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Wikipedia

Kerosene

Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from Greek: κηρός (keros) meaning "wax", and was registered as a trademark by Canadian geologist and inventor Abraham Gesner in 1854 before evolving into a generic trademark. It is sometimes spelled kerosine in scientific and industrial usage.[1] The term kerosene is common in much of Argentina, Australia, Canada, India, New Zealand, Nigeria, and the United States,[2][3] while the term paraffin (or a closely related variant) is used in Chile, eastern Africa, South Africa, Norway, and in the United Kingdom.[4] The term lamp oil, or the equivalent in the local languages, is common in the majority of Asia and the Southeastern United States.[5] Liquid paraffin (called mineral oil in the US) is a more viscous and highly refined product which is used as a laxative. Paraffin wax is a waxy solid extracted from petroleum.

A kerosene bottle, containing blue-dyed kerosene

Kerosene is widely used to power jet engines of aircraft (jet fuel), as well as some rocket engines in a highly refined form called RP-1. It is also commonly used as a cooking and lighting fuel, and for fire toys such as poi. In parts of Asia, kerosene is sometimes used as fuel for small outboard motors or even motorcycles.[6] World total kerosene consumption for all purposes is equivalent to about 1,110,000 cubic metres (39 million cubic feet) per day.[7]

To prevent confusion between kerosene and the much more flammable and volatile gasoline (petrol), some jurisdictions regulate markings or colourings for containers used to store or dispense kerosene. For example, in the United States, Pennsylvania requires that portable containers used at retail service stations for kerosene be colored blue, as opposed to red (for gasoline) or yellow (for diesel).[8][9]

The World Health Organization considers kerosene to be a polluting fuel and recommends that "governments and practitioners immediately stop promoting its household use".[10] Kerosene smoke contains high levels of harmful particulate matter, and household use of kerosene is associated with higher risks of cancer, respiratory infections, asthma, tuberculosis, cataracts, and adverse pregnancy outcomes.[11]

Properties and grades

Kerosene is a low-viscosity, clear liquid formed from hydrocarbons obtained from the fractional distillation of petroleum between 150 and 275 °C (300 and 525 °F), resulting in a mixture with a density of 0.78–0.81 g/cm3. It is miscible in petroleum solvents but immiscible in water. It is composed of hydrocarbon molecules that typically contain between 6 and 20 carbon atoms per molecule,[12] predominantly containing 9 to 16 carbon atoms.[13]

Regardless of crude oil source or processing history, kerosene's major components are branched- and straight-chain alkanes (hydrocarbon chains) and naphthenes (cycloalkanes), which normally account for at least 70% by volume. Aromatic hydrocarbons such as alkylbenzenes (single ring) and alkylnaphthalenes (double ring), do not normally exceed 25% by volume of kerosene streams. Olefins are usually not present at more than 5% by volume.[14]

Heat of combustion of kerosene is similar to that of diesel fuel; its lower heating value is 43.1 MJ/kg (around 18,500 Btu/lb), and its higher heating value is 46.2 MJ/kg (19,900 Btu/lb).[15]

The ASTM International standard specification D-3699-19 recognizes two grades of kerosene: grades 1-K (less than 0.04% sulfur by weight) and 2-K (0.3% sulfur by weight). 1-K-grade kerosene burns cleaner with fewer deposits, fewer toxins, and less frequent maintenance than 2-K-grade kerosene, and is the preferred grade of kerosene for indoor kerosene heaters and stoves.[16]

In the United Kingdom, two grades of heating oil are defined. BS 2869 Class C1 is the lightest grade used for lanterns, camping stoves, wick heaters, and mixed with petrol in some vintage combustion engines as a substitute for tractor vaporising oil. BS 2869 Class C2 is a heavier distillate, which is used as domestic heating oil. Premium kerosene is usually sold in 5- or 20-liter containers from hardware, camping and garden stores, and is often dyed purple. Standard kerosene is usually dispensed in bulk by a tanker and is undyed.

National and international standards define the properties of several grades of kerosene used for jet fuel. Flash point and freezing point properties are of particular interest for operation and safety; the standards also define additives for control of static electricity and other purposes.

Melting, freeze and flash points

Kerosene is liquid around room temperature: 25 °C (77 °F).[17] The flash point of kerosene is between 37 °C (99 °F) and 65 °C (149 °F), and its autoignition temperature is 220 °C (428 °F).[18] The freeze point of kerosene depends on grade, with commercial aviation fuel standardized at −47 °C (−53 °F).

1-K-grade kerosene freezes around −40 °C (−40 °F, 233 K).[19]

 
Persian scholar Rāzi (or Rhazes) was the first to distill kerosene in the ninth century. He is depicted here in a manuscript by Gerard of Cremona.

History

 
A queue for kerosene. Moscow, Russia, 1920s

The process of distilling crude oil/petroleum into kerosene, as well as other hydrocarbon compounds, was first written about in the ninth century by the Persian scholar Rāzi (or Rhazes). In his Kitab al-Asrar (Book of Secrets), the physician and chemist Razi described two methods for the production of kerosene, termed naft abyad (نفط ابيض"white naphtha"), using an apparatus called an alembic. One method used clay as an absorbent, and later the other method using chemicals like ammonium chloride (sal ammoniac). The distillation process was repeated until most of the volatile hydrocarbon fractions had been removed and the final product was perfectly clear and safe to burn. Kerosene was also produced during the same period from oil shale and bitumen by heating the rock to extract the oil, which was then distilled.[20] During the Chinese Ming Dynasty, the Chinese made use of kerosene through extracting and purifying petroleum and then converted it into lamp fuel.[21] The Chinese made use of petroleum for lighting lamps and heating homes as early as 1500 BC.[22]

Illuminating oil from coal and oil shale

 
Abraham Gesner distilled kerosene from bituminous coal and oil shale experimentally in 1846; commercial production followed in 1854

Although "coal oil" was well known by industrial chemists at least as early as the 1700s as a byproduct of making coal gas and coal tar, it burned with a smoky flame that prevented its use for indoor illumination. In cities, much indoor illumination was provided by piped-in coal gas, but outside the cities, and for spot lighting within the cities, the lucrative market for fueling indoor lamps was supplied by whale oil, specifically that from sperm whales, which burned brighter and cleaner.[23][24]

Canadian geologist Abraham Pineo Gesner claimed that in 1846, he had given a public demonstration in Charlottetown, Prince Edward Island of a new process he had discovered.[23][note 1] He heated coal in a retort, and distilled from it a clear, thin fluid that he showed made an excellent lamp fuel. He coined the name "kerosene" for his fuel, a contraction of keroselaion, meaning wax-oil.[25] The cost of extracting kerosene from coal was high.

Gesner recalled from his extensive knowledge of New Brunswick's geology a naturally occurring asphaltum called albertite. He was blocked from using it by the New Brunswick coal conglomerate because they had coal extraction rights for the province, and he lost a court case when their experts claimed albertite was a form of coal.[26] In 1854, Gesner moved to Newtown Creek, Long Island, New York. There, he secured backing from a group of businessmen. They formed the North American Gas Light Company, to which he assigned his patents.

