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Diesel fuel

Diesel fuel /ˈdzəl/, also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel. Therefore, diesel fuel needs good compression ignition characteristics.

A tank of diesel fuel on a truck

The most common type of diesel fuel is a specific fractional distillate of petroleum fuel oil, but alternatives that are not derived from petroleum, such as biodiesel, biomass to liquid (BTL) or gas to liquid (GTL) diesel are increasingly being developed and adopted. To distinguish these types, petroleum-derived diesel is sometimes called petrodiesel in some academic circles.[1]

In many countries, diesel fuel is standardised. For example, in the European Union, the standard for diesel fuel is EN 590. Diesel fuel has many colloquial names; most commonly, it is simply referred to as diesel. In the United Kingdom, diesel fuel for on-road use is commonly called diesel or sometimes white diesel if required to differentiate it from a tax-advantaged agricultural-only product containing an identifying coloured dye known as red diesel. The official term for white diesel is DERV, standing for diesel-engine road vehicle.[2] In Australia, diesel fuel is also known as distillate[3] (not to be confused with "distillate" in an older sense referring to a different motor fuel), and in Indonesia, it is known as Solar, a trademarked name from the country's national petroleum company Pertamina. The term gas oil (French: gazole) is sometimes also used to refer to diesel fuel.

Ultra-low-sulfur diesel (ULSD) is a diesel fuel with substantially lowered sulfur contents. As of 2016, almost all of the petroleum-based diesel fuel available in the United Kingdom, mainland Europe, and North America is of a ULSD type.

Before diesel fuel had been standardised, the majority of diesel engines typically ran on cheap fuel oils. These fuel oils are still used in watercraft diesel engines. Despite being specifically designed for diesel engines, diesel fuel can also be used as fuel for several non-diesel engines, for example the Akroyd engine, the Stirling engine, or boilers for steam engines.

History

Origins

Diesel fuel originated from experiments conducted by German scientist and inventor Rudolf Diesel for his compression-ignition engine he invented in 1892. Originally, Diesel did not consider using any specific type of fuel, instead, he claimed that the operating principle of his rational heat motor would work with any kind of fuel in any state of matter.[4] However, both the first diesel engine prototype and the first functional Diesel engine were only designed for liquid fuels.[5]

At first, Diesel tested crude oil from Pechelbronn, but soon replaced it with petrol and kerosene, because crude oil proved to be too viscous,[6] with the main testing fuel for the Diesel engine being kerosene.[7] In addition to that, Diesel experimented with different types of lamp oil from various sources, as well as different types of petrol and ligroin, which all worked well as Diesel engine fuels. Later, Diesel tested coal tar creosote,[8] paraffin oil, crude oil, gasoil, and fuel oil, which eventually worked as well.[9] In Scotland and France, shale oil was used as fuel for the first 1898 production Diesel engines because other fuels were too expensive.[10] In 1900, the French Otto society built a Diesel engine for the use with crude oil, which was exhibited at the 1900 Paris Exposition[11] and the 1911 World's Fair in Paris.[12] The engine actually ran on peanut oil instead of crude oil, and no modifications were necessary for peanut oil operation.[11]

During his first Diesel engine tests, Diesel also used illuminating gas as fuel, and managed to build functional designs, both with and without pilot injection.[13] According to Diesel, neither was a coal-dust–producing industry existent, nor was fine, high quality coal-dust commercially available in the late 1890s. This is the reason why the Diesel engine was never designed or planned as a coal-dust engine.[14] Only in December 1899, did Diesel test a coal-dust prototype, which used external mixture formation and liquid fuel pilot injection.[15] This engine proved to be functional, but suffered from piston ring failure after a very few minutes due to coal dust deposition.[16]

Since the 20th century

Before diesel fuel had been standardised, diesel engines typically ran on cheap fuel oils. In the United States, these were distilled from petroleum, whereas in Europe, coal-tar creosote oil was used. Some diesel engines were fuelled with mixtures of several different fuels, such as petrol, kerosine, rapeseed oil, or lubricating oil, because they were untaxed and thus cheap.[17] The introduction of motor-vehicle diesel engines, such as the Mercedes-Benz OM 138, in the 1930s meant that higher quality fuels with proper ignition characteristics were needed. At first no improvements were made to motor-vehicle diesel fuel quality. After World War II, the first modern high quality diesel fuels were standardised. These standards were, for instance, the DIN 51601, VTL 9140-001, and NATO F 54 standards.[18] In 1993, the DIN 51601 was rendered obsolete by the new EN 590 standard, which has been used in the European Union ever since. In sea-going watercraft, where diesel propulsion had gained prevalence by the late 1970s due to increasing fuel costs caused by the 1970s energy crisis, cheap heavy fuel oils are still used instead of conventional motor-vehicle diesel fuel. These heavy fuel oils (often called Bunker C) can be used in diesel-powered and steam-powered vessels.[19]

Types

Diesel fuel is produced from various sources, the most common being petroleum. Other sources include biomass, animal fat, biogas, natural gas, and coal liquefaction.

Petroleum diesel

 
A modern diesel dispenser

Petroleum diesel, also called petrodiesel,[20] fossil diesel, or mineral diesel, is the most common type of diesel fuel. It is produced from the fractional distillation of crude oil between 200 and 350 °C (392 and 662 °F) at atmospheric pressure, resulting in a mixture of carbon chains that typically contain between 9 and 25 carbon atoms per molecule.[21]

Synthetic diesel

Synthetic diesel can be produced from any carbonaceous material, including biomass, biogas, natural gas, coal and many others. The raw material is gasified into synthesis gas, which after purification is converted by the Fischer–Tropsch process to a synthetic diesel.[22]

The process is typically referred to as biomass-to-liquid (BTL), gas-to-liquid (GTL) or coal-to-liquid (CTL), depending on the raw material used.

