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Svante Arrhenius

Svante August Arrhenius (/əˈrniəs, əˈrniəs/ ə-REE-nee-əs, -⁠RAY-,[1][2] Swedish: [ˈsvânːtɛ aˈrěːnɪɵs]; 19 February 1859 – 2 October 1927) was a Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry. He received the Nobel Prize for Chemistry in 1903, becoming the first Swedish Nobel laureate. In 1905, he became director of the Nobel Institute, where he remained until his death.[3]

Svante Arrhenius
Svante Arrhenius around 1910
Born
Svante August Arrhenius

(1859-02-19)19 February 1859
Died2 October 1927(1927-10-02) (aged 68)
Stockholm, Sweden
NationalitySwedish
Alma mater
Known for
  • Calculation of warming for double carbon dioxide in the atmosphere.
Awards
Scientific career
Fields
Doctoral advisor
Doctoral studentsOskar Benjamin Klein

Arrhenius was the first to use principles of physical chemistry to estimate the extent to which increases in atmospheric carbon dioxide are responsible for the Earth's increasing surface temperature. His work played an important role in the emergence of modern climate science.[4] In the 1960s, Charles David Keeling demonstrated that the quantity of human-caused carbon dioxide emissions into the air is enough to cause global warming.[5]

The Arrhenius equation, Arrhenius acid, Arrhenius base, lunar crater Arrhenius, Martian crater Arrhenius,[6] the mountain of Arrheniusfjellet, and the Arrhenius Labs at Stockholm University were so named to commemorate his contributions to science.

Biography

Early years

Arrhenius was born on 19 February 1859 at Vik (also spelled Wik or Wijk), near Uppsala, Kingdom of Sweden, United Kingdoms of Sweden and Norway, the son of Svante Gustav and Carolina Thunberg Arrhenius, who were Lutheran.[7] His father had been a land surveyor for Uppsala University, moving up to a supervisory position. At the age of three, Arrhenius taught himself to read without the encouragement of his parents and, by watching his father's addition of numbers in his account books, became an arithmetical prodigy. In later life, Arrhenius was profoundly passionate about mathematical concepts, data analysis and discovering their relationships and laws.

At age eight, he entered the local cathedral school, starting in the fifth grade, distinguishing himself in physics and mathematics, and graduating as the youngest and most able student in 1876.

Ionic disassociation

At the University of Uppsala, he was dissatisfied with the chief instructor of physics and the only faculty member who could have supervised him in chemistry, Per Teodor Cleve, so he left to study at the Physical Institute of the Swedish Academy of Sciences in Stockholm under the physicist Erik Edlund in 1881.[citation needed]

His work focused on the conductivities of electrolytes. In 1884, based on this work, he submitted a 150-page dissertation on electrolytic conductivity to Uppsala for the doctorate. It did not impress the professors, who included Cleve, and he received a fourth-class degree, but upon his defense it was reclassified as third-class. Later, extensions of this very work would earn him the 1903 Nobel Prize in Chemistry.[8]

Arrhenius put forth 56 theses in his 1884 dissertation, most of which would still be accepted today unchanged or with minor modifications. The most important idea in the dissertation was his explanation of the fact that solid crystalline salts disassociate into paired charged particles when dissolved, for which he would win the 1903 Nobel Prize in Chemistry. Arrhenius's explanation was that in forming a solution, the salt disassociates into charged particles that Michael Faraday had given the name ions many years earlier. Faraday's belief had been that ions were produced in the process of electrolysis, that is, an external direct current source of electricity was necessary to form ions. Arrhenius proposed that, even in the absence of an electric current, aqueous solutions of salts contained ions. He thus proposed that chemical reactions in solution were reactions between ions.[9][10][11]

The dissertation did not impress the professors at Uppsala, but Arrhenius sent it to a number of scientists in Europe who were developing the new science of physical chemistry, such as Rudolf Clausius, Wilhelm Ostwald, and Jacobus Henricus van 't Hoff. They were far more impressed, and Ostwald even came to Uppsala to persuade Arrhenius to join his research team. Arrhenius declined, however, as he preferred to stay in Sweden-Norway for a while (his father was very ill and would die in 1885) and had received an appointment at Uppsala.[9][10][11]

In an extension of his ionic theory Arrhenius proposed definitions for acids and bases, in 1884. He believed that acids were substances that produce hydrogen ions in solution and that bases were substances that produce hydroxide ions in solution.

Middle period

 
Lehrbuch der kosmischen Physik, 1903

In 1885, Arrhenius next received a travel grant from the Swedish Academy of Sciences, which enabled him to study with Ostwald in Riga (now in Latvia), with Friedrich Kohlrausch in Würzburg, Germany, with Ludwig Boltzmann in Graz, Austria, and with Jacobus Henricus van 't Hoff in Amsterdam.

In 1889, Arrhenius explained the fact that most reactions require added heat energy to proceed by formulating the concept of activation energy, an energy barrier that must be overcome before two molecules will react. The Arrhenius equation gives the quantitative basis of the relationship between the activation energy and the rate at which a reaction proceeds.

In 1891, he became a lecturer at the Stockholm University College (Stockholms Högskola, now Stockholm University), being promoted to professor of physics (with much opposition) in 1895, and rector in 1896.

Nobel Prizes

About 1900, Arrhenius became involved in setting up the Nobel Institutes and the Nobel Prizes. He was elected a member of the Royal Swedish Academy of Sciences in 1901. For the rest of his life, he would be a member of the Nobel Committee on Physics and a de facto member of the Nobel Committee on Chemistry. He used his positions to arrange prizes for his friends (Jacobus van 't Hoff, Wilhelm Ostwald, Theodore Richards) and to attempt to deny them to his enemies (Paul Ehrlich, Walther Nernst, Dmitri Mendeleev).[12] In 1901 Arrhenius was elected to the Swedish Academy of Sciences, against strong opposition. In 1903 he became the first Swede to be awarded the Nobel Prize in Chemistry. In 1905, upon the founding of the Nobel Institute for Physical Research at Stockholm, he was appointed rector of the institute, the position where he remained until retirement in 1927.