Despite clear priority of discovery, Gesner did not obtain his first kerosene patent until 1854, two years after James Young's United States patent.[27][28] Gesner's method of purifying the distillation products appears to have been superior to Young's, resulting in a cleaner and better-smelling fuel. Manufacture of kerosene under the Gesner patents began in New York in 1854 and later in Boston—being distilled from bituminous coal and oil shale.[25] Gesner registered the word "Kerosene" as a trademark in 1854, and for several years, only the North American Gas Light Company and the Downer Company (to which Gesner had granted the right) were allowed to call their lamp oil "Kerosene" in the United States.[29]

In 1848, Scottish chemist James Young experimented with oil discovered seeping in a coal mine as a source of lubricating oil and illuminating fuel. When the seep became exhausted, he experimented with the dry distillation of coal, especially the resinous "boghead coal" (torbanite). He extracted a number of useful liquids from it, one of which he named paraffine oil because at low temperatures, it congealed into a substance that resembled paraffin wax. Young took out a patent on his process and the resulting products in 1850, and built the first truly commercial oil-works in the world at Bathgate in 1851, using oil extracted from locally mined torbanite, shale, and bituminous coal. In 1852, he took out a United States patent for the same invention. These patents were subsequently upheld in both countries in a series of lawsuits, and other producers were obliged to pay him royalties.[25]

Kerosene from petroleum

In 1851, Samuel Martin Kier began selling lamp oil to local miners, under the name "Carbon Oil". He distilled this from crude oil by a process of his own invention. He also invented a new lamp to burn his product.[30] He has been dubbed the Grandfather of the American Oil Industry by historians.[31] Kier's salt wells began to be fouled with petroleum in the 1840s. At first, Kier simply dumped the oil into the nearby Pennsylvania Main Line Canal as useless waste, but later he began experimenting with several distillates of the crude oil, along with a chemist from eastern Pennsylvania.[32]

Ignacy Łukasiewicz, a Polish pharmacist residing in Lviv, and his Hungarian partner Jan Zeh [pl] had been experimenting with different distillation techniques, trying to improve on Gesner's kerosene process, but using oil from a local petroleum seep. Many people knew of his work, but paid little attention to it. On the night of 31 July 1853, doctors at the local hospital needed to perform an emergency operation, virtually impossible by candlelight. They therefore sent a messenger for Łukasiewicz and his new lamps. The lamp burned so brightly and cleanly that the hospital officials ordered several lamps plus a large supply of fuel. Łukasiewicz realized the potential of his work and quit the pharmacy to find a business partner, and then travelled to Vienna to register his technique with the government. Łukasiewicz moved to the Gorlice region of Poland in 1854, and sank several wells across southern Poland over the following decade, setting up a refinery near Jasło in 1859.[33]

The petroleum discovery at the Drake Well in western Pennsylvania in 1859 caused a great deal of public excitement and investment drilling in new wells, not only in Pennsylvania, but also in Canada, where petroleum had been discovered at Oil Springs, Ontario in 1858, and southern Poland, where Ignacy Łukasiewicz had been distilling lamp oil from petroleum seeps since 1852. The increased supply of petroleum allowed oil refiners to entirely side-step the oil-from-coal patents of both Young and Gesner, and produce illuminating oil from petroleum without paying royalties to anyone. As a result, the illuminating oil industry in the United States completely switched over to petroleum in the 1860s. The petroleum-based illuminating oil was widely sold as Kerosene, and the trade name soon lost its proprietary status, and became the lower-case generic product "kerosene".[34] Because Gesner's original Kerosene had been also known as "coal oil," generic kerosene from petroleum was commonly called "coal oil" in some parts of the United States well into the 20th century.

In the United Kingdom, manufacturing oil from coal (or oil shale) continued into the early 20th century, although increasingly overshadowed by petroleum oils.

As kerosene production increased, whaling declined. The American whaling fleet, which had been steadily growing for 50 years, reached its all-time peak of 199 ships in 1858. By 1860, just two years later, the fleet had dropped to 167 ships. The Civil War cut into American whaling temporarily, but only 105 whaling ships returned to sea in 1866, the first full year of peace, and that number dwindled until only 39 American ships set out to hunt whales in 1876.[35] Kerosene, made first from coal and oil shale, then from petroleum, had largely taken over whaling's lucrative market in lamp oil.

Electric lighting started displacing kerosene as an illuminant in the late 19th century, especially in urban areas. However, kerosene remained the predominant commercial end-use for petroleum refined in the United States until 1909, when it was exceeded by motor fuels. The rise of the gasoline-powered automobile in the early 20th century created a demand for the lighter hydrocarbon fractions, and refiners invented methods to increase their output of gasoline, while decreasing their output of kerosene. In addition, some of the heavier hydrocarbons that previously went into kerosene were incorporated into diesel fuel. Kerosene kept some market share by being increasingly used in stoves and portable heaters.[36]

Kerosene from carbon dioxide and water

A pilot project by ETH Zurich used solar power to produce kerosene from carbon dioxide and water in July 2022. The product can be used in existing aviation applications, and "can also be blended with fossil-derived kerosene."[37][38]

Production

Kerosene is produced by fractional distillation of crude oil in an oil refinery. It condenses at a temperature intermediate between diesel fuel, which is less volatile, and naphtha and gasoline, which are more volatile.

Kerosene made up 8.5 percent by volume of petroleum refinery output in 2021 in the United States, of which nearly all was kerosene-type jet fuel (8.4 percent).[39]

Applications

As fuel

Fuels for heating

Heating and lighting

The fuel, also known as heating oil in the UK and Ireland, remains widely used in kerosene lamps and lanterns in the developing world.[40] Although it replaced whale oil, the 1873 edition of Elements of Chemistry said, "The vapor of this substance [kerosene] mixed with air is as explosive as gunpowder."[41] This statement may have been due to the common practice of adulterating kerosene with cheaper but more volatile hydrocarbon mixtures, such as naphtha.[42] Kerosene was a significant fire risk; in 1880, nearly two of every five New York City fires were caused by defective kerosene lamps.[43]

In less-developed countries kerosene is an important source of energy for cooking and lighting. It is used as a cooking fuel in portable stoves for backpackers. As a heating fuel, it is often used in portable stoves, and is sold in some filling stations. It is sometimes used as a heat source during power failures.

 
A truck delivering kerosene in Japan
 
Kerosene Storage Tank

Kerosene is widely used in Japan and Chile as a home heating fuel for portable and installed kerosene heaters. In Chile and Japan, kerosene can be readily bought at any filling station or be delivered to homes in some cases.[44] In the United Kingdom and Ireland, kerosene is often used as a heating fuel in areas not connected to a gas pipeline network. It is used less for cooking, with LPG being preferred because it is easier to light. Kerosene is often the fuel of choice for range cookers such as Rayburn. Additives such as RangeKlene can be put into kerosene to ensure that it burns cleaner and produces less soot when used in range cookers.[45]

The Amish, who generally abstain from the use of electricity, rely on kerosene for lighting at night. More ubiquitous in the late 19th and early 20th centuries, kerosene space heaters were often built into kitchen ranges, and kept many farm and fishing families warm and dry through the winter. At one time, citrus growers used a smudge pot fueled by kerosene to create a pall of thick smoke over a grove in an effort to prevent freezing temperatures from damaging crops. "Salamanders" are kerosene space heaters used on construction sites to dry out building materials and to warm workers. Before the days of electrically lighted road barriers, highway construction zones were marked at night by kerosene fired, pot-bellied torches. Most of these uses of kerosene created thick black smoke because of the low temperature of combustion.

