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Thermometer

A thermometer is a device that measures temperature (the degree of hotness or coldness of an object) or temperature gradient (the rates of change of temperature in space). A thermometer has two important elements: (1) a temperature sensor (e.g. the bulb of a mercury-in-glass thermometer or the pyrometric sensor in an infrared thermometer) in which some change occurs with a change in temperature; and (2) some means of converting this change into a numerical value (e.g. the visible scale that is marked on a mercury-in-glass thermometer or the digital readout on an infrared model). Thermometers are widely used in technology and industry to monitor processes, in meteorology, in medicine (medical thermometer), and in scientific research.

Mercury thermometer (mercury-in-glass thermometer) for measurement of room temperature.[1]

A standard scale edit

While an individual thermometer is able to measure degrees of hotness, the readings on two thermometers cannot be compared unless they conform to an agreed scale. Today there is an absolute thermodynamic temperature scale. Internationally agreed temperature scales are designed to approximate this closely, based on fixed points and interpolating thermometers. The most recent official temperature scale is the International Temperature Scale of 1990. It extends from 0.65 K (−272.5 °C; −458.5 °F) to approximately 1,358 K (1,085 °C; 1,985 °F).

History edit

Sparse and conflicting historical records make it difficult to pinpoint the invention of the thermometer to any single person or date with certitude. In addition, given the many parallel developments in the thermometer's history and its many gradual improvements over time, the instrument is best viewed not as a single invention, but an evolving technology.

Ancient developments edit

Early pneumatic devices and ideas from antiquity provided inspiration for the thermometer's invention during the Renaissance period.

Philo of Byzantium edit

 
Fludd's figure of Philo's experiment

In the 3rd century BC, Philo of Byzantium documented his experiment with a tube submerged in a container of liquid on one end and connected to an air-tight, hollow sphere on the other. When air in the sphere is heated with a candle or by exposing it to the sun, expanding air exits the sphere and generates bubbles in the vessel. As air in the sphere cools, a partial vacuum is created, sucking liquid up into the tube. Any changes in the position of the liquid will now indicate whether the air in the sphere is getting hotter or colder.

Translations of Philo's experiment from the original ancient Greek were utilized by Robert Fludd sometime around 1617 and used as the basis for his air thermometer.[2]: 15 

Hero of Alexandria edit

In his book, Pneumatics, Hero of Alexandria (10–70 AD) provides a recipe for building a "Fountain which trickles by the Action of the Sun's Rays," a more elaborate version of Philo's pneumatic experiment but which worked on the same principle of heating and cooling air to move water around.[3] Translations of the ancient work Pneumatics were introduced to late 16th century Italy and studied by many, including Galileo Galilei, who had read it by 1594.[2]: 5 

First temperature scale with a fixed point edit

 
Hasler's temperature scale showing degrees of body temperature based on an individual's latitude.

The Roman Greek physician Galen is given credit for introducing two concepts important to the development of a scale of temperature and the eventual invention of the thermometer. First, he had the idea that hotness or coldness may be measured by "degrees of hot and cold." He also conceived of a fixed reference temperature, a mixture of equal amounts of ice and boiling water, with four degrees of heat above this point and four degrees of cold below. 16th century physician Johann Hasler developed body temperature scales based on Galen's theory of degrees to help him mix the appropriate amount of medicine for patients.[2]: 3 

Late Renaissance developments edit

Thermoscope edit

In the late 16th and early 17th centuries, several European scientists, notably Galileo Galilei[4] and Italian physiologist Santorio Santorio[5] developed devices with an air-filled glass bulb, connected to a tube, partially filled with water. As the air in the bulb warms or cools, the height of the column of water in the tube falls or rises, allowing an observer to compare the current height of the water to previous heights to detect relative changes of the heat in the bulb and its immediate environment. Such devices, with no scale for assigning a numerical value to the height of the liquid, are referred to as a thermoscope because they provide an observable indication of sensible heat (the modern concept of temperature was yet to arise).[2]

Air thermometer edit

The difference between a thermoscope and a thermometer is that the latter has a scale.[6][2]: 4 

A thermometer is simply a thermoscope with a scale. ... I propose to regard it as axiomatic that a “meter” must have a scale or something equivalent. ... If this is admitted, the problem of the invention of the thermometer becomes more straightforward; that of the invention of the thermoscope remains as obscure as ever.

— W. E. Knowles Middleton, A history of the thermometer and its use in meteorology

Given this, the possible inventors of the thermometer are usually considered to be Galileo, Santorio, Dutch inventor Cornelis Drebbel, or British mathematician Robert Fludd.[2]: 5  Though Galileo is often said to be the inventor of the thermometer, there is no surviving document that he actually produced any such instrument.

The first diagrams edit

The first clear diagram of a thermoscope was published in 1617 by Giuseppe Biancani (1566 – 1624);[2]: 10  the first showing a scale and thus constituting a thermometer was by Santorio Santorio in 1625.[5] This was a vertical tube, closed by a bulb of air at the top, with the lower end opening into a vessel of water. The water level in the tube was controlled by the expansion and contraction of the air, so it was what we would now call an air thermometer.[7]

Coining of "thermometer" edit

The word thermometer (in its French form) first appeared in 1624 in La Récréation Mathématique by Jean Leurechon, who describes one with a scale of 8 degrees.[8] The word comes from the Greek words θερμός, thermos, meaning "hot" and μέτρον, metron, meaning "measure".

Sealed liquid-in-glass thermometer edit

 
Fifty-degree thermometers from the mid-17th century on exhibit at the Museo Galileo with black dots representing single degrees and white represented 10-degree increments; used to measure atmospheric temperatures

The above instruments suffered from the disadvantage that they were also barometers, i.e. sensitive to air pressure. In 1629, Joseph Solomon Delmedigo, a student of Galileo and Santorio in Padua, published what is apparently the first description and illustration of a sealed liquid-in-glass thermometer. It is described as having a bulb at the bottom of a sealed tube partially filled with brandy. The tube had a numbered scale. Delmedigo did not claim to have invented this instrument. Nor did he name anyone else as its inventor.[9] In about 1654, Ferdinando II de' Medici, Grand Duke of Tuscany (1610–1670) did produce such an instrument, the first modern-style thermometer, dependent on the expansion of a liquid and independent of air pressure.[8] Many other scientists experimented with various liquids and designs of thermometer. However, each inventor and each thermometer was unique — there was no standard scale.

Early attempts at standardization edit

Early attempts at standardization added a single reference point such as the freezing point of water. The use of two references for graduating the thermometer is said to have been introduced by Joachim Dalence in 1668,[10] although Christiaan Huygens (1629–1695) in 1665 had already suggested the use of graduations based on the melting and boiling points of water as standards[11] and, in 1694, Carlo Renaldini (1615–1698) proposed using them as fixed points along a universal scale. In 1701, Isaac Newton (1642–1726/27) proposed a scale of 12 degrees between the melting point of ice and body temperature.

Era of precision thermometry edit

 
A medical mercury-in-glass maximum thermometer.
 
An alcohol thermometer.
 
Thermometer with Fahrenheit (symbol °F) and Celsius (symbol °C) units.

In 1714, scientist and inventor Daniel Gabriel Fahrenheit invented a reliable thermometer, using mercury instead of alcohol and water mixtures. In 1724, he proposed a temperature scale which now (slightly adjusted) bears his name. In 1742, Anders Celsius (1701–1744) proposed a scale with zero at the boiling point and 100 degrees at the freezing point of water,[12] though the scale which now bears his name has them the other way around.[13] French entomologist René Antoine Ferchault de Réaumur invented an alcohol thermometer and, temperature scale in 1730, that ultimately proved to be less reliable than Fahrenheit's mercury thermometer.