In 1911, he won the first Willard Gibbs Award.[13]

Society memberships

He was elected an Honorary Member of the Netherlands Chemical Society in 1909.[14]

He became a Foreign Member of the Royal Society (ForMemRS) in 1910.[15]

In 1912, he was elected a Foreign Honorary Member of the American Academy of Arts and Sciences[16]

In 1919, he became foreign member of the Royal Netherlands Academy of Arts and Sciences.[17]

Later years

 
Arrhenius family grave in Uppsala

Eventually, Arrhenius's theories became generally accepted and he turned to other scientific topics. In 1902, he began to investigate physiological problems in terms of chemical theory. He determined that reactions in living organisms and in the test tube followed the same laws.

In 1904, he delivered at the University of California a course of lectures, the object of which was to illustrate the application of the methods of physical chemistry to the study of the theory of toxins and antitoxins, and which were published in 1907 under the title Immunochemistry.[18][19] He also turned his attention to geology (the origin of ice ages), astronomy, physical cosmology, and astrophysics, accounting for the birth of the Solar System by interstellar collision. He considered radiation pressure as accounting for comets, the solar corona, the aurora borealis, and zodiacal light.

He thought life might have been carried from planet to planet by the transport of spores, the theory now known as panspermia.[18][20] He thought of the idea of a universal language, proposing a modification of the English language.

He was a board member for the Swedish Society for Racial Hygiene (founded 1909), which endorsed mendelism at the time, and contributed to the topic of contraceptives around 1910. However, until 1938 information and sale of contraceptives was prohibited in the Kingdom of Sweden. Gordon Stein wrote that Svante Arrhenius was an atheist.[21][22] In his last years he wrote both textbooks and popular books, trying to emphasize the need for further work on the topics he discussed. In September 1927, he came down with an attack of acute intestinal catarrh and died on 2 October. He was buried in Uppsala.

Marriages and family

He was married twice, first to his former pupil Sofia Rudbeck (1894–1896), with whom he had one son, Olof Arrhenius [sv; fr], and then to Maria Johansson (1905–1927), with whom he had two daughters and a son.

Arrhenius was the grandfather of bacteriologist Agnes Wold,[23] chemist Svante Wold [sv],[24] and ocean biogeochemist Gustaf Arrhenius [sv; fr].[25]

Greenhouse effect

 
This 1902 article attributes to Arrhenius a theory that coal combustion could cause a degree of global warming eventually leading to human extinction.[26]

In developing a theory to explain the ice ages, Arrhenius, in 1896, was the first to use basic principles of physical chemistry to calculate estimates of the extent to which increases in atmospheric carbon dioxide (CO2) will increase Earth's surface temperature through the greenhouse effect.[5][27][28] These calculations led him to conclude that human-caused CO2 emissions, from fossil-fuel burning and other combustion processes, are large enough to cause global warming. This conclusion has been extensively tested, winning a place at the core of modern climate science.[29][30] Arrhenius, in this work, built upon the prior work of other famous scientists, including Joseph Fourier, John Tyndall and Claude Pouillet. Arrhenius wanted to determine whether greenhouse gases could contribute to the explanation of the temperature variation between glacial and inter-glacial periods.[31] Arrhenius used infrared observations of the moon – by Frank Washington Very and Samuel Pierpont Langley at the Allegheny Observatory in Pittsburgh – to calculate how much of infrared (heat) radiation is captured by CO2 and water (H2O) vapour in Earth's atmosphere. Using 'Stefan's law' (better known as the Stefan–Boltzmann law), he formulated what he referred to as a 'rule'. In its original form, Arrhenius's rule reads as follows:

if the quantity of carbonic acid increases in geometric progression, the augmentation of the temperature will increase nearly in arithmetic progression.

Here, Arrhenius refers to CO2 as carbonic acid (which refers only to the aqueous form H2CO3 in modern usage). The following formulation of Arrhenius's rule is still in use today:[32]

 

where   is the concentration of CO2 at the beginning (time-zero) of the period being studied (if the same concentration unit is used for both   and  , then it doesn't matter which concentration unit is used);   is the CO2 concentration at end of the period being studied; ln is the natural logarithm (= log base e (loge)); and   is the augmentation of the temperature, in other words the change in the rate of heating Earth's surface (radiative forcing), which is measured in Watts per square meter.[32] Derivations from atmospheric radiative transfer models have found that   (alpha) for CO2 is 5.35 (± 10%) W/m2 for Earth's atmosphere.[33]

 
Arrhenius at the first Solvay conference on chemistry in 1922 in Brussels.

Based on information from his colleague Arvid Högbom,[34] Arrhenius was the first person to predict that emissions of carbon dioxide from the burning of fossil fuels and other combustion processes were large enough to cause global warming. In his calculation Arrhenius included the feedback from changes in water vapor as well as latitudinal effects, but he omitted clouds, convection of heat upward in the atmosphere, and other essential factors. His work is currently seen less as an accurate quantification of global warming than as the first demonstration that increases in atmospheric CO2 will cause global warming, everything else being equal.

 
Svante Arrhenius (1909)

Arrhenius's absorption values for CO2 and his conclusions met criticism by Knut Ångström in 1900, who published the first modern infrared absorption spectrum of CO2 with two absorption bands, and published experimental results that seemed to show that absorption of infrared radiation by the gas in the atmosphere was already "saturated" so that adding more could make no difference. Arrhenius replied strongly in 1901 (Annalen der Physik), dismissing the critique altogether. He touched on the subject briefly in a technical book titled Lehrbuch der kosmischen Physik (1903). He later wrote Världarnas utveckling (1906) (German: Das Werden der Welten [1907], English: Worlds in the Making [1908]) directed at a general audience, where he suggested that the human emission of CO2 would be strong enough to prevent the world from entering a new ice age, and that a warmer earth would be needed to feed the rapidly increasing population:

"To a certain extent the temperature of the earth's surface, as we shall presently see, is conditioned by the properties of the atmosphere surrounding it, and particularly by the permeability of the latter for the rays of heat." (p. 46)
"That the atmospheric envelopes limit the heat losses from the planets had been suggested about 1800 by the great French physicist Fourier. His ideas were further developed afterwards by Pouillet and Tyndall. Their theory has been styled the hot-house theory, because they thought that the atmosphere acted after the manner of the glass panes of hot-houses." (p. 51)
"If the quantity of carbonic acid [ CO2 + H2O H2CO3 (carbonic acid) ] in the air should sink to one-half its present percentage, the temperature would fall by about 4°; a diminution to one-quarter would reduce the temperature by 8°. On the other hand, any doubling of the percentage of carbon dioxide in the air would raise the temperature of the earth's surface by 4°; and if the carbon dioxide were increased fourfold, the temperature would rise by 8°." (p. 53)
"Although the sea, by absorbing carbonic acid, acts as a regulator of huge capacity, which takes up about five-sixths of the produced carbonic acid, we yet recognize that the slight percentage of carbonic acid in the atmosphere may by the advances of industry be changed to a noticeable degree in the course of a few centuries." (p. 54)
"Since, now, warm ages have alternated with glacial periods, even after man appeared on the earth, we have to ask ourselves: Is it probable that we shall in the coming geological ages be visited by a new ice period that will drive us from our temperate countries into the hotter climates of Africa? There does not appear to be much ground for such an apprehension. The enormous combustion of coal by our industrial establishments suffices to increase the percentage of carbon dioxide in the air to a perceptible degree." (p. 61)
"We often hear lamentations that the coal stored up in the earth is wasted by the present generation without any thought of the future, and we are terrified by the awful destruction of life and property which has followed the volcanic eruptions of our days. We may find a kind of consolation in the consideration that here, as in every other case, there is good mixed with the evil. By the influence of the increasing percentage of carbonic acid in the atmosphere, we may hope to enjoy ages with more equable and better climates, especially as regards the colder regions of the earth, ages when the earth will bring forth much more abundant crops than at present, for the benefit of rapidly propagating mankind." (p. 63)

At this time, the accepted consensus explanation is that, historically, orbital forcing has set the timing for ice ages, with CO2 acting as an essential amplifying feedback.[35][36] However, CO2 releases since the industrial revolution have increased CO2 to a level not found since 10 to 15 million years ago, when the global average surface temperature was up to 11 °F (6 °C) warmer than now and almost all ice had melted, raising world sea-levels to about 100 feet (30 m.) higher than today's.[37]

Arrhenius estimated based on the CO2 levels at his time, that reducing levels by 0.62–0.55 would decrease temperatures by 4–5 °C (Celsius) and an increase of 2.5 to 3 times of CO2 would cause a temperature rise of 8–9 °C in the Arctic.[27][38] In his book Worlds in the Making he described the "hot-house" theory of the atmosphere.[39]

Works

  • 1884, Recherches sur la conductibilité galvanique des électrolytes, doctoral dissertation, Stockholm, Royal publishing house, P. A. Norstedt & Söner, 155 pages.
  • 1896a, Ueber den Einfluss des Atmosphärischen Kohlensäurengehalts auf die Temperatur der Erdoberfläche, in the Proceedings of the Royal Swedish Academy of Science, Stockholm 1896, Volume 22, I N. 1, pages 1–101.
  • 1896b, On the Influence of Carbonic Acid in the Air upon the Temperature of the Ground, London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science (fifth series), April 1896. vol 41, pages 237–275.
  • 1901a, Ueber die Wärmeabsorption durch Kohlensäure, Annalen der Physik, Vol 4, 1901, pages 690–705.
  • 1901b, Über Die Wärmeabsorption Durch Kohlensäure Und Ihren Einfluss Auf Die Temperatur Der Erdoberfläche. Abstract of the proceedings of the Royal Academy of Science, 58, 25–58.
  • Arrhenius, Svante. Die Verbreitung des Lebens im Weltenraum. Die Umschau, Frankfurt a. M., 7, 1903, 481–486.
  • Lehrbuch der kosmischen Physik (in German). Vol. 1. Leipzig: Hirzel. 1903.
    • Lehrbuch der kosmischen Physik (in German). Vol. 2. Leipzig: Hirzel. 1903.
  • 1906, Die vermutliche Ursache der Klimaschwankungen, Meddelanden från K. Vetenskapsakademiens Nobelinstitut, Vol 1 No 2, pages 1–10
  • 1908, Das Werden der Welten (Worlds in the making; the evolution of the universe), Academic Publishing House, Leipzig, 208 pages.