Paraffinic synthetic diesel generally has a near-zero content of sulfur and very low aromatics content, reducing unregulated emissions[clarification needed] of toxic hydrocarbons, nitrous oxides[clarification needed] and particulate matter (PM).[23]

Biodiesel

 

Biodiesel is obtained from vegetable oil or animal fats (biolipids) which are mainly fatty acid methyl esters (FAME), and transesterified with methanol. It can be produced from many types of oils, the most common being rapeseed oil (rapeseed methyl ester, RME) in Europe and soybean oil (soy methyl ester, SME) in the US. Methanol can also be replaced with ethanol for the transesterification process, which results in the production of ethyl esters. The transesterification processes use catalysts, such as sodium or potassium hydroxide, to convert vegetable oil and methanol into biodiesel and the undesirable byproducts glycerine and water, which will need to be removed from the fuel along with methanol traces. Biodiesel can be used pure (B100) in engines where the manufacturer approves such use, but it is more often used as a mix with diesel, BXX where XX is the biodiesel content in percent.[24][25]

FAME used as fuel is specified in DIN EN 14214[26] and ASTM D6751 standards.[27]

Fuel Injection Equipment (FIE) manufacturers have raised several concerns regarding biodiesel, identifying FAME as being the cause of the following problems: corrosion of fuel injection components, low-pressure fuel system blockage, increased dilution and polymerization of engine sump oil, pump seizures due to high fuel viscosity at low temperature, increased injection pressure, elastomeric seal failures and fuel injector spray blockage.[28] Pure biodiesel has an energy content about 5–10% lower than petroleum diesel.[29] The loss in power when using pure biodiesel is 5–7%.[25]

Unsaturated fatty acids are the source for the lower oxidation stability. They react with oxygen and form peroxides and result in degradation byproducts, which can cause sludge and lacquer in the fuel system.[30]

As biodiesel contains low levels of sulfur, the emissions of sulfur oxides and sulfates, major components of acid rain, are low. Use of biodiesel also results in reductions of unburned hydrocarbons, carbon monoxide (CO), and particulate matter. CO emissions using biodiesel are substantially reduced, on the order of 50% compared to most petrodiesel fuels. The exhaust emissions of particulate matter from biodiesel have been found to be 30% lower than overall particulate matter emissions from petrodiesel. The exhaust emissions of total hydrocarbons (a contributing factor in the localized formation of smog and ozone) are up to 93% lower for biodiesel than diesel fuel.

Biodiesel also may reduce health risks associated with petroleum diesel. Biodiesel emissions showed decreased levels of polycyclic aromatic hydrocarbon (PAH) and nitrated PAH compounds, which have been identified as potential carcinogens. In recent testing, PAH compounds were reduced by 75–85%, except for benz(a)anthracene, which was reduced by roughly 50%. Targeted nPAH compounds were also reduced dramatically with biodiesel fuel, with 2-nitrofluorene and 1-nitropyrene reduced by 90%, and the rest of the nPAH compounds reduced to only trace levels.[31]

Hydrogenated oils and fats

This category of diesel fuels involves converting the triglycerides in vegetable oil and animal fats into alkanes by refining and hydrogenation, such as Neste Renewable Diesel or H-Bio. The produced fuel has many properties that are similar to synthetic diesel, and are free from the many disadvantages of FAME.

DME

Dimethyl ether, DME, is a synthetic, gaseous diesel fuel that results in clean combustion with very little soot and reduced NOx emissions.[24]

Storage

 
Large diesel fuel tanks in Sörnäinen, Helsinki, Finland

In the US, diesel is recommended to be stored in a yellow container to differentiate it from kerosene, which is typically kept in blue containers, and gasoline (petrol), which is typically kept in red containers.[32] In the UK, diesel is normally stored in a black container to differentiate it from unleaded or leaded petrol, which are stored in green and red containers, respectively.[33]

Standards

The diesel engine is a multifuel engine and can run on a huge variety of fuels. However, development of high-performance, high-speed diesel engines for cars and lorries in the 1930s meant that a proper fuel specifically designed for such engines was needed: diesel fuel. In order to ensure consistent quality, diesel fuel is standardised; the first standards were introduced after World War II.[18] Typically, a standard defines certain properties of the fuel, such as cetane number, density, flash point, sulphur content, or biodiesel content. Diesel fuel standards include:

Diesel fuel

  • EN 590 (European Union)
  • ASTM D975 (United States)
  • GOST R 52368 (Russia; equivalent to EN 590)
  • NATO F 54 (NATO; equivalent to EN 590)
  • DIN 51601 (West Germany; obsolete)

Biodiesel fuel

  • EN 14214 (European Union)
  • ASTM D6751 (United States)
  • CAN/CGSB-3.524 (Canada)

Measurements and pricing

Cetane number

The principal measure of diesel fuel quality is its cetane number. A cetane number is a measure of the delay of ignition of a diesel fuel.[34] A higher cetane number indicates that the fuel ignites more readily when sprayed into hot compressed air.[34] European (EN 590 standard) road diesel has a minimum cetane number of 51. Fuels with higher cetane numbers, normally "premium" diesel fuels with additional cleaning agents and some synthetic content, are available in some markets.

Fuel value and price

About 86.1% of diesel fuel mass is carbon, and when burned, it offers a net heating value of 43.1 MJ/kg as opposed to 43.2 MJ/kg for gasoline. Due to the higher density, diesel fuel offers a higher volumetric energy density: the density of EN 590 diesel fuel is defined as 0.820 to 0.845 kg/L (6.84 to 7.05 lb/US gal) at 15 °C (59 °F), about 9.0-13.9% more than EN 228 gasoline (petrol)'s 0.720–0.775 kg/L (6.01–6.47 lb/US gal) at 15 °C, which should be put into consideration when comparing volumetric fuel prices. The CO2 emissions from diesel are 73.25 g/MJ, just slightly lower than for gasoline at 73.38 g/MJ.[35]

Diesel fuel is generally simpler to refine from petroleum than gasoline, and contains hydrocarbons having a boiling point in the range of 180–360 °C (356–680 °F). Additional refining is required to remove sulfur, which contributes to a sometimes higher cost. In many parts of the United States and throughout the United Kingdom and Australia,[36] diesel fuel may be priced higher than petrol per gallon or litre.[37][38] Reasons for higher-priced diesel include the shutdown of some refineries in the Gulf of Mexico, diversion of mass refining capacity to gasoline production, and a recent transfer to ultra-low-sulfur diesel (ULSD), which causes infrastructural complications.[39] In Sweden, a diesel fuel designated as MK-1 (class 1 environmental diesel) is also being sold. This is a ULSD that also has a lower aromatics content, with a limit of 5%.[40] This fuel is slightly more expensive to produce than regular ULSD. In Germany, the fuel tax on diesel fuel is about 28% lower than the petrol fuel tax.

Taxation

Diesel fuel is similar to heating oil, which is used in central heating. In Europe, the United States, and Canada, taxes on diesel fuel are higher than on heating oil due to the fuel tax, and in those areas, heating oil is marked with fuel dyes and trace chemicals to prevent and detect tax fraud. "Untaxed" diesel (sometimes called "off-road diesel" or "red diesel" due to its red dye) is available in some countries for use primarily in agricultural applications, such as fuel for tractors, recreational and utility vehicles or other noncommercial vehicles that do not use public roads. This fuel may have sulfur levels that exceed the limits for road use in some countries (e.g. US).