A notable exception, discovered in the early 19th century, is the use of a gas mantle mounted above the wick on a kerosene lamp. Looking like a delicate woven bag above the woven cotton wick, the mantle is a residue of mineral materials (mostly thorium dioxide), heated to incandescence by the flame from the wick. The thorium and cerium oxide combination produces both a whiter light and a greater fraction of the energy in the form of visible light than a black body at the same temperature would. These types of lamps are still in use today in areas of the world without electricity, because they give a much better light than a simple wick-type lamp does.[citation needed] Recently, a multipurpose lantern that doubles as a cook stove has been introduced in India in areas with no electricity.[46]

Cooking

 
Advertisement for an oil stove, from the Albion Lamp Company, Birmingham, England, c. 1900
 
Old kerosene stoves of India.

In countries such as Nigeria, kerosene is the main fuel used for cooking, especially by the poor, and kerosene stoves have replaced traditional wood-based cooking appliances. As such, increase in the price of kerosene can have a major political and environmental consequence. The Indian government subsidizes the fuel to keep the price very low, to around 15 U.S. cents per liter as of February 2007, as lower prices discourage dismantling of forests for cooking fuel.[47] In Nigeria an attempt by the government to remove a fuel subsidy that includes kerosene met with strong opposition.[48]

Kerosene is used as a fuel in portable stoves, especially in Primus stoves invented in 1892. Portable kerosene stoves earn a reputation of reliable and durable stove in everyday use, and perform especially well under adverse conditions. In outdoor activities and mountaineering, a decisive advantage of pressurized kerosene stoves over gas cartridge stoves is their particularly high thermal output and their ability to operate at very low temperature in winter or at high altitude. Wick stoves like Perfection's or wickless like Boss continue to be used by the Amish and off grid living and in natural disasters where there is no power available.

Engines

In the early to mid-20th century, kerosene or tractor vaporising oil (TVO) was used as a cheap fuel for tractors and hit 'n miss engines. The engine would start on gasoline, then switch over to kerosene once the engine warmed up. On some engines a heat valve on the manifold would route the exhaust gases around the intake pipe, heating the kerosene to the point where it was vaporized and could be ignited by an electric spark.

In Europe following the Second World War, automobiles were similarly modified to run on kerosene rather than gasoline, which they would have to import and pay heavy taxes on. Besides additional piping and the switch between fuels, the head gasket was replaced by a much thicker one to diminish the compression ratio (making the engine less powerful and less efficient, but able to run on kerosene). The necessary equipment was sold under the trademark "Econom".[49]

During the fuel crisis of the 1970s, Saab-Valmet developed and series-produced the Saab 99 Petro that ran on kerosene, turpentine or gasoline. The project, codenamed "Project Lapponia", was headed by Simo Vuorio, and towards the end of the 1970s, a working prototype was produced based on the Saab 99 GL. The car was designed to run on two fuels. Gasoline was used for cold starts and when extra power was needed, but normally it ran on kerosene or turpentine. The idea was that the gasoline could be made from peat using the Fischer–Tropsch process. Between 1980 and 1984, 3,756 Saab 99 Petros and 2,385 Talbot Horizons (a version of the Chrysler Horizon that integrated many Saab components) were made. One reason to manufacture kerosene-fueled cars was that in Finland kerosene was less heavily taxed than gasoline.[50]

Kerosene is used to fuel smaller-horsepower outboard motors built by Yamaha, Suzuki, and Tohatsu. Primarily used on small fishing craft, these are dual-fuel engines that start on gasoline and then transition to kerosene once the engine reaches optimum operating temperature. Multiple fuel Evinrude and Mercury Racing engines also burn kerosene, as well as jet fuel.[51]

Today, kerosene is mainly used in fuel for jet engines in several grades. One highly refined form of the fuel is known as RP-1, and is often burned with liquid oxygen as rocket fuel. These fuel grade kerosenes meet specifications for smoke points and freeze points. The combustion reaction can be approximated as follows, with the molecular formula C12H26 (dodecane):

2 C12H26(l) + 37 O2(g) → 24 CO2(g) + 26 H2O(g); H˚ = -7513 kJ

In the initial phase of liftoff, the Saturn V launch vehicle was powered by the reaction of liquid oxygen with RP-1.[52] For the five 6.4 meganewton sea-level thrust F-1 rocket engines of the Saturn V, burning together, the reaction generated roughly 1.62 × 1011 watts (J/s) (162 gigawatt) or 217 million horsepower.[52]

Kerosene is sometimes used as an additive in diesel fuel to prevent gelling or waxing in cold temperatures.[53]

Ultra-low sulfur kerosene is a custom-blended fuel used by the New York City Transit Authority to power its bus fleet. The transit agency started using this fuel in 2004, prior to the widespread adoption of ultra-low-sulfur diesel, which has since become the standard. In 2008, the suppliers of the custom fuel failed to tender for a renewal of the transit agency's contract, leading to a negotiated contract at a significantly increased cost.[54]

JP-8, (for "Jet Propellant 8") a kerosene-based fuel, is used by the United States military as a replacement in diesel fueled vehicles and for powering aircraft. JP-8 is also used by the U.S. military and its NATO allies as a fuel for heaters, stoves, tanks and as a replacement for diesel fuel in the engines of nearly all tactical ground vehicles and electrical generators.

Chemical processes

Kerosene is used as a diluent in the PUREX extraction process, but it is increasingly being supplanted by dodecane.

In X-ray crystallography, kerosene can be used to store crystals. When a hydrated crystal is left in air, dehydration may occur slowly. This makes the color of the crystal become dull. Kerosene can keep air away from the crystal.

It can be also used to prevent air from re-dissolving in a boiled liquid,[55] and to store alkali metals such as potassium, sodium, and rubidium (with the exception of lithium, which is less dense than kerosene, causing it to float).[56]

In entertainment

Kerosene is often used in the entertainment industry for fire performances, such as fire breathing, fire juggling or poi, and fire dancing. Because of its low flame temperature when burnt in free air, the risk is lower should the performer come in contact with the flame. Kerosene is generally not recommended as fuel for indoor fire dancing, as it produces an unpleasant (to some) odor, which becomes poisonous in sufficient concentration. Ethanol was sometimes used instead, but the flames it produces look less impressive, and its lower flash point poses a high risk.

In industry

As a petroleum product miscible with many industrial liquids, kerosene can be used as both a solvent, able to remove other petroleum products, such as chain grease, and as a lubricant, with less risk of combustion when compared to using gasoline. It can also be used as a cooling agent in metal production and treatment (oxygen-free conditions).[57]

In the petroleum industry, kerosene is often used as a synthetic hydrocarbon for corrosion experiments to simulate crude oil in field conditions.

Solvent

Kerosene can be used as an adhesive remover on hard-to-remove mucilage or adhesive left by stickers on a glass surface (such as in show windows of stores).[55]

It can be used to remove candle wax that has dripped onto a glass surface; it is recommended that the excess wax be scraped off prior to applying kerosene via a soaked cloth or tissue paper.[55]

It can be used to clean bicycle and motorcycle chains of old lubricant before relubrication.[55]

It can also be used to thin oil-based paint used in fine art. Some artists even use it to clean their brushes; however, it leaves the bristles greasy to the touch.