See also

References

  1. ^ . Lexico UK English Dictionary. Oxford University Press. Archived from the original on 27 August 2022.
  2. ^ "Arrhenius". Merriam-Webster Dictionary. Retrieved 16 August 2021.
  3. ^ "Arrhenius, Svante August" in Chambers's Encyclopædia. London: George Newnes, 1961, Vol. 1, p. 635.
  4. ^ Dessler, Andrew E. (2021). Introduction to Modern Climate Change. Cambridge University Press. p. 222. ISBN 978-1-108-84018-7.
  5. ^ a b Baum, Rudy M. Sr. (2016). "Future Calculations: The first climate change believer". Distillations. 2 (2): 38–39. Retrieved 22 March 2018.
  6. ^ de Vaucouleurs, G.; et al. (September 1975). "The new Martian nomenclature of the International Astronomical Union". Icarus. 26 (1): 85−98. Bibcode:1975Icar...26...85D. doi:10.1016/0019-1035(75)90146-3.
  7. ^ The Who's Who of Nobel Prize Winners, 1901-1995. Oryx Press. 1996. ISBN 9780897748995.
  8. ^ "The Nobel Prize in Chemistry 1903". www.nobelprize.org. Retrieved 18 March 2018.
  9. ^ a b Harris, William; Levey, Judith, eds. (1975). The New Columbia Encyclopedia (4th ed.). New York City: Columbia University. p. 155. ISBN 978-0-231035-729.
  10. ^ a b McHenry, Charles, ed. (1992). The New Encyclopædia Britannica. Vol. 1 (15 ed.). Chicago: Encyclopædia Britannica, Inc. p. 587. ISBN 978-085-229553-3.
  11. ^ a b Cillispie, Charles, ed. (1970). Dictionary of Scientific Biography (1 ed.). New York City: Charles Scribner's Sons. pp. 296–302. ISBN 978-0-684101-125.
  12. ^ Patrick Coffey, Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry, Oxford University Press, 2008,
  13. ^ "Willard Gibbs Award". chicagoacs.org. Retrieved 18 March 2018.
  14. ^ Honorary members - website of the Royal Netherlands Chemical Society
  15. ^ Royal Society. "Fellows of the Royal Society".
  16. ^ (PDF). American Academy of Arts and Sciences. Archived from the original (PDF) on 18 June 2006. Retrieved 25 April 2011. Page 14, third column, on the right.
  17. ^ "Svante August Arrhenius (1859–1927)". Royal Netherlands Academy of Arts and Sciences. Retrieved 19 July 2015.
  18. ^ a b Chisholm 1911.
  19. ^ Svante Arrhenius (1907). Immunochemistry; the application of the principles of physical chemistry to the study of the biological antibodies. The Macmillan Company.
  20. ^ Arrhenius, S., Worlds in the Making: The Evolution of the Universe. New York, Harper & Row, 1908,
  21. ^ Gordon Stein (1988). The encyclopedia of unbelief. Vol. 1. Prometheus Books. p. 594. ISBN 9780879753078. Svante Arrhenius (I859-I927), recipient of the Nobel Prize in chemistry (I903), was a declared atheist and the author of The Evolution of the Worlds and other works on cosmic physics.
  22. ^ NNDB.com. "Svante Arrhenius". Soylent Communications. Retrieved 11 September 2012.
  23. ^ "Mot bacillskräck och gubbvälde" [Against bacillus fear and old man rule]. 1 February 2011. Retrieved 17 December 2022.
  24. ^ "Svante Wold". www.umu.se (in Swedish).[dead link]
  25. ^ Arrhenius, O. (January 1923). "Statistical Investigations in the Constitution of Plant Associations". Ecology. 4 (1): 68–73. doi:10.2307/1929275. JSTOR 1929275.
  26. ^ "Hint to Coal Consumers". The Selma Morning Times. Selma, Alabama, US. 15 October 1902. p. 4.
  27. ^ a b Arrhenius, Svante (1896). "On the influence of carbonic acid in the air upon the temperature of the ground" (PDF). The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 41 (251): 237–276. doi:10.1080/14786449608620846.
  28. ^ Arrhenius, Svante (1897). "On the Influence of Carbonic Acid in the Air Upon the Temperature of the Ground". Publications of the Astronomical Society of the Pacific. 9 (54): 14. Bibcode:1897PASP....9...14A. doi:10.1086/121158.
  29. ^ "How do we know more CO2 is causing global warming?", Skeptical Science, founded by John Cook, the Climate Communication Fellow for the Global Change Institute, University of Queensland, Brisbane, Australia
  30. ^ "Climate Change 2013 – The Physical Science Basis, by the Intergovernmental Panel on Climate Change (IPCC)", IPCC, 2013: Summary for Policymakers. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, England and New York, NY.
  31. ^ Rodhe, Henning, et al. "Svante Arrhenius and the Greenhouse Effect". Ambio, vol. 26, no. 1, 1997, pp. 2–5. JSTOR 4314542.
  32. ^ a b Martin E. Walter, "Earthquakes and Weatherquakes: Mathematics and Climate Change", Notices of the American Mathematical Society, Volume 57, Number 10, p. 1278 (November 2010).
  33. ^ "NOAA Annual Greenhouse Gas Index, Spring 2016", NOAA Annual Greenhouse Gas Index, NOAA Earth System Research Laboratory, Boulder, CO, James H Butler and Stephen A Montzka
  34. ^ Weart, Spencer R. (2008). The Discovery of Global Warming. Harvard University Press. p. 6. ISBN 978-0-674-03189-0.
  35. ^ Monroe, Rob (20 June 2014). "How do CO2 levels relate to ice ages and sea-level?". The Keeling Curve. Retrieved 19 December 2019.
  36. ^ Ganopolski, A.; Calov, R. (2011). "The role of orbital forcing, carbon dioxide and regolith in 100 kyr glacial cycles" (PDF). Climate of the Past. 7 (4): 1415–1425. Bibcode:2011CliPa...7.1415G. doi:10.5194/cp-7-1415-2011. Archived (PDF) from the original on 9 October 2022.
  37. ^ Andrew Freedman. "The Last Time CO2 Was This High, Humans Didn't Exist". www.climatecentral.org. Retrieved 19 December 2019.
  38. ^ Graham, Steve (18 January 2000). "Svante Arrhenius : Arrhenius' Carbon Dioxide Research". Nasa Earth Observatory.
  39. ^ Graham, Steve (18 January 2000). "Svante Arrhenius : Hot House Theory". Nasa Earth Observatory.
  40. ^ Ernman, Beata; Ernman, Malena; Thunberg, Greta; Thunberg, Svante (17 March 2020). Our House is on Fire: Scenes of a Family and a Planet in Crisis. p. 152. ISBN 9780525507376.

Sources

  •   This article incorporates text from a publication now in the public domainChisholm, Hugh, ed. (1911). "Arrhenius, Svante August". Encyclopædia Britannica. Vol. 2 (11th ed.). Cambridge University Press. p. 648.

Further reading

  • Snelders, H. A. M. (1970). "Arrhenius, Svante August". Dictionary of Scientific Biography. Vol. 1. New York: Charles Scribner's Sons. pp. 296–301. ISBN 978-0-684-10114-9.
  • Crawford, Elisabeth T. (1996). Arrhenius: from ionic theory to the greenhouse effect. Canton, MA: Science History Publications. ISBN 978-0-88135-166-8.
  • Coffey, Patrick (2008). Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry. Oxford University Press. ISBN 978-0-19-532134-0.