This untaxed diesel is dyed red for identification,[41] and using this untaxed diesel fuel for a typically taxed purpose (such as driving use), the user can be fined (e.g. US$10,000 in the US). In the United Kingdom, Belgium and the Netherlands, it is known as red diesel (or gas oil), and is also used in agricultural vehicles, home heating tanks, refrigeration units on vans/trucks which contain perishable items such as food and medicine and for marine craft. Diesel fuel, or marked gas oil is dyed green in the Republic of Ireland and Norway. The term "diesel-engined road vehicle" (DERV) is used in the UK as a synonym for unmarked road diesel fuel. In India, taxes on diesel fuel are lower than on petrol, as the majority of the transportation for grain and other essential commodities across the country runs on diesel.

Taxes on biodiesel in the US vary between states. Some states (Texas, for example) have no tax on biodiesel and a reduced tax on biodiesel blends equivalent to the amount of biodiesel in the blend, so that B20 fuel is taxed 20% less than pure petrodiesel.[42] Other states, such as North Carolina, tax biodiesel (in any blended configuration) the same as petrodiesel, although they have introduced new incentives to producers and users of all biofuels.[43]

Uses

Diesel fuel is mostly used in high-speed diesel engines, especially motor-vehicle (e.g. car, lorry) diesel engines, but not all diesel engines run on diesel fuel. For example, large two-stroke watercraft engines typically use heavy fuel oils instead of diesel fuel,[19] and certain types of diesel engines, such as MAN M-System engines, are designed to run on petrol with knock resistances of up to 86 RON.[44] On the other hand, gas turbine and some other types of internal combustion engines, and external combustion engines, can also be designed to take diesel fuel.

The viscosity requirement of diesel fuel is usually specified at 40 °C.[34] A disadvantage of diesel fuel in cold climates is that its viscosity increases as the temperature decreases, changing it into a gel (see Compression Ignition – Gelling) that cannot flow in fuel systems. Special low-temperature diesel contains additives to keep it liquid at lower temperatures.

On-road vehicles

Trucks and buses, which were often otto-powered in the 1920s through 1950s, are now almost exclusively diesel-powered. Due to its ignition characteristics, diesel fuel is thus widely used in these vehicles. Since diesel fuel is not well-suited for otto engines, passenger cars, which often use otto or otto-derived engines, typically run on petrol instead of diesel fuel. However, especially in Europe and India, many passenger cars have, due to better engine efficiency,[45] diesel engines, and thus run on regular diesel fuel.

Railroad

Diesel displaced coal and fuel oil for steam-powered vehicles in the latter half of the 20th century, and is now used almost exclusively for the combustion engines of self-powered rail vehicles (locomotives and railcars).[46][47]

Aircraft

 
Packard DR-980 9-cylinder diesel aircraft engine, used in the first diesel-engine airplane

In general, diesel engines are not well-suited for planes and helicopters. This is because of the diesel engine's comparatively low power-to-mass ratio, meaning that diesel engines are typically rather heavy, which is a disadvantage in aircraft. Therefore, there is little need for using diesel fuel in aircraft, and diesel fuel is not commercially used as aviation fuel. Instead, petrol (Avgas), and jet fuel (e. g. Jet A-1) are used. However, especially in the 1920s and 1930s, numerous series-production aircraft diesel engines that ran on fuel oils were made, because they had several advantages: their fuel consumption was low, they were reliable, not prone to catching fire, and required minimal maintenance. The introduction of petrol direct injection in the 1930s outweighed these advantages, and aircraft diesel engines quickly fell out of use.[48] With improvements in power-to-mass ratios of diesel engines, several on-road diesel engines have been converted to and certified for aircraft use since the early 21st century. These engines typically run on Jet A-1 aircraft fuel (but can also run on diesel fuel). Jet A-1 has ignition characteristics similar to diesel fuel, and is thus suited for certain (but not all) diesel engines.[49]

Military vehicles

Until World War II, several military vehicles, especially those that required high engine performance (armored fighting vehicles, for example the M26 Pershing or Panther tanks), used conventional otto engines and ran on petrol. Ever since World War II, several military vehicles with diesel engines have been made, capable of running on diesel fuel. This is because diesel engines are more fuel efficient, and diesel fuel is less prone to catching fire.[50] Some of these diesel-powered vehicles (such as the Leopard 1 or MAN 630) still ran on petrol, and some military vehicles were still made with otto engines (e. g. Ural-375 or Unimog 404), incapable of running on diesel fuel.

Tractors and heavy equipment

Today's tractors and heavy equipment are mostly diesel-powered. Among tractors, only the smaller classes may also offer gasoline-fuelled engines. The dieselization of tractors and heavy equipment began in Germany before World War II but was unusual in the United States until after that war. During the 1950s and 1960s, it progressed in the US as well. Diesel fuel is commonly used in oil and gas extracting equipment, although some locales use electric or natural gas powered equipment.

Tractors and heavy equipment were often multifuel in the 1920s through 1940s, running either spark-ignition and low-compression engines, akryod engines, or diesel engines. Thus many farm tractors of the era could burn gasoline, alcohol, kerosene, and any light grade of fuel oil such as heating oil, or tractor vaporising oil, according to whichever was most affordable in a region at any given time. On US farms during this era, the name "distillate" often referred to any of the aforementioned light fuel oils. Spark ignition engines did not start as well on distillate, so typically a small auxiliary gasoline tank was used for cold starting, and the fuel valves were adjusted several minutes later, after warm-up, to transition to distillate. Engine accessories such as vaporizers and radiator shrouds were also used, both with the aim of capturing heat, because when such an engine was run on distillate, it ran better when both it and the air it inhaled were warmer rather than at ambient temperature. Dieselization with dedicated diesel engines (high-compression with mechanical fuel injection and compression ignition) replaced such systems and made more efficient use of the diesel fuel being burned.

Other uses

Poor quality diesel fuel has been used as an extraction agent for liquid–liquid extraction of palladium from nitric acid mixtures.[51] Such use has been proposed as a means of separating the fission product palladium from PUREX raffinate which comes from used nuclear fuel.[51] In this system of solvent extraction, the hydrocarbons of the diesel act as the diluent while the dialkyl sulfides act as the extractant.[51] This extraction operates by a solvation mechanism.[51] So far, neither a pilot plant nor full scale plant has been constructed to recover palladium, rhodium or ruthenium from nuclear wastes created by the use of nuclear fuel.[52]

Diesel fuel is often used as the main ingredient in oil-base mud drilling fluid.[53] The advantage of using diesel is its low cost and its ability to drill a wide variety of difficult strata, including shale, salt and gypsum formations.[53] Diesel-oil mud is typically mixed with up to 40% brine water.[54] Due to health, safety and environmental concerns, Diesel-oil mud is often replaced with vegetable, mineral, or synthetic food-grade oil-base drilling fluids, although diesel-oil mud is still in widespread use in certain regions.[55]

During development of rocket engines in Germany during World War II J-2 Diesel fuel was used as the fuel component in several engines including the BMW 109-718.[56] J-2 diesel fuel was also used as a fuel for gas turbine engines.[56]

Chemical analysis

Chemical composition

 
Diesel does not mix with water. This picture also showcases the phenomenon of Thin-film interference.