 
Very Slippy-Weather
A caricature by James Gillray, 1808

The first physician to use thermometer measurements in clinical practice was Herman Boerhaave (1668–1738).[14] In 1866, Sir Thomas Clifford Allbutt (1836–1925) invented a clinical thermometer that produced a body temperature reading in five minutes as opposed to twenty.[15] In 1999, Dr. Francesco Pompei of the Exergen Corporation introduced the world's first temporal artery thermometer, a non-invasive temperature sensor which scans the forehead in about two seconds and provides a medically accurate body temperature.[16][17]

Registering edit

Traditional thermometers were all non-registering thermometers. That is, the thermometer did not hold the temperature reading after it was moved to a place with a different temperature. Determining the temperature of a pot of hot liquid required the user to leave the thermometer in the hot liquid until after reading it. If the non-registering thermometer was removed from the hot liquid, then the temperature indicated on the thermometer would immediately begin changing to reflect the temperature of its new conditions (in this case, the air temperature). Registering thermometers are designed to hold the temperature indefinitely, so that the thermometer can be removed and read at a later time or in a more convenient place. Mechanical registering thermometers hold either the highest or lowest temperature recorded until manually re-set, e.g., by shaking down a mercury-in-glass thermometer, or until an even more extreme temperature is experienced. Electronic registering thermometers may be designed to remember the highest or lowest temperature, or to remember whatever temperature was present at a specified point in time.

Thermometers increasingly use electronic means to provide a digital display or input to a computer.

Physical principles of thermometry edit

 
Various thermometers from the 19th century.
 
Comparison of the Celsius and Fahrenheit scales

Thermometers may be described as empirical or absolute. Absolute thermometers are calibrated numerically by the thermodynamic absolute temperature scale. Empirical thermometers are not in general necessarily in exact agreement with absolute thermometers as to their numerical scale readings, but to qualify as thermometers at all they must agree with absolute thermometers and with each other in the following way: given any two bodies isolated in their separate respective thermodynamic equilibrium states, all thermometers agree as to which of the two has the higher temperature, or that the two have equal temperatures.[18] For any two empirical thermometers, this does not require that the relation between their numerical scale readings be linear, but it does require that relation to be strictly monotonic.[19] This is a fundamental character of temperature and thermometers.[20][21][22]

As it is customarily stated in textbooks, taken alone, the so-called "zeroth law of thermodynamics" fails to deliver this information, but the statement of the zeroth law of thermodynamics by James Serrin in 1977, though rather mathematically abstract, is more informative for thermometry: "Zeroth Law – There exists a topological line   which serves as a coordinate manifold of material behaviour. The points   of the manifold   are called 'hotness levels', and   is called the 'universal hotness manifold'."[23] To this information there needs to be added a sense of greater hotness; this sense can be had, independently of calorimetry, of thermodynamics, and of properties of particular materials, from Wien's displacement law of thermal radiation: the temperature of a bath of thermal radiation is proportional, by a universal constant, to the frequency of the maximum of its frequency spectrum; this frequency is always positive, but can have values that tend to zero. Another way of identifying hotter as opposed to colder conditions is supplied by Planck's principle, that when a process of isochoric adiabatic work is the sole means of change of internal energy of a closed system, the final state of the system is never colder than the initial state; except for phase changes with latent heat, it is hotter than the initial state.[24][25][26]

There are several principles on which empirical thermometers are built, as listed in the section of this article entitled "Primary and secondary thermometers". Several such principles are essentially based on the constitutive relation between the state of a suitably selected particular material and its temperature. Only some materials are suitable for this purpose, and they may be considered as "thermometric materials". Radiometric thermometry, in contrast, can be only slightly dependent on the constitutive relations of materials. In a sense then, radiometric thermometry might be thought of as "universal". This is because it rests mainly on a universality character of thermodynamic equilibrium, that it has the universal property of producing blackbody radiation.

Thermometric materials edit

 
Bi-metallic stem thermometers used to measure the temperature of steamed milk
 
Bi-metallic thermometer for cooking and baking in an oven

There are various kinds of empirical thermometer based on material properties.

Many empirical thermometers rely on the constitutive relation between pressure, volume and temperature of their thermometric material. For example, mercury expands when heated.

If it is used for its relation between pressure and volume and temperature, a thermometric material must have three properties:

(1) Its heating and cooling must be rapid. That is to say, when a quantity of heat enters or leaves a body of the material, the material must expand or contract to its final volume or reach its final pressure and must reach its final temperature with practically no delay; some of the heat that enters can be considered to change the volume of the body at constant temperature, and is called the latent heat of expansion at constant temperature; and the rest of it can be considered to change the temperature of the body at constant volume, and is called the specific heat at constant volume. Some materials do not have this property, and take some time to distribute the heat between temperature and volume change.[27]

(2) Its heating and cooling must be reversible. That is to say, the material must be able to be heated and cooled indefinitely often by the same increment and decrement of heat, and still return to its original pressure, volume and temperature every time. Some plastics do not have this property;[28]

(3) Its heating and cooling must be monotonic.[19][29] That is to say, throughout the range of temperatures for which it is intended to work,

(a) at a given fixed pressure,
either (i) the volume increases when the temperature increases, or else (ii) the volume decreases when the temperature increases;
but not (i) for some temperatures and (ii) for others; or
(b) at a given fixed volume,
either (i) the pressure increases when the temperature increases, or else (ii) the pressure decreases when the temperature increases;
but not (i) for some temperatures and (ii) for others.

At temperatures around about 4 °C, water does not have the property (3), and is said to behave anomalously in this respect; thus water cannot be used as a material for this kind of thermometry for temperature ranges near 4 °C.[21][30][31][32][33]

Gases, on the other hand, all have the properties (1), (2), and (3)(a)(α) and (3)(b)(α). Consequently, they are suitable thermometric materials, and that is why they were important in the development of thermometry.[34]

Constant volume thermometry edit

According to Preston (1894/1904), Regnault found constant pressure air thermometers unsatisfactory, because they needed troublesome corrections. He therefore built a constant volume air thermometer.[35] Constant volume thermometers do not provide a way to avoid the problem of anomalous behaviour like that of water at approximately 4 °C.[33]

Radiometric thermometry edit

Planck's law very accurately quantitatively describes the power spectral density of electromagnetic radiation, inside a rigid walled cavity in a body made of material that is completely opaque and poorly reflective, when it has reached thermodynamic equilibrium, as a function of absolute thermodynamic temperature alone. A small enough hole in the wall of the cavity emits near enough blackbody radiation of which the spectral radiance can be precisely measured. The walls of the cavity, provided they are completely opaque and poorly reflective, can be of any material indifferently. This provides a well-reproducible absolute thermometer over a very wide range of temperatures, able to measure the absolute temperature of a body inside the cavity.

Primary and secondary thermometers edit

A thermometer is called primary or secondary based on how the raw physical quantity it measures is mapped to a temperature. As summarized by Kauppinen et al., "For primary thermometers the measured property of matter is known so well that temperature can be calculated without any unknown quantities. Examples of these are thermometers based on the equation of state of a gas, on the velocity of sound in a gas, on the thermal noise voltage or current of an electrical resistor, and on the angular anisotropy of gamma ray emission of certain radioactive nuclei in a magnetic field."[36]

In contrast, "Secondary thermometers are most widely used because of their convenience. Also, they are often much more sensitive than primary ones. For secondary thermometers knowledge of the measured property is not sufficient to allow direct calculation of temperature. They have to be calibrated against a primary thermometer at least at one temperature or at a number of fixed temperatures. Such fixed points, for example, triple points and superconducting transitions, occur reproducibly at the same temperature."[36]

Calibration edit

 
Mercury-in-glass thermometer

Thermometers can be calibrated either by comparing them with other calibrated thermometers or by checking them against known fixed points on the temperature scale. The best known of these fixed points are the melting and boiling points of pure water. (Note that the boiling point of water varies with pressure, so this must be controlled.)

The traditional way of putting a scale on a liquid-in-glass or liquid-in-metal thermometer was in three stages:

  1. Immerse the sensing portion in a stirred mixture of pure ice and water at atmospheric pressure and mark the point indicated when it had come to thermal equilibrium.
  2. Immerse the sensing portion in a steam bath at standard atmospheric pressure and again mark the point indicated.
  3. Divide the distance between these marks into equal portions according to the temperature scale being used.

