Big Bang. The next three elements in the periodic table (lithium, beryllium, and boron) are rare, despite their low atomic number. They had little time to form in the Big Bang. They are produced in small quantities by nuclear fusion in dying stars or by breakup of heavier elements in interstellar dust, caused by cosmic ray spallation. In supernova stars, they are produced by nuclear fusion, but then destroyed by other reactions.[1]

 
Periodic table showing the cosmological origin of each element

Heavier elements, beginning with carbon, have been produced in dying or supernova stars by buildup from alpha particles (helium nuclei), contributing to an alternatingly larger abundance of elements with even atomic numbers (these are also more stable). The effect of odd-numbered chemical elements generally being more rare in the universe was empirically noticed in 1914, and is known as the Oddo-Harkins rule.

The following graph (note log scale) shows abundance of elements in the Solar System.

 
Estimated abundances of the chemical elements in the Solar System (logarithmic scale)
Most abundant nuclides
in the Solar System[5]
Nuclide A Mass fraction in parts per million Atom fraction in parts per million
Hydrogen-1 1 705,700 909,964
Helium-4 4 275,200 88,714
Oxygen-16 16 9,592 477
Carbon-12 12 3,032 326
Nitrogen-14 14 1,105 102
Neon-20 20 1,548 100
 
Other nuclides: 3,616 172
Silicon-28 28 653 30
Magnesium-24 24 513 28
Iron-56 56 1,169 27
Sulfur-32 32 396 16
Helium-3 3 35 15
Hydrogen-2 2 23 15
Neon-22 22 208 12
Magnesium-26 26 79 4
Carbon-13 13 37 4
Magnesium-25 25 69 4
Aluminium-27 27 58 3
Argon-36 36 77 3
Calcium-40 40 60 2
Sodium-23 23 33 2
Iron-54 54 72 2
Silicon-29 29 34 2
Nickel-58 58 49 1
Silicon-30 30 23 1
Iron-57 57 28 1

Relation to nuclear binding energy edit

 
Binding energy per nucleon for a selection of nuclides. The nuclide with the highest value, 62Ni, does not appear. The horizontal lines are at 8 and 8.5 MeV.

Loose correlations have been observed between estimated elemental abundances in the universe and the nuclear binding energy curve (also called the binding energy per nucleon). Roughly speaking, the relative stability of various atomic nuclides in withstanding the extremely energetic conditions of Big Bang Nucleosynthesis (BBN) has exerted a strong influence on the relative abundance of elements formed in the Big Bang, and during the development of the universe thereafter.[9]

See the article about nucleosynthesis for an explanation of how certain nuclear fusion processes in stars (such as carbon burning, etc.) create the elements heavier than hydrogen and helium.

 

A further observed peculiarity is the jagged alternation between relative abundance and scarcity of adjacent atomic numbers in the estimated abundances of the chemical elements in which the relative abundance of even atomic numbers is roughly 2 orders of magnitude greater than the relative abundance of odd atomic numbers (Oddo-Harkins rule). A similar alternation between even and odd atomic numbers can be observed in the nuclear binding energy curve in the neighborhood of carbon and oxygen, but here the loose correlation between relative abundance and binding energy ends. The binding energy for beryllium (an even atomic number), for example, is less than the binding energy for boron (an odd atomic number), as illustrated in the nuclear binding energy curve. Additionally, the alternation in the nuclear binding energy between even and odd atomic numbers resolves above oxygen as the graph increases steadily up to its peak at iron. The semi-empirical mass formula (SEMF), also called Weizsäcker's formula or the Bethe-Weizsäcker mass formula, gives a theoretical explanation of the overall shape of the curve of nuclear binding energy.[10]

Earth edit

 
Parts-per-million cube of relative abundance by mass of elements of the entire Earth down to around 1 ppm

The Earth formed from the same cloud of matter that formed the Sun, but the planets acquired different compositions during the formation and evolution of the Solar System. In turn, the natural history of the Earth caused parts of this planet to have differing concentrations of the elements.

The mass of the Earth is approximately 5.97×1024 kg. In bulk, by mass, it is composed mostly of iron (32.1%), oxygen (30.1%), silicon (15.1%), magnesium (13.9%), sulfur (2.9%), nickel (1.8%), calcium (1.5%), and aluminium (1.4%); with the remaining 1.2% consisting of trace amounts of other elements.[11]

The bulk composition of the Earth by elemental-mass is roughly similar to the gross composition of the solar system, with the major differences being that Earth is missing a great deal of the volatile elements hydrogen, helium, neon, and nitrogen, as well as carbon which has been lost as volatile hydrocarbons.

The remaining elemental composition is roughly typical of the "rocky" inner planets, which formed in the thermal zone where solar heat drove volatile compounds into space.

The Earth retains oxygen as the second-largest component of its mass (and largest atomic fraction), mainly from this element being retained in silicate minerals which have a very high melting point and low vapor pressure.

Crust edit

 
Abundance (atom fraction) of the chemical elements in Earth's upper continental crust as a function of atomic number. The rarest elements in the crust (shown in yellow) are rare due to a combination of factors: all but one are the densest siderophiles (iron-loving) elements in the Goldschmidt classification, meaning they have a tendency to mix well with metallic iron, depleting them by being relocated deeper into the Earth's core. Their abundance in meteoroids is higher. Additionally, tellurium has been depleted by preaccretional sorting in the nebula via formation of volatile hydrogen telluride.[13]

The mass-abundance of the nine most abundant elements in the Earth's crust is approximately: oxygen 46%, silicon 28%, aluminium 8.3%, iron 5.6%, calcium 4.2%, sodium 2.5%, magnesium 2.4%, potassium 2.0%, and titanium 0.61%. Other elements occur at less than 0.15%. For a complete list, see abundance of elements in Earth's crust.

The graph at right illustrates the relative atomic-abundance of the chemical elements in Earth's upper continental crust—the part that is relatively accessible for measurements and estimation.