In the United States, petroleum-derived diesel is composed of about 75% saturated hydrocarbons (primarily paraffins including n, iso, and cycloparaffins), and 25% aromatic hydrocarbons (including naphthalenes and alkylbenzenes).[57] The average chemical formula for common diesel fuel is C12H23, ranging approximately from C10H20 to C15H28.[58]

Chemical properties

Most diesel fuels freeze at common winter temperatures, while the temperatures greatly vary.[59] Petrodiesel typically freezes around temperatures of −8.1 °C (17.5 °F), whereas biodiesel freezes between temperatures of 2° to 15 °C (35° to 60 °F).[59] The viscosity of diesel noticeably increases as the temperature decreases, changing it into a gel at temperatures of −19 °C (−2.2 °F) to −15 °C (5 °F), that cannot flow in fuel systems. Conventional diesel fuels vaporise at temperatures between 149 °C and 371 °C.[34]

Conventional diesel flash points vary between 52 and 96 °C, which makes it safer than petrol and unsuitable for spark-ignition engines.[60] Unlike petrol, the flash point of a diesel fuel has no relation to its performance in an engine nor to its auto ignition qualities.[34]

Carbon dioxide formation

As a good approximation the chemical formula of diesel is C
n
H
2n
. Note that diesel is a mixture of different molecules. As carbon has a molar mass of 12 g/mol and hydrogen has a molar mass of about 1 g/mol, so the fraction by weight of carbon in EN 590 diesel fuel is roughly 12/14.

The reaction of diesel combustion is given by:

2C
n
H
2n
+ 3nO
2
⇌ 2nCO
2
+ 2nH
2
O

Carbon dioxide has a molar mass of 44g/mol as it consists of 2 atoms of oxygen (16 g/mol) and 1 atom of carbon (12 g/mol). So 12 g of carbon yield 44 g of Carbon dioxide.

Diesel has a density of 0.838 kg per liter.

Putting everything together the mass of carbon dioxide that is produced by burning 1 liter of diesel fuel can be calculated as:

 

The figure obtained with this estimation is close to the values found in the literature.

For gasoline, with a density of 0.75 kg/L and a ratio of carbon to hydrogen atoms of about 6 to 14, the estimated value of carbon emission if 1 liter of gasoline is burnt gives:

 

Source[61]

Hazards

Environment hazards of sulfur

In the past, diesel fuel contained higher quantities of sulfur. European emission standards and preferential taxation have forced oil refineries to dramatically reduce the level of sulfur in diesel fuels. In the European Union, the sulfur content has dramatically reduced during the last 20 years. Automotive diesel fuel is covered in the European Union by standard EN 590. In the 1990s specifications allowed a content of 2000 ppm max of sulfur, reduced to a limit of 350 ppm by the beginning of the 21st century with the introduction of Euro 3 specifications. The limit was lowered with the introduction of Euro 4 by 2006 to 50 ppm (ULSD, Ultra Low Sulfur Diesel). The standard for diesel fuel in force in Europe as of 2009 is the Euro 5, with a maximum content of 10 ppm.[62]

Emission standard At latest Sulfur content Cetane number
N/a 1 January 1994 max. 2000 ppm min. 49
Euro 2 1 January 1996 max. 500 ppm min. 49
Euro 3 1 January 2001 max. 350 ppm min. 51
Euro 4 1 January 2006 max. 50 ppm min. 51
Euro 5 1 January 2009 max. 10 ppm min. 51

In the United States, more stringent emission standards have been adopted with the transition to ULSD starting in 2006, and becoming mandatory on June 1, 2010 (see also diesel exhaust).

Algae, microbes, and water contamination

There has been much discussion and misunderstanding of algae in diesel fuel. Algae need light to live and grow. As there is no sunlight in a closed fuel tank, no algae can survive, but some microbes can survive and feed on the diesel fuel.[63]

These microbes form a colony that lives at the interface of fuel and water. They grow quite fast in warmer temperatures. They can even grow in cold weather when fuel tank heaters are installed. Parts of the colony can break off and clog the fuel lines and fuel filters.[64]

Water in fuel can damage a fuel injection pump. Some diesel fuel filters also trap water. Water contamination in diesel fuel can lead to freezing while in the fuel tank. The freezing water that saturates the fuel will sometimes clog the fuel injector pump.[65] Once the water inside the fuel tank has started to freeze, gelling is more likely to occur. When the fuel is gelled it is not effective until the temperature is raised and the fuel returns to a liquid state.

Road hazard

Diesel is less flammable than gasoline / petrol. However, because it evaporates slowly, any spills on a roadway can pose a slip hazard to vehicles.[66] After the light fractions have evaporated, a greasy slick is left on the road which reduces tire grip and traction, and can cause vehicles to skid. The loss of traction is similar to that encountered on black ice, resulting in especially dangerous situations for two-wheeled vehicles, such as motorcycles and bicycles, in roundabouts.

See also

References

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Further reading

  • L. D. Danny Harvey, 2010, "Energy and the New Reality 1: Energy Efficiency and the Demand for Energy Services," London:Routledge-Earthscan, ISBN 1-84407-912-0, 672 pp.; see [3], accessed 28 September 2014.

External links

  • U.S. Department of Labor Occupational Safety & Health Administration: Safety and Health Topics: Diesel Exhaust