Other fixed points used in the past are the body temperature (of a healthy adult male) which was originally used by Fahrenheit as his upper fixed point (96 °F (35.6 °C) to be a number divisible by 12) and the lowest temperature given by a mixture of salt and ice, which was originally the definition of 0 °F (−17.8 °C).[37] (This is an example of a frigorific mixture.) As body temperature varies, the Fahrenheit scale was later changed to use an upper fixed point of boiling water at 212 °F (100 °C).[38]

These have now been replaced by the defining points in the International Temperature Scale of 1990, though in practice the melting point of water is more commonly used than its triple point, the latter being more difficult to manage and thus restricted to critical standard measurement. Nowadays manufacturers will often use a thermostat bath or solid block where the temperature is held constant relative to a calibrated thermometer. Other thermometers to be calibrated are put into the same bath or block and allowed to come to equilibrium, then the scale marked, or any deviation from the instrument scale recorded.[39] For many modern devices calibration will be stating some value to be used in processing an electronic signal to convert it to a temperature.

Precision, accuracy, and reproducibility edit

 
The "Boyce MotoMeter" radiator cap on a 1913 Car-Nation automobile, used to measure temperature of vapor in 1910s and 1920s cars.
 
Separated columns are often a problem in both alcohol and mercury thermometers, and they can make a temperature reading inaccurate.

The precision or resolution of a thermometer is simply to what fraction of a degree it is possible to make a reading. For high temperature work it may only be possible to measure to the nearest 10 °C or more. Clinical thermometers and many electronic thermometers are usually readable to 0.1 °C. Special instruments can give readings to one thousandth of a degree.[40] However, this precision does not mean the reading is true or accurate, it only means that very small changes can be observed.

A thermometer calibrated to a known fixed point is accurate (i.e. gives a true reading) at that point. The invention of the technology to measure temperature led to the creation of scales of temperature.[41] In between fixed calibration points, interpolation is used, usually linear.[39] This may give significant differences between different types of thermometer at points far away from the fixed points. For example, the expansion of mercury in a glass thermometer is slightly different from the change in resistance of a platinum resistance thermometer, so these two will disagree slightly at around 50 °C.[42] There may be other causes due to imperfections in the instrument, e.g. in a liquid-in-glass thermometer if the capillary tube varies in diameter.[42]

For many purposes reproducibility is important. That is, does the same thermometer give the same reading for the same temperature (or do replacement or multiple thermometers give the same reading)? Reproducible temperature measurement means that comparisons are valid in scientific experiments and industrial processes are consistent. Thus if the same type of thermometer is calibrated in the same way its readings will be valid even if it is slightly inaccurate compared to the absolute scale.

An example of a reference thermometer used to check others to industrial standards would be a platinum resistance thermometer with a digital display to 0.1 °C (its precision) which has been calibrated at 5 points against national standards (−18, 0, 40, 70, 100 °C) and which is certified to an accuracy of ±0.2 °C.[43]

According to British Standards, correctly calibrated, used and maintained liquid-in-glass thermometers can achieve a measurement uncertainty of ±0.01 °C in the range 0 to 100 °C, and a larger uncertainty outside this range: ±0.05 °C up to 200 or down to −40 °C, ±0.2 °C up to 450 or down to −80 °C.[44]

Indirect methods of temperature measurement edit

Thermal expansion
Utilizing the property of thermal expansion of various phases of matter.
Pairs of solid metals with different expansion coefficients can be used for bi-metal mechanical thermometers. Another design using this principle is Breguet's thermometer.
Some liquids possess relatively high expansion coefficients over a useful temperature ranges thus forming the basis for an alcohol or mercury thermometer. Alternative designs using this principle are the reversing thermometer and Beckmann differential thermometer.
As with liquids, gases can also be used to form a gas thermometer.
Pressure
Vapour pressure thermometer
Density
Galileo thermometer[45]
Thermochromism
Some compounds exhibit thermochromism at distinct temperature changes. Thus by tuning the phase transition temperatures for a series of substances the temperature can be quantified in discrete increments, a form of digitization. This is the basis for a liquid crystal thermometer.
Band edge thermometry (BET)
Band edge thermometry (BET) takes advantage of the temperature-dependence of the band gap of semiconductor materials to provide very precise optical (i.e. non-contact) temperature measurements.[46] BET systems require a specialized optical system, as well as custom data analysis software.[47][48]
Blackbody radiation
 
An infrared thermometer is a kind of pyrometer (bolometer).
All objects above absolute zero emit blackbody radiation for which the spectra is directly proportional to the temperature. This property is the basis for a pyrometer or infrared thermometer and thermography. It has the advantage of remote temperature sensing; it does not require contact or even close proximity unlike most thermometers. At higher temperatures, blackbody radiation becomes visible and is described by the colour temperature. For example a glowing heating element or an approximation of a star's surface temperature.
Fluorescence
Phosphor thermometry
Optical absorbance spectra
Fiber optical thermometer
Electrical resistance
Resistance thermometer which use materials such as Balco alloy
Thermistor
Coulomb blockade thermometer
Electrical potential
Thermocouples are useful over a wide temperature range from cryogenic temperatures to over 1000°C, but typically have an error of ±0.5-1.5°C.
Silicon bandgap temperature sensors are commonly found packaged in integrated circuits with accompanying ADC and interface such as I2C. Typically they are specified to work within about —50 to 150°C with accuracies in the ±0.25 to 1°C range but can be improved by binning.[49][50]
Electrical resonance
Quartz thermometer
Nuclear magnetic resonance
Chemical shift is temperature dependent. This property is used to calibrate the thermostat of NMR probes, usually using methanol or ethylene glycol.[51][52] This can potentially be problematic for internal standards which are usually assumed to have a defined chemical shift (e.g 0 ppm for TMS) but in fact exhibit a temperature dependence.[53]
Magnetic susceptibility
Above the Curie temperature, the magnetic susceptibility of a paramagnetic material exhibits an inverse temperature dependence. This phenomenon is the basis of a magnetic cryometer.[54][55]

Applications edit

Thermometers utilize a range of physical effects to measure temperature. Temperature sensors are used in a wide variety of scientific and engineering applications, especially measurement systems. Temperature systems are primarily either electrical or mechanical, occasionally inseparable from the system which they control (as in the case of a mercury-in-glass thermometer). Thermometers are used in roadways in cold weather climates to help determine if icing conditions exist. Indoors, thermistors are used in climate control systems such as air conditioners, freezers, heaters, refrigerators, and water heaters.[56] Galileo thermometers are used to measure indoor air temperature, due to their limited measurement range.

Such liquid crystal thermometers (which use thermochromic liquid crystals) are also used in mood rings and used to measure the temperature of water in fish tanks.

Fiber Bragg grating temperature sensors are used in nuclear power facilities to monitor reactor core temperatures and avoid the possibility of nuclear meltdowns.[57]

Nanothermometry edit

Nanothermometry is an emergent research field dealing with the knowledge of temperature in the sub-micrometric scale. Conventional thermometers cannot measure the temperature of an object which is smaller than a micrometre, and new methods and materials have to be used. Nanothermometry is used in such cases. Nanothermometers are classified as luminescent thermometers (if they use light to measure temperature) and non-luminescent thermometers (systems where thermometric properties are not directly related to luminescence).[58]

Cryometer edit

Thermometers used specifically for low temperatures.

Medical edit

 
A Kinsa QuickCare smart thermometer.

Various thermometric techniques have been used throughout history such as the Galileo thermometer to thermal imaging.[45] Medical thermometers such as mercury-in-glass thermometers, infrared thermometers, pill thermometers, and liquid crystal thermometers are used in health care settings to determine if individuals have a fever or are hypothermic.

Food and food safety edit

Thermometers are important in food safety, where food at temperatures within 41 and 135 °F (5 and 57 °C) can be prone to potentially harmful levels of bacterial growth after several hours which could lead to foodborne illness. This includes monitoring refrigeration temperatures and maintaining temperatures in foods being served under heat lamps or hot water baths.[56] Cooking thermometers are important for determining if a food is properly cooked. In particular meat thermometers are used to aid in cooking meat to a safe internal temperature while preventing over cooking. They are commonly found using either a bimetallic coil, or a thermocouple or thermistor with a digital readout. Candy thermometers are used to aid in achieving a specific water content in a sugar solution based on its boiling temperature.