External links

  • Works by Svante Arrhenius at Project Gutenberg
  • "Enter the Anthropocene: Climate Science in the Early 20th Century," podcast about Arrhenius, Guy Callendar, and Charles David Keeling, Initial Conditions, Episode 2
  • Svante Arrhenius on Nobelprize.org   including the Nobel Lecture, December 11, 1903 Development of the Theory of Electrolytic Dissociation
  • , published in 2008 by the Royal Swedish Academy of Engineering Sciences
  • Svante Arrhenius (1859–1927)
  • Obs 50 (1927) 363 – Obituary (one paragraph)
  • PASP 39 (1927) 385 – Obituary (one paragraph)
  • "On the influence of Carbonic Acid in the Air upon the Temperature of the Ground", Arrhenius, 1896, online and analyzed on BibNum [click 'à télécharger' for English analysis]
  • Newspaper clippings about Svante Arrhenius in the 20th Century Press Archives of the ZBW  

svante, arrhenius, confused, with, carl, axel, arrhenius, svante, august, arrhenius, swedish, ˈsvânːtɛ, aˈrěːnɪɵs, february, 1859, october, 1927, swedish, scientist, originally, physicist, often, referred, chemist, arrhenius, founders, science, physical, chemi. Not to be confused with Carl Axel Arrhenius Svante August Arrhenius e ˈ r iː n i e s e ˈ r eɪ n i e s e REE nee es RAY 1 2 Swedish ˈsvanːtɛ aˈreːnɪɵs 19 February 1859 2 October 1927 was a Swedish scientist Originally a physicist but often referred to as a chemist Arrhenius was one of the founders of the science of physical chemistry He received the Nobel Prize for Chemistry in 1903 becoming the first Swedish Nobel laureate In 1905 he became director of the Nobel Institute where he remained until his death 3 Svante ArrheniusSvante Arrhenius around 1910BornSvante August Arrhenius 1859 02 19 19 February 1859Wik Castle Sweden Sweden NorwayDied2 October 1927 1927 10 02 aged 68 Stockholm SwedenNationalitySwedishAlma materUppsala University Stockholm UniversityKnown forArrhenius equation Theory of ionic dissociation Acid base theory Calculation of warming for double carbon dioxide in the atmosphere AwardsDavy Medal 1902 Nobel Prize for Chemistry 1903 ForMemRS 1910 Willard Gibbs Award 1911 Faraday Lectureship Prize 1914 Franklin Medal 1920 Scientific careerFieldsPhysics ChemistryDoctoral advisorPer Teodor Cleve Erik Edlund citation needed Doctoral studentsOskar Benjamin KleinArrhenius was the first to use principles of physical chemistry to estimate the extent to which increases in atmospheric carbon dioxide are responsible for the Earth s increasing surface temperature His work played an important role in the emergence of modern climate science 4 In the 1960s Charles David Keeling demonstrated that the quantity of human caused carbon dioxide emissions into the air is enough to cause global warming 5 The Arrhenius equation Arrhenius acid Arrhenius base lunar crater Arrhenius Martian crater Arrhenius 6 the mountain of Arrheniusfjellet and the Arrhenius Labs at Stockholm University were so named to commemorate his contributions to science Contents 1 Biography 1 1 Early years 1 2 Ionic disassociation 1 3 Middle period 1 4 Nobel Prizes 1 5 Society memberships 1 6 Later years 2 Marriages and family 3 Greenhouse effect 4 Works 5 See also 6 References 7 Sources 8 Further reading 9 External linksBiography EditEarly years Edit Arrhenius was born on 19 February 1859 at Vik also spelled Wik or Wijk near Uppsala Kingdom of Sweden United Kingdoms of Sweden and Norway the son of Svante Gustav and Carolina Thunberg Arrhenius who were Lutheran 7 His father had been a land surveyor for Uppsala University moving up to a supervisory position At the age of three Arrhenius taught himself to read without the encouragement of his parents and by watching his father s addition of numbers in his account books became an arithmetical prodigy In later life Arrhenius was profoundly passionate about mathematical concepts data analysis and discovering their relationships and laws At age eight he entered the local cathedral school starting in the fifth grade distinguishing himself in physics and mathematics and graduating as the youngest and most able student in 1876 Ionic disassociation Edit At the University of Uppsala he was dissatisfied with the chief instructor of physics and the only faculty member who could have supervised him in chemistry Per Teodor Cleve so he left to study at the Physical Institute of the Swedish Academy of Sciences in Stockholm under the physicist Erik Edlund in 1881 citation needed His work focused on the conductivities of electrolytes In 1884 based on this work he submitted a 150 page dissertation on electrolytic conductivity to Uppsala for the doctorate It did not impress the professors who included Cleve and he received a fourth class degree but upon his defense it was reclassified as third class Later extensions of this very work would earn him the 1903 Nobel Prize in Chemistry 8 Arrhenius put forth 56 theses in his 1884 dissertation most of which would still be accepted today unchanged or with minor modifications The most important idea in the dissertation was his explanation of the fact that solid crystalline salts disassociate into paired charged particles when dissolved for which he would win the 1903 Nobel Prize in Chemistry Arrhenius s explanation was that in forming a solution the salt disassociates into charged particles that Michael Faraday had given the name ions many years earlier Faraday s belief had been that ions were produced in the process of electrolysis that is an external direct current source of electricity was necessary to form ions Arrhenius proposed that even in the absence of an electric current aqueous solutions of salts contained ions He thus proposed that chemical reactions in solution were reactions between ions 9 10 11 The dissertation did not impress the professors at Uppsala but Arrhenius sent it to a number of scientists in Europe who were developing the new science of physical chemistry such as Rudolf Clausius Wilhelm Ostwald and Jacobus Henricus van t Hoff They were far more impressed and Ostwald even came to Uppsala to persuade Arrhenius to join his research team Arrhenius declined however as he preferred to stay in Sweden Norway for a while his father was very ill and would die in 1885 and had received an appointment at Uppsala 9 10 11 In an extension of his ionic theory Arrhenius proposed definitions for acids and bases in 1884 He believed that acids were substances that produce hydrogen ions in solution and that bases were substances that produce hydroxide ions in solution Middle period Edit Lehrbuch der kosmischen Physik 1903 In 1885 Arrhenius next received a travel grant from the Swedish Academy of Sciences which enabled him to study with Ostwald in Riga now in Latvia with Friedrich Kohlrausch in