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Proton

A proton is a stable subatomic particle, symbol
p
, H+, or 1H+ with a positive electric charge of +1 e (elementary charge). Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei).

Proton
The quark content of a proton. The color assignment of individual quarks is arbitrary, but all three colors must be present. Forces between quarks are mediated by gluons.
ClassificationBaryon
Composition2 up quarks (u), 1 down quark (d)
StatisticsFermionic
FamilyHadron
InteractionsGravity, electromagnetic, weak, strong
Symbol
p
,
p+
,
N+
, 1
1
H+
AntiparticleAntiproton
TheorizedWilliam Prout (1815)
DiscoveredObserved as H+ by Eugen Goldstein (1886). Identified in other nuclei (and named) by Ernest Rutherford (1917–1920).
Mass1.67262192369(51)×10−27 kg[1]
1.007276466621(53) Da[2]
938.27208816(29) MeV/c2[3]
Mean lifetime> 3.6×1029 years[4] (stable)
Electric charge+1 e
Charge radius0.8414(19) fm[5]
Electric dipole moment< 2.1×10−25 e⋅cm[6]
Electric polarizability0.00112(4) fm3
Magnetic moment1.41060679736(60)×10−26 J⋅T−1[7]
1.52103220230(46)×10−3 μB[5]
2.79284734463(82) μN[8]
Magnetic polarizability1.9(5)×10−4 fm3
Spin1/2
Isospin1/2
Parity+1
CondensedI(JP) = 1/2(1/2+)

One or more protons are present in the nucleus of every atom. They provide the attractive electrostatic central force that binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol Z). Since each element has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element.

The word proton is Greek for "first", and this name was given to the hydrogen nucleus by Ernest Rutherford in 1920. In previous years, Rutherford had discovered that the hydrogen nucleus (known to be the lightest nucleus) could be extracted from the nuclei of nitrogen by atomic collisions.[9] Protons were therefore a candidate to be a fundamental or elementary particle, and hence a building block of nitrogen and all other heavier atomic nuclei.

Although protons were originally considered to be elementary particles, in the modern Standard Model of particle physics, protons are now known to be composite particles, containing three valence quarks, and together with neutrons are now classified as hadrons. Protons are composed of two up quarks of charge +2/3e and one down quark of charge −1/3e. The rest masses of quarks contribute only about 1% of a proton's mass.[10] The remainder of a proton's mass is due to quantum chromodynamics binding energy, which includes the kinetic energy of the quarks and the energy of the gluon fields that bind the quarks together. Because protons are not fundamental particles, they possess a measurable size; the root mean square charge radius of a proton is about 0.84–0.87 fm (1 fm = 10−15 m).[11][12] In 2019, two different studies, using different techniques, found this radius to be 0.833 fm, with an uncertainty of ±0.010 fm.[13][14]

Free protons occur occasionally on Earth: thunderstorms can produce protons with energies of up to several tens of MeV.[15][16] At sufficiently low temperatures and kinetic energies, free protons will bind to electrons. However, the character of such bound protons does not change, and they remain protons. A fast proton moving through matter will slow by interactions with electrons and nuclei, until it is captured by the electron cloud of an atom. The result is a protonated atom, which is a chemical compound of hydrogen. In a vacuum, when free electrons are present, a sufficiently slow proton may pick up a single free electron, becoming a neutral hydrogen atom, which is chemically a free radical. Such "free hydrogen atoms" tend to react chemically with many other types of atoms at sufficiently low energies. When free hydrogen atoms react with each other, they form neutral hydrogen molecules (H2), which are the most common molecular component of molecular clouds in interstellar space.

Free protons are routinely used for accelerators for proton therapy or various particle physics experiments, with the most powerful example being the Large Hadron Collider.

Description

Unsolved problem in physics:

How do the quarks and gluons carry the spin of protons?

Protons are spin-1/2 fermions and are composed of three valence quarks,[17] making them baryons (a sub-type of hadrons). The two up quarks and one down quark of a proton are held together by the strong force, mediated by gluons.[18]: 21–22  A modern perspective has a proton composed of the valence quarks (up, up, down), the gluons, and transitory pairs of sea quarks. Protons have a positive charge distribution, which decays approximately exponentially, with a root mean square charge radius of about 0.8 fm.[19]

Protons and neutrons are both nucleons, which may be bound together by the nuclear force to form atomic nuclei. The nucleus of the most common isotope of the hydrogen atom (with the chemical symbol "H") is a lone proton. The nuclei of the heavy hydrogen isotopes deuterium and tritium contain one proton bound to one and two neutrons, respectively. All other types of atomic nuclei are composed of two or more protons and various numbers of neutrons.

History

The concept of a hydrogen-like particle as a constituent of other atoms was developed over a long period. As early as 1815, William Prout proposed that all atoms are composed of hydrogen atoms (which he called "protyles"), based on a simplistic interpretation of early values of atomic weights (see Prout's hypothesis), which was disproved when more accurate values were measured.[20]: 39–42 

 
 
Proton detected in an isopropanol cloud chamber

In 1886, Eugen Goldstein discovered canal rays (also known as anode rays) and showed that they were positively charged particles (ions) produced from gases. However, since particles from different gases had different values of charge-to-mass ratio (q/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Wilhelm Wien in 1898 identified the hydrogen ion as the particle with the highest charge-to-mass ratio in ionized gases.[21]

Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra.

In 1917 (in experiments reported in 1919 and 1925), Rutherford proved that the hydrogen nucleus is present in other nuclei, a result usually described as the discovery of protons.[22] These experiments began after Rutherford had noticed that, when alpha particles were shot into air (mostly nitrogen), his scintillation detectors showed the signatures of typical hydrogen nuclei as a product. After experimentation Rutherford traced the reaction to the nitrogen in air and found that when alpha particles were introduced into pure nitrogen gas, the effect was larger. In 1919 Rutherford assumed that the alpha particle merely knocked a proton out of nitrogen, turning it into carbon. After observing Blackett's cloud chamber images in 1925, Rutherford realized that the alpha particle was absorbed. After capture of the alpha particle, a hydrogen nucleus is ejected, so that heavy oxygen, not carbon, is the result – i.e., the atomic number Z of the nucleus is increased rather than reduced. This was the first reported nuclear reaction, 14N + α → 17O + p. Rutherford at first thought of our modern "p" in this equation as a hydrogen ion, H+.