Many of the elements shown in the graph are classified into (partially overlapping) categories:

  1. rock-forming elements (major elements in green field, and minor elements in light green field);
  2. rare earth elements (lanthanides (La–Lu), Sc, and Y; labeled in blue);
  3. major industrial metals (global production >~3×107 kg/year; labeled in red);
  4. precious metals (labeled in purple);
  5. the nine rarest "metals" – the six platinum group elements plus Au, Re, and Te (a metalloid) – in the yellow field. These are rare in the crust from being soluble in iron and thus concentrated in the Earth's core. Tellurium is the single most depleted element in the silicate Earth relative to cosmic abundance, because in addition to being concentrated as dense chalcogenides in the core it was severely depleted by preaccretional sorting in the nebula as volatile hydrogen telluride.[13]

There are two breaks where the unstable (radioactive) elements technetium (atomic number 43) and promethium (atomic number 61) would be. These elements are surrounded by stable elements, yet their most stable isotopes have relatively short half lives (~4 million years and ~18 years respectively). These are thus extremely rare, since any primordial initial fractions of these in pre-Solar System materials have long since decayed. These two elements are now only produced naturally through the spontaneous fission of very heavy radioactive elements (for example, uranium, thorium, or the trace amounts of plutonium that exist in uranium ores), or by the interaction of certain other elements with cosmic rays. Both technetium and promethium have been identified spectroscopically in the atmospheres of stars, where they are produced by ongoing nucleosynthetic processes.

There are also breaks in the abundance graph where the six noble gases would be, since they are not chemically bound in the Earth's crust, and they are only generated in the crust by decay chains from radioactive elements, and are therefore extremely rare there.

The eight naturally occurring very rare, highly radioactive elements (polonium, astatine, francium, radium, actinium, protactinium, neptunium, and plutonium) are not included, since any of these elements that were present at the formation of the Earth have decayed away eons ago, and their quantity today is negligible and is only produced from the radioactive decay of uranium and thorium.

Oxygen and silicon are notably the most common elements in the crust. On Earth and in rocky planets in general, silicon and oxygen are far more common than their cosmic abundance. The reason is that they combine with each other to form silicate minerals.[13] Other cosmically common elements such as hydrogen, carbon and nitrogen form volatile compounds such as ammonia and methane that easily boil away into space from the heat of planetary formation and/or the Sun's light.

Rare-earth elements edit

"Rare" earth elements is a historical misnomer. The persistence of the term reflects unfamiliarity rather than true rarity. The more abundant rare earth elements are similarly concentrated in the crust compared to commonplace industrial metals such as chromium, nickel, copper, zinc, molybdenum, tin, tungsten, or lead. The two least abundant stable rare earth elements (thulium and lutetium) are nearly 200 times more common than gold. However, in contrast to the ordinary base and precious metals, rare earth elements have very little tendency to become concentrated in exploitable ore deposits. Consequently, most of the world's supply of rare earth elements comes from only a handful of sources. Furthermore, the rare earth metals are all quite chemically similar to each other, and they are thus quite difficult to separate into quantities of the pure elements.

Differences in abundances of individual rare earth elements in the upper continental crust of the Earth represent the superposition of two effects, one nuclear and one geochemical. First, the rare earth elements with even atomic numbers (58Ce, 60Nd, ...) have greater cosmic and terrestrial abundances than the adjacent rare earth elements with odd atomic numbers (57La, 59Pr, ...). Second, the lighter rare earth elements are more incompatible (because they have larger ionic radii) and therefore more strongly concentrated in the continental crust than the heavier rare earth elements. In most rare earth ore deposits, the first four rare earth elements – lanthanum, cerium, praseodymium, and neodymium – constitute 80% to 99% of the total amount of rare earth metal that can be found in the ore.

Mantle edit

The mass-abundance of the seven most abundant elements in the Earth's mantle is approximately: oxygen 44.3%, magnesium 22.3%, silicon 21.3%, iron 6.32%, calcium 2.48%, aluminium 2.29%, nickel 0.19%.[14]

Core edit

Due to mass segregation, the core of the Earth is believed to be primarily composed of iron (88.8%), with smaller amounts of nickel (5.8%), sulfur (4.5%), and less than 1% trace elements.[5]

Ocean edit

The most abundant elements in the ocean by proportion of mass in percent are oxygen (85.84%), hydrogen (10.82%), chlorine (1.94%), sodium (1.08%), magnesium (0.13%), sulfur (0.09%), calcium (0.04%), potassium (0.04%), bromine (0.007%), carbon (0.003%), and boron (0.0004%).

Atmosphere edit

The order of elements by volume fraction (which is approximately molecular mole fraction) in the atmosphere is nitrogen (78.1%), oxygen (20.9%),[15] argon (0.96%), followed by (in uncertain order) carbon and hydrogen because water vapor and carbon dioxide, which represent most of these two elements in the air, are variable components. Sulfur, phosphorus, and all other elements are present in significantly lower proportions.

According to the abundance curve graph, argon, a significant if not major component of the atmosphere, does not appear in the crust at all. This is because the atmosphere has a far smaller mass than the crust, so argon remaining in the crust contributes little to mass fraction there, while at the same time buildup of argon in the atmosphere has become large enough to be significant.

Urban soils edit

For a complete list of the abundance of elements in urban soils, see Abundances of the elements (data page)#Urban soils.

Human body edit

 
Parts-per-million cube of relative abundance by mass of elements in an average adult human down to 1 ppm

By mass, human cells consist of 65–90% water (H2O), and a significant portion of the remainder is composed of carbon-containing organic molecules. Oxygen therefore contributes a majority of a human body's mass, followed by carbon. Almost 99% of the mass of the human body is made up of six elements: hydrogen (H), carbon (C), nitrogen (N), oxygen (O), calcium (Ca), and phosphorus (P) . The next 0.75% is made up of the next five elements: potassium (K), sulfur (S), chlorine (Cl), sodium (Na), and magnesium (Mg). Only 17 elements are known for certain to be necessary to human life, with one additional element (fluorine) thought to be helpful for tooth enamel strength. A few more trace elements may play some role in the health of mammals. Boron and silicon are notably necessary for plants but have uncertain roles in animals. The elements aluminium and silicon, although very common in the earth's crust, are conspicuously rare in the human body.[16]

Below is a periodic table highlighting nutritional elements.[17]