Environmental edit

Alcohol thermometers, infrared thermometers, mercury-in-glass thermometers, recording thermometers, thermistors, and Six's thermometers (maximum-minimum thermometer) are used in meteorology and climatology in various levels of the atmosphere and oceans. Aircraft use thermometers and hygrometers to determine if atmospheric icing conditions exist along their flight path. These measurements are used to initialize weather forecast models. Thermometers are used in roadways in cold weather climates to help determine if icing conditions exist and indoors in climate control systems.

See also edit

References edit

  1. ^ Knake, Maria (April 2011). "The Anatomy of a Liquid-in-Glass Thermometer". AASHTO re:source, formerly AMRL (aashtoresource.org). Retrieved 4 August 2018. For decades mercury thermometers were a mainstay in many testing laboratories. If used properly and calibrated correctly, certain types of mercury thermometers can be incredibly accurate. Mercury thermometers can be used in temperatures ranging from about -38 to 350°C. The use of a mercury-thallium mixture can extend the low-temperature usability of mercury thermometers to -56°C. (...) Nevertheless, few liquids have been found to mimic the thermometric properties of mercury in repeatability and accuracy of temperature measurement. Toxic though it may be, when it comes to LiG [Liquid-in-Glass] thermometers, mercury is still hard to beat.
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  3. ^ Hero (1851). The Pneumatics of Hero of Alexandria. London: Taylor Walton and Maberly. p. 69. Bibcode:1851phal.book.....W. Retrieved 28 November 2023.
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Further reading edit

  • Middleton, W.E.K. (1966). A history of the thermometer and its use in meteorology. Baltimore: Johns Hopkins Press. Reprinted ed. 2002, ISBN 0-8018-7153-0.
  • History of the Thermometer 2016-03-06 at the Wayback Machine
  • Thermometry at the Nanoscale – Recent review

External links edit

  • (archived 25 February 2008)
  • The Chemical Educator, Vol. 5, No. 2 (2000) 2004-03-10 at the Wayback Machine The Thermometer—From The Feeling To The Instrument
  • – Notable Modern Inventions and Discoveries (archived 24 April 2008)
  • About – Thermometer 2020-01-22 at the Wayback Machine – Thermometers – Early History, Anders Celsius, Gabriel Fahrenheit and Thomson Kelvin.
  • Thermometers and Thermometric Liquids – Mercury and Alcohol.
  • The NIST Industrial Thermometer Calibration Laboratory 2016-07-22 at the Wayback Machine
  • Thermometry at the Nanoscale—Review