Others

It has seen use for water tank mosquito control in Australia, where a temporary thin floating layer above the water protects it until the defective tank is repaired.[58]

Toxicity

The World Health Organization considers kerosene to be a polluting fuel and recommends that “governments and practitioners immediately stop promoting its household use”.[59] Kerosene smoke contains high levels of harmful particulate matter, and household use of kerosene is associated with higher risks of cancer, respiratory infections, asthma, tuberculosis, cataract, and adverse pregnancy outcomes.[60]

Ingestion of kerosene is harmful. Kerosene is sometimes recommended as a folk remedy for killing head lice, but health agencies warn against this as it can cause burns and serious illness. A kerosene shampoo can even be fatal if fumes are inhaled.[61][62]

People can be exposed to kerosene in the workplace by breathing it in, swallowing it, skin contact, and eye contact. The US National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit of 100 mg/m3 over an 8-hour workday.[63]

See also

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Notes

  1. ^ In his book of 1861 and its second edition of 1865, Gesner claimed to have demonstrated liquid kerosene – an "oil" – in 1846 during his public lectures on Prince Edward's Island.
    • Gesner, Abraham (1861) A Practical Treatise on Coal, Petroleum, and Other Distilled Oils. New York, New York, USA: Bailliere Brothers, p. 9.
    • Gesner, Abraham ; Gesner, George Weltden (1865) A Practical Treatise on Coal, Petroleum, and Other Distilled Oils, 2nd ed., New York, New York, USA: Bailliere Brothers, p. 9.
    However, John Butt characterized Gesner's book as " … a piece of propaganda designed to get people to believe that he had been constantly interested in inventing burning oil from 1846 to 1854." Butt also stated that "No independent documentary proof has ever been produced to support Gesner's claim." Furthermore, "He [Gesner] omitted to mention that kerosene had first been used to describe an illuminating gas."
    • Butt, John (1963) "James Young, Scottish Industrialist and Philanthropist," PhD thesis (University of Glasgow, Scotland, UK), p. 227.
    As late as 1850, Gesner promoted his "kerosene" as an illuminating gas:
    • In his U.S. patent of 1850, Gesner called the product of his distillations an "illuminating gas", not an oil: Gesner, Abraham "Manufacture of illuminating-gas from bitumen" U.S. Patent no. 7,052 (issued: 29 January 1850).
    • In his prospectus of 1850, Gesner repeatedly identified "kerosene" as a gas, not an oil: Gesner, Abraham (1850) "Prospectus of Gesner's patent kerosene gas, obtained from bitumen, asphaltum, or mineral pitch." New York, New York, USA: Trehern & Williamson.

External links

  • , Webster Online Dictionary
  • Kerosene Fuel Primer
  • Material Safety Data Sheet 15 April 2016 at the Wayback Machine
  • CDC – NIOSH Pocket Guide to Chemical Hazards