Depending on one's perspective, either 1919 (when it was seen experimentally as derived from another source than hydrogen) or 1920 (when it was recognized and proposed as an elementary particle) may be regarded as the moment when the proton was 'discovered'.

Rutherford knew hydrogen to be the simplest and lightest element and was influenced by Prout's hypothesis that hydrogen was the building block of all elements. Discovery that the hydrogen nucleus is present in other nuclei as an elementary particle led Rutherford to give the hydrogen nucleus H+ a special name as a particle, since he suspected that hydrogen, the lightest element, contained only one of these particles. He named this new fundamental building block of the nucleus the proton, after the neuter singular of the Greek word for "first", πρῶτον. However, Rutherford also had in mind the word protyle as used by Prout. Rutherford spoke at the British Association for the Advancement of Science at its Cardiff meeting beginning 24 August 1920.[23] At the meeting, he was asked by Oliver Lodge for a new name for the positive hydrogen nucleus to avoid confusion with the neutral hydrogen atom. He initially suggested both proton and prouton (after Prout).[24] Rutherford later reported that the meeting had accepted his suggestion that the hydrogen nucleus be named the "proton", following Prout's word "protyle".[25] The first use of the word "proton" in the scientific literature appeared in 1920.[26][27]

Stability

Unsolved problem in physics:

Are protons fundamentally stable? Or do they decay with a finite lifetime as predicted by some extensions to the standard model?

The free proton (a proton not bound to nucleons or electrons) is a stable particle that has not been observed to break down spontaneously to other particles. Free protons are found naturally in a number of situations in which energies or temperatures are high enough to separate them from electrons, for which they have some affinity. Free protons exist in plasmas in which temperatures are too high to allow them to combine with electrons. Free protons of high energy and velocity make up 90% of cosmic rays, which propagate in vacuum for interstellar distances. Free protons are emitted directly from atomic nuclei in some rare types of radioactive decay. Protons also result (along with electrons and antineutrinos) from the radioactive decay of free neutrons, which are unstable.

The spontaneous decay of free protons has never been observed, and protons are therefore considered stable particles according to the Standard Model. However, some grand unified theories (GUTs) of particle physics predict that proton decay should take place with lifetimes between 1031 to 1036 years and experimental searches have established lower bounds on the mean lifetime of a proton for various assumed decay products.[28][29][30]

Experiments at the Super-Kamiokande detector in Japan gave lower limits for proton mean lifetime of 6.6×1033 years for decay to an antimuon and a neutral pion, and 8.2×1033 years for decay to a positron and a neutral pion.[31] Another experiment at the Sudbury Neutrino Observatory in Canada searched for gamma rays resulting from residual nuclei resulting from the decay of a proton from oxygen-16. This experiment was designed to detect decay to any product, and established a lower limit to a proton lifetime of 2.1×1029 years.[32]

However, protons are known to transform into neutrons through the process of electron capture (also called inverse beta decay). For free protons, this process does not occur spontaneously but only when energy is supplied. The equation is:


p+
+
e

n
+
ν
e

The process is reversible; neutrons can convert back to protons through beta decay, a common form of radioactive decay. In fact, a free neutron decays this way, with a mean lifetime of about 15 minutes. A proton can also transform into neutrons through beta plus decay (β+ decay).

According to quantum field theory, the mean proper lifetime of protons   becomes finite when they are accelerating with proper acceleration  , and   decreases with increasing  . Acceleration gives rise to a non-vanishing probability for the transition
p+

n
+
e+
+
ν
e
. This was a matter of concern in the later 1990s because   is a scalar that can be measured by the inertial and coaccelerated observers. In the inertial frame, the accelerating proton should decay according to the formula above. However, according to the coaccelerated observer the proton is at rest and hence should not decay. This puzzle is solved by realizing that in the coaccelerated frame there is a thermal bath due to Fulling–Davies–Unruh effect, an intrinsic effect of quantum field theory. In this thermal bath, experienced by the proton, there are electrons and antineutrinos with which the proton may interact according to the processes: (i)
p+
+
e

n
+
ν
, (ii)
p+
+
ν

n
+
e+
and (iii)
p+
+
e
+
ν

n
. Adding the contributions of each of these processes, one should obtain  .[33][34][35][36]

Quarks and the mass of a proton

In quantum chromodynamics, the modern theory of the nuclear force, most of the mass of protons and neutrons is explained by special relativity. The mass of a proton is about 80–100 times greater than the sum of the rest masses of its three valence quarks, while the gluons have zero rest mass. The extra energy of the quarks and gluons in a proton, as compared to the rest energy of the quarks alone in the QCD vacuum, accounts for almost 99% of the proton's mass. The rest mass of a proton is, thus, the invariant mass of the system of moving quarks and gluons that make up the particle, and, in such systems, even the energy of massless particles confined to a system is still measured as part of the rest mass of the system.

Two terms are used in referring to the mass of the quarks that make up protons: current quark mass refers to the mass of a quark by itself, while constituent quark mass refers to the current quark mass plus the mass of the gluon particle field surrounding the quark.[37]: 285–286  [38]: 150–151  These masses typically have very different values. The kinetic energy of the quarks that is a consequence of confinement is a contribution (see Mass in special relativity). Using lattice QCD calculations, the contributions to the mass of the proton are the quark condensate (~9%, comprising the up and down quarks and a sea of virtual strange quarks), the quark kinetic energy (~32%), the gluon kinetic energy (~37%), and the anomalous gluonic contribution (~23%, comprising contributions from condensates of all quark flavors).[39]

The constituent quark model wavefunction for the proton is

 

The internal dynamics of protons are complicated, because they are determined by the quarks' exchanging gluons, and interacting with various vacuum condensates. Lattice QCD provides a way of calculating the mass of a proton directly from the theory to any accuracy, in principle. The most recent calculations[40][41] claim that the mass is determined to better than 4% accuracy, even to 1% accuracy (see Figure S5 in Dürr et al.[41]). These claims are still controversial, because the calculations cannot yet be done with quarks as light as they are in the real world. This means that the predictions are found by a process of extrapolation, which can introduce systematic errors.[42] It is hard to tell whether these errors are controlled properly, because the quantities that are compared to experiment are the masses of the hadrons, which are known in advance.