Essential elements[18][19][20][21][22]
H   He
Li Be   B C N O F Ne
Na Mg   Al Si P S Cl Ar
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs Ba * Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
  * La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
  ** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
Legend:
  Quantity elements
  Essential trace elements
  Essentiality or function in mammals debated
  No evidence for biological action in mammals, but essential in some lower organisms.
(In the case of the lanthanides, the definition of an essential nutrient as being indispensable and irreplaceable is not completely applicable due to their extreme similarity. The stable early lanthanides La–Nd are known to stimulate the growth of various lanthanide-using organisms, and Sm–Gd show lesser effects for some such organisms. The later elements in the lanthanide series do not appear to have such effects.)[23]

See also edit

References edit

Footnotes edit

  1. ^ a b Vangioni-Flam, Elisabeth; Cassé, Michel (2012). Spite, Monique (ed.). Galaxy Evolution: Connecting the Distant Universe with the Local Fossil Record. Springer Science & Business Media. pp. 77–86. ISBN 978-9401142137.
  2. ^ Trimble, Virginia (1996). "The Origin and Evolution of the Chemical Elements". In Malkan, Matthew A.; Zuckerman, Ben (eds.). The origin and evolution of the universe. Sudbury, Mass.: Jones and Bartlett Publishers. p. 101. ISBN 0-7637-0030-4.
  3. ^ a b Croswell, Ken (February 1996). Alchemy of the Heavens. Anchor. ISBN 0-385-47214-5. from the original on 2011-05-13.
  4. ^ What is Dark Energy? 2016-01-15 at the Wayback Machine, Space.com, 1 May 2013.
  5. ^ a b c Arnett, David (1996). Supernovae and Nucleosynthesis (First ed.). Princeton, New Jersey: Princeton University Press. p. 11. ISBN 0-691-01147-8. OCLC 33162440.
  6. ^ Suess, Hans; Urey, Harold (1956). "Abundances of the Elements". Reviews of Modern Physics. 28 (1): 53. Bibcode:1956RvMP...28...53S. doi:10.1103/RevModPhys.28.53.
  7. ^ Cameron, A. G. W. (1973). "Abundances of the elements in the solar system". Space Science Reviews. 15 (1): 121. Bibcode:1973SSRv...15..121C. doi:10.1007/BF00172440. S2CID 120201972.
  8. ^ Anders, E.; Ebihara, M. (1982). "Solar-system abundances of the elements". Geochimica et Cosmochimica Acta. 46 (11): 2363. Bibcode:1982GeCoA..46.2363A. doi:10.1016/0016-7037(82)90208-3.
  9. ^ Bell, Jerry A.; GenChem Editorial/Writing Team (2005). "Chapter 3: Origin of Atoms". Chemistry: a project of the American Chemical Society. New York [u.a.]: Freeman. pp. 191–193. ISBN 978-0-7167-3126-9. Correlations between abundance and nuclear binding energy [Subsection title]
  10. ^ Bailey, David. "Semi-empirical Nuclear Mass Formula". PHY357: Strings & Binding Energy. University of Toronto. from the original on 2011-07-24. Retrieved 2011-03-31.
  11. ^ Morgan, J. W.; Anders, E. (1980). "Chemical composition of Earth, Venus, and Mercury". Proceedings of the National Academy of Sciences. 77 (12): 6973–6977. Bibcode:1980PNAS...77.6973M. doi:10.1073/pnas.77.12.6973. PMC 350422. PMID 16592930.
  12. ^ a b William F McDonough . quake.mit.edu, archived by the Internet Archive Wayback Machine.
  13. ^ a b c Anderson, Don L.; ‘Chemical Composition of the Mantle’ in Theory of the Earth, pp. 147–175 ISBN 0865421234
  14. ^ Wang, Haiyang S.; Lineweaver, Charles H.; Ireland, Trevor R. (2018-01-01). "The elemental abundances (with uncertainties) of the most Earth-like planet". Icarus. 299: 460–474. doi:10.1016/j.icarus.2017.08.024. hdl:1885/139094. ISSN 0019-1035. S2CID 119434532.
  15. ^ Zimmer, Carl (3 October 2013). "Earth's Oxygen: A Mystery Easy to Take for Granted". The New York Times. from the original on 3 October 2013. Retrieved 3 October 2013.
  16. ^ Table data from Chang, Raymond (2007). Chemistry (Ninth ed.). McGraw-Hill. p. 52. ISBN 978-0-07-110595-8.
  17. ^ Nielsen, Forrest H. (1998). "Ultratrace minerals.". In Maurice E. Shils; James A. Olsen; Moshe Shine; A. Catharine Ross (eds.). Modern nutrition in health and disease. Baltimore: Lippincott Williams & Wilkins. pp. 283–303. hdl:10113/46493. ISBN 978-0683307696.
  18. ^ Ultratrace minerals. Authors: Nielsen, Forrest H. USDA, ARS Source: Modern nutrition in health and disease / editors, Maurice E. Shils ... et al. Baltimore: Williams & Wilkins, c1999., p. 283-303. Issue Date: 1999 URI: [1]
  19. ^ Szklarska D, Rzymski P (May 2019). "Is Lithium a Micronutrient? From Biological Activity and Epidemiological Observation to Food Fortification". Biol Trace Elem Res. 189 (1): 18–27. doi:10.1007/s12011-018-1455-2. PMC 6443601. PMID 30066063.
  20. ^ Enderle J, Klink U, di Giuseppe R, Koch M, Seidel U, Weber K, Birringer M, Ratjen I, Rimbach G, Lieb W (August 2020). "Plasma Lithium Levels in a General Population: A Cross-Sectional Analysis of Metabolic and Dietary Correlates". Nutrients. 12 (8): 2489. doi:10.3390/nu12082489. PMC 7468710. PMID 32824874.
  21. ^ McCall AS, Cummings CF, Bhave G, Vanacore R, Page-McCaw A, Hudson BG (June 2014). "Bromine is an essential trace element for assembly of collagen IV scaffolds in tissue development and architecture". Cell. 157 (6): 1380–92. doi:10.1016/j.cell.2014.05.009. PMC 4144415. PMID 24906154.
  22. ^ Zoroddu, Maria Antonietta; Aaseth, Jan; Crisponi, Guido; Medici, Serenella; Peana, Massimiliano; Nurchi, Valeria Marina (2019). "The essential metals for humans: a brief overview". Journal of Inorganic Biochemistry. 195: 120–129. doi:10.1016/j.jinorgbio.2019.03.013.
  23. ^ Daumann, Lena J. (25 April 2019). "Essential and Ubiquitous: The Emergence of Lanthanide Metallobiochemistry". Angewandte Chemie International Edition. doi:10.1002/anie.201904090. Retrieved 15 June 2019.