kerosene, confused, with, kerogen, other, uses, disambiguation, paraffin, lamp, combustible, hydrocarbon, liquid, which, derived, from, petroleum, widely, used, fuel, aviation, well, households, name, derives, from, greek, κηρός, keros, meaning, registered, tr. Not to be confused with Kerogen For other uses see Kerosene disambiguation Kerosene paraffin or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum It is widely used as a fuel in aviation as well as households Its name derives from Greek khros keros meaning wax and was registered as a trademark by Canadian geologist and inventor Abraham Gesner in 1854 before evolving into a generic trademark It is sometimes spelled kerosine in scientific and industrial usage 1 The term kerosene is common in much of Argentina Australia Canada India New Zealand Nigeria and the United States 2 3 while the term paraffin or a closely related variant is used in Chile eastern Africa South Africa Norway and in the United Kingdom 4 The term lamp oil or the equivalent in the local languages is common in the majority of Asia and the Southeastern United States 5 Liquid paraffin called mineral oil in the US is a more viscous and highly refined product which is used as a laxative Paraffin wax is a waxy solid extracted from petroleum A kerosene bottle containing blue dyed kerosene Kerosene is widely used to power jet engines of aircraft jet fuel as well as some rocket engines in a highly refined form called RP 1 It is also commonly used as a cooking and lighting fuel and for fire toys such as poi In parts of Asia kerosene is sometimes used as fuel for small outboard motors or even motorcycles 6 World total kerosene consumption for all purposes is equivalent to about 1 110 000 cubic metres 39 million cubic feet per day 7 To prevent confusion between kerosene and the much more flammable and volatile gasoline petrol some jurisdictions regulate markings or colourings for containers used to store or dispense kerosene For example in the United States Pennsylvania requires that portable containers used at retail service stations for kerosene be colored blue as opposed to red for gasoline or yellow for diesel 8 9 The World Health Organization considers kerosene to be a polluting fuel and recommends that governments and practitioners immediately stop promoting its household use 10 Kerosene smoke contains high levels of harmful particulate matter and household use of kerosene is associated with higher risks of cancer respiratory infections asthma tuberculosis cataracts and adverse pregnancy outcomes 11 Contents 1 Properties and grades 1 1 Melting freeze and flash points 2 History 2 1 Illuminating oil from coal and oil shale 2 2 Kerosene from petroleum 2 3 Kerosene from carbon dioxide and water 3 Production 4 Applications 4 1 As fuel 4 1 1 Heating and lighting 4 1 2 Cooking 4 1 3 Engines 4 2 Chemical processes 4 3 In entertainment 4 4 In industry 4 5 Solvent 4 6 Others 5 Toxicity 6 See also 7 References 8 Notes 9 External linksProperties and grades EditKerosene is a low viscosity clear liquid formed from hydrocarbons obtained from the fractional distillation of petroleum between 150 and 275 C 300 and 525 F resulting in a mixture with a density of 0 78 0 81 g cm3 It is miscible in petroleum solvents but immiscible in water It is composed of hydrocarbon molecules that typically contain between 6 and 20 carbon atoms per molecule 12 predominantly containing 9 to 16 carbon atoms 13 Regardless of crude oil source or processing history kerosene s major components are branched and straight chain alkanes hydrocarbon chains and naphthenes cycloalkanes which normally account for at least 70 by volume Aromatic hydrocarbons such as alkylbenzenes single ring and alkylnaphthalenes double ring do not normally exceed 25 by volume of kerosene streams Olefins are usually not present at more than 5 by volume 14 Heat of combustion of kerosene is similar to that of diesel fuel its lower heating value is 43 1 MJ kg around 18 500 Btu lb and its higher heating value is 46 2 MJ kg 19 900 Btu lb 15 The ASTM International standard specification D 3699 19 recognizes two grades of kerosene grades 1 K less than 0 04 sulfur by weight and 2 K 0 3 sulfur by weight 1 K grade kerosene burns cleaner with fewer deposits fewer toxins and less frequent maintenance than 2 K grade kerosene and is the preferred grade of kerosene for indoor kerosene heaters and stoves 16 In the United Kingdom two grades of heating oil are defined BS 2869 Class C1 is the lightest grade used for lanterns camping stoves wick heaters and mixed with petrol in some vintage combustion engines as a substitute for tractor vaporising oil BS 2869 Class C2 is a heavier distillate which is used as domestic heating oil Premium kerosene is usually sold in 5 or 20 liter containers from hardware camping and garden stores and is often dyed purple Standard kerosene is usually dispensed in bulk by a tanker and is undyed National and international standards define the properties of several grades of kerosene used for jet fuel Flash point and freezing point properties are of particular interest for operation and safety the standards also define additives for control of static electricity and other purposes Melting freeze and flash points Edit Kerosene is liquid around room temperature 25 C 77 F 17 The flash point of kerosene is between 37 C 99 F and 65 C 149 F and its autoignition temperature is 220 C 428 F 18 The freeze point of kerosene depends on grade with commercial aviation fuel standardized at 47 C 53 F 1 K grade kerosene freezes around 40 C 40 F 233 K 19 Persian scholar Razi or Rhazes was the first to distill kerosene in the ninth century He is depicted here in a manuscript by Gerard of Cremona History Edit A queue for kerosene Moscow Russia 1920s See also Coal oil The process of distilling crude oil petroleum into kerosene as well as other hydrocarbon compounds was first written about in the ninth century by the Persian scholar Razi or Rhazes In his Kitab al Asrar Book of Secrets the physician and chemist Razi described two methods for the production of kerosene termed naft abyad نفط ابيض white naphtha using an apparatus called an alembic One method used clay as an absorbent and later the other method using chemicals like ammonium chloride sal ammoniac The distillation process was repeated until most of the volatile hydrocarbon fractions had been removed and the final product was perfectly clear and safe to burn Kerosene was also produced during the same period from oil shale and bitumen by heating the rock to extract the oil which was then distilled 20 During the Chinese Ming Dynasty the Chinese made use of kerosene through extracting and purifying petroleum and then converted it into lamp fuel 21 The Chinese made use of petroleum for lighting lamps and heating homes as early as 1500 BC 22 Illuminating oil from coal and oil shale Edit Abraham Gesner distilled kerosene from bituminous coal and oil shale experimentally in 1846 commercial production followed in 1854 Although coal oil was well known by industrial chemists at least as early as the 1700s as a byproduct of making coal gas and coal tar it burned with a smoky flame that prevented its use for indoor illumination In cities much indoor illumination was provided by piped in coal gas but outside the cities and for spot lighting within the cities the lucrative market for fueling indoor lamps was supplied by whale oil specifically that from sperm whales which burned brighter and cleaner 23 24 Canadian geologist Abraham Pineo Gesner claimed that in 1846 he had given a public demonstration in Charlottetown Prince Edward Island of a new process he had discovered 23 note 1 He heated coal in a retort and distilled from it a clear thin fluid that he showed made an excellent lamp fuel He coined the name kerosene for his fuel a contraction of keroselaion meaning wax oil 25 The cost of extracting kerosene from coal was high Gesner recalled from his extensive knowledge of New Brunswick s geology a naturally occurring asphaltum called albertite He was blocked from using it by the New Brunswick coal conglomerate because they had coal extraction rights for the province and he lost a court case when their experts claimed albertite was a form of coal 26 In 1854 Gesner moved to Newtown Creek Long Island New York There he secured backing from a group of businessmen They formed the North American Gas Light Company to which he assigned his patents Despite clear priority of discovery Gesner did not obtain his first kerosene patent until 1854 two years after James Young s United States patent 27 28 Gesner s method of purifying the distillation products appears to have been superior to Young s resulting in a cleaner and better smelling fuel Manufacture of kerosene under the Gesner patents began in New York in 1854 and later in Boston being distilled from bituminous coal and oil shale 25 Gesner registered the word Kerosene as a trademark in 1854 and for several years only the North American Gas Light Company and the Downer Company to which Gesner had granted the right were allowed to call their lamp oil Kerosene in the United States 29 In 1848 Scottish chemist James Young experimented