These recent calculations are performed by massive supercomputers, and, as noted by Boffi and Pasquini: "a detailed description of the nucleon structure is still missing because ... long-distance behavior requires a nonperturbative and/or numerical treatment ..."[43] More conceptual approaches to the structure of protons are: the topological soliton approach originally due to Tony Skyrme and the more accurate AdS/QCD approach that extends it to include a string theory of gluons,[44] various QCD-inspired models like the bag model and the constituent quark model, which were popular in the 1980s, and the SVZ sum rules, which allow for rough approximate mass calculations.[45] These methods do not have the same accuracy as the more brute-force lattice QCD methods, at least not yet.

Charge radius

The problem of defining a radius for an atomic nucleus (proton) is similar to the problem of atomic radius, in that neither atoms nor their nuclei have definite boundaries. However, the nucleus can be modeled as a sphere of positive charge for the interpretation of electron scattering experiments: because there is no definite boundary to the nucleus, the electrons "see" a range of cross-sections, for which a mean can be taken. The qualification of "rms" (for "root mean square") arises because it is the nuclear cross-section, proportional to the square of the radius, which is determining for electron scattering.[dubious ]

The internationally accepted value of a proton's charge radius is 0.8768 fm. This value is based on measurements involving a proton and an electron (namely, electron scattering measurements and complex calculation involving scattering cross section based on Rosenbluth equation for momentum-transfer cross section), and studies of the atomic energy levels of hydrogen and deuterium.

However, in 2010 an international research team published a proton charge radius measurement via the Lamb shift in muonic hydrogen (an exotic atom made of a proton and a negatively charged muon). As a muon is 200 times heavier than an electron, its de Broglie wavelength is correspondingly shorter. This smaller atomic orbital is much more sensitive to the proton's charge radius, so allows more precise measurement. Their measurement of the root-mean-square charge radius of a proton is "0.84184(67) fm, which differs by 5.0 standard deviations from the CODATA value of 0.8768(69) fm".[46] In January 2013, an updated value for the charge radius of a proton—0.84087(39) fm—was published. The precision was improved by 1.7 times, increasing the significance of the discrepancy to 7σ.[12] The 2014 CODATA adjustment slightly reduced the recommended value for the proton radius (computed using electron measurements only) to 0.8751(61) fm, but this leaves the discrepancy at 5.6σ.

If no errors were found in the measurements or calculations, it would have been necessary to re-examine the world's most precise and best-tested fundamental theory: quantum electrodynamics.[47] The proton radius was a puzzle as of 2017.[48][49]

A resolution came in 2019, when two different studies, using different techniques involving the Lamb shift of the electron in hydrogen, and electron–proton scattering, found the radius of the proton to be 0.833 fm, with an uncertainty of ±0.010 fm, and 0.831 fm.[13][14]

The radius of the proton is linked to the form factor and momentum-transfer cross section. The atomic form factor G modifies the cross section corresponding to point-like proton.

 

The atomic form factor is related to the wave function density of the target:

 

The form factor can be split in electric and magnetic form factors. These can be further written as linear combinations of Dirac and Pauli form factors.[49]

 

Pressure inside the proton

Since the proton is composed of quarks confined by gluons, an equivalent pressure that acts on the quarks can be defined. This allows calculation of their distribution as a function of distance from the centre using Compton scattering of high-energy electrons (DVCS, for deeply virtual Compton scattering). The pressure is maximum at the centre, about 1035 Pa, which is greater than the pressure inside a neutron star.[50] It is positive (repulsive) to a radial distance of about 0.6 fm, negative (attractive) at greater distances, and very weak beyond about 2 fm.

Charge radius in solvated proton, hydronium

The radius of the hydrated proton appears in the Born equation for calculating the hydration enthalpy of hydronium.

Interaction of free protons with ordinary matter

Although protons have affinity for oppositely charged electrons, this is a relatively low-energy interaction and so free protons must lose sufficient velocity (and kinetic energy) in order to become closely associated and bound to electrons. High energy protons, in traversing ordinary matter, lose energy by collisions with atomic nuclei, and by ionization of atoms (removing electrons) until they are slowed sufficiently to be captured by the electron cloud in a normal atom.

However, in such an association with an electron, the character of the bound proton is not changed, and it remains a proton. The attraction of low-energy free protons to any electrons present in normal matter (such as the electrons in normal atoms) causes free protons to stop and to form a new chemical bond with an atom. Such a bond happens at any sufficiently "cold" temperature (that is, comparable to temperatures at the surface of the Sun) and with any type of atom. Thus, in interaction with any type of normal (non-plasma) matter, low-velocity free protons do not remain free but are attracted to electrons in any atom or molecule with which they come into contact, causing the proton and molecule to combine. Such molecules are then said to be "protonated", and chemically they are simply compounds of hydrogen, often positively charged. Often, as a result, they become so-called Brønsted acids. For example, a proton captured by a water molecule in water becomes hydronium, the aqueous cation H3O+.

Proton in chemistry

Atomic number

In chemistry, the number of protons in the nucleus of an atom is known as the atomic number, which determines the chemical element to which the atom belongs. For example, the atomic number of chlorine is 17; this means that each chlorine atom has 17 protons and that all atoms with 17 protons are chlorine atoms. The chemical properties of each atom are determined by the number of (negatively charged) electrons, which for neutral atoms is equal to the number of (positive) protons so that the total charge is zero. For example, a neutral chlorine atom has 17 protons and 17 electrons, whereas a Cl anion has 17 protons and 18 electrons for a total charge of −1.

All atoms of a given element are not necessarily identical, however. The number of neutrons may vary to form different isotopes, and energy levels may differ, resulting in different nuclear isomers. For example, there are two stable isotopes of chlorine: 35
17
Cl
with 35 − 17 = 18 neutrons and 37
17
Cl
with 37 − 17 = 20 neutrons.