thermometer, broader, coverage, this, topic, temperature, measurement, thermometer, device, that, measures, temperature, degree, hotness, coldness, object, temperature, gradient, rates, change, temperature, space, thermometer, important, elements, temperature,. For broader coverage of this topic see Temperature measurement A thermometer is a device that measures temperature the degree of hotness or coldness of an object or temperature gradient the rates of change of temperature in space A thermometer has two important elements 1 a temperature sensor e g the bulb of a mercury in glass thermometer or the pyrometric sensor in an infrared thermometer in which some change occurs with a change in temperature and 2 some means of converting this change into a numerical value e g the visible scale that is marked on a mercury in glass thermometer or the digital readout on an infrared model Thermometers are widely used in technology and industry to monitor processes in meteorology in medicine medical thermometer and in scientific research Mercury thermometer mercury in glass thermometer for measurement of room temperature 1 Contents 1 A standard scale 2 History 2 1 Ancient developments 2 1 1 Philo of Byzantium 2 1 2 Hero of Alexandria 2 1 3 First temperature scale with a fixed point 2 2 Late Renaissance developments 2 2 1 Thermoscope 2 2 2 Air thermometer 2 2 3 The first diagrams 2 2 4 Coining of thermometer 2 2 5 Sealed liquid in glass thermometer 2 2 6 Early attempts at standardization 2 3 Era of precision thermometry 3 Registering 4 Physical principles of thermometry 4 1 Thermometric materials 4 2 Constant volume thermometry 4 3 Radiometric thermometry 5 Primary and secondary thermometers 6 Calibration 7 Precision accuracy and reproducibility 8 Indirect methods of temperature measurement 9 Applications 9 1 Nanothermometry 9 2 Cryometer 9 3 Medical 9 4 Food and food safety 9 5 Environmental 10 See also 11 References 12 Further reading 13 External linksA standard scale editMain articles Temperature and Temperature measurementSee also Scale of temperature While an individual thermometer is able to measure degrees of hotness the readings on two thermometers cannot be compared unless they conform to an agreed scale Today there is an absolute thermodynamic temperature scale Internationally agreed temperature scales are designed to approximate this closely based on fixed points and interpolating thermometers The most recent official temperature scale is the International Temperature Scale of 1990 It extends from 0 65 K 272 5 C 458 5 F to approximately 1 358 K 1 085 C 1 985 F History editSee also Timeline of temperature and pressure measurement technology Sparse and conflicting historical records make it difficult to pinpoint the invention of the thermometer to any single person or date with certitude In addition given the many parallel developments in the thermometer s history and its many gradual improvements over time the instrument is best viewed not as a single invention but an evolving technology Ancient developments edit Early pneumatic devices and ideas from antiquity provided inspiration for the thermometer s invention during the Renaissance period Philo of Byzantium edit nbsp Fludd s figure of Philo s experiment In the 3rd century BC Philo of Byzantium documented his experiment with a tube submerged in a container of liquid on one end and connected to an air tight hollow sphere on the other When air in the sphere is heated with a candle or by exposing it to the sun expanding air exits the sphere and generates bubbles in the vessel As air in the sphere cools a partial vacuum is created sucking liquid up into the tube Any changes in the position of the liquid will now indicate whether the air in the sphere is getting hotter or colder Translations of Philo s experiment from the original ancient Greek were utilized by Robert Fludd sometime around 1617 and used as the basis for his air thermometer 2 15 Hero of Alexandria edit In his book Pneumatics Hero of Alexandria 10 70 AD provides a recipe for building a Fountain which trickles by the Action of the Sun s Rays a more elaborate version of Philo s pneumatic experiment but which worked on the same principle of heating and cooling air to move water around 3 Translations of the ancient work Pneumatics were introduced to late 16th century Italy and studied by many including Galileo Galilei who had read it by 1594 2 5 First temperature scale with a fixed point edit nbsp Hasler s temperature scale showing degrees of body temperature based on an individual s latitude The Roman Greek physician Galen is given credit for introducing two concepts important to the development of a scale of temperature and the eventual invention of the thermometer First he had the idea that hotness or coldness may be measured by degrees of hot and cold He also conceived of a fixed reference temperature a mixture of equal amounts of ice and boiling water with four degrees of heat above this point and four degrees of cold below 16th century physician Johann Hasler developed body temperature scales based on Galen s theory of degrees to help him mix the appropriate amount of medicine for patients 2 3 Late Renaissance developments edit Thermoscope edit Main article Thermoscope In the late 16th and early 17th centuries several European scientists notably Galileo Galilei 4 and Italian physiologist Santorio Santorio 5 developed devices with an air filled glass bulb connected to a tube partially filled with water As the air in the bulb warms or cools the height of the column of water in the tube falls or rises allowing an observer to compare the current height of the water to previous heights to detect relative changes of the heat in the bulb and its immediate environment Such devices with no scale for assigning a numerical value to the height of the liquid are referred to as a thermoscope because they provide an observable indication of sensible heat the modern concept of temperature was yet to arise 2 Air thermometer edit The difference between a thermoscope and a thermometer is that the latter has a scale 6 2 4 A thermometer is simply a thermoscope with a scale I propose to regard it as axiomatic that a meter must have a scale or something equivalent If this is admitted the problem of the invention of the thermometer becomes more straightforward that of the invention of the thermoscope remains as obscure as ever W E Knowles Middleton A history of the thermometer and its use in meteorology Given this the possible inventors of the thermometer are usually considered to be Galileo Santorio Dutch inventor Cornelis Drebbel or British mathematician Robert Fludd 2 5 Though Galileo is often said to be the inventor of the thermometer there is no surviving document that he actually produced any such instrument The first diagrams edit The first clear diagram of a thermoscope was published in 1617 by Giuseppe Biancani 1566 1624 2 10 the first showing a scale and thus constituting a thermometer was by Santorio Santorio in 1625 5 This was a vertical tube closed by a bulb of air at the top with the lower end opening into a vessel of water The water level in the tube was controlled by the expansion and contraction of the air so it was what we would now call an air thermometer 7 Coining of thermometer edit The word thermometer in its French form first appeared in 1624 in La Recreation Mathematique by Jean Leurechon who describes one with a scale of 8 degrees 8 The word comes from the Greek words 8ermos thermos meaning hot and metron metron meaning measure Sealed liquid in glass thermometer edit nbsp Fifty degree thermometers from the mid 17th century on exhibit at the Museo Galileo with black dots representing single degrees and white represented 10 degree increments used to measure atmospheric temperatures See also Alcohol thermometer The above instruments suffered from the disadvantage that they were also barometers i e sensitive to air pressure In 1629 Joseph Solomon Delmedigo a student of Galileo and Santorio in Padua published what is apparently the first description and illustration of a sealed liquid in glass thermometer It is described as having a bulb at the bottom of a sealed tube partially filled with brandy The tube had a numbered scale Delmedigo did not claim to have invented this instrument Nor did he name anyone else as its inventor 9 In about 1654 Ferdinando II de Medici Grand Duke of Tuscany 1610 1670 did produce such an instrument the first modern style thermometer dependent on the expansion of a liquid and independent of air pressure 8 Many other scientists experimented with various liquids and designs of thermometer However each inventor and each thermometer was unique there was no standard scale Early attempts at standardization edit Early attempts at standardization added a single reference point such as the freezing point of water The use of two references for graduating the thermometer is said to have been introduced by Joachim Dalence in 1668 10 although Christiaan Huygens 1629 1695 in 1665 had already suggested the use of graduations based on the melting and boiling points of water as standards 11 and in 1694 Carlo Renaldini 1615 1698 proposed using them as fixed points along a universal scale In 1701 Isaac Newton 1642 1726 27 proposed a scale of 12 degrees between the melting point of ice and body temperature Era of precision thermometry edit See also Precision thermometry Fahrenheit scale Celsius scale Mercury in glass thermometer mercury thermometer Medical thermometer Pyrometer and Infrared thermometer nbsp A medical mercury in glass maximum thermometer nbsp An alcohol thermometer nbsp Thermometer with Fahrenheit symbol F and Celsius symbol C units In 1714 scientist and inventor Daniel Gabriel Fahrenheit invented a reliable thermometer using mercury instead of alcohol and water mixtures In 1724 he proposed a temperature scale which now slightly adjusted bears his name In 1742 Anders Celsius 1701 1744 proposed a scale with zero at the boiling point and 100 degrees at the freezing point of water 12 though the scale which now bears his name has them the other way around 13 French entomologist Rene Antoine Ferchault de Reaumur invented an alcohol thermometer and temperature scale in 1730 that ultimately proved to be less reliable than Fahrenheit s mercury thermometer nbsp Very Slippy WeatherA caricature by James Gillray 1808 The first physician to use thermometer measurements in clinical practice was Herman Boerhaave 1668 1738 14 In 1866 Sir Thomas Clifford Allbutt 1836 1925 invented a clinical thermometer that produced a body temperature reading in five minutes as opposed to twenty 15 In 1999 Dr Francesco Pompei of the Exergen Corporation introduced