Notes edit

  1. ^ Below Jupiter's outer atmosphere, volume fractions are significantly different from mole fractions due to high temperatures (ionization and disproportionation) and high density where the Ideal Gas Law is inapplicable.

Notations edit

  • "Rare Earth Elements—Critical Resources for High Technology | USGS Fact Sheet 087-02". geopubs.wr.usgs.gov.
  • . 3 December 2003. Archived from the original on 3 December 2003.

External links edit

  • List of elements in order of abundance in the Earth's crust (only correct for the twenty most common elements)
  • Lists of elemental abundances for the Universe, Sun, meteorites, Earth, ocean, streamwater, etc.

abundance, chemical, elements, abundance, chemical, elements, measure, occurrence, chemical, elements, relative, other, elements, given, environment, abundance, measured, three, ways, mass, fraction, commercial, contexts, often, called, weight, fraction, mole,. The abundance of the chemical elements is a measure of the occurrence of the chemical elements relative to all other elements in a given environment Abundance is measured in one of three ways by mass fraction in commercial contexts often called weight fraction by mole fraction fraction of atoms by numerical count or sometimes fraction of molecules in gases or by volume fraction Volume fraction is a common abundance measure in mixed gases such as planetary atmospheres and is similar in value to molecular mole fraction for gas mixtures at relatively low densities and pressures and ideal gas mixtures Most abundance values in this article are given as mass fractions For example the abundance of oxygen in pure water can be measured in two ways the mass fraction is about 89 because that is the fraction of water s mass which is oxygen However the mole fraction is about 33 because only 1 atom of 3 in water H2O is oxygen As another example looking at the mass fraction abundance of hydrogen and helium in both the universe as a whole and in the atmospheres of gas giant planets such as Jupiter it is 74 for hydrogen and 23 25 for helium while the atomic mole fraction for hydrogen is 92 and for helium is 8 in these environments Changing the given environment to Jupiter s outer atmosphere where hydrogen is diatomic while helium is not changes the molecular mole fraction fraction of total gas molecules as well as the fraction of atmosphere by volume of hydrogen to about 86 and of helium to 13 Note 1 The abundance of chemical elements in the universe is dominated by the large amounts of hydrogen and helium which were produced during the Big Bang Remaining elements making up only about 2 of the universe were largely produced by supernovae and certain red giant stars Lithium beryllium and boron despite their low atomic number are rare because although they are produced by nuclear fusion they are destroyed by other reactions in the stars 1 2 Their natural occurrence is the result of cosmic ray spallation of carbon nitrogen and oxygen in a type of nuclear fission reaction The elements from carbon to iron are relatively more abundant in the universe because of the ease of making them in supernova nucleosynthesis Elements of higher atomic numbers than iron element 26 become progressively rarer in the universe because they increasingly absorb stellar energy in their production Also elements with even atomic numbers are generally more common than their neighbors in the periodic table due to favorable energetics of formation see Oddo Harkins rule and among the lightest nuclides helium through sulfur the most abundant isotopes of equal number of protons and neutrons The abundance of elements in the Sun and outer planets is similar to that in the universe Due to solar heating the elements of Earth and the inner rocky planets of the Solar System have undergone an additional depletion of volatile hydrogen helium neon nitrogen and carbon which volatilizes as methane The crust mantle and core of the Earth show evidence of chemical segregation plus some sequestration by density Lighter silicates of aluminium are found in the crust with more magnesium silicate in the mantle while metallic iron and nickel compose the core The abundance of elements in specialized environments such as atmospheres oceans or the human body are primarily a product of chemical interactions with the medium in which they reside Contents 1 Universe 1 1 Relation to nuclear binding energy 2 Earth 2 1 Crust 2 1 1 Rare earth elements 2 2 Mantle 2 3 Core 2 4 Ocean 2 5 Atmosphere 2 6 Urban soils 3 Human body 4 See also 5 References 5 1 Footnotes 5 2 Notes 5 3 Notations 6 External linksUniverse editSee also Stellar population Cosmochemistry and Astrochemistry Ten most common elements in the Milky Way Galaxy estimated spectroscopically 3 Z Element Mass fraction ppm 1 Hydrogen 739 000 2 Helium 240 000 8 Oxygen 10 400 6 Carbon 4 600 10 Neon 1 340 26 Iron 1 090 7 Nitrogen 960 14 Silicon 650 12 Magnesium 580 16 Sulfur 440 Total 999 060 The elements that is ordinary baryonic matter made of protons neutrons and electrons are only a small part of the content of the Universe Cosmological observations suggest that only 4 6 of the universe s energy including the mass contributed by energy E mc2 m E c2 comprises the visible baryonic matter that constitutes stars planets and living beings The rest is thought to be made up of dark energy 68 and dark matter 27 4 These are forms of matter and energy believed to exist on the basis of scientific theory and inductive reasoning based on observations but they have not been directly observed and their nature is not well understood Most ordinary baryonic matter is found in intergalactic gas stars and interstellar clouds in the form of atoms or ions plasma although it can be found in degenerate forms in extreme astrophysical settings such as the high densities inside white dwarfs and neutron stars Hydrogen is the most abundant element in the Universe helium is second However after this the rank of abundance does not continue to correspond to the atomic number oxygen has abundance rank 3 but atomic number 8 All others are substantially less common nbsp The most abundant isotopes Isotopes with equal numbers of protons and neutrons are unusually abundant Relative abundance is proportional to the area H 1 displaystyle ce 1 H nbsp large blue circle comprises 74 of the ordinary matter of the universe Color nucleosynthetic process Blue Big Bang