diesel, fuel, redirects, here, other, classes, fuel, fuel, diesel, redirects, here, confused, with, lubricating, diesel, engines, also, called, diesel, liquid, fuel, specifically, designed, diesel, engine, type, internal, combustion, engine, which, fuel, ignit. Gas oil redirects here For gas oil as other classes of fuel oil see Fuel oil Diesel oil redirects here Not to be confused with lubricating oil for diesel engines Diesel fuel ˈ d iː z el also called diesel oil is any liquid fuel specifically designed for use in a diesel engine a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel Therefore diesel fuel needs good compression ignition characteristics A tank of diesel fuel on a truck The most common type of diesel fuel is a specific fractional distillate of petroleum fuel oil but alternatives that are not derived from petroleum such as biodiesel biomass to liquid BTL or gas to liquid GTL diesel are increasingly being developed and adopted To distinguish these types petroleum derived diesel is sometimes called petrodiesel in some academic circles 1 In many countries diesel fuel is standardised For example in the European Union the standard for diesel fuel is EN 590 Diesel fuel has many colloquial names most commonly it is simply referred to as diesel In the United Kingdom diesel fuel for on road use is commonly called diesel or sometimes white diesel if required to differentiate it from a tax advantaged agricultural only product containing an identifying coloured dye known as red diesel The official term for white diesel is DERV standing for diesel engine road vehicle 2 In Australia diesel fuel is also known as distillate 3 not to be confused with distillate in an older sense referring to a different motor fuel and in Indonesia it is known as Solar a trademarked name from the country s national petroleum company Pertamina The term gas oil French gazole is sometimes also used to refer to diesel fuel Ultra low sulfur diesel ULSD is a diesel fuel with substantially lowered sulfur contents As of 2016 almost all of the petroleum based diesel fuel available in the United Kingdom mainland Europe and North America is of a ULSD type Before diesel fuel had been standardised the majority of diesel engines typically ran on cheap fuel oils These fuel oils are still used in watercraft diesel engines Despite being specifically designed for diesel engines diesel fuel can also be used as fuel for several non diesel engines for example the Akroyd engine the Stirling engine or boilers for steam engines Contents 1 History 1 1 Origins 1 2 Since the 20th century 2 Types 2 1 Petroleum diesel 2 2 Synthetic diesel 2 3 Biodiesel 2 4 Hydrogenated oils and fats 2 5 DME 3 Storage 4 Standards 5 Measurements and pricing 5 1 Cetane number 5 2 Fuel value and price 5 3 Taxation 6 Uses 6 1 On road vehicles 6 2 Railroad 6 3 Aircraft 6 4 Military vehicles 6 5 Tractors and heavy equipment 6 6 Other uses 7 Chemical analysis 7 1 Chemical composition 7 2 Chemical properties 8 Carbon dioxide formation 9 Hazards 9 1 Environment hazards of sulfur 9 2 Algae microbes and water contamination 9 3 Road hazard 10 See also 11 References 12 Further reading 13 External linksHistory EditOrigins Edit Diesel fuel originated from experiments conducted by German scientist and inventor Rudolf Diesel for his compression ignition engine he invented in 1892 Originally Diesel did not consider using any specific type of fuel instead he claimed that the operating principle of his rational heat motor would work with any kind of fuel in any state of matter 4 However both the first diesel engine prototype and the first functional Diesel engine were only designed for liquid fuels 5 At first Diesel tested crude oil from Pechelbronn but soon replaced it with petrol and kerosene because crude oil proved to be too viscous 6 with the main testing fuel for the Diesel engine being kerosene 7 In addition to that Diesel experimented with different types of lamp oil from various sources as well as different types of petrol and ligroin which all worked well as Diesel engine fuels Later Diesel tested coal tar creosote 8 paraffin oil crude oil gasoil and fuel oil which eventually worked as well 9 In Scotland and France shale oil was used as fuel for the first 1898 production Diesel engines because other fuels were too expensive 10 In 1900 the French Otto society built a Diesel engine for the use with crude oil which was exhibited at the 1900 Paris Exposition 11 and the 1911 World s Fair in Paris 12 The engine actually ran on peanut oil instead of crude oil and no modifications were necessary for peanut oil operation 11 During his first Diesel engine tests Diesel also used illuminating gas as fuel and managed to build functional designs both with and without pilot injection 13 According to Diesel neither was a coal dust producing industry existent nor was fine high quality coal dust commercially available in the late 1890s This is the reason why the Diesel engine was never designed or planned as a coal dust engine 14 Only in December 1899 did Diesel test a coal dust prototype which used external mixture formation and liquid fuel pilot injection 15 This engine proved to be functional but suffered from piston ring failure after a very few minutes due to coal dust deposition 16 Since the 20th century Edit Before diesel fuel had been standardised diesel engines typically ran on cheap fuel oils In the United States these were distilled from petroleum whereas in Europe coal tar creosote oil was used Some diesel engines were fuelled with mixtures of several different fuels such as petrol kerosine rapeseed oil or lubricating oil because they were untaxed and thus cheap 17 The introduction of motor vehicle diesel engines such as the Mercedes Benz OM 138 in the 1930s meant that higher quality fuels with proper ignition characteristics were needed At first no improvements were made to motor vehicle diesel fuel quality After World War II the first modern high quality diesel fuels were standardised These standards were for instance the DIN 51601 VTL 9140 001 and NATO F 54 standards 18 In 1993 the DIN 51601 was rendered obsolete by the new EN 590 standard which has been used in the European Union ever since In sea going watercraft where diesel propulsion had gained prevalence by the late 1970s due to increasing fuel costs caused by the 1970s energy crisis cheap heavy fuel oils are still used instead of conventional motor vehicle diesel fuel These heavy fuel oils often called Bunker C can be used in diesel powered and steam powered vessels 19 Types EditDiesel fuel is produced from various sources the most common being petroleum Other sources include biomass animal fat biogas natural gas and coal liquefaction Petroleum diesel Edit A modern diesel dispenser Petroleum diesel also called petrodiesel 20 fossil diesel or mineral diesel is the most common type of diesel fuel It is produced from the fractional distillation of crude oil between 200 and 350 C 392 and 662 F at atmospheric pressure resulting in a mixture of carbon chains that typically contain between 9 and 25 carbon atoms per molecule 21 Synthetic diesel Edit Main article Synthetic fuel See also Electrofuel Synthetic diesel can be produced from any carbonaceous material including biomass biogas natural gas coal and many others The raw material is gasified into synthesis gas which after purification is converted by the Fischer Tropsch process to a synthetic diesel 22 The process is typically referred to as biomass to liquid BTL gas to liquid GTL or coal to liquid CTL depending on the raw material used Paraffinic synthetic diesel generally has a near zero content of sulfur and very low aromatics content reducing unregulated emissions clarification needed of toxic hydrocarbons nitrous oxides clarification needed and particulate matter PM 23 Biodiesel