Hydrogen ion

 
Protium, the most common isotope of hydrogen, consists of one proton and one electron (it has no neutrons). The term "hydrogen ion" (H+
) implies that that H-atom has lost its one electron, causing only a proton to remain. Thus, in chemistry, the terms "proton" and "hydrogen ion" (for the protium isotope) are used synonymously

The proton is a unique chemical species, being a bare nucleus. As a consequence it has no independent existence in the condensed state and is invariably found bound by a pair of electrons to another atom.

Ross Stewart, The Proton: Application to Organic Chemistry (1985, p. 1)

In chemistry, the term proton refers to the hydrogen ion, H+
. Since the atomic number of hydrogen is 1, a hydrogen ion has no electrons and corresponds to a bare nucleus, consisting of a proton (and 0 neutrons for the most abundant isotope protium 1
1
H
). The proton is a "bare charge" with only about 1/64,000 of the radius of a hydrogen atom, and so is extremely reactive chemically. The free proton, thus, has an extremely short lifetime in chemical systems such as liquids and it reacts immediately with the electron cloud of any available molecule. In aqueous solution, it forms the hydronium ion, H3O+, which in turn is further solvated by water molecules in clusters such as [H5O2]+ and [H9O4]+.[51]

The transfer of H+
in an acid–base reaction is usually referred to as "proton transfer". The acid is referred to as a proton donor and the base as a proton acceptor. Likewise, biochemical terms such as proton pump and proton channel refer to the movement of hydrated H+
ions.

The ion produced by removing the electron from a deuterium atom is known as a deuteron, not a proton. Likewise, removing an electron from a tritium atom produces a triton.

Proton nuclear magnetic resonance (NMR)

Also in chemistry, the term "proton NMR" refers to the observation of hydrogen-1 nuclei in (mostly organic) molecules by nuclear magnetic resonance. This method uses the quantized spin magnetic moment of the proton, which is due to its angular momentum (or spin), which in turn has a magnitude of one-half the reduced Planck constant. ( ). The name refers to examination of protons as they occur in protium (hydrogen-1 atoms) in compounds, and does not imply that free protons exist in the compound being studied.

Human exposure

The Apollo Lunar Surface Experiments Packages (ALSEP) determined that more than 95% of the particles in the solar wind are electrons and protons, in approximately equal numbers.[52][53]

Because the Solar Wind Spectrometer made continuous measurements, it was possible to measure how the Earth's magnetic field affects arriving solar wind particles. For about two-thirds of each orbit, the Moon is outside of the Earth's magnetic field. At these times, a typical proton density was 10 to 20 per cubic centimeter, with most protons having velocities between 400 and 650 kilometers per second. For about five days of each month, the Moon is inside the Earth's geomagnetic tail, and typically no solar wind particles were detectable. For the remainder of each lunar orbit, the Moon is in a transitional region known as the magnetosheath, where the Earth's magnetic field affects the solar wind, but does not completely exclude it. In this region, the particle flux is reduced, with typical proton velocities of 250 to 450 kilometers per second. During the lunar night, the spectrometer was shielded from the solar wind by the Moon and no solar wind particles were measured.[52]

Protons also have extrasolar origin from galactic cosmic rays, where they make up about 90% of the total particle flux. These protons often have higher energy than solar wind protons, and their intensity is far more uniform and less variable than protons coming from the Sun, the production of which is heavily affected by solar proton events such as coronal mass ejections.

Research has been performed on the dose-rate effects of protons, as typically found in space travel, on human health.[53][54] To be more specific, there are hopes to identify what specific chromosomes are damaged, and to define the damage, during cancer development from proton exposure.[53] Another study looks into determining "the effects of exposure to proton irradiation on neurochemical and behavioral endpoints, including dopaminergic functioning, amphetamine-induced conditioned taste aversion learning, and spatial learning and memory as measured by the Morris water maze.[54] Electrical charging of a spacecraft due to interplanetary proton bombardment has also been proposed for study.[55] There are many more studies that pertain to space travel, including galactic cosmic rays and their possible health effects, and solar proton event exposure.

The American Biostack and Soviet Biorack space travel experiments have demonstrated the severity of molecular damage induced by heavy ions on microorganisms including Artemia cysts.[56]

Antiproton

CPT-symmetry puts strong constraints on the relative properties of particles and antiparticles and, therefore, is open to stringent tests. For example, the charges of a proton and antiproton must sum to exactly zero. This equality has been tested to one part in 108. The equality of their masses has also been tested to better than one part in 108. By holding antiprotons in a Penning trap, the equality of the charge-to-mass ratio of protons and antiprotons has been tested to one part in 6×109.[57] The magnetic moment of antiprotons has been measured with an error of 8×10−3 nuclear Bohr magnetons, and is found to be equal and opposite to that of a proton.[58]

See also

References

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Further reading

  • Ball, Richard D.; Candido, Alessandro; Cruz-Martinez, Juan; Forte, Stefano; Giani, Tommaso; Hekhorn, Felix; Kudashkin, Kirill; Magni, Giacomo; Rojo, Juan (August 2022). "Evidence for intrinsic charm quarks in the proton". Nature. 608 (7923): 483–487. arXiv:2208.08372. Bibcode:2022Natur.608..483N. doi:10.1038/s41586-022-04998-2. ISSN 1476-4687. PMC 9385499. PMID 35978125.

External links

  •   Media related to Protons at Wikimedia Commons
  • Particle Data Group at LBL
  • Large Hadron Collider
  • Eaves, Laurence; Copeland, Ed; Padilla, Antonio (Tony) (2010). "The shrinking proton". Sixty Symbols. Brady Haran for the University of Nottingham.
  • Inside the Proton, the ‘Most Complicated Thing You Could Possibly Imagine’, Quanta Magazine, Oct 19 2022