Green dying low mass stars Yellow exploding massive stars There are 80 known stable elements and the lightest 16 comprise 99 9 of the ordinary matter of the universe These same 16 elements hydrogen through sulfur fall on the initial linear portion of the Table of Nuclides also called the Segre plot a plot of the proton versus neutron numbers of all matter both ordinary and exotic containing hundreds of stable isotopes and thousands more that are unstable The Segre plot is initially linear because aside from hydrogen the vast majority of ordinary matter 99 4 in the Solar System 5 contains an equal number of protons and neutrons Z N To be sure 74 ordinary matter exists as mononucleonic protons hydrogen But when nucleons combine to form stable nuclides they combine in a ratio of one part proton to one part neutron in 99 4 of ordinary matter The structural basis of the equality of nucleon numbers in baryonic matter is one of the simplest and most profound unsolved mysteries of the atomic nucleus The abundance of the lightest elements is well predicted by the standard cosmological model since they were mostly produced shortly i e within a few hundred seconds after the Big Bang in a process known as Big Bang nucleosynthesis Heavier elements were mostly produced much later inside of stars Hydrogen and helium are estimated to make up roughly 74 and 24 of all baryonic matter in the universe respectively Despite comprising only a very small fraction of the universe the remaining heavy elements can greatly influence astronomical phenomena Only about 2 by mass of the Milky Way galaxy s disk is composed of heavy elements These other elements are generated by stellar processes 6 7 8 In astronomy a metal is any element other than hydrogen or helium This distinction is significant because hydrogen and helium are the only elements that were produced in significant quantities in the Big Bang Thus the metallicity of a galaxy or other object is an indication of stellar activity after the Big Bang In general elements up to iron are made by large stars in the process of becoming supernovae or by smaller stars in the process of dying One type of Iron Iron 56 is particularly common since it is the most stable nuclide in that it has the highest nuclear binding energy per nucleon and can easily be made from alpha particles being a product of decay of radioactive nickel 56 ultimately made from 14 helium nuclei Elements heavier than iron are made in energy absorbing processes in large stars and their abundance in the universe and on Earth generally decreases with increasing atomic number The table shows the ten most common elements in our galaxy estimated spectroscopically as measured in parts per million by mass 3 Nearby galaxies that have evolved along similar lines have a corresponding enrichment of elements heavier than hydrogen and helium The more distant galaxies are being viewed as they appeared in the past so their abundances of elements appear closer to the primordial mixture Since physical laws and processes are apparently uniform throughout the universe however it is expected that these galaxies will likewise have evolved similar abundances of elements As shown in the periodic table the abundance of elements is in keeping with their origin Very abundant hydrogen and helium are products of the Big Bang The next three elements in the periodic table lithium beryllium and boron are rare despite their low atomic number They had little time to form in the Big Bang They are produced in small quantities by nuclear fusion in dying stars or by breakup of heavier elements in interstellar dust caused by cosmic ray spallation In supernova stars they are produced by nuclear fusion but then destroyed by other reactions 1 nbsp Periodic table showing the cosmological origin of each element Heavier elements beginning with carbon have been produced in dying or supernova stars by buildup from alpha particles helium nuclei contributing to an alternatingly larger abundance of elements with even atomic numbers these are also more stable The effect of odd numbered chemical elements generally being more rare in the universe was empirically noticed in 1914 and is known as the Oddo Harkins rule The following graph note log scale shows abundance of elements in the Solar System nbsp Estimated abundances of the chemical elements in the Solar System logarithmic scale Most abundant nuclides in the Solar System 5 Nuclide A Mass fraction in parts per million Atom fraction in parts per million Hydrogen 1 1 705 700 909 964 Helium 4 4 275 200 88 714 Oxygen 16 16 9 592 477 Carbon 12 12 3 032 326 Nitrogen 14 14 1 105 102 Neon 20 20 1 548 100 nbsp Other nuclides 3 616 172 Silicon 28 28 653 30 Magnesium 24 24 513 28 Iron 56 56 1 169 27 Sulfur 32 32 396 16 Helium 3 3 35 15 Hydrogen 2 2 23 15 Neon 22 22 208 12 Magnesium 26 26 79 4 Carbon 13 13 37 4 Magnesium 25 25 69 4 Aluminium 27 27 58 3 Argon 36 36 77 3 Calcium 40 40 60 2 Sodium 23 23 33 2 Iron 54 54 72 2 Silicon 29 29 34 2 Nickel 58 58 49 1 Silicon 30 30 23 1 Iron 57 57 28 1 Relation to nuclear binding energy edit nbsp Binding energy per nucleon for a selection of nuclides The nuclide with the highest value 62Ni does not appear The horizontal lines are at 8 and 8 5 MeV Loose correlations have been observed between estimated elemental abundances in the universe and the nuclear binding energy curve also called the binding energy per nucleon Roughly speaking the relative stability of various atomic nuclides in withstanding the extremely energetic conditions of Big Bang Nucleosynthesis BBN has exerted a strong influence on the relative abundance of elements formed in the Big Bang and during the development of the universe thereafter 9 See the article about nucleosynthesis for an explanation of how certain nuclear fusion processes in stars such as carbon burning etc create the elements heavier than hydrogen and helium nbsp A further observed peculiarity is the jagged alternation between relative abundance and scarcity of adjacent atomic numbers in the estimated abundances of the chemical elements in which the relative abundance of even atomic numbers is roughly 2 orders of magnitude greater than the relative abundance of odd atomic numbers Oddo Harkins rule A similar alternation between even and odd atomic numbers can be observed in the nuclear binding energy curve in the neighborhood of carbon and oxygen but here the loose