the world s first temporal artery thermometer a non invasive temperature sensor which scans the forehead in about two seconds and provides a medically accurate body temperature 16 17 Registering editTraditional thermometers were all non registering thermometers That is the thermometer did not hold the temperature reading after it was moved to a place with a different temperature Determining the temperature of a pot of hot liquid required the user to leave the thermometer in the hot liquid until after reading it If the non registering thermometer was removed from the hot liquid then the temperature indicated on the thermometer would immediately begin changing to reflect the temperature of its new conditions in this case the air temperature Registering thermometers are designed to hold the temperature indefinitely so that the thermometer can be removed and read at a later time or in a more convenient place Mechanical registering thermometers hold either the highest or lowest temperature recorded until manually re set e g by shaking down a mercury in glass thermometer or until an even more extreme temperature is experienced Electronic registering thermometers may be designed to remember the highest or lowest temperature or to remember whatever temperature was present at a specified point in time Thermometers increasingly use electronic means to provide a digital display or input to a computer Physical principles of thermometry edit nbsp Various thermometers from the 19th century nbsp Comparison of the Celsius and Fahrenheit scales Thermometers may be described as empirical or absolute Absolute thermometers are calibrated numerically by the thermodynamic absolute temperature scale Empirical thermometers are not in general necessarily in exact agreement with absolute thermometers as to their numerical scale readings but to qualify as thermometers at all they must agree with absolute thermometers and with each other in the following way given any two bodies isolated in their separate respective thermodynamic equilibrium states all thermometers agree as to which of the two has the higher temperature or that the two have equal temperatures 18 For any two empirical thermometers this does not require that the relation between their numerical scale readings be linear but it does require that relation to be strictly monotonic 19 This is a fundamental character of temperature and thermometers 20 21 22 As it is customarily stated in textbooks taken alone the so called zeroth law of thermodynamics fails to deliver this information but the statement of the zeroth law of thermodynamics by James Serrin in 1977 though rather mathematically abstract is more informative for thermometry Zeroth Law There exists a topological line M displaystyle M nbsp which serves as a coordinate manifold of material behaviour The points L displaystyle L nbsp of the manifold M displaystyle M nbsp are called hotness levels and M displaystyle M nbsp is called the universal hotness manifold 23 To this information there needs to be added a sense of greater hotness this sense can be had independently of calorimetry of thermodynamics and of properties of particular materials from Wien s displacement law of thermal radiation the temperature of a bath of thermal radiation is proportional by a universal constant to the frequency of the maximum of its frequency spectrum this frequency is always positive but can have values that tend to zero Another way of identifying hotter as opposed to colder conditions is supplied by Planck s principle that when a process of isochoric adiabatic work is the sole means of change of internal energy of a closed system the final state of the system is never colder than the initial state except for phase changes with latent heat it is hotter than the initial state 24 25 26 There are several principles on which empirical thermometers are built as listed in the section of this article entitled Primary and secondary thermometers Several such principles are essentially based on the constitutive relation between the state of a suitably selected particular material and its temperature Only some materials are suitable for this purpose and they may be considered as thermometric materials Radiometric thermometry in contrast can be only slightly dependent on the constitutive relations of materials In a sense then radiometric thermometry might be thought of as universal This is because it rests mainly on a universality character of thermodynamic equilibrium that it has the universal property of producing blackbody radiation Thermometric materials edit nbsp Bi metallic stem thermometers used to measure the temperature of steamed milk nbsp Bi metallic thermometer for cooking and baking in an oven There are various kinds of empirical thermometer based on material properties Many empirical thermometers rely on the constitutive relation between pressure volume and temperature of their thermometric material For example mercury expands when heated If it is used for its relation between pressure and volume and temperature a thermometric material must have three properties 1 Its heating and cooling must be rapid That is to say when a quantity of heat enters or leaves a body of the material the material must expand or contract to its final volume or reach its final pressure and must reach its final temperature with practically no delay some of the heat that enters can be considered to change the volume of the body at constant temperature and is called the latent heat of expansion at constant temperature and the rest of it can be considered to change the temperature of the body at constant volume and is called the specific heat at constant volume Some materials do not have this property and take some time to distribute the heat between temperature and volume change 27 2 Its heating and cooling must be reversible That is to say the material must be able to be heated and cooled indefinitely often by the same increment and decrement of heat and still return to its original pressure volume and temperature every time Some plastics do not have this property 28 3 Its heating and cooling must be monotonic 19 29 That is to say throughout the range of temperatures for which it is intended to work a at a given fixed pressure either i the volume increases when the temperature increases or else ii the volume decreases when the temperature increases dd but not i for some temperatures and ii for others or dd b at a given fixed volume either i the pressure increases when the temperature increases or else ii the pressure decreases when the temperature increases dd but not i for some temperatures and ii for others dd At temperatures around about 4 C water does not have the property 3 and is said to behave anomalously in this respect thus water cannot be used as a material for this kind of thermometry for temperature ranges near 4 C 21 30 31 32 33 Gases on the other hand all have the properties 1 2 and 3 a a and 3 b a Consequently they are suitable thermometric materials and that is why they were important in the development of thermometry 34 Constant volume thermometry edit According to Preston 1894 1904 Regnault found constant pressure air thermometers unsatisfactory because they needed troublesome corrections He therefore built a constant volume air thermometer 35 Constant volume thermometers do not provide a way to avoid the problem of anomalous behaviour like that of water at approximately 4 C 33 Radiometric thermometry edit Planck s law very accurately quantitatively describes the power spectral density of electromagnetic radiation inside a rigid walled cavity in a body made of material that is completely opaque and poorly reflective when it has reached thermodynamic equilibrium as a function of absolute thermodynamic temperature alone A small enough hole in the wall of the cavity emits near enough blackbody radiation of which the spectral radiance can be precisely measured The walls of the cavity provided they are completely opaque and poorly reflective can be of any material indifferently This provides a well reproducible absolute thermometer over a very wide range of temperatures able to measure the absolute temperature of a body inside the cavity Primary and secondary thermometers editA thermometer is called primary or secondary based on how the raw physical quantity it measures is mapped to a temperature As summarized by Kauppinen et al For primary thermometers the measured property of matter is known so well that temperature can be calculated without any unknown quantities Examples of these are thermometers based on the equation of state of a gas on the velocity of sound in a gas on the thermal noise voltage or current of an electrical resistor and on the angular anisotropy of gamma ray emission of certain radioactive nuclei in a magnetic field 36 In contrast Secondary thermometers are most widely used because of their convenience Also they are often much more sensitive than primary ones For secondary thermometers knowledge of the measured property is not sufficient to allow direct calculation of temperature They have to be calibrated against a primary thermometer at least at one temperature or at a number of fixed temperatures Such fixed points for example triple points and superconducting transitions occur reproducibly at the same temperature 36 Calibration edit nbsp Mercury in glass thermometer Thermometers can be calibrated either by comparing them with other calibrated thermometers or by checking them against known fixed points on the temperature scale The best known of these fixed points are the melting and boiling points of pure water Note that the boiling point of water varies with pressure so this must be controlled The traditional way of putting a scale on a liquid in glass or liquid in metal thermometer was in three stages Immerse the sensing portion in a stirred mixture of pure ice and water at atmospheric pressure and mark the point indicated when it had come to thermal equilibrium Immerse the sensing portion in a steam bath at standard atmospheric pressure and again mark the point indicated Divide the distance between these marks into equal portions according to the temperature scale being used Other fixed points used in the past are the body temperature of a healthy adult male which was originally used by Fahrenheit as his upper fixed point 96 F 35 6 C to be a number divisible by 12 and the lowest temperature given by a mixture of salt and ice which was originally the definition of 0 F 17 8 C 37 This is an example of a frigorific mixture As body temperature varies the Fahrenheit scale was later changed to use an upper fixed point of boiling water at 212 F 100 C 38 These have now been