Edit Main article Biodiesel Biodiesel made from soybean oil Biodiesel is obtained from vegetable oil or animal fats biolipids which are mainly fatty acid methyl esters FAME and transesterified with methanol It can be produced from many types of oils the most common being rapeseed oil rapeseed methyl ester RME in Europe and soybean oil soy methyl ester SME in the US Methanol can also be replaced with ethanol for the transesterification process which results in the production of ethyl esters The transesterification processes use catalysts such as sodium or potassium hydroxide to convert vegetable oil and methanol into biodiesel and the undesirable byproducts glycerine and water which will need to be removed from the fuel along with methanol traces Biodiesel can be used pure B100 in engines where the manufacturer approves such use but it is more often used as a mix with diesel BXX where XX is the biodiesel content in percent 24 25 FAME used as fuel is specified in DIN EN 14214 26 and ASTM D6751 standards 27 Fuel Injection Equipment FIE manufacturers have raised several concerns regarding biodiesel identifying FAME as being the cause of the following problems corrosion of fuel injection components low pressure fuel system blockage increased dilution and polymerization of engine sump oil pump seizures due to high fuel viscosity at low temperature increased injection pressure elastomeric seal failures and fuel injector spray blockage 28 Pure biodiesel has an energy content about 5 10 lower than petroleum diesel 29 The loss in power when using pure biodiesel is 5 7 25 Unsaturated fatty acids are the source for the lower oxidation stability They react with oxygen and form peroxides and result in degradation byproducts which can cause sludge and lacquer in the fuel system 30 As biodiesel contains low levels of sulfur the emissions of sulfur oxides and sulfates major components of acid rain are low Use of biodiesel also results in reductions of unburned hydrocarbons carbon monoxide CO and particulate matter CO emissions using biodiesel are substantially reduced on the order of 50 compared to most petrodiesel fuels The exhaust emissions of particulate matter from biodiesel have been found to be 30 lower than overall particulate matter emissions from petrodiesel The exhaust emissions of total hydrocarbons a contributing factor in the localized formation of smog and ozone are up to 93 lower for biodiesel than diesel fuel Biodiesel also may reduce health risks associated with petroleum diesel Biodiesel emissions showed decreased levels of polycyclic aromatic hydrocarbon PAH and nitrated PAH compounds which have been identified as potential carcinogens In recent testing PAH compounds were reduced by 75 85 except for benz a anthracene which was reduced by roughly 50 Targeted nPAH compounds were also reduced dramatically with biodiesel fuel with 2 nitrofluorene and 1 nitropyrene reduced by 90 and the rest of the nPAH compounds reduced to only trace levels 31 Hydrogenated oils and fats Edit This category of diesel fuels involves converting the triglycerides in vegetable oil and animal fats into alkanes by refining and hydrogenation such as Neste Renewable Diesel or H Bio The produced fuel has many properties that are similar to synthetic diesel and are free from the many disadvantages of FAME DME Edit Dimethyl ether DME is a synthetic gaseous diesel fuel that results in clean combustion with very little soot and reduced NOx emissions 24 Storage Edit Large diesel fuel tanks in Sornainen Helsinki Finland In the US diesel is recommended to be stored in a yellow container to differentiate it from kerosene which is typically kept in blue containers and gasoline petrol which is typically kept in red containers 32 In the UK diesel is normally stored in a black container to differentiate it from unleaded or leaded petrol which are stored in green and red containers respectively 33 Standards EditThe diesel engine is a multifuel engine and can run on a huge variety of fuels However development of high performance high speed diesel engines for cars and lorries in the 1930s meant that a proper fuel specifically designed for such engines was needed diesel fuel In order to ensure consistent quality diesel fuel is standardised the first standards were introduced after World War II 18 Typically a standard defines certain properties of the fuel such as cetane number density flash point sulphur content or biodiesel content Diesel fuel standards include Diesel fuel EN 590 European Union ASTM D975 United States GOST R 52368 Russia equivalent to EN 590 NATO F 54 NATO equivalent to EN 590 DIN 51601 West Germany obsolete Biodiesel fuel EN 14214 European Union ASTM D6751 United States CAN CGSB 3 524 Canada Measurements and pricing EditCetane number Edit Main article Cetane number The principal measure of diesel fuel quality is its cetane number A cetane number is a measure of the delay of ignition of a diesel fuel 34 A higher cetane number indicates that the fuel ignites more readily when sprayed into hot compressed air 34 European EN 590 standard road diesel has a minimum cetane number of 51 Fuels with higher cetane numbers normally premium diesel fuels with additional cleaning agents and some synthetic content are available in some markets Fuel value and price Edit Further information Gasoline and diesel usage and pricing About 86 1 of diesel fuel mass is carbon and when burned it offers a net heating value of 43 1 MJ kg as opposed to 43 2 MJ kg for gasoline Due to the higher density diesel fuel offers a higher volumetric energy density the density of EN 590 diesel fuel is defined as 0 820 to 0 845 kg L 6 84 to 7 05 lb US gal at 15 C 59 F about 9 0 13 9 more than EN 228 gasoline petrol s 0 720 0 775 kg L 6 01 6 47 lb US gal at 15 C which should be put into consideration when comparing volumetric fuel prices The CO2 emissions from diesel are 73 25 g MJ just slightly lower than for gasoline at 73 38 g MJ 35 Diesel fuel is generally simpler to refine from petroleum than gasoline and contains hydrocarbons having a boiling point in the range of 180 360 C 356 680 F Additional refining is required to remove sulfur which contributes to a sometimes higher cost In many parts of the United States and throughout the United Kingdom and Australia 36 diesel fuel may be priced higher than petrol per gallon or litre 37 38 Reasons for higher priced diesel include the shutdown of some refineries in the Gulf of Mexico diversion of mass refining capacity to gasoline production and a recent transfer to ultra low sulfur diesel ULSD which causes infrastructural complications 39 In Sweden a diesel fuel designated as MK 1 class 1 environmental diesel is also being sold This is a ULSD that also has a lower aromatics content with a limit of 5 40 This fuel is slightly more expensive to produce than regular ULSD In Germany the fuel tax on diesel fuel is about 28 lower than the petrol fuel tax Taxation Edit Diesel fuel is similar to heating oil which is used in central heating In Europe the United States and Canada taxes on diesel fuel are higher than on heating oil due to the fuel tax and in those areas heating oil is marked with fuel dyes and trace chemicals to prevent and detect tax fraud Untaxed diesel sometimes called off road diesel or red diesel due to its red dye is available in some countries for use primarily in agricultural applications such as fuel for tractors recreational and utility vehicles or other noncommercial vehicles that do not use public roads This fuel may have sulfur levels that exceed the limits for road use in some countries e g US This untaxed diesel is dyed red for identification 41 and using this untaxed diesel fuel for a typically taxed purpose such as driving use the user can be fined e g US 10 000 in the US In the United Kingdom Belgium and