correlation between relative abundance and binding energy ends The binding energy for beryllium an even atomic number for example is less than the binding energy for boron an odd atomic number as illustrated in the nuclear binding energy curve Additionally the alternation in the nuclear binding energy between even and odd atomic numbers resolves above oxygen as the graph increases steadily up to its peak at iron The semi empirical mass formula SEMF also called Weizsacker s formula or the Bethe Weizsacker mass formula gives a theoretical explanation of the overall shape of the curve of nuclear binding energy 10 Earth edit nbsp Parts per million cube of relative abundance by mass of elements of the entire Earth down to around 1 ppm See also Earth Chemical composition The Earth formed from the same cloud of matter that formed the Sun but the planets acquired different compositions during the formation and evolution of the Solar System In turn the natural history of the Earth caused parts of this planet to have differing concentrations of the elements The mass of the Earth is approximately 5 97 1024 kg In bulk by mass it is composed mostly of iron 32 1 oxygen 30 1 silicon 15 1 magnesium 13 9 sulfur 2 9 nickel 1 8 calcium 1 5 and aluminium 1 4 with the remaining 1 2 consisting of trace amounts of other elements 11 The bulk composition of the Earth by elemental mass is roughly similar to the gross composition of the solar system with the major differences being that Earth is missing a great deal of the volatile elements hydrogen helium neon and nitrogen as well as carbon which has been lost as volatile hydrocarbons The remaining elemental composition is roughly typical of the rocky inner planets which formed in the thermal zone where solar heat drove volatile compounds into space The Earth retains oxygen as the second largest component of its mass and largest atomic fraction mainly from this element being retained in silicate minerals which have a very high melting point and low vapor pressure Estimated abundances of chemical elements in the Earth 12 The right two columns give the fraction of the mass in parts per million ppm and the fraction by number of atoms in parts per billion ppb Atomic number Name Symbol Mass fraction ppm 12 Atomic fraction ppb 8 oxygen O 297 000 482 000 000 12 magnesium Mg 154 000 164 000 000 14 silicon Si 161 000 150 000 000 26 iron Fe 319 000 148 000 000 13 aluminium Al 15 900 15 300 000 20 calcium Ca 17 100 11 100 000 28 nickel Ni 18 220 8 010 000 1 hydrogen H 260 6 700 000 16 sulfur S 6 350 5 150 000 24 chromium Cr 4 700 2 300 000 11 sodium Na 1 800 2 000 000 6 carbon C 730 1 600 000 15 phosphorus P 1 210 1 020 000 25 manganese Mn 1 700 800 000 22 titanium Ti 810 440 000 27 cobalt Co 880 390 000 19 potassium K 160 110 000 17 chlorine Cl 76 56 000 23 vanadium V 105 53 600 7 nitrogen N 25 46 000 29 copper Cu 60 25 000 30 zinc Zn 40 16 000 9 fluorine F 10 14 000 21 scandium Sc 11 6 300 3 lithium Li 1 10 4 100 38 strontium Sr 13 3 900 32 germanium Ge 7 00 2 500 40 zirconium Zr 7 10 2 000 31 gallium Ga 3 00 1 000 34 selenium Se 2 70 890 56 barium Ba 4 50 850 39 yttrium Y 2 90 850 33 arsenic As 1 70 590 5 boron B 0 20 480 42 molybdenum Mo 1 70 460 44 ruthenium Ru 1 30 330 78 platinum Pt 1 90 250 46 palladium Pd 1 00 240 58 cerium Ce 1 13 210 60 neodymium Nd 0 84 150 4 beryllium Be 0 05 140 41 niobium Nb 0 44 120 76 osmium Os 0 90 120 77 iridium Ir 0 90 120 37 rubidium Rb 0 40 120 35 bromine Br 0 30 97 57 lanthanum La 0 44 82 66 dysprosium Dy 0 46 74 64 gadolinium Gd 0 37 61 52 tellurium Te 0 30 61 45 rhodium Rh 0 24 61 50 tin Sn 0 25 55 62 samarium Sm 0 27 47 68 erbium Er 0 30 47 70 ytterbium Yb 0 30 45 59 praseodymium Pr 0 17 31 82 lead Pb 0 23 29 72 hafnium Hf 0 19 28 74 tungsten W 0 17 24 79 gold Au 0 16 21 48 cadmium Cd 0 08 18 63 europium Eu 0 10 17 67 holmium Ho 0 10 16 47 silver Ag 0 05 12 65 terbium Tb 0 07 11 51 antimony Sb 0 05 11 75 rhenium Re 0 08 10 53 iodine I 0 05 10 69 thulium Tm 0 05 7 55 caesium Cs 0 04 7 71 lutetium Lu 0 05 7 90 thorium Th 0 06 6 73 tantalum Ta 0 03 4 80 mercury Hg 0 02 3 92 uranium U 0 02 2 49 indium In 0 01 2 81 thallium Tl 0 01 2 83 bismuth Bi 0 01 1 Crust edit Main article Abundance of elements in Earth s crust nbsp Abundance atom fraction of the chemical elements in Earth s upper continental crust as a function of atomic number The rarest elements in the crust shown in yellow are rare due to a combination of factors all but one are the densest siderophiles iron loving elements in the Goldschmidt classification meaning they have a tendency to mix well with metallic iron depleting them by being relocated deeper into the Earth s core Their abundance in meteoroids is higher Additionally tellurium has been depleted by preaccretional sorting in the nebula via formation of volatile hydrogen telluride 13 The mass abundance of the nine most abundant elements in the Earth s crust is approximately oxygen 46 silicon 28 aluminium 8 3 iron 5 6 calcium 4 2 sodium 2 5 magnesium 2 4 potassium 2 0 and titanium 0 61 Other elements occur at less than 0 15 For a complete list see abundance of elements in Earth s crust The graph at right illustrates the relative atomic abundance of the chemical elements in Earth s upper continental crust the part that is relatively accessible for measurements and estimation Many of the elements shown in the graph are classified into partially overlapping categories rock forming elements major elements in green field and minor elements in light green field rare earth elements lanthanides La Lu Sc and Y labeled in blue major industrial metals global production gt 3 107 kg year labeled in red precious metals labeled in purple the nine rarest metals the six platinum group elements plus Au Re and Te a metalloid in the yellow field These are rare in the crust from being soluble in iron and thus concentrated in the Earth s core Tellurium is the single most depleted element in the silicate Earth relative to cosmic abundance because in addition to being concentrated as dense chalcogenides in the core it was severely depleted by preaccretional sorting in the nebula as volatile hydrogen telluride 13 There are two breaks where the unstable radioactive elements technetium atomic number 43 and promethium atomic number 61 would be These elements are surrounded by stable elements yet their most stable isotopes have relatively short half lives 4 million years and 18 years