proton, other, uses, disambiguation, redirects, here, record, label, jean, dawson, proton, stable, subatomic, particle, symbol, with, positive, electric, charge, elementary, charge, mass, slightly, less, than, that, neutron, times, mass, electron, proton, elec. For other uses see Proton disambiguation P redirects here For the record label see Jean Dawson A proton is a stable subatomic particle symbol p H or 1H with a positive electric charge of 1 e elementary charge Its mass is slightly less than that of a neutron and 1 836 times the mass of an electron the proton electron mass ratio Protons and neutrons each with masses of approximately one atomic mass unit are jointly referred to as nucleons particles present in atomic nuclei ProtonThe quark content of a proton The color assignment of individual quarks is arbitrary but all three colors must be present Forces between quarks are mediated by gluons ClassificationBaryonComposition2 up quarks u 1 down quark d StatisticsFermionicFamilyHadronInteractionsGravity electromagnetic weak strongSymbolp p N 11 H AntiparticleAntiprotonTheorizedWilliam Prout 1815 DiscoveredObserved as H by Eugen Goldstein 1886 Identified in other nuclei and named by Ernest Rutherford 1917 1920 Mass1 672621 923 69 51 10 27 kg 1 1 007276 466 621 53 Da 2 938 272088 16 29 MeV c2 3 Mean lifetime gt 3 6 1029 years 4 stable Electric charge 1 eCharge radius0 8414 19 fm 5 Electric dipole moment lt 2 1 10 25 e cm 6 Electric polarizability0 00112 4 fm3Magnetic moment1 410606 797 36 60 10 26 J T 1 7 1 521032 202 30 46 10 3 mB 5 2 792847 344 63 82 mN 8 Magnetic polarizability1 9 5 10 4 fm3Spin1 2Isospin1 2Parity 1CondensedI JP 1 2 1 2 One or more protons are present in the nucleus of every atom They provide the attractive electrostatic central force that binds the atomic electrons The number of protons in the nucleus is the defining property of an element and is referred to as the atomic number represented by the symbol Z Since each element has a unique number of protons each element has its own unique atomic number which determines the number of atomic electrons and consequently the chemical characteristics of the element The word proton is Greek for first and this name was given to the hydrogen nucleus by Ernest Rutherford in 1920 In previous years Rutherford had discovered that the hydrogen nucleus known to be the lightest nucleus could be extracted from the nuclei of nitrogen by atomic collisions 9 Protons were therefore a candidate to be a fundamental or elementary particle and hence a building block of nitrogen and all other heavier atomic nuclei Although protons were originally considered to be elementary particles in the modern Standard Model of particle physics protons are now known to be composite particles containing three valence quarks and together with neutrons are now classified as hadrons Protons are composed of two up quarks of charge 2 3 e and one down quark of charge 1 3 e The rest masses of quarks contribute only about 1 of a proton s mass 10 The remainder of a proton s mass is due to quantum chromodynamics binding energy which includes the kinetic energy of the quarks and the energy of the gluon fields that bind the quarks together Because protons are not fundamental particles they possess a measurable size the root mean square charge radius of a proton is about 0 84 0 87 fm 1 fm 10 15 m 11 12 In 2019 two different studies using different techniques found this radius to be 0 833 fm with an uncertainty of 0 010 fm 13 14 Free protons occur occasionally on Earth thunderstorms can produce protons with energies of up to several tens of MeV 15 16 At sufficiently low temperatures and kinetic energies free protons will bind to electrons However the character of such bound protons does not change and they remain protons A fast proton moving through matter will slow by interactions with electrons and nuclei until it is captured by the electron cloud of an atom The result is a protonated atom which is a chemical compound of hydrogen In a vacuum when free electrons are present a sufficiently slow proton may pick up a single free electron becoming a neutral hydrogen atom which is chemically a free radical Such free hydrogen atoms tend to react chemically with many other types of atoms at sufficiently low energies When free hydrogen atoms react with each other they form neutral hydrogen molecules H2 which are the most common molecular component of molecular clouds in interstellar space Free protons are routinely used for accelerators for proton therapy or various particle physics experiments with the most powerful example being the Large Hadron Collider Contents 1 Description 2 History 3 Stability 4 Quarks and the mass of a proton 5 Charge radius 5 1 Pressure inside the proton 5 2 Charge radius in solvated proton hydronium 6 Interaction of free protons with ordinary matter 7 Proton in chemistry 7 1 Atomic number 7 2 Hydrogen ion 7 3 Proton nuclear magnetic resonance NMR 8 Human exposure 9 Antiproton 10 See also 11 References 12 Further reading 13 External linksDescription EditUnsolved problem in physics How do the quarks and gluons carry the spin of protons more unsolved problems in physics Protons are spin 1 2 fermions and are composed of three valence quarks 17 making them baryons a sub type of hadrons The two up quarks and one down quark of a proton are held together by the strong force mediated by gluons 18 21 22 A modern perspective has a proton composed of the valence quarks up up down the gluons and transitory pairs of sea quarks Protons have a positive charge distribution which decays approximately exponentially with a root mean square charge radius of about 0 8 fm 19 Protons and neutrons are both nucleons which may be bound together by the nuclear force to form atomic nuclei The nucleus of the most common isotope of the hydrogen atom with the chemical symbol H is a lone proton The nuclei of the heavy hydrogen isotopes deuterium and tritium contain one proton bound to one and two neutrons respectively All other types of atomic nuclei are composed of two or more protons and various numbers of neutrons History EditThe concept of a hydrogen like particle as a constituent of other atoms was developed over a long period As early as 1815 William Prout proposed that all atoms are composed of hydrogen atoms which he called protyles based on a simplistic interpretation of early values of atomic weights see Prout s hypothesis which was disproved when more accurate values were measured 20 39 42 Ernest Rutherford at the first Solvay Conference 1911 Proton detected in an isopropanol cloud chamber In 1886 Eugen Goldstein discovered canal rays also known as anode rays and showed that they were positively charged particles ions produced from gases However since particles from different gases had different values of charge to mass ratio q m they could not be identified with a single particle unlike the negative electrons discovered by J J Thomson Wilhelm Wien in 1898 identified the hydrogen ion as the particle with the highest charge to mass ratio in ionized gases 21 Following the discovery of the atomic nucleus by Ernest Rutherford in 1911 Antonius van den Broek proposed that the place of each element in the periodic table its atomic number is equal to its nuclear charge This was confirmed experimentally by Henry Moseley in 1913 using X ray spectra In 1917 in experiments reported in 1919 and 1925 Rutherford proved that the hydrogen nucleus is present in other nuclei a result usually described as the discovery of protons 22 These experiments began after Rutherford had noticed that when alpha particles were shot