with oil discovered seeping in a coal mine as a source of lubricating oil and illuminating fuel When the seep became exhausted he experimented with the dry distillation of coal especially the resinous boghead coal torbanite He extracted a number of useful liquids from it one of which he named paraffine oil because at low temperatures it congealed into a substance that resembled paraffin wax Young took out a patent on his process and the resulting products in 1850 and built the first truly commercial oil works in the world at Bathgate in 1851 using oil extracted from locally mined torbanite shale and bituminous coal In 1852 he took out a United States patent for the same invention These patents were subsequently upheld in both countries in a series of lawsuits and other producers were obliged to pay him royalties 25 Kerosene from petroleum Edit In 1851 Samuel Martin Kier began selling lamp oil to local miners under the name Carbon Oil He distilled this from crude oil by a process of his own invention He also invented a new lamp to burn his product 30 He has been dubbed the Grandfather of the American Oil Industry by historians 31 Kier s salt wells began to be fouled with petroleum in the 1840s At first Kier simply dumped the oil into the nearby Pennsylvania Main Line Canal as useless waste but later he began experimenting with several distillates of the crude oil along with a chemist from eastern Pennsylvania 32 Ignacy Lukasiewicz a Polish pharmacist residing in Lviv and his Hungarian partner Jan Zeh pl had been experimenting with different distillation techniques trying to improve on Gesner s kerosene process but using oil from a local petroleum seep Many people knew of his work but paid little attention to it On the night of 31 July 1853 doctors at the local hospital needed to perform an emergency operation virtually impossible by candlelight They therefore sent a messenger for Lukasiewicz and his new lamps The lamp burned so brightly and cleanly that the hospital officials ordered several lamps plus a large supply of fuel Lukasiewicz realized the potential of his work and quit the pharmacy to find a business partner and then travelled to Vienna to register his technique with the government Lukasiewicz moved to the Gorlice region of Poland in 1854 and sank several wells across southern Poland over the following decade setting up a refinery near Jaslo in 1859 33 The petroleum discovery at the Drake Well in western Pennsylvania in 1859 caused a great deal of public excitement and investment drilling in new wells not only in Pennsylvania but also in Canada where petroleum had been discovered at Oil Springs Ontario in 1858 and southern Poland where Ignacy Lukasiewicz had been distilling lamp oil from petroleum seeps since 1852 The increased supply of petroleum allowed oil refiners to entirely side step the oil from coal patents of both Young and Gesner and produce illuminating oil from petroleum without paying royalties to anyone As a result the illuminating oil industry in the United States completely switched over to petroleum in the 1860s The petroleum based illuminating oil was widely sold as Kerosene and the trade name soon lost its proprietary status and became the lower case generic product kerosene 34 Because Gesner s original Kerosene had been also known as coal oil generic kerosene from petroleum was commonly called coal oil in some parts of the United States well into the 20th century In the United Kingdom manufacturing oil from coal or oil shale continued into the early 20th century although increasingly overshadowed by petroleum oils As kerosene production increased whaling declined The American whaling fleet which had been steadily growing for 50 years reached its all time peak of 199 ships in 1858 By 1860 just two years later the fleet had dropped to 167 ships The Civil War cut into American whaling temporarily but only 105 whaling ships returned to sea in 1866 the first full year of peace and that number dwindled until only 39 American ships set out to hunt whales in 1876 35 Kerosene made first from coal and oil shale then from petroleum had largely taken over whaling s lucrative market in lamp oil Electric lighting started displacing kerosene as an illuminant in the late 19th century especially in urban areas However kerosene remained the predominant commercial end use for petroleum refined in the United States until 1909 when it was exceeded by motor fuels The rise of the gasoline powered automobile in the early 20th century created a demand for the lighter hydrocarbon fractions and refiners invented methods to increase their output of gasoline while decreasing their output of kerosene In addition some of the heavier hydrocarbons that previously went into kerosene were incorporated into diesel fuel Kerosene kept some market share by being increasingly used in stoves and portable heaters 36 Kerosene from carbon dioxide and water Edit A pilot project by ETH Zurich used solar power to produce kerosene from carbon dioxide and water in July 2022 The product can be used in existing aviation applications and can also be blended with fossil derived kerosene 37 38 Production EditFurther information Jet fuel Kerosene is produced by fractional distillation of crude oil in an oil refinery It condenses at a temperature intermediate between diesel fuel which is less volatile and naphtha and gasoline which are more volatile Kerosene made up 8 5 percent by volume of petroleum refinery output in 2021 in the United States of which nearly all was kerosene type jet fuel 8 4 percent 39 Applications EditAs fuel Edit Fuels for heatingHeating oil Wood pellet Kerosene Propane Natural gas Wood CoalHeating and lighting Edit The fuel also known as heating oil in the UK and Ireland remains widely used in kerosene lamps and lanterns in the developing world 40 Although it replaced whale oil the 1873 edition of Elements of Chemistry said The vapor of this substance kerosene mixed with air is as explosive as gunpowder 41 This statement may have been due to the common practice of adulterating kerosene with cheaper but more volatile hydrocarbon mixtures such as naphtha 42 Kerosene was a significant fire risk in 1880 nearly two of every five New York City fires were caused by defective kerosene lamps 43 In less developed countries kerosene is an important source of energy for cooking and lighting It is used as a cooking fuel in portable stoves for backpackers As a heating fuel it is often used in portable stoves and is sold in some filling stations It is sometimes used as a heat source during power failures A truck delivering kerosene in Japan Kerosene Storage Tank Kerosene is widely used in Japan and Chile as a home heating fuel for portable and installed kerosene heaters In Chile and Japan kerosene can be readily bought at any filling station or be delivered to homes in some cases 44 In the United Kingdom and Ireland kerosene is often used as a heating fuel in areas not connected to a gas pipeline network It is used less for cooking with LPG being preferred because it is easier to light Kerosene is often the fuel of choice for range cookers such as Rayburn Additives such as RangeKlene can be put into kerosene to ensure that it burns cleaner and produces less soot when used in range cookers 45 The Amish who generally abstain from the use of electricity rely on kerosene for lighting at night More ubiquitous in the late 19th and early 20th centuries kerosene space heaters were often built into kitchen ranges and kept many farm and fishing families warm and dry through the winter At one time citrus growers used a smudge pot fueled by kerosene to create a pall of thick smoke over a grove in an effort to prevent freezing temperatures from damaging crops Salamanders are kerosene space heaters used on construction sites to dry out building materials and to warm workers Before the days of electrically lighted road barriers highway construction zones were marked at night by kerosene fired pot bellied torches Most of these uses of kerosene created thick black smoke because of the low temperature of combustion A notable exception discovered in the early 19th century is the use of a gas mantle mounted above the wick on a kerosene lamp Looking like a delicate woven bag above the woven cotton wick the mantle is a residue of mineral materials mostly thorium dioxide heated to incandescence by the flame from the wick The thorium and cerium oxide combination produces both a whiter light and a greater fraction of the energy in the form of visible light than a black body at the same temperature would These types of lamps are still in use today in areas of the world without electricity because they give a much better light than a simple wick type lamp does citation needed Recently a multipurpose lantern that doubles as a cook stove has been introduced in India in areas with no electricity 46 Cooking Edit Advertisement for an oil stove from the Albion Lamp Company Birmingham England c 1900 Old kerosene stoves of India In countries such as Nigeria kerosene is the main fuel used for cooking especially by the poor and kerosene stoves have replaced traditional wood based cooking appliances As such