respectively These are thus extremely rare since any primordial initial fractions of these in pre Solar System materials have long since decayed These two elements are now only produced naturally through the spontaneous fission of very heavy radioactive elements for example uranium thorium or the trace amounts of plutonium that exist in uranium ores or by the interaction of certain other elements with cosmic rays Both technetium and promethium have been identified spectroscopically in the atmospheres of stars where they are produced by ongoing nucleosynthetic processes There are also breaks in the abundance graph where the six noble gases would be since they are not chemically bound in the Earth s crust and they are only generated in the crust by decay chains from radioactive elements and are therefore extremely rare there The eight naturally occurring very rare highly radioactive elements polonium astatine francium radium actinium protactinium neptunium and plutonium are not included since any of these elements that were present at the formation of the Earth have decayed away eons ago and their quantity today is negligible and is only produced from the radioactive decay of uranium and thorium Oxygen and silicon are notably the most common elements in the crust On Earth and in rocky planets in general silicon and oxygen are far more common than their cosmic abundance The reason is that they combine with each other to form silicate minerals 13 Other cosmically common elements such as hydrogen carbon and nitrogen form volatile compounds such as ammonia and methane that easily boil away into space from the heat of planetary formation and or the Sun s light Rare earth elements edit Rare earth elements is a historical misnomer The persistence of the term reflects unfamiliarity rather than true rarity The more abundant rare earth elements are similarly concentrated in the crust compared to commonplace industrial metals such as chromium nickel copper zinc molybdenum tin tungsten or lead The two least abundant stable rare earth elements thulium and lutetium are nearly 200 times more common than gold However in contrast to the ordinary base and precious metals rare earth elements have very little tendency to become concentrated in exploitable ore deposits Consequently most of the world s supply of rare earth elements comes from only a handful of sources Furthermore the rare earth metals are all quite chemically similar to each other and they are thus quite difficult to separate into quantities of the pure elements Differences in abundances of individual rare earth elements in the upper continental crust of the Earth represent the superposition of two effects one nuclear and one geochemical First the rare earth elements with even atomic numbers 58Ce 60Nd have greater cosmic and terrestrial abundances than the adjacent rare earth elements with odd atomic numbers 57La 59Pr Second the lighter rare earth elements are more incompatible because they have larger ionic radii and therefore more strongly concentrated in the continental crust than the heavier rare earth elements In most rare earth ore deposits the first four rare earth elements lanthanum cerium praseodymium and neodymium constitute 80 to 99 of the total amount of rare earth metal that can be found in the ore Mantle edit Main article Earth s mantle The mass abundance of the seven most abundant elements in the Earth s mantle is approximately oxygen 44 3 magnesium 22 3 silicon 21 3 iron 6 32 calcium 2 48 aluminium 2 29 nickel 0 19 14 Core edit See also Structure of Earth Core Due to mass segregation the core of the Earth is believed to be primarily composed of iron 88 8 with smaller amounts of nickel 5 8 sulfur 4 5 and less than 1 trace elements 5 Ocean edit For a complete list see Abundances of the elements data page Sea water See also Seawater Chemical composition The most abundant elements in the ocean by proportion of mass in percent are oxygen 85 84 hydrogen 10 82 chlorine 1 94 sodium 1 08 magnesium 0 13 sulfur 0 09 calcium 0 04 potassium 0 04 bromine 0 007 carbon 0 003 and boron 0 0004 Atmosphere edit See also Atmosphere of Earth Composition The order of elements by volume fraction which is approximately molecular mole fraction in the atmosphere is nitrogen 78 1 oxygen 20 9 15 argon 0 96 followed by in uncertain order carbon and hydrogen because water vapor and carbon dioxide which represent most of these two elements in the air are variable components Sulfur phosphorus and all other elements are present in significantly lower proportions According to the abundance curve graph argon a significant if not major component of the atmosphere does not appear in the crust at all This is because the atmosphere has a far smaller mass than the crust so argon remaining in the crust contributes little to mass fraction there while at the same time buildup of argon in the atmosphere has become large enough to be significant Urban soils edit For a complete list of the abundance of elements in urban soils see Abundances of the elements data page Urban soils See also Soil ChemistryHuman body editMain article Composition of the human body Elemental abundance in the human body Element Proportion by mass Oxygen 65 Carbon 18 Hydrogen 10 Nitrogen 3 Calcium 1 5 Phosphorus 1 2 Potassium 0 2 Sulfur 0 2 Chlorine 0 2 Sodium 0 1 Magnesium 0 05 Iron lt 0 05 Cobalt lt 0 05 Copper lt 0 05 Zinc lt 0 05 Iodine lt 0 05 Selenium lt 0 01 nbsp Parts per million cube of relative abundance by mass of elements in an average adult human down to 1 ppm By mass human cells consist of 65 90 water H2O and a significant portion of the remainder is composed of carbon containing organic molecules Oxygen therefore contributes a majority of a human body s mass followed by carbon Almost 99 of the mass of the human body is made up of six elements hydrogen H carbon C nitrogen N oxygen O calcium Ca and phosphorus P The next 0 75 is made up of the next five elements potassium K sulfur S chlorine Cl sodium Na and magnesium Mg Only 17 elements are known for certain to be necessary to human life with one additional element fluorine thought to be helpful for tooth enamel strength A few more trace elements may play some role in the health of mammals Boron and silicon are notably necessary for plants but have uncertain roles in animals The elements aluminium and silicon although very common in the earth s crust are conspicuously