the Netherlands it is known as red diesel or gas oil and is also used in agricultural vehicles home heating tanks refrigeration units on vans trucks which contain perishable items such as food and medicine and for marine craft Diesel fuel or marked gas oil is dyed green in the Republic of Ireland and Norway The term diesel engined road vehicle DERV is used in the UK as a synonym for unmarked road diesel fuel In India taxes on diesel fuel are lower than on petrol as the majority of the transportation for grain and other essential commodities across the country runs on diesel Taxes on biodiesel in the US vary between states Some states Texas for example have no tax on biodiesel and a reduced tax on biodiesel blends equivalent to the amount of biodiesel in the blend so that B20 fuel is taxed 20 less than pure petrodiesel 42 Other states such as North Carolina tax biodiesel in any blended configuration the same as petrodiesel although they have introduced new incentives to producers and users of all biofuels 43 Uses EditDiesel fuel is mostly used in high speed diesel engines especially motor vehicle e g car lorry diesel engines but not all diesel engines run on diesel fuel For example large two stroke watercraft engines typically use heavy fuel oils instead of diesel fuel 19 and certain types of diesel engines such as MAN M System engines are designed to run on petrol with knock resistances of up to 86 RON 44 On the other hand gas turbine and some other types of internal combustion engines and external combustion engines can also be designed to take diesel fuel The viscosity requirement of diesel fuel is usually specified at 40 C 34 A disadvantage of diesel fuel in cold climates is that its viscosity increases as the temperature decreases changing it into a gel see Compression Ignition Gelling that cannot flow in fuel systems Special low temperature diesel contains additives to keep it liquid at lower temperatures On road vehicles Edit Trucks and buses which were often otto powered in the 1920s through 1950s are now almost exclusively diesel powered Due to its ignition characteristics diesel fuel is thus widely used in these vehicles Since diesel fuel is not well suited for otto engines passenger cars which often use otto or otto derived engines typically run on petrol instead of diesel fuel However especially in Europe and India many passenger cars have due to better engine efficiency 45 diesel engines and thus run on regular diesel fuel Railroad Edit See also Dieselization and Diesel locomotive Diesel displaced coal and fuel oil for steam powered vehicles in the latter half of the 20th century and is now used almost exclusively for the combustion engines of self powered rail vehicles locomotives and railcars 46 47 Aircraft Edit Packard DR 980 9 cylinder diesel aircraft engine used in the first diesel engine airplane In general diesel engines are not well suited for planes and helicopters This is because of the diesel engine s comparatively low power to mass ratio meaning that diesel engines are typically rather heavy which is a disadvantage in aircraft Therefore there is little need for using diesel fuel in aircraft and diesel fuel is not commercially used as aviation fuel Instead petrol Avgas and jet fuel e g Jet A 1 are used However especially in the 1920s and 1930s numerous series production aircraft diesel engines that ran on fuel oils were made because they had several advantages their fuel consumption was low they were reliable not prone to catching fire and required minimal maintenance The introduction of petrol direct injection in the 1930s outweighed these advantages and aircraft diesel engines quickly fell out of use 48 With improvements in power to mass ratios of diesel engines several on road diesel engines have been converted to and certified for aircraft use since the early 21st century These engines typically run on Jet A 1 aircraft fuel but can also run on diesel fuel Jet A 1 has ignition characteristics similar to diesel fuel and is thus suited for certain but not all diesel engines 49 Military vehicles Edit Until World War II several military vehicles especially those that required high engine performance armored fighting vehicles for example the M26 Pershing or Panther tanks used conventional otto engines and ran on petrol Ever since World War II several military vehicles with diesel engines have been made capable of running on diesel fuel This is because diesel engines are more fuel efficient and diesel fuel is less prone to catching fire 50 Some of these diesel powered vehicles such as the Leopard 1 or MAN 630 still ran on petrol and some military vehicles were still made with otto engines e g Ural 375 or Unimog 404 incapable of running on diesel fuel Tractors and heavy equipment Edit Today s tractors and heavy equipment are mostly diesel powered Among tractors only the smaller classes may also offer gasoline fuelled engines The dieselization of tractors and heavy equipment began in Germany before World War II but was unusual in the United States until after that war During the 1950s and 1960s it progressed in the US as well Diesel fuel is commonly used in oil and gas extracting equipment although some locales use electric or natural gas powered equipment Tractors and heavy equipment were often multifuel in the 1920s through 1940s running either spark ignition and low compression engines akryod engines or diesel engines Thus many farm tractors of the era could burn gasoline alcohol kerosene and any light grade of fuel oil such as heating oil or tractor vaporising oil according to whichever was most affordable in a region at any given time On US farms during this era the name distillate often referred to any of the aforementioned light fuel oils Spark ignition engines did not start as well on distillate so typically a small auxiliary gasoline tank was used for cold starting and the fuel valves were adjusted several minutes later after warm up to transition to distillate Engine accessories such as vaporizers and radiator shrouds were also used both with the aim of capturing heat because when such an engine was run on distillate it ran better when both it and the air it inhaled were warmer rather than at ambient temperature Dieselization with dedicated diesel engines high compression with mechanical fuel injection and compression ignition replaced such systems and made more efficient use of the diesel fuel being burned Other uses Edit Poor quality diesel fuel has been used as an extraction agent for liquid liquid extraction of palladium from nitric acid mixtures 51 Such use has been proposed as a means of separating the fission product palladium from PUREX raffinate which comes from used nuclear fuel 51 In this system of solvent extraction the hydrocarbons of the diesel act as the diluent while the dialkyl sulfides act as the extractant 51 This extraction operates by a solvation mechanism 51 So far neither a pilot plant nor full scale plant has been constructed to recover palladium rhodium or ruthenium from nuclear wastes created by the use of nuclear fuel 52 Diesel fuel is often used as the main ingredient in oil base mud drilling fluid 53 The advantage of using diesel is its low cost and its ability to drill a wide variety of difficult strata including shale salt and gypsum formations 53 Diesel oil mud is typically mixed with up to 40 brine water 54 Due to health safety and environmental concerns Diesel oil mud is often replaced with vegetable mineral or synthetic food grade oil base drilling fluids although diesel oil mud is still in widespread use in certain regions 55 During development of rocket engines in Germany during World War II J 2 Diesel fuel was used as the fuel component in several engines including the BMW 109 718 56 J 2 diesel fuel was also used as a fuel for gas turbine engines 