replaced by the defining points in the International Temperature Scale of 1990 though in practice the melting point of water is more commonly used than its triple point the latter being more difficult to manage and thus restricted to critical standard measurement Nowadays manufacturers will often use a thermostat bath or solid block where the temperature is held constant relative to a calibrated thermometer Other thermometers to be calibrated are put into the same bath or block and allowed to come to equilibrium then the scale marked or any deviation from the instrument scale recorded 39 For many modern devices calibration will be stating some value to be used in processing an electronic signal to convert it to a temperature Precision accuracy and reproducibility edit nbsp The Boyce MotoMeter radiator cap on a 1913 Car Nation automobile used to measure temperature of vapor in 1910s and 1920s cars nbsp Separated columns are often a problem in both alcohol and mercury thermometers and they can make a temperature reading inaccurate The precision or resolution of a thermometer is simply to what fraction of a degree it is possible to make a reading For high temperature work it may only be possible to measure to the nearest 10 C or more Clinical thermometers and many electronic thermometers are usually readable to 0 1 C Special instruments can give readings to one thousandth of a degree 40 However this precision does not mean the reading is true or accurate it only means that very small changes can be observed A thermometer calibrated to a known fixed point is accurate i e gives a true reading at that point The invention of the technology to measure temperature led to the creation of scales of temperature 41 In between fixed calibration points interpolation is used usually linear 39 This may give significant differences between different types of thermometer at points far away from the fixed points For example the expansion of mercury in a glass thermometer is slightly different from the change in resistance of a platinum resistance thermometer so these two will disagree slightly at around 50 C 42 There may be other causes due to imperfections in the instrument e g in a liquid in glass thermometer if the capillary tube varies in diameter 42 For many purposes reproducibility is important That is does the same thermometer give the same reading for the same temperature or do replacement or multiple thermometers give the same reading Reproducible temperature measurement means that comparisons are valid in scientific experiments and industrial processes are consistent Thus if the same type of thermometer is calibrated in the same way its readings will be valid even if it is slightly inaccurate compared to the absolute scale An example of a reference thermometer used to check others to industrial standards would be a platinum resistance thermometer with a digital display to 0 1 C its precision which has been calibrated at 5 points against national standards 18 0 40 70 100 C and which is certified to an accuracy of 0 2 C 43 According to British Standards correctly calibrated used and maintained liquid in glass thermometers can achieve a measurement uncertainty of 0 01 C in the range 0 to 100 C and a larger uncertainty outside this range 0 05 C up to 200 or down to 40 C 0 2 C up to 450 or down to 80 C 44 Indirect methods of temperature measurement editMain article Temperature measurement Technologies Thermal expansion Utilizing the property of thermal expansion of various phases of matter Pairs of solid metals with different expansion coefficients can be used for bi metal mechanical thermometers Another design using this principle is Breguet s thermometer Some liquids possess relatively high expansion coefficients over a useful temperature ranges thus forming the basis for an alcohol or mercury thermometer Alternative designs using this principle are the reversing thermometer and Beckmann differential thermometer As with liquids gases can also be used to form a gas thermometer Pressure Vapour pressure thermometer Density Galileo thermometer 45 Thermochromism Some compounds exhibit thermochromism at distinct temperature changes Thus by tuning the phase transition temperatures for a series of substances the temperature can be quantified in discrete increments a form of digitization This is the basis for a liquid crystal thermometer Band edge thermometry BET Band edge thermometry BET takes advantage of the temperature dependence of the band gap of semiconductor materials to provide very precise optical i e non contact temperature measurements 46 BET systems require a specialized optical system as well as custom data analysis software 47 48 Blackbody radiation nbsp An infrared thermometer is a kind of pyrometer bolometer All objects above absolute zero emit blackbody radiation for which the spectra is directly proportional to the temperature This property is the basis for a pyrometer or infrared thermometer and thermography It has the advantage of remote temperature sensing it does not require contact or even close proximity unlike most thermometers At higher temperatures blackbody radiation becomes visible and is described by the colour temperature For example a glowing heating element or an approximation of a star s surface temperature Fluorescence Phosphor thermometry Optical absorbance spectra Fiber optical thermometer Electrical resistance Resistance thermometer which use materials such as Balco alloy Thermistor Coulomb blockade thermometer Electrical potential Thermocouples are useful over a wide temperature range from cryogenic temperatures to over 1000 C but typically have an error of 0 5 1 5 C Silicon bandgap temperature sensors are commonly found packaged in integrated circuits with accompanying ADC and interface such as I2C Typically they are specified to work within about 50 to 150 C with accuracies in the 0 25 to 1 C range but can be improved by binning 49 50 Electrical resonance Quartz thermometer Nuclear magnetic resonance Chemical shift is temperature dependent This property is used to calibrate the thermostat of NMR probes usually using methanol or ethylene glycol 51 52 This can potentially be problematic for internal standards which are usually assumed to have a defined chemical shift e g 0 ppm for TMS but in fact exhibit a temperature dependence 53 Magnetic susceptibility See also Paramagnetism Curie s law Above the Curie temperature the magnetic susceptibility of a paramagnetic material exhibits an inverse temperature dependence This phenomenon is the basis of a magnetic cryometer 54 55 Applications editSee also List of temperature sensors Thermometers utilize a range of physical effects to measure temperature Temperature sensors are used in a wide variety of scientific and engineering applications especially measurement systems Temperature systems are primarily either electrical or mechanical occasionally inseparable from the system which they control as in the case of a mercury in glass thermometer Thermometers are used in roadways in cold weather climates to help determine if icing conditions exist Indoors thermistors are used in climate control systems such as air conditioners freezers heaters refrigerators and water heaters 56 Galileo thermometers are used to measure indoor air temperature due to their limited measurement range Such liquid crystal thermometers which use thermochromic liquid crystals are also used in mood rings and used to measure the temperature of water in fish tanks Fiber Bragg grating temperature sensors are used in nuclear power facilities to monitor reactor core temperatures and avoid the possibility of nuclear meltdowns 57 Nanothermometry edit Nanothermometry is an emergent research field dealing with the knowledge of temperature in the sub micrometric scale Conventional thermometers cannot measure the temperature of an object which is smaller than a micrometre and new methods and materials have to be used Nanothermometry is used in such cases Nanothermometers are classified as luminescent thermometers if they use light to measure temperature and non luminescent thermometers systems where thermometric properties are not directly related to luminescence 58 Cryometer edit Main article cryometer Thermometers used specifically for low temperatures Medical edit Main article Medical thermometer nbsp A Kinsa QuickCare smart thermometer Ear thermometers tend to be an infrared thermometer Forehead thermometer is an example of a liquid crystal thermometer Rectal and oral thermometers have typically been mercury but have since largely been superseded by NTC thermistors with a digital readout 59 Various thermometric techniques have been used throughout history such as the Galileo thermometer to thermal imaging 45 Medical thermometers such as mercury in glass thermometers infrared thermometers pill thermometers and liquid crystal thermometers are used in health care settings to determine if individuals have a fever or are hypothermic Food and food safety edit Thermometers are important in food safety where food at temperatures within 41 and 135 F 5 and 57 C can be prone to potentially harmful levels of bacterial growth after several hours which could lead to foodborne illness This includes monitoring refrigeration temperatures and maintaining temperatures in foods being served under heat lamps or hot water baths 56 Cooking thermometers are important for determining if a food is properly cooked In particular meat thermometers are used to aid in cooking meat to a safe internal temperature while preventing over cooking They are commonly found using either a bimetallic coil or a thermocouple or thermistor with a digital readout Candy thermometers are used to aid in achieving a specific water content in a sugar solution based on its boiling temperature Environmental edit Indoor outdoor thermometer Heat meter uses a thermometer to measure rate of heat flow Thermostats have used bimetallic strips but digital thermistors have since become popular Alcohol thermometers infrared thermometers mercury in glass thermometers recording thermometers thermistors and Six s thermometers maximum minimum thermometer are used in meteorology and climatology in various levels of the atmosphere and oceans Aircraft use thermometers and hygrometers to determine if atmospheric icing conditions exist along their flight path These measurements are used to initialize weather forecast models Thermometers are used in roadways in cold weather climates to help determine if icing conditions exist and indoors in climate control systems See also editAutomated airport weather station Thermodynamic instruments Hygrometer Psychrometer wet and dry bulb thermometer References edit Knake