into air mostly nitrogen his scintillation detectors showed the signatures of typical hydrogen nuclei as a product After experimentation Rutherford traced the reaction to the nitrogen in air and found that when alpha particles were introduced into pure nitrogen gas the effect was larger In 1919 Rutherford assumed that the alpha particle merely knocked a proton out of nitrogen turning it into carbon After observing Blackett s cloud chamber images in 1925 Rutherford realized that the alpha particle was absorbed After capture of the alpha particle a hydrogen nucleus is ejected so that heavy oxygen not carbon is the result i e the atomic number Z of the nucleus is increased rather than reduced This was the first reported nuclear reaction 14N a 17O p Rutherford at first thought of our modern p in this equation as a hydrogen ion H Depending on one s perspective either 1919 when it was seen experimentally as derived from another source than hydrogen or 1920 when it was recognized and proposed as an elementary particle may be regarded as the moment when the proton was discovered Rutherford knew hydrogen to be the simplest and lightest element and was influenced by Prout s hypothesis that hydrogen was the building block of all elements Discovery that the hydrogen nucleus is present in other nuclei as an elementary particle led Rutherford to give the hydrogen nucleus H a special name as a particle since he suspected that hydrogen the lightest element contained only one of these particles He named this new fundamental building block of the nucleus the proton after the neuter singular of the Greek word for first prῶton However Rutherford also had in mind the word protyle as used by Prout Rutherford spoke at the British Association for the Advancement of Science at its Cardiff meeting beginning 24 August 1920 23 At the meeting he was asked by Oliver Lodge for a new name for the positive hydrogen nucleus to avoid confusion with the neutral hydrogen atom He initially suggested both proton and prouton after Prout 24 Rutherford later reported that the meeting had accepted his suggestion that the hydrogen nucleus be named the proton following Prout s word protyle 25 The first use of the word proton in the scientific literature appeared in 1920 26 27 Stability EditMain article Proton decay Unsolved problem in physics Are protons fundamentally stable Or do they decay with a finite lifetime as predicted by some extensions to the standard model more unsolved problems in physics The free proton a proton not bound to nucleons or electrons is a stable particle that has not been observed to break down spontaneously to other particles Free protons are found naturally in a number of situations in which energies or temperatures are high enough to separate them from electrons for which they have some affinity Free protons exist in plasmas in which temperatures are too high to allow them to combine with electrons Free protons of high energy and velocity make up 90 of cosmic rays which propagate in vacuum for interstellar distances Free protons are emitted directly from atomic nuclei in some rare types of radioactive decay Protons also result along with electrons and antineutrinos from the radioactive decay of free neutrons which are unstable The spontaneous decay of free protons has never been observed and protons are therefore considered stable particles according to the Standard Model However some grand unified theories GUTs of particle physics predict that proton decay should take place with lifetimes between 1031 to 1036 years and experimental searches have established lower bounds on the mean lifetime of a proton for various assumed decay products 28 29 30 Experiments at the Super Kamiokande detector in Japan gave lower limits for proton mean lifetime of 6 6 1033 years for decay to an antimuon and a neutral pion and 8 2 1033 years for decay to a positron and a neutral pion 31 Another experiment at the Sudbury Neutrino Observatory in Canada searched for gamma rays resulting from residual nuclei resulting from the decay of a proton from oxygen 16 This experiment was designed to detect decay to any product and established a lower limit to a proton lifetime of 2 1 1029 years 32 However protons are known to transform into neutrons through the process of electron capture also called inverse beta decay For free protons this process does not occur spontaneously but only when energy is supplied The equation is p e n neThe process is reversible neutrons can convert back to protons through beta decay a common form of radioactive decay In fact a free neutron decays this way with a mean lifetime of about 15 minutes A proton can also transform into neutrons through beta plus decay b decay According to quantum field theory the mean proper lifetime of protons t p displaystyle tau mathrm p becomes finite when they are accelerating with proper acceleration a displaystyle a and t p displaystyle tau mathrm p decreases with increasing a displaystyle a Acceleration gives rise to a non vanishing probability for the transition p n e ne This was a matter of concern in the later 1990s because t p displaystyle tau mathrm p is a scalar that can be measured by the inertial and coaccelerated observers In the inertial frame the accelerating proton should decay according to the formula above However according to the coaccelerated observer the proton is at rest and hence should not decay This puzzle is solved by realizing that in the coaccelerated frame there is a thermal bath due to Fulling Davies Unruh effect an intrinsic effect of quantum field theory In this thermal bath experienced by the proton there are electrons and antineutrinos with which the proton may interact according to the processes i p e n n ii p n n e and iii p e n n Adding the contributions of each of these processes one should obtain t p displaystyle tau mathrm p 33 34 35 36 Quarks and the mass of a proton EditIn quantum chromodynamics the modern theory of the nuclear force most of the mass of protons and neutrons is explained by special relativity The mass of a proton is about 80 100 times greater than the sum of the rest masses of its three valence quarks while the gluons have zero rest mass The extra energy of the quarks and gluons in a proton as compared to the rest energy of the quarks alone in the QCD vacuum accounts for almost 99 of the proton s mass The rest mass of a proton is thus the invariant mass of the system of moving quarks and gluons that make up the particle and in such systems even the energy of massless particles confined to a system is still measured as part of the rest mass of the system Two terms are used in referring to the mass of the quarks that make up protons current quark mass refers to the mass of a quark by itself while constituent quark mass refers to the current quark mass plus the mass of the gluon particle field surrounding the quark 37 285 286 38 150 151 These masses typically have very different values The kinetic energy of the quarks that is a consequence of confinement is a contribution see Mass in special relativity Using lattice QCD calculations the contributions to the mass of the proton are the quark condensate 9 comprising the up and down quarks and a sea of virtual strange quarks the quark kinetic energy 32 the gluon kinetic energy 37 and the anomalous gluonic contribution 23 comprising contributions from condensates of all quark flavors 39 The constituent quark model wavefunction for the proton is p 1 18 2 u d u 2 u u d 2 d u u u u d u d u u d u d u u d u u u u d displaystyle mathrm p uparrow rangle tfrac 1 sqrt 18 left 2 u uparrow d downarrow u uparrow