56 Chemical analysis EditChemical composition Edit Diesel does not mix with water This picture also showcases the phenomenon of Thin film interference In the United States petroleum derived diesel is composed of about 75 saturated hydrocarbons primarily paraffins including n iso and cycloparaffins and 25 aromatic hydrocarbons including naphthalenes and alkylbenzenes 57 The average chemical formula for common diesel fuel is C12H23 ranging approximately from C10H20 to C15H28 58 Chemical properties Edit Further information Diesel exhaust and Gel point petroleum Most diesel fuels freeze at common winter temperatures while the temperatures greatly vary 59 Petrodiesel typically freezes around temperatures of 8 1 C 17 5 F whereas biodiesel freezes between temperatures of 2 to 15 C 35 to 60 F 59 The viscosity of diesel noticeably increases as the temperature decreases changing it into a gel at temperatures of 19 C 2 2 F to 15 C 5 F that cannot flow in fuel systems Conventional diesel fuels vaporise at temperatures between 149 C and 371 C 34 Conventional diesel flash points vary between 52 and 96 C which makes it safer than petrol and unsuitable for spark ignition engines 60 Unlike petrol the flash point of a diesel fuel has no relation to its performance in an engine nor to its auto ignition qualities 34 Carbon dioxide formation EditAs a good approximation the chemical formula of diesel is Cn H2n Note that diesel is a mixture of different molecules As carbon has a molar mass of 12 g mol and hydrogen has a molar mass of about 1 g mol so the fraction by weight of carbon in EN 590 diesel fuel is roughly 12 14 The reaction of diesel combustion is given by 2Cn H2n 3nO2 2nCO2 2nH2 OCarbon dioxide has a molar mass of 44g mol as it consists of 2 atoms of oxygen 16 g mol and 1 atom of carbon 12 g mol So 12 g of carbon yield 44 g of Carbon dioxide Diesel has a density of 0 838 kg per liter Putting everything together the mass of carbon dioxide that is produced by burning 1 liter of diesel fuel can be calculated as 0 838 k g L 12 14 44 12 2 63 k g L displaystyle 0 838kg L cdot frac 12 14 cdot frac 44 12 2 63kg L The figure obtained with this estimation is close to the values found in the literature For gasoline with a density of 0 75 kg L and a ratio of carbon to hydrogen atoms of about 6 to 14 the estimated value of carbon emission if 1 liter of gasoline is burnt gives 0 75 k g L 6 12 6 12 14 1 44 12 2 3 k g L displaystyle 0 75kg L cdot frac 6 cdot 12 6 cdot 12 14 cdot 1 cdot frac 44 12 2 3kg L Source 61 Hazards EditSee also diesel exhaust Environment hazards of sulfur Edit In the past diesel fuel contained higher quantities of sulfur European emission standards and preferential taxation have forced oil refineries to dramatically reduce the level of sulfur in diesel fuels In the European Union the sulfur content has dramatically reduced during the last 20 years Automotive diesel fuel is covered in the European Union by standard EN 590 In the 1990s specifications allowed a content of 2000 ppm max of sulfur reduced to a limit of 350 ppm by the beginning of the 21st century with the introduction of Euro 3 specifications The limit was lowered with the introduction of Euro 4 by 2006 to 50 ppm ULSD Ultra Low Sulfur Diesel The standard for diesel fuel in force in Europe as of 2009 is the Euro 5 with a maximum content of 10 ppm 62 Emission standard At latest Sulfur content Cetane numberN a 1 January 1994 max 2000 ppm min 49Euro 2 1 January 1996 max 500 ppm min 49Euro 3 1 January 2001 max 350 ppm min 51Euro 4 1 January 2006 max 50 ppm min 51Euro 5 1 January 2009 max 10 ppm min 51In the United States more stringent emission standards have been adopted with the transition to ULSD starting in 2006 and becoming mandatory on June 1 2010 see also diesel exhaust Algae microbes and water contamination Edit Main article microbial contamination of diesel fuel There has been much discussion and misunderstanding of algae in diesel fuel Algae need light to live and grow As there is no sunlight in a closed fuel tank no algae can survive but some microbes can survive and feed on the diesel fuel 63 These microbes form a colony that lives at the interface of fuel and water They grow quite fast in warmer temperatures They can even grow in cold weather when fuel tank heaters are installed Parts of the colony can break off and clog the fuel lines and fuel filters 64 Water in fuel can damage a fuel injection pump Some diesel fuel filters also trap water Water contamination in diesel fuel can lead to freezing while in the fuel tank The freezing water that saturates the fuel will sometimes clog the fuel injector pump 65 Once the water inside the fuel tank has started to freeze gelling is more likely to occur When the fuel is gelled it is not effective until the temperature is raised and the fuel returns to a liquid state Road hazard Edit Diesel is less flammable than gasoline petrol However because it evaporates slowly any spills on a roadway can pose a slip hazard to vehicles 66 After the light fractions have evaporated a greasy slick is left on the road which reduces tire grip and traction and can cause vehicles to skid The loss of traction is similar to that encountered on black ice resulting in especially dangerous situations for two wheeled vehicles such as motorcycles and bicycles in roundabouts See also Edit Energy portal Renewable energy portalCommon ethanol fuel mixtures Biodiesel Diesel automobile racing Dieselisation Gasoline Gasoline gallon equivalent Hybrid vehicle Liquid fuel List of diesel automobiles Turbo diesel United States vs Imperial Petroleum Winter diesel fuelReferences Edit Knothe Gerhard Sharp Christopher A Ryan Thomas W 2006 Exhaust Emissions of Biodiesel Petrodiesel Neat Methyl Esters and Alkanes in a New Technology Engine Energy amp Fuels 20 403 408 doi 10 1021 ef0502711 S2CID 53386870 DERV FAQ Nationwide Fuels and Lubricants Ltd 8 November 2022 p 5 The Macquarie Dictionary 3rd ed The Macquarie Library 1997 DE 67207 Rudolf Diesel Arbeitsverfahren und Ausfuhrungsart fur Verbrennungskraftmaschinen pg 4 Alle Brennmaterialien in allen Aggregatzustanden sind fur Durchfuhrung des Verfahrens brauchbar Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 125 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 107 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 108 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 110 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 111 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 114 a b Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 115 Ayhan Demirbas 2008 Biodiesel A Realistic Fuel Alternative for Diesel Engines Berlin Springer p 74 ISBN 978 1 84628 994 1 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 116 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 126 Rudolf Diesel Die Entstehung des Dieselmotors Springer Berlin Heidelberg 1913 ISBN 978 3 642 64940 0 p 127 Friedrich Sass Geschichte des deutschen Verbrennungsmotorenbaues von 1860 bis 1918 Springer Berlin Heidelberg 1962 ISBN 978 3 662 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Separations Society Archived from the original on 2015 03 23 Oil on the road as a cause of accidents ICBCclaiminfo com Archived from the original on 7 April 2013 Further reading EditL D Danny Harvey 2010 Energy and the New Reality 1 Energy Efficiency and the Demand for Energy Services London Routledge Earthscan ISBN 1 84407 912 0 672 pp see 3 accessed 28 September 2014 External links Edit Wikimedia Commons has media related to Diesel U S Department of Labor Occupational Safety amp Health Administration Safety and Health Topics Diesel Exhaust Retrieved from https en wikipedia org w index php title Diesel fuel amp oldid 1127757633, wikipedia, wiki, book, books, library,

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