Wurzburg Germany with Ludwig Boltzmann in Graz Austria and with Jacobus Henricus van t Hoff in Amsterdam In 1889 Arrhenius explained the fact that most reactions require added heat energy to proceed by formulating the concept of activation energy an energy barrier that must be overcome before two molecules will react The Arrhenius equation gives the quantitative basis of the relationship between the activation energy and the rate at which a reaction proceeds In 1891 he became a lecturer at the Stockholm University College Stockholms Hogskola now Stockholm University being promoted to professor of physics with much opposition in 1895 and rector in 1896 Nobel Prizes Edit About 1900 Arrhenius became involved in setting up the Nobel Institutes and the Nobel Prizes He was elected a member of the Royal Swedish Academy of Sciences in 1901 For the rest of his life he would be a member of the Nobel Committee on Physics and a de facto member of the Nobel Committee on Chemistry He used his positions to arrange prizes for his friends Jacobus van t Hoff Wilhelm Ostwald Theodore Richards and to attempt to deny them to his enemies Paul Ehrlich Walther Nernst Dmitri Mendeleev 12 In 1901 Arrhenius was elected to the Swedish Academy of Sciences against strong opposition In 1903 he became the first Swede to be awarded the Nobel Prize in Chemistry In 1905 upon the founding of the Nobel Institute for Physical Research at Stockholm he was appointed rector of the institute the position where he remained until retirement in 1927 In 1911 he won the first Willard Gibbs Award 13 Society memberships Edit He was elected an Honorary Member of the Netherlands Chemical Society in 1909 14 He became a Foreign Member of the Royal Society ForMemRS in 1910 15 In 1912 he was elected a Foreign Honorary Member of the American Academy of Arts and Sciences 16 In 1919 he became foreign member of the Royal Netherlands Academy of Arts and Sciences 17 Later years Edit Arrhenius family grave in Uppsala Eventually Arrhenius s theories became generally accepted and he turned to other scientific topics In 1902 he began to investigate physiological problems in terms of chemical theory He determined that reactions in living organisms and in the test tube followed the same laws In 1904 he delivered at the University of California a course of lectures the object of which was to illustrate the application of the methods of physical chemistry to the study of the theory of toxins and antitoxins and which were published in 1907 under the title Immunochemistry 18 19 He also turned his attention to geology the origin of ice ages astronomy physical cosmology and astrophysics accounting for the birth of the Solar System by interstellar collision He considered radiation pressure as accounting for comets the solar corona the aurora borealis and zodiacal light He thought life might have been carried from planet to planet by the transport of spores the theory now known as panspermia 18 20 He thought of the idea of a universal language proposing a modification of the English language He was a board member for the Swedish Society for Racial Hygiene founded 1909 which endorsed mendelism at the time and contributed to the topic of contraceptives around 1910 However until 1938 information and sale of contraceptives was prohibited in the Kingdom of Sweden Gordon Stein wrote that Svante Arrhenius was an atheist 21 22 In his last years he wrote both textbooks and popular books trying to emphasize the need for further work on the topics he discussed In September 1927 he came down with an attack of acute intestinal catarrh and died on 2 October He was buried in Uppsala Marriages and family EditHe was married twice first to his former pupil Sofia Rudbeck 1894 1896 with whom he had one son Olof Arrhenius sv fr and then to Maria Johansson 1905 1927 with whom he had two daughters and a son Arrhenius was the grandfather of bacteriologist Agnes Wold 23 chemist Svante Wold sv 24 and ocean biogeochemist Gustaf Arrhenius sv fr 25 Greenhouse effect Edit This 1902 article attributes to Arrhenius a theory that coal combustion could cause a degree of global warming eventually leading to human extinction 26 In developing a theory to explain the ice ages Arrhenius in 1896 was the first to use basic principles of physical chemistry to calculate estimates of the extent to which increases in atmospheric carbon dioxide CO2 will increase Earth s surface temperature through the greenhouse effect 5 27 28 These calculations led him to conclude that human caused CO2 emissions from fossil fuel burning and other combustion processes are large enough to cause global warming This conclusion has been extensively tested winning a place at the core of modern climate science 29 30 Arrhenius in this work built upon the prior work of other famous scientists including Joseph Fourier John Tyndall and Claude Pouillet Arrhenius wanted to determine whether greenhouse gases could contribute to the explanation of the temperature variation between glacial and inter glacial periods 31 Arrhenius used infrared observations of the moon by Frank Washington Very and Samuel Pierpont Langley at the Allegheny Observatory in Pittsburgh to calculate how much of infrared heat radiation is captured by CO2 and water H2O vapour in Earth s atmosphere Using Stefan s law better known as the Stefan Boltzmann law he formulated what he referred to as a rule In its original form Arrhenius s rule reads as follows if the quantity of carbonic acid increases in geometric progression the augmentation of the temperature will increase nearly in arithmetic progression dd Here Arrhenius refers to CO2 as carbonic acid which refers only to the aqueous form H2CO3 in modern usage The following formulation of Arrhenius s rule is still in use today 32 D F a ln C C 0 displaystyle Delta F alpha ln C C 0 dd where C 0 displaystyle C 0 is the concentration of CO2 at the beginning time zero of the period being studied if the same concentration unit is used for both C displaystyle C and C 0 displaystyle C 0 then it doesn t matter which concentration unit is used C displaystyle C is the CO2 concentration at end of the period being studied ln is the natural logarithm log base e loge and D F displaystyle Delta F is the augmentation of the temperature in other words the change in the rate of heating Earth s surface radiative forcing which is measured in Watts per square meter 32 Derivations from atmospheric radiative transfer models have found that a displaystyle alpha alpha for CO2 is 5 35 10 W m2 for Earth s atmosphere 33 Arrhenius at the first Solvay conference on chemistry in 1922 in Brussels Based on information from his colleague Arvid Hogbom 34 Arrhenius was the first person to predict that