rangle 2 u uparrow u uparrow d downarrow rangle 2 d downarrow u uparrow u uparrow rangle u uparrow u downarrow d uparrow rangle u uparrow d uparrow u downarrow rangle u downarrow d uparrow u uparrow rangle d uparrow u downarrow u uparrow rangle d uparrow u uparrow u downarrow rangle u downarrow u uparrow d uparrow rangle right The internal dynamics of protons are complicated because they are determined by the quarks exchanging gluons and interacting with various vacuum condensates Lattice QCD provides a way of calculating the mass of a proton directly from the theory to any accuracy in principle The most recent calculations 40 41 claim that the mass is determined to better than 4 accuracy even to 1 accuracy see Figure S5 in Durr et al 41 These claims are still controversial because the calculations cannot yet be done with quarks as light as they are in the real world This means that the predictions are found by a process of extrapolation which can introduce systematic errors 42 It is hard to tell whether these errors are controlled properly because the quantities that are compared to experiment are the masses of the hadrons which are known in advance These recent calculations are performed by massive supercomputers and as noted by Boffi and Pasquini a detailed description of the nucleon structure is still missing because long distance behavior requires a nonperturbative and or numerical treatment 43 More conceptual approaches to the structure of protons are the topological soliton approach originally due to Tony Skyrme and the more accurate AdS QCD approach that extends it to include a string theory of gluons 44 various QCD inspired models like the bag model and the constituent quark model which were popular in the 1980s and the SVZ sum rules which allow for rough approximate mass calculations 45 These methods do not have the same accuracy as the more brute force lattice QCD methods at least not yet Charge radius EditMain article Proton radius puzzle The problem of defining a radius for an atomic nucleus proton is similar to the problem of atomic radius in that neither atoms nor their nuclei have definite boundaries However the nucleus can be modeled as a sphere of positive charge for the interpretation of electron scattering experiments because there is no definite boundary to the nucleus the electrons see a range of cross sections for which a mean can be taken The qualification of rms for root mean square arises because it is the nuclear cross section proportional to the square of the radius which is determining for electron scattering dubious discuss The internationally accepted value of a proton s charge radius is 0 8768 fm This value is based on measurements involving a proton and an electron namely electron scattering measurements and complex calculation involving scattering cross section based on Rosenbluth equation for momentum transfer cross section and studies of the atomic energy levels of hydrogen and deuterium However in 2010 an international research team published a proton charge radius measurement via the Lamb shift in muonic hydrogen an exotic atom made of a proton and a negatively charged muon As a muon is 200 times heavier than an electron its de Broglie wavelength is correspondingly shorter This smaller atomic orbital is much more sensitive to the proton s charge radius so allows more precise measurement Their measurement of the root mean square charge radius of a proton is 0 84184 67 fm which differs by 5 0 standard deviations from the CODATA value of 0 8768 69 fm 46 In January 2013 an updated value for the charge radius of a proton 0 84087 39 fm was published The precision was improved by 1 7 times increasing the significance of the discrepancy to 7s 12 The 2014 CODATA adjustment slightly reduced the recommended value for the proton radius computed using electron measurements only to 0 8751 61 fm but this leaves the discrepancy at 5 6s If no errors were found in the measurements or calculations it would have been necessary to re examine the world s most precise and best tested fundamental theory quantum electrodynamics 47 The proton radius was a puzzle as of 2017 48 49 A resolution came in 2019 when two different studies using different techniques involving the Lamb shift of the electron in hydrogen and electron proton scattering found the radius of the proton to be 0 833 fm with an uncertainty of 0 010 fm and 0 831 fm 13 14 The radius of the proton is linked to the form factor and momentum transfer cross section The atomic form factor G modifies the cross section corresponding to point like proton R e 2 6 d G e d q 2 q 2 0 d s d W d s d W point G 2 q 2 displaystyle begin aligned R text e 2 amp 6 frac dG text e dq 2 Bigg vert q 2 0 frac d sigma d Omega amp frac d sigma d Omega Bigg vert text point G 2 q 2 end aligned The atomic form factor is related to the wave function density of the target G q 2 e i q r ps r 2 d r 3 displaystyle G q 2 int e iqr psi r 2 dr 3 The form factor can be split in electric and magnetic form factors These can be further written as linear combinations of Dirac and Pauli form factors 49 G m F D F P G e F D t F P d s d W d s d W N S 1 1 t G e 2 q 2 t ϵ G m 2 q 2 displaystyle begin aligned G text m amp F text D F text P G text e amp F text D tau F text P frac d sigma d Omega amp frac d sigma d Omega Bigg vert NS frac 1 1 tau left G text e 2 left q 2 right frac tau epsilon G text m 2 left q 2 right right end aligned Pressure inside the proton Edit Since the proton is composed of quarks confined by gluons an equivalent pressure that acts on the quarks can be defined This allows calculation of their distribution as a function of distance from the centre using Compton scattering of high energy electrons DVCS for deeply virtual Compton scattering The pressure is maximum at the centre about 1035 Pa which is greater than the pressure inside a neutron star 50 It is positive repulsive to a radial distance of about 0 6 fm negative attractive at greater distances and very weak beyond about 2 fm Charge radius in solvated proton hydronium Edit The radius of the hydrated proton appears in the Born equation for calculating the hydration enthalpy of hydronium Interaction of free protons with ordinary matter EditAlthough protons have affinity for oppositely charged electrons this is a relatively low energy interaction and so free protons must lose sufficient velocity and kinetic energy in order to become closely associated and bound to electrons High energy protons in traversing ordinary matter lose energy by collisions with atomic nuclei and by ionization of atoms removing electrons until they are slowed sufficiently to be captured by the electron cloud in a normal atom However in such an association with an electron the character of the bound proton is not changed and it remains a proton The attraction of low energy free protons to any electrons present in normal matter such as the electrons in normal atoms causes free protons to stop and to form a new chemical bond with an atom Such a bond happens at any sufficiently cold temperature that is comparable to temperatures at the surface of the Sun and with any type of atom Thus in interaction with any type of normal non plasma matter low velocity free protons do not remain free but are attracted to electrons in any atom or molecule with which they come into contact causing the proton and molecule to combine Such molecules are then said to be protonated and chemically they are simply compounds of hydrogen often positively charged Often as a result they become so called Bronsted acids For example a proton captured by a water molecule in water