Maria April 2011 The Anatomy of a Liquid in Glass Thermometer AASHTO re source formerly AMRL aashtoresource org Retrieved 4 August 2018 For decades mercury thermometers were a mainstay in many testing laboratories If used properly and calibrated correctly certain types of mercury thermometers can be incredibly accurate Mercury thermometers can be used in temperatures ranging from about 38 to 350 C The use of a mercury thallium mixture can extend the low temperature usability of mercury thermometers to 56 C Nevertheless few liquids have been found to mimic the thermometric properties of mercury in repeatability and accuracy of temperature measurement Toxic though it may be when it comes to LiG Liquid in Glass thermometers mercury is still hard to beat a b c d e f g Middleton W E K 1966 A history of the thermometer and its use in meteorology Internet Archive Johns Hopkins Press ISBN 9780801871535 Hero 1851 The Pneumatics of Hero of Alexandria London Taylor Walton and Maberly p 69 Bibcode 1851phal book W Retrieved 28 November 2023 R S Doak 2005 Galileo astronomer and physicist ISBN 0 7565 0813 4 p36 a b Bigotti Fabrizio 2018 The Weight of the Air Santorio s Thermometers and the Early History of Medical Quantification Reconsidered Journal of Early Modern Studies 7 1 73 103 doi 10 5840 jems2018714 ISSN 2285 6382 PMC 6407691 PMID 30854347 T D McGee 1988 Principles and Methods of Temperature Measurement page 3 ISBN 0 471 62767 4 T D McGee 1988 Principles and Methods of Temperature Measurement pages 2 4 ISBN 0 471 62767 4 a b R P Benedict 1984 Fundamentals of Temperature Pressure and Flow Measurements 3rd ed ISBN 0 471 89383 8 page 4 Adler Jacob 1997 J S Delmedigo and the Liquid in Glass Thermometer Annals of Science 54 3 293 299 doi 10 1080 00033799700200221 Bolton H C 1900 Evolution of the thermometer 1592 1743 Easton PA The Chemical Publishing Company pp 7 8 Wright William F 2016 Early evolution of the thermometer and application to clinical medicine Journal of Thermal Biology 56 18 30 doi 10 1016 j jtherbio 2015 12 003 PMID 26857973 R P Benedict 1984 Fundamentals of Temperature Pressure and Flow Measurements 3rd ed ISBN 0 471 89383 8 page 6 Christin s thermometer Archived 2013 06 01 at the Wayback Machine and Linnaeus thermometer Tan S Y Hu M 2004 Medicine in Stamps Hermann Boerhaave 1668 1738 18th Century Teacher Extraordinaire PDF Singapore Medical Journal Vol 45 no 1 pp 3 5 Sir Thomas Clifford Allbutt Encyclopaedia Britannica Exergen Corporation Exergen com Retrieved on 2011 03 30 Patents By Inventor Francesco Pompei Justia Patents Patents justia com Retrieved on 2011 03 30 Beattie J A Oppenheim I 1979 Principles of Thermodynamics Elsevier Scientific Publishing Company Amsterdam ISBN 0 444 41806 7 page 29 a b Thomsen J S 1962 A restatement of the zeroth law of thermodynamics Am J Phys 30 4 294 296 Bibcode 1962AmJPh 30 294T doi 10 1119 1 1941991 Mach E 1900 Die Principien der Warmelehre Historisch kritisch entwickelt Johann Ambrosius Barth Leipzig section 22 pages 56 57 English translation edited by McGuinness B 1986 Principles of the Theory of Heat Historically and Critically Elucidated D Reidel Publishing Dordrecht ISBN 90 277 2206 4 section 5 pp 48 49 section 22 pages 60 61 a b Truesdell C A 1980 The Tragicomical History of Thermodynamics 1822 1854 Springer New York ISBN 0 387 90403 4 Serrin J 1986 Chapter 1 An Outline of Thermodynamical Structure pages 3 32 especially page 6 in New Perspectives in Thermodynamics edited by J Serrin Springer Berlin ISBN 3 540 15931 2 Serrin J 1978 The concepts of thermodynamics in Contemporary Developments in Continuum Mechanics and Partial Differential Equations Proceedings of the International Symposium on Continuum Mechanics and Partial Differential Equations Rio de Janeiro August 1977 edited by G M de La Penha L A J Medeiros North Holland Amsterdam ISBN 0 444 85166 6 pages 411 451 Planck M 1926 Uber die Begrundung des zweiten Hauptsatzes der Thermodynamik S B Preuss Akad Wiss phys math Kl 453 463 Buchdahl H A 1966 The Concepts of Classical Thermodynamics Cambridge University Press London pp 42 43 Lieb E H Yngvason J 1999 The physics and mathematics of the second law of thermodynamics Physics Reports 314 1 2 1 96 56 arXiv hep ph 9807278 Bibcode 1999PhR 314 1L doi 10 1016 S0370 1573 98 00128 8 S2CID 119517140 Truesdell C Bharatha S 1977 The Concepts and Logic of Classical Thermodynamics as a Theory of Heat Engines Rigorously Constructed upon the Foundation Laid by S Carnot and F Reech Springer New York ISBN 0 387 07971 8 page 20 Ziegler H 1983 An Introduction to Thermomechanics North Holland Amsterdam ISBN 0 444 86503 9 Landsberg P T 1961 Thermodynamics with Quantum Statistical Illustrations Interscience Publishers New York page 17 Maxwell J C 1872 Theory of Heat third edition Longmans Green and Co London pages 232 233 Lewis G N Randall M 1923 1961 Thermodynamics second edition revised by K S Pitzer L Brewer McGraw Hill New York pages 378 379 Thomsen J S Hartka T J 1962 Strange Carnot cycles thermodynamics of a system with a density extremum Am J Phys 30 1 26 33 Bibcode 1962AmJPh 30 26T doi 10 1119 1 1941890 a b Truesdell C Bharatha S 1977 The Concepts and Logic of Classical Thermodynamics as a Theory of Heat Engines Rigorously Constructed upon the Foundation Laid by S Carnot and F Reech Springer New York ISBN 0 387 07971 8 pages 9 10 15 18 36 37 Planck M 1897 1903 Treatise on Thermodynamics translated by A Ogg Longmans Green amp Co London Preston T 1894 1904 The Theory of Heat second edition revised by J R Cotter Macmillan London Section 92 0 a b Kauppinen J P Loberg K T Manninen A J Pekola J P 1998 Coulomb blockade thermometer Tests and instrumentation Rev Sci Instrum 69 12 4166 4175 Bibcode 1998RScI 69 4166K doi 10 1063 1 1149265 S2CID 33345808 R P Benedict 1984 Fundamentals of Temperature Pressure and Flow Measurements 3rd ed ISBN 0 471 89383 8 page 5 J Lord 1994 Sizes ISBN 0 06 273228 5 page 293 a b R P Benedict 1984 Fundamentals of Temperature Pressure and Flow Measurements 3rd ed ISBN 0 471 89383 8 chapter 11 Calibration of Temperature Sensors Yoon Howard W Khromchenko Vladimir Eppeldauer George P 2 May 2019 Improvements in the design of thermal infrared radiation thermometers and sensors Optics Express 27 10 14246 14259 Bibcode 2019OExpr 2714246Y doi 10 1364 OE 27 014246 PMID 31163876 S2CID 155990906 Retrieved 7 March 2023 The Strange History of the Invention of the Thermometer Time Retrieved 2022 12 21 a b T Duncan 1973 Advanced Physics Materials and Mechanics John Murray London ISBN 0 7195 2844 5 Peak Sensors Archived 2011 09 21 at the Wayback Machine Reference Thermometer BS1041 2 1 1985 Temperature Measurement Part 2 Expansion thermometers Section 2 1 Guide to selection and use of liquid in glass thermometers a b E F J Ring January 2007 The historical development of temperature measurement in medicine Infrared Physics amp Technology 49 3 297 301 Bibcode 2007InPhT 49 297R doi 10 1016 j infrared 2006 06 029 Band edge thermometry Molecular Beam Epitaxy Research Group 2014 08 19 Retrieved 2019 08 14 Johnson Shane May 1998 In situ temperature control of molecular beam epitaxy growth using band edge thermometry Journal of Vacuum Science amp Technology B Microelectronics and Nanometer Structures 16 3 1502 1506 Bibcode 1998JVSTB 16 1502J doi 10 1116 1 589975 hdl 2286 R I 27894 Wissman Barry June 2016 The truth behind today s wafer temperature methods Band edge thermometry vs emissivity corrected pyrometry PDF Retrieved December 22 2020 MCP9804 0 25 C Typical Accuracy Digital Temperature Sensor Microchip 2012 Retrieved 2017 01 03 Si7050 1 3 4 5 A20 I2C Temperature Sensors PDF Silicon Labs 2016 Retrieved 2017 01 03 Findeisen M Brand T Berger S February 2007 A1H NMR thermometer suitable for cryoprobes Magnetic Resonance in Chemistry 45 2 175 178 doi 10 1002 mrc 1941 PMID 17154329 S2CID 43214876 Braun Stefan Berger Siegmar 2004 200 and more NMR experiments a practical course 3 ed ed Weinheim WILEY VCH ISBN 978 3 527 31067 8 a href Template Cite book html title Template Cite book cite book a CS1 maint multiple names authors list link Hoffman Roy E Becker Edwin D September 2005 Temperature dependence of the 1H chemical shift of tetramethylsilane in chloroform methanol and dimethylsulfoxide Journal of Magnetic Resonance 176 1 87 98 Bibcode 2005JMagR 176 87H doi 10 1016 j jmr 2005 05 015 PMID 15996496 Krusius Matti 2014 Magnetic thermometer AccessScience doi 10 1036 1097 8542 398650 Sergatskov D A Oct 2003 New Paramagnetic Susceptibility Thermometers for Fundamental Physics Measurements PDF AIP Conference Proceedings PDF Vol 684 pp 1009 1014 doi 10 1063 1 1627261 a b Angela M Fraser Ph D 2006 04 24 Food Safety Thermometers PDF North Carolina State University pp 1 2 Retrieved 2010 02 26 Fernandez Alberto Fernandez Gusarov Andrei I Brichard Benoit Bodart Serge Lammens Koen Berghmans Francis Decreton Marc Megret Patrice Blondel Michel Delchambre Alain 2002 Temperature monitoring of nuclear reactor cores with multiplexed fiber Bragg grating sensors Optical Engineering 41 6 1246 1254 Bibcode 2002OptEn 41 1246F CiteSeerX 10 1 1 59 1761 doi 10 1117 1 1475739 Brites Carlos D S Lima Patricia P Silva Nuno J O Millan Angel Amaral Vitor S Palacio Fernando Carlos Luis D 2012 Thermometry at the nanoscale Nanoscale 4 16 4799 829 Bibcode 2012Nanos 4 4799B doi 10 1039 C2NR30663H hdl 10261 76059 PMID 22763389 US Active 6854882 Ming Yun Chen Rapid response electronic clinical thermometer published 2005 02 15 assigned to Actherm Inc Further reading editMiddleton W E K 1966 A history of the thermometer and its use in meteorology Baltimore Johns Hopkins Press Reprinted ed 2002 ISBN 0 8018 7153 0 History of the Thermometer Archived 2016 03 06 at the Wayback Machine Thermometry at the Nanoscale Recent reviewExternal links edit nbsp Look up thermometer in Wiktionary the free dictionary nbsp Wikimedia Commons has media related to Measuring instruments temperature History of Temperature and Thermometry archived 25 February 2008 The Chemical Educator Vol 5 No 2 2000 Archived 2004 03 10 at the Wayback Machine The Thermometer From The Feeling To The Instrument History Channel Invention Notable Modern Inventions and Discoveries archived 24 April 2008 About Thermometer Archived 2020 01 22 at the Wayback Machine Thermometers Early History Anders Celsius Gabriel Fahrenheit and Thomson Kelvin Thermometers and Thermometric Liquids Mercury and Alcohol The NIST Industrial Thermometer Calibration Laboratory Archived 2016 07 22 at the Wayback Machine Thermometry at the Nanoscale Review Retrieved from https en wikipedia org w index php title Thermometer amp oldid 1217190341, wikipedia, wiki, book, books, library,

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