increase in the price of kerosene can have a major political and environmental consequence The Indian government subsidizes the fuel to keep the price very low to around 15 U S cents per liter as of February 2007 as lower prices discourage dismantling of forests for cooking fuel 47 In Nigeria an attempt by the government to remove a fuel subsidy that includes kerosene met with strong opposition 48 Kerosene is used as a fuel in portable stoves especially in Primus stoves invented in 1892 Portable kerosene stoves earn a reputation of reliable and durable stove in everyday use and perform especially well under adverse conditions In outdoor activities and mountaineering a decisive advantage of pressurized kerosene stoves over gas cartridge stoves is their particularly high thermal output and their ability to operate at very low temperature in winter or at high altitude Wick stoves like Perfection s or wickless like Boss continue to be used by the Amish and off grid living and in natural disasters where there is no power available Engines Edit In the early to mid 20th century kerosene or tractor vaporising oil TVO was used as a cheap fuel for tractors and hit n miss engines The engine would start on gasoline then switch over to kerosene once the engine warmed up On some engines a heat valve on the manifold would route the exhaust gases around the intake pipe heating the kerosene to the point where it was vaporized and could be ignited by an electric spark In Europe following the Second World War automobiles were similarly modified to run on kerosene rather than gasoline which they would have to import and pay heavy taxes on Besides additional piping and the switch between fuels the head gasket was replaced by a much thicker one to diminish the compression ratio making the engine less powerful and less efficient but able to run on kerosene The necessary equipment was sold under the trademark Econom 49 During the fuel crisis of the 1970s Saab Valmet developed and series produced the Saab 99 Petro that ran on kerosene turpentine or gasoline The project codenamed Project Lapponia was headed by Simo Vuorio and towards the end of the 1970s a working prototype was produced based on the Saab 99 GL The car was designed to run on two fuels Gasoline was used for cold starts and when extra power was needed but normally it ran on kerosene or turpentine The idea was that the gasoline could be made from peat using the Fischer Tropsch process Between 1980 and 1984 3 756 Saab 99 Petros and 2 385 Talbot Horizons a version of the Chrysler Horizon that integrated many Saab components were made One reason to manufacture kerosene fueled cars was that in Finland kerosene was less heavily taxed than gasoline 50 Kerosene is used to fuel smaller horsepower outboard motors built by Yamaha Suzuki and Tohatsu Primarily used on small fishing craft these are dual fuel engines that start on gasoline and then transition to kerosene once the engine reaches optimum operating temperature Multiple fuel Evinrude and Mercury Racing engines also burn kerosene as well as jet fuel 51 Today kerosene is mainly used in fuel for jet engines in several grades One highly refined form of the fuel is known as RP 1 and is often burned with liquid oxygen as rocket fuel These fuel grade kerosenes meet specifications for smoke points and freeze points The combustion reaction can be approximated as follows with the molecular formula C12H26 dodecane 2 C12H26 l 37 O2 g 24 CO2 g 26 H2O g H 7513 kJIn the initial phase of liftoff the Saturn V launch vehicle was powered by the reaction of liquid oxygen with RP 1 52 For the five 6 4 meganewton sea level thrust F 1 rocket engines of the Saturn V burning together the reaction generated roughly 1 62 1011 watts J s 162 gigawatt or 217 million horsepower 52 Kerosene is sometimes used as an additive in diesel fuel to prevent gelling or waxing in cold temperatures 53 Ultra low sulfur kerosene is a custom blended fuel used by the New York City Transit Authority to power its bus fleet The transit agency started using this fuel in 2004 prior to the widespread adoption of ultra low sulfur diesel which has since become the standard In 2008 the suppliers of the custom fuel failed to tender for a renewal of the transit agency s contract leading to a negotiated contract at a significantly increased cost 54 JP 8 for Jet Propellant 8 a kerosene based fuel is used by the United States military as a replacement in diesel fueled vehicles and for powering aircraft JP 8 is also used by the U S military and its NATO allies as a fuel for heaters stoves tanks and as a replacement for diesel fuel in the engines of nearly all tactical ground vehicles and electrical generators Chemical processes Edit Kerosene is used as a diluent in the PUREX extraction process but it is increasingly being supplanted by dodecane In X ray crystallography kerosene can be used to store crystals When a hydrated crystal is left in air dehydration may occur slowly This makes the color of the crystal become dull Kerosene can keep air away from the crystal It can be also used to prevent air from re dissolving in a boiled liquid 55 and to store alkali metals such as potassium sodium and rubidium with the exception of lithium which is less dense than kerosene causing it to float 56 In entertainment Edit Kerosene is often used in the entertainment industry for fire performances such as fire breathing fire juggling or poi and fire dancing Because of its low flame temperature when burnt in free air the risk is lower should the performer come in contact with the flame Kerosene is generally not recommended as fuel for indoor fire dancing as it produces an unpleasant to some odor which becomes poisonous in sufficient concentration Ethanol was sometimes used instead but the flames it produces look less impressive and its lower flash point poses a high risk In industry Edit As a petroleum product miscible with many industrial liquids kerosene can be used as both a solvent able to remove other petroleum products such as chain grease and as a lubricant with less risk of combustion when compared to using gasoline It can also be used as a cooling agent in metal production and treatment oxygen free conditions 57 In the petroleum industry kerosene is often used as a synthetic hydrocarbon for corrosion experiments to simulate crude oil in field conditions Solvent Edit Kerosene can be used as an adhesive remover on hard to remove mucilage or adhesive left by stickers on a glass surface such as in show windows of stores 55 It can be used to remove candle wax that has dripped onto a glass surface it is recommended that the excess wax be scraped off prior to applying kerosene via a soaked cloth or tissue paper 55 It can be used to clean bicycle and motorcycle chains of old lubricant before relubrication 55 It can also be used to thin oil based paint used in fine art Some artists even use it to clean their brushes however it leaves the bristles greasy to the touch Others Edit It has seen use for water tank mosquito control in Australia where a temporary thin floating layer above the water protects it until the defective tank is repaired 58 Toxicity EditThe World Health Organization considers kerosene to be a polluting fuel and recommends that governments and practitioners immediately stop promoting its household use 59 Kerosene smoke contains high levels of harmful particulate matter and household use of kerosene is associated with higher risks of cancer respiratory infections asthma tuberculosis cataract and adverse pregnancy outcomes 60 Ingestion of kerosene is harmful Kerosene is sometimes recommended as a folk remedy for killing head lice but health agencies warn against this as it can cause burns and serious illness A kerosene shampoo can even be fatal if fumes are inhaled 61 62 People can be exposed to kerosene in the workplace by breathing it in swallowing it skin contact and eye contact The US National Institute for Occupational Safety and Health NIOSH has set a recommended exposure limit of 100 mg m3 over an 8 hour workday 63 See also EditAdiabatic flame temperature Aviation fuel Gasoline gallon equivalent Kerosene jet fuel List of CO2 emitted per million Btu of energy from various fuels Rocket propellant RP 1 Tractor vaporising oilReferences Edit Kerosene Webster s New World College Dictionary Kerosene Oxford English Dictionary Has kerosene become a generic trademark genericides org 23 March 2020 Archived from the original on 7 February 2021 Retrieved 28 January 2021 What is Kerosene Ingoe Oils Ltd Ingoeoils co uk on 2 June 2015 Lamp oil Definition amp Meaning Dictionary com Kerosene Outboard Motors Retrieved 25 October 2011 International Energy Statistics United States Department of Energy Pennsylvania Combustible and Flammable Liquids Act Retrieved 28 April 2014 Fuel Storage Cans Getting the Color Right Horizon Distributors Irrigation amp Landscape Supply Retrieved 20 October 2020 World Health Organization 2016 Burning opportunity clean household energy for health sustainable development and wellbeing of women and children Geneva Switzerland p X Archived from the original on 24 November 2017 World Health Organization 2016 Burning