becomes hydronium the aqueous cation H3O Proton in chemistry EditAtomic number Edit In chemistry the number of protons in the nucleus of an atom is known as the atomic number which determines the chemical element to which the atom belongs For example the atomic number of chlorine is 17 this means that each chlorine atom has 17 protons and that all atoms with 17 protons are chlorine atoms The chemical properties of each atom are determined by the number of negatively charged electrons which for neutral atoms is equal to the number of positive protons so that the total charge is zero For example a neutral chlorine atom has 17 protons and 17 electrons whereas a Cl anion has 17 protons and 18 electrons for a total charge of 1 All atoms of a given element are not necessarily identical however The number of neutrons may vary to form different isotopes and energy levels may differ resulting in different nuclear isomers For example there are two stable isotopes of chlorine 3517 Cl with 35 17 18 neutrons and 3717 Cl with 37 17 20 neutrons Hydrogen ion Edit See also Hydron chemistry Protium the most common isotope of hydrogen consists of one proton and one electron it has no neutrons The term hydrogen ion H implies that that H atom has lost its one electron causing only a proton to remain Thus in chemistry the terms proton and hydrogen ion for the protium isotope are used synonymously The proton is a unique chemical species being a bare nucleus As a consequence it has no independent existence in the condensed state and is invariably found bound by a pair of electrons to another atom Ross Stewart The Proton Application to Organic Chemistry 1985 p 1 In chemistry the term proton refers to the hydrogen ion H Since the atomic number of hydrogen is 1 a hydrogen ion has no electrons and corresponds to a bare nucleus consisting of a proton and 0 neutrons for the most abundant isotope protium 11 H The proton is a bare charge with only about 1 64 000 of the radius of a hydrogen atom and so is extremely reactive chemically The free proton thus has an extremely short lifetime in chemical systems such as liquids and it reacts immediately with the electron cloud of any available molecule In aqueous solution it forms the hydronium ion H3O which in turn is further solvated by water molecules in clusters such as H5O2 and H9O4 51 The transfer of H in an acid base reaction is usually referred to as proton transfer The acid is referred to as a proton donor and the base as a proton acceptor Likewise biochemical terms such as proton pump and proton channel refer to the movement of hydrated H ions The ion produced by removing the electron from a deuterium atom is known as a deuteron not a proton Likewise removing an electron from a tritium atom produces a triton Proton nuclear magnetic resonance NMR Edit Also in chemistry the term proton NMR refers to the observation of hydrogen 1 nuclei in mostly organic molecules by nuclear magnetic resonance This method uses the quantized spin magnetic moment of the proton which is due to its angular momentum or spin which in turn has a magnitude of one half the reduced Planck constant ℏ 2 displaystyle hbar 2 The name refers to examination of protons as they occur in protium hydrogen 1 atoms in compounds and does not imply that free protons exist in the compound being studied Human exposure EditMain article Effect of spaceflight on the body See also Proton therapy The Apollo Lunar Surface Experiments Packages ALSEP determined that more than 95 of the particles in the solar wind are electrons and protons in approximately equal numbers 52 53 Because the Solar Wind Spectrometer made continuous measurements it was possible to measure how the Earth s magnetic field affects arriving solar wind particles For about two thirds of each orbit the Moon is outside of the Earth s magnetic field At these times a typical proton density was 10 to 20 per cubic centimeter with most protons having velocities between 400 and 650 kilometers per second For about five days of each month the Moon is inside the Earth s geomagnetic tail and typically no solar wind particles were detectable For the remainder of each lunar orbit the Moon is in a transitional region known as the magnetosheath where the Earth s magnetic field affects the solar wind but does not completely exclude it In this region the particle flux is reduced with typical proton velocities of 250 to 450 kilometers per second During the lunar night the spectrometer was shielded from the solar wind by the Moon and no solar wind particles were measured 52 Protons also have extrasolar origin from galactic cosmic rays where they make up about 90 of the total particle flux These protons often have higher energy than solar wind protons and their intensity is far more uniform and less variable than protons coming from the Sun the production of which is heavily affected by solar proton events such as coronal mass ejections Research has been performed on the dose rate effects of protons as typically found in space travel on human health 53 54 To be more specific there are hopes to identify what specific chromosomes are damaged and to define the damage during cancer development from proton exposure 53 Another study looks into determining the effects of exposure to proton irradiation on neurochemical and behavioral endpoints including dopaminergic functioning amphetamine induced conditioned taste aversion learning and spatial learning and memory as measured by the Morris water maze 54 Electrical charging of a spacecraft due to interplanetary proton bombardment has also been proposed for study 55 There are many more studies that pertain to space travel including galactic cosmic rays and their possible health effects and solar proton event exposure The American Biostack and Soviet Biorack space travel experiments have demonstrated the severity of molecular damage induced by heavy ions on microorganisms including Artemia cysts 56 Antiproton EditMain article Antiproton CPT symmetry puts strong constraints on the relative properties of particles and antiparticles and therefore is open to stringent tests For example the charges of a proton and antiproton must sum to exactly zero This equality has been tested to one part in 108 The equality of their masses has also been tested to better than one part in 108 By holding antiprotons in a Penning trap the equality of the charge to mass ratio of protons and antiprotons has been tested to one part in 6 109 57 The magnetic moment of antiprotons has been measured with an error of 8 10 3 nuclear Bohr magnetons and is found to be equal and opposite to that of a proton 58 See also Edit Physics portalFermion field Hydrogen Hydron chemistry List of particles Proton proton chain Quark model Proton spin crisis Proton therapyReferences Edit 2018 CODATA Value proton mass The NIST Reference on Constants Units and Uncertainty NIST 20 May 2019 Retrieved 2019 05 20 2018 CODATA Value proton mass in u The NIST Reference on Constants Units and Uncertainty NIST 20 May 2019 Retrieved 2022 09 11 2018 CODATA Value proton mass energy equivalent in MeV The NIST Reference on Constants Units and Uncertainty NIST 20 May 2019 Retrieved 2022 09 11 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Padilla Antonio Tony 2010 The shrinking proton Sixty Symbols Brady Haran for the University of Nottingham Inside the Proton the Most Complicated Thing You Could Possibly Imagine Quanta Magazine Oct 19 2022 Retrieved from https en wikipedia org w index php title Proton amp oldid 1147637147, wikipedia, wiki, book, books, library,

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