emissions of carbon dioxide from the burning of fossil fuels and other combustion processes were large enough to cause global warming In his calculation Arrhenius included the feedback from changes in water vapor as well as latitudinal effects but he omitted clouds convection of heat upward in the atmosphere and other essential factors His work is currently seen less as an accurate quantification of global warming than as the first demonstration that increases in atmospheric CO2 will cause global warming everything else being equal Svante Arrhenius 1909 Arrhenius s absorption values for CO2 and his conclusions met criticism by Knut Angstrom in 1900 who published the first modern infrared absorption spectrum of CO2 with two absorption bands and published experimental results that seemed to show that absorption of infrared radiation by the gas in the atmosphere was already saturated so that adding more could make no difference Arrhenius replied strongly in 1901 Annalen der Physik dismissing the critique altogether He touched on the subject briefly in a technical book titled Lehrbuch der kosmischen Physik 1903 He later wrote Varldarnas utveckling 1906 German Das Werden der Welten 1907 English Worlds in the Making 1908 directed at a general audience where he suggested that the human emission of CO2 would be strong enough to prevent the world from entering a new ice age and that a warmer earth would be needed to feed the rapidly increasing population To a certain extent the temperature of the earth s surface as we shall presently see is conditioned by the properties of the atmosphere surrounding it and particularly by the permeability of the latter for the rays of heat p 46 dd That the atmospheric envelopes limit the heat losses from the planets had been suggested about 1800 by the great French physicist Fourier His ideas were further developed afterwards by Pouillet and Tyndall Their theory has been styled the hot house theory because they thought that the atmosphere acted after the manner of the glass panes of hot houses p 51 dd If the quantity of carbonic acid CO2 H2O H2CO3 carbonic acid in the air should sink to one half its present percentage the temperature would fall by about 4 a diminution to one quarter would reduce the temperature by 8 On the other hand any doubling of the percentage of carbon dioxide in the air would raise the temperature of the earth s surface by 4 and if the carbon dioxide were increased fourfold the temperature would rise by 8 p 53 dd Although the sea by absorbing carbonic acid acts as a regulator of huge capacity which takes up about five sixths of the produced carbonic acid we yet recognize that the slight percentage of carbonic acid in the atmosphere may by the advances of industry be changed to a noticeable degree in the course of a few centuries p 54 dd Since now warm ages have alternated with glacial periods even after man appeared on the earth we have to ask ourselves Is it probable that we shall in the coming geological ages be visited by a new ice period that will drive us from our temperate countries into the hotter climates of Africa There does not appear to be much ground for such an apprehension The enormous combustion of coal by our industrial establishments suffices to increase the percentage of carbon dioxide in the air to a perceptible degree p 61 dd We often hear lamentations that the coal stored up in the earth is wasted by the present generation without any thought of the future and we are terrified by the awful destruction of life and property which has followed the volcanic eruptions of our days We may find a kind of consolation in the consideration that here as in every other case there is good mixed with the evil By the influence of the increasing percentage of carbonic acid in the atmosphere we may hope to enjoy ages with more equable and better climates especially as regards the colder regions of the earth ages when the earth will bring forth much more abundant crops than at present for the benefit of rapidly propagating mankind p 63 dd At this time the accepted consensus explanation is that historically orbital forcing has set the timing for ice ages with CO2 acting as an essential amplifying feedback 35 36 However CO2 releases since the industrial revolution have increased CO2 to a level not found since 10 to 15 million years ago when the global average surface temperature was up to 11 F 6 C warmer than now and almost all ice had melted raising world sea levels to about 100 feet 30 m higher than today s 37 Arrhenius estimated based on the CO2 levels at his time that reducing levels by 0 62 0 55 would decrease temperatures by 4 5 C Celsius and an increase of 2 5 to 3 times of CO2 would cause a temperature rise of 8 9 C in the Arctic 27 38 In his book Worlds in the Making he described the hot house theory of the atmosphere 39 Works Edit1884 Recherches sur la conductibilite galvanique des electrolytes doctoral dissertation Stockholm Royal publishing house P A Norstedt amp Soner 155 pages 1896a Ueber den Einfluss des Atmospharischen Kohlensaurengehalts auf die Temperatur der Erdoberflache in the Proceedings of the Royal Swedish Academy of Science Stockholm 1896 Volume 22 I N 1 pages 1 101 1896b On the Influence of Carbonic Acid in the Air upon the Temperature of the Ground London Edinburgh and Dublin Philosophical Magazine and Journal of Science fifth series April 1896 vol 41 pages 237 275 1901a Ueber die Warmeabsorption durch Kohlensaure Annalen der Physik Vol 4 1901 pages 690 705 1901b Uber Die Warmeabsorption Durch Kohlensaure Und Ihren Einfluss Auf Die Temperatur Der Erdoberflache Abstract of the proceedings of the Royal Academy of Science 58 25 58 Arrhenius Svante Die Verbreitung des Lebens im Weltenraum Die Umschau Frankfurt a M 7 1903 481 486 Lehrbuch der kosmischen Physik in German Vol 1 Leipzig Hirzel 1903 Lehrbuch der kosmischen Physik in German Vol 2 Leipzig Hirzel 1903 1906 Die vermutliche Ursache der Klimaschwankungen Meddelanden fran K Vetenskapsakademiens Nobelinstitut Vol 1 No 2 pages 1 10 1908 Das Werden der Welten Worlds in the making the evolution of the universe Academic Publishing House Leipzig 208 pages See also EditActivation energy Arrhenius acid Arrhenius law Arrhenius plot Neel Arrhenius theory History of climate change science James Croll Eunice Newton Foote George Perkins Marsh Milutin Milankovic Greta Thunberg climate activist and distant relative of Arrhenius 40 Viscosity models for mixturesReferences Edit Arrhenius Svante August Lexico UK English Dictionary Oxford University Press Archived from the original on 27 August 2022 Arrhenius Merriam Webster Dictionary Retrieved 16 August 2021 Arrhenius Svante August in Chambers s Encyclopaedia London George Newnes 