opportunity clean household energy for health sustainable development and wellbeing of women and children Geneva Switzerland p 49 Archived from the original on 24 November 2017 Collins Chris 2007 Implementing Phytoremediation of Petroleum Hydrocarbons Methods in Biotechnology Humana Press 23 23 99 108 doi 10 1007 978 1 59745 098 0 8 ISBN 978 1 58829 541 5 Shepherd J E Nuyt C D Lee J J 2 March 2000 Flash Point and Chemical Composition of Aviation Kerosene Jet A PDF Graduate Aeronautical Laboratories California Institute of Technology American Institute of Petroleum September 2010 Kerosene Jet Fuel Assessment Document PDF EPA p 8 Archived from the original PDF on 28 February 2014 Retrieved 28 October 2016 Annamalai Kalyan Ishwar Kanwar Puri 2006 Combustion Science and Engineering CRC Press p 851 ISBN 978 0 8493 2071 2 1301 7 5 10 Fuel for kerosene heaters Baldwin s Ohio Monthly Record Banks Baldwin Law 2 1109 1984 8008 20 6 CAS MSDS Kerosene Melting Point Boiling Point Density CAS Chemical Properties www chemicalbook com Retrieved 28 May 2022 Kerosene Retrieved 10 June 2009 Ask com 4 August 2015 Retrieved 14 December 2015 Bilkadi Zayn The Oil Weapons Saudi Aramco World 46 1 20 27 Feng Lianyong Hu Yan Hall Charles A S Wang Jianliang 2013 The Chinese Oil Industry History and Future Springer published 28 November 2012 p 2 ISBN 978 1441994097 Chang Samuel Hsu Robinson Paul R 2006 Practical Advances in Petroleum Processing Vol 1 Springer p 2 Bibcode 2006papp book H a b Ed Butts 4 October 2019 The cautionary tale of whale oil The Globe and Mail Archived from the original on 6 October 2019 Then in 1846 a Nova Scotian physician and geologist named Abraham Gesner invented kerosene This pioneering form of fossil fuel which some called coal oil burned cleaner and brighter than whale oil and didn t have a pungent odour Samuel T Pees Whale oil versus the others Petroleum History Institute accessed 17 November 2014 a b c Russell Loris S 2003 A Heritage of Light Lamps and Lighting in the Early Canadian Home University of Toronto Press ISBN 978 0 8020 3765 7 Black Harry 1997 Canadian Scientists and Inventors Pembroke Publishers ISBN 978 1 55138 081 0 Gesner Abraham Improvement in kerosene burning fluids U S Patent no s 11 203 11 204 11 205 issued 27 June 1854 Young James Improvement in making paraffine oil U S Patent no 8 833 issued 23 March 1852 Asbury Herbert 1942 The golden flood an informal history of America s first oil field Alfred A Knopf p 35 World American Manufacturer and Iron 1901 Greater Pittsburgh and Allegheny County Past Present Future The Pioneer Oil Refiner The American Manufacturer and Iron World McInnis Karen Kier Samuel Martin Bio biography The Pennsylvania State University Archived from the original on 13 June 2010 Retrieved 12 December 2008 Harper J A 1995 Samuel Kier Medicine Man amp Refiner Pennsylvania Geology Oil Region Alliance of Business Industry amp Tourism 26 1 Archived from the original Excerpt from Yo Ho Ho and a Bottle of Unrefined Complex Liquid Hydrocarbons on 15 March 2012 Retrieved 12 December 2008 Steil Tim Luning Jim 2002 Fantastic Filling Stations MBI Publishing pp 19 20 ISBN 978 0 7603 1064 9 Paul Lucier 2008 Scientists and Swindlers Consulting on Coal and Oil in America 1820 1890 Baltimore JHU Press pp 232 233 ISBN 978 1 4214 0285 7 United States Bureau of the Census 1960 Historical Statistics of the United States Colonial Times to 1957 p 445 Harold F Williamson and others The American Petroleum Industry the Age of Energy 1899 1959 Evanston Ill Northwestern Univ Press 1963 170 172 194 204 All in one solar powered tower makes carbon neutral kerosene in the field at pilot scale Green Car Congress 21 July 2022 Retrieved 24 July 2022 Zoller Stefan Koepf Erik Nizamian Dustin Stephan Marco Patane Adriano Haueter Philipp Romero Manuel Gonzalez Aguilar Jose Lieftink Dick de Wit Ellart Brendelberger Stefan 2022 A solar tower fuel plant for the thermochemical production of kerosene from H2O and CO2 Joule 6 7 1606 1616 doi 10 1016 j joule 2022 06 012 PMC 9332358 PMID 35915707 U S Refinery Yield U S Energy Information Administration EIA Retrieved 8 August 2022 Aglionby John 17 March 2016 Lightbulb moment for M Kopa Financial Times Archived from the original on 10 December 2022 Cooley Le Roy Clark 1873 Elements of Chemistry for Common and High Schools Scribner Armstrong p 98 Crew Benjamin Johnson Ashburner Charles Albert 1887 A Practical Treatise on Petroleum Baird pp 395 This reference uses benzene in the obsolescent generic sense of a volatile hydrocarbon mixture now called benzine petroleum ether ligroin or naphtha rather than the modern meaning of benzene as the specific aromatic hydrocarbon C6H6 Bettmann Otto 1974 The Good Old Days They Were Terrible Random House p 34 ISBN 978 0 394 70941 3 Heating Your Home in Winter Kerosene Fan Heater Nagoya International Center 30 November 2011 Archived from the original on 3 August 2017 Retrieved 3 November 2016 Additives KeroKlene and Range Klene Craggs Energy 25 January 2016 Retrieved 30 May 2017 Lanstove A lamp that s also a stove Ibnlive in com 14 February 2011 Retrieved on 2 June 2015 Bradsher Keith 28 July 2008 Fuel Subsidies Overseas Take a Toll on U S New York Times Ibikun Yinka 25 July 2011 Nigeria Kerosene Too Expensive For Oil Rich Country s Poor Huffington Post Baer Frederick H December 1951 Report from abroad on kerosene fed cars Popular Science December 1951 Bonnier Corporation p 193 Bakrutan Saab 99 Petro by Petri Tyrkos n 4 2008 dead link Banse Timothy 7 July 2010 Kerosene Outboards An Alternative Fuel Marine Engine Digest a b Ebbing Darrell 3 December 2007 General Chemistry Cengage Learning pp 251 ISBN 978 1 111 80895 2 Kerosene blending pdf from EPA How a Plan for Bus Fuel Grew Expensive The New York Times 25 September 2008 a b c d Kerosene Other uses Miscellaneous Archived 29 December 2011 at the Wayback Machine Oilfielddirectory com Retrieved on 2 June 2015 S and P Block Elements Solved Problems for IIT JEE askIITians www askiitians com Oil atomisation puts a different face on iron alloy powders Metal Powder Report 59 10 26 06 2004 doi 10 1016 S0026 0657 04 00279 6 Guidance on use of rainwater tanks PDF Australian Government Department of Health March 2011 pp 22 23 ISBN 978 1 74241 325 9 Archived from the original PDF on 21 March 2019 Retrieved 16 March 2019 World Health Organization 2016 Burning opportunity clean household energy for health sustainable development and wellbeing of women and children Geneva Switzerland p X Archived from the original on 24 November 2017 World Health Organization 2016 Burning opportunity clean household energy for health sustainable development and wellbeing of women and children Geneva Switzerland p 49 Archived from the original on 24 November 2017 Levine Michael D Gresham Chip III 30 April 2009 Toxicity Hydrocarbons emedicine Retrieved 1 December 2009 Mahdi Awad Hassan 1988 Kerosene Poisoning in Children in Riyadh Journal of Tropical Pediatrics Oxford University Press 34 6 316 318 doi 10 1093 tropej 34 6 316 PMID 3221417 Radiological signs of pneumonia were shown in nine out of 27 patients who had chest X rays There was one death CDC NIOSH Pocket Guide to Chemical Hazards Kerosene www cdc gov Retrieved 6 November 2015 Notes Edit In his book of 1861 and its second edition of 1865 Gesner claimed to have demonstrated liquid kerosene an oil in 1846 during his public lectures on Prince Edward s Island Gesner Abraham 1861 A Practical Treatise on Coal Petroleum and Other Distilled Oils New York New York USA Bailliere Brothers p 9 Gesner Abraham Gesner George Weltden 1865 A Practical Treatise on Coal Petroleum and Other Distilled Oils 2nd ed New York New York USA Bailliere Brothers p 9 However John Butt characterized Gesner s book as a piece of propaganda designed to get people to believe that he had been constantly interested in inventing burning oil from 1846 to 1854 Butt also stated that No independent documentary proof has ever been produced to support Gesner s claim Furthermore He Gesner omitted to mention that kerosene had first been used to describe an illuminating gas Butt John 1963 James Young Scottish Industrialist and Philanthropist PhD thesis University of Glasgow Scotland UK p 227 As late as 1850 Gesner promoted his kerosene as an illuminating gas In his U S patent of 1850 Gesner called the product of his distillations an illuminating gas not an oil Gesner Abraham Manufacture of illuminating gas from bitumen U S Patent no 7 052 issued 29 January 1850 In his prospectus of 1850 Gesner repeatedly identified kerosene as a gas not an oil Gesner Abraham 1850 Prospectus of Gesner s patent kerosene gas obtained from bitumen asphaltum or mineral pitch New York New York USA Trehern amp Williamson External links Edit Look up kerosene in Wiktionary the free dictionary Wikimedia Commons has media related to Kerosene Kerosene Webster Online Dictionary Kerosene Fuel Primer Material Safety Data Sheet Archived 15 April 2016 at the Wayback Machine CDC NIOSH Pocket Guide to Chemical Hazards Retrieved from https en wikipedia org w index php title Kerosene amp oldid 1130479037, wikipedia, wiki, book, books, library,

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