rare in the human body 16 Below is a periodic table highlighting nutritional elements 17 Essential elements 18 19 20 21 22 vte H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Legend The four basic organic elements Quantity elements Essential trace elements Essentiality or function in mammals debated No evidence for biological action in mammals but essential in some lower organisms In the case of the lanthanides the definition of an essential nutrient as being indispensable and irreplaceable is not completely applicable due to their extreme similarity The stable early lanthanides La Nd are known to stimulate the growth of various lanthanide using organisms and Sm Gd show lesser effects for some such organisms The later elements in the lanthanide series do not appear to have such effects 23 See also editAbundances of the elements data page Abundance of elements in Earth s crust Natural abundance isotopic abundance Goldschmidt classification Geochemical classification Primordial nuclide Nuclides predating the Earth s formation found on Earth Radiative levitation List of data references for chemical elementsReferences editFootnotes edit a b Vangioni Flam Elisabeth Casse Michel 2012 Spite Monique ed Galaxy Evolution Connecting the Distant Universe with the Local Fossil Record Springer Science amp Business Media pp 77 86 ISBN 978 9401142137 Trimble Virginia 1996 The Origin and Evolution of the Chemical Elements In Malkan Matthew A Zuckerman Ben eds The origin and evolution of the universe Sudbury Mass Jones and Bartlett Publishers p 101 ISBN 0 7637 0030 4 a b Croswell Ken February 1996 Alchemy of the Heavens Anchor ISBN 0 385 47214 5 Archived from the original on 2011 05 13 What is Dark Energy Archived 2016 01 15 at the Wayback Machine Space com 1 May 2013 a b c Arnett David 1996 Supernovae and Nucleosynthesis First ed Princeton New Jersey Princeton University Press p 11 ISBN 0 691 01147 8 OCLC 33162440 Suess Hans Urey Harold 1956 Abundances of the Elements Reviews of Modern Physics 28 1 53 Bibcode 1956RvMP 28 53S doi 10 1103 RevModPhys 28 53 Cameron A G W 1973 Abundances of the elements in the solar system Space Science Reviews 15 1 121 Bibcode 1973SSRv 15 121C doi 10 1007 BF00172440 S2CID 120201972 Anders E Ebihara M 1982 Solar system abundances of the elements Geochimica et Cosmochimica Acta 46 11 2363 Bibcode 1982GeCoA 46 2363A doi 10 1016 0016 7037 82 90208 3 Bell Jerry A GenChem Editorial Writing Team 2005 Chapter 3 Origin of Atoms Chemistry a project of the American Chemical Society New York u a Freeman pp 191 193 ISBN 978 0 7167 3126 9 Correlations between abundance and nuclear binding energy Subsection title Bailey David Semi empirical Nuclear Mass Formula PHY357 Strings amp Binding Energy University of Toronto Archived from the original on 2011 07 24 Retrieved 2011 03 31 Morgan J W Anders E 1980 Chemical composition of Earth Venus and Mercury Proceedings of the National Academy of Sciences 77 12 6973 6977 Bibcode 1980PNAS 77 6973M doi 10 1073 pnas 77 12 6973 PMC 350422 PMID 16592930 a b William F McDonough The composition of the Earth quake mit edu archived by the Internet Archive Wayback Machine a b c Anderson Don L Chemical Composition of the Mantle in Theory of the Earth pp 147 175 ISBN 0865421234 Wang Haiyang S Lineweaver Charles H Ireland Trevor R 2018 01 01 The elemental abundances with uncertainties of the most Earth like planet Icarus 299 460 474 doi 10 1016 j icarus 2017 08 024 hdl 1885 139094 ISSN 0019 1035 S2CID 119434532 Zimmer Carl 3 October 2013 Earth s Oxygen A Mystery Easy to Take for Granted The New York Times Archived from the original on 3 October 2013 Retrieved 3 October 2013 Table data from Chang Raymond 2007 Chemistry Ninth ed McGraw Hill p 52 ISBN 978 0 07 110595 8 Nielsen Forrest H 1998 Ultratrace minerals In Maurice E Shils James A Olsen Moshe Shine A Catharine Ross eds Modern nutrition in health and disease Baltimore Lippincott Williams amp Wilkins pp 283 303 hdl 10113 46493 ISBN 978 0683307696 Ultratrace minerals Authors Nielsen Forrest H USDA ARS Source Modern nutrition in health and disease editors Maurice E Shils et al Baltimore Williams amp Wilkins c1999 p 283 303 Issue Date 1999 URI 1 Szklarska D Rzymski P May 2019 Is Lithium a Micronutrient From Biological Activity and Epidemiological Observation to Food Fortification Biol Trace Elem Res 189 1 18 27 doi 10 1007 s12011 018 1455 2 PMC 6443601 PMID 30066063 Enderle J Klink U di Giuseppe R Koch M Seidel U Weber K Birringer M Ratjen I Rimbach G Lieb W August 2020 Plasma Lithium Levels in a General Population A Cross Sectional Analysis of Metabolic and Dietary Correlates Nutrients 12 8 2489 doi 10 3390 nu12082489 PMC 7468710 PMID 32824874 McCall AS Cummings CF Bhave G Vanacore R Page McCaw A Hudson BG June 2014 Bromine is an essential trace element for assembly of collagen IV scaffolds in tissue development and architecture Cell 157 6 1380 92 doi 10 1016 j cell 2014 05 009 PMC 4144415 PMID 24906154 Zoroddu Maria Antonietta Aaseth Jan Crisponi Guido Medici Serenella Peana Massimiliano Nurchi Valeria Marina 2019 The essential metals for humans a brief overview Journal of Inorganic Biochemistry 195 120 129 doi 10 1016 j jinorgbio 2019 03 013 Daumann Lena J 25 April 2019 Essential and Ubiquitous The Emergence of Lanthanide Metallobiochemistry Angewandte Chemie International Edition doi 10 1002 anie 201904090 Retrieved 15 June 2019 Notes edit Below Jupiter s outer atmosphere volume fractions are significantly different from mole fractions due to high temperatures ionization and disproportionation and high density where the Ideal Gas Law is inapplicable Notations edit Rare Earth Elements Critical Resources for High Technology USGS Fact Sheet 087 02 geopubs wr usgs gov Imagine the Universe Dictionary 3 December 2003 Archived from the original on 3 December 2003 External links editList of elements in order of abundance in the Earth s crust only correct for the twenty most common elements Cosmic abundance of the elements and nucleosynthesis WebElements com Lists of elemental abundances for the Universe Sun meteorites Earth ocean streamwater etc Portals nbsp Earth sciences nbsp Chemistry nbsp Geography nbsp Astronomy nbsp Stars nbsp Science Retrieved from https en wikipedia org w index php title Abundance of the chemical elements amp oldid 1220769636, wikipedia, wiki, book, books, library,

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