1961 Vol 1 p 635 Dessler Andrew E 2021 Introduction to Modern Climate Change Cambridge University Press p 222 ISBN 978 1 108 84018 7 a b Baum Rudy M Sr 2016 Future Calculations The first climate change believer Distillations 2 2 38 39 Retrieved 22 March 2018 de Vaucouleurs G et al September 1975 The new Martian nomenclature of the International Astronomical Union Icarus 26 1 85 98 Bibcode 1975Icar 26 85D doi 10 1016 0019 1035 75 90146 3 The Who s Who of Nobel Prize Winners 1901 1995 Oryx Press 1996 ISBN 9780897748995 The Nobel Prize in Chemistry 1903 www nobelprize org Retrieved 18 March 2018 a b Harris William Levey Judith eds 1975 The New Columbia Encyclopedia 4th ed New York City Columbia University p 155 ISBN 978 0 231035 729 a b McHenry Charles ed 1992 The New Encyclopaedia Britannica Vol 1 15 ed Chicago Encyclopaedia Britannica Inc p 587 ISBN 978 085 229553 3 a b Cillispie Charles ed 1970 Dictionary of Scientific Biography 1 ed New York City Charles Scribner s Sons pp 296 302 ISBN 978 0 684101 125 Patrick Coffey Cathedrals of Science The Personalities and Rivalries That Made Modern Chemistry Oxford University Press 2008 Willard Gibbs Award chicagoacs org Retrieved 18 March 2018 Honorary members website of the Royal Netherlands Chemical Society Royal Society Fellows of the Royal Society Book of Members 1780 2010 Chapter A PDF American Academy of Arts and Sciences Archived from the original PDF on 18 June 2006 Retrieved 25 April 2011 Page 14 third column on the right Svante August Arrhenius 1859 1927 Royal Netherlands Academy of Arts and Sciences Retrieved 19 July 2015 a b Chisholm 1911 Svante Arrhenius 1907 Immunochemistry the application of the principles of physical chemistry to the study of the biological antibodies The Macmillan Company Arrhenius S Worlds in the Making The Evolution of the Universe New York Harper amp Row 1908 Gordon Stein 1988 The encyclopedia of unbelief Vol 1 Prometheus Books p 594 ISBN 9780879753078 Svante Arrhenius I859 I927 recipient of the Nobel Prize in chemistry I903 was a declared atheist and the author of The Evolution of the Worlds and other works on cosmic physics NNDB com Svante Arrhenius Soylent Communications Retrieved 11 September 2012 Mot bacillskrack och gubbvalde Against bacillus fear and old man rule 1 February 2011 Retrieved 17 December 2022 Svante Wold www umu se in Swedish dead link Arrhenius O January 1923 Statistical Investigations in the Constitution of Plant Associations Ecology 4 1 68 73 doi 10 2307 1929275 JSTOR 1929275 Hint to Coal Consumers The Selma Morning Times Selma Alabama US 15 October 1902 p 4 a b Arrhenius Svante 1896 On the influence of carbonic acid in the air upon the temperature of the ground PDF The London Edinburgh and Dublin Philosophical Magazine and Journal of Science 41 251 237 276 doi 10 1080 14786449608620846 Arrhenius Svante 1897 On the Influence of Carbonic Acid in the Air Upon the Temperature of the Ground Publications of the Astronomical Society of the Pacific 9 54 14 Bibcode 1897PASP 9 14A doi 10 1086 121158 How do we know more CO2 is causing global warming Skeptical Science founded by John Cook the Climate Communication Fellow for the Global Change Institute University of Queensland Brisbane Australia Climate Change 2013 The Physical Science Basis by the Intergovernmental Panel on Climate Change IPCC IPCC 2013 Summary for Policymakers In Climate Change 2013 The Physical Science Basis Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change Stocker T F D Qin G K Plattner M Tignor S K Allen J Boschung A Nauels Y Xia V Bex and P M Midgley eds Cambridge University Press Cambridge England and New York NY Rodhe Henning et al Svante Arrhenius and the Greenhouse Effect Ambio vol 26 no 1 1997 pp 2 5 JSTOR 4314542 a b Martin E Walter Earthquakes and Weatherquakes Mathematics and Climate Change Notices of the American Mathematical Society Volume 57 Number 10 p 1278 November 2010 NOAA Annual Greenhouse Gas Index Spring 2016 NOAA Annual Greenhouse Gas Index NOAA Earth System Research Laboratory Boulder CO James H Butler and Stephen A Montzka Weart Spencer R 2008 The Discovery of Global Warming Harvard University Press p 6 ISBN 978 0 674 03189 0 Monroe Rob 20 June 2014 How do CO2 levels relate to ice ages and sea level The Keeling Curve Retrieved 19 December 2019 Ganopolski A Calov R 2011 The role of orbital forcing carbon dioxide and regolith in 100 kyr glacial cycles PDF Climate of the Past 7 4 1415 1425 Bibcode 2011CliPa 7 1415G doi 10 5194 cp 7 1415 2011 Archived PDF from the original on 9 October 2022 Andrew Freedman The Last Time CO2 Was This High Humans Didn t Exist www climatecentral org Retrieved 19 December 2019 Graham Steve 18 January 2000 Svante Arrhenius Arrhenius Carbon Dioxide Research Nasa Earth Observatory Graham Steve 18 January 2000 Svante Arrhenius Hot House Theory Nasa Earth Observatory Ernman Beata Ernman Malena Thunberg Greta Thunberg Svante 17 March 2020 Our House is on Fire Scenes of a Family and a Planet in Crisis p 152 ISBN 9780525507376 Sources Edit This article incorporates text from a publication now in the public domain Chisholm Hugh ed 1911 Arrhenius Svante August Encyclopaedia Britannica Vol 2 11th ed Cambridge University Press p 648 Further reading EditSnelders H A M 1970 Arrhenius Svante August Dictionary of Scientific Biography Vol 1 New York Charles Scribner s Sons pp 296 301 ISBN 978 0 684 10114 9 Crawford Elisabeth T 1996 Arrhenius from ionic theory to the greenhouse effect Canton MA Science History Publications ISBN 978 0 88135 166 8 Coffey Patrick 2008 Cathedrals of Science The Personalities and Rivalries That Made Modern Chemistry Oxford University Press ISBN 978 0 19 532134 0 External links Edit Wikimedia Commons has media related to Svante Arrhenius Works by Svante Arrhenius at Project Gutenberg Enter the Anthropocene Climate Science in the Early 20th Century podcast about Arrhenius Guy Callendar and Charles David Keeling Initial Conditions Episode 2 Svante Arrhenius on Nobelprize org including the Nobel Lecture December 11 1903 Development of the Theory of Electrolytic Dissociation A Tribute to the Memory of Svante Arrhenius 1859 1927 a scientist ahead of his time published in 2008 by the Royal Swedish Academy of Engineering Sciences Svante Arrhenius 1859 1927 Obs 50 1927 363 Obituary one paragraph PASP 39 1927 385 Obituary one paragraph On the influence of Carbonic Acid in the Air upon the Temperature of the Ground Arrhenius 1896 online and analyzed on BibNum click a telecharger for English analysis Newspaper clippings about Svante Arrhenius in the 20th Century Press Archives of the ZBW Portals Biography Sweden Astronomy Stars Outer space Solar System Education Science 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