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Wikipedia

Gemstone

A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewelry or other adornments.[1][2][3] Certain rocks (such as lapis lazuli, opal, and obsidian) and occasionally organic materials that are not minerals (such as amber, jet, and pearl) may also be used for jewelry and are therefore often considered to be gemstones as well.[4][5] Most gemstones are hard, but some softer minerals such as brazilianite may be used in jewelry[6] because of their color or luster or other physical properties that have aesthetic value. However, generally speaking, soft minerals are not typically used as gemstones by virtue of their brittleness and lack of durability.[7]

Group of precious and semiprecious stones—both uncut and faceted—including (clockwise from top left) diamond, uncut synthetic sapphire, ruby, uncut emerald, and amethyst crystal cluster.

Found all over the world, the industry of coloured gemstones (i.e. anything other than diamonds) is currently estimated at around US$ 1.55 billion as of 2023 and is projected to steadily increase to a value of US$ 4.46 billion by 2033.[8]

A gem expert is a gemologist, a gem maker is called a lapidarist or gemcutter; a diamond cutter is called a diamantaire.

Characteristics and classification edit

 
A collection of gemstone pebbles made by tumbling the rough stones, except the ruby and tourmaline, with abrasive grit inside a rotating barrel. The largest pebble here is 40 mm (1.6 in) long.

The traditional classification in the West, which goes back to the ancient Greeks, begins with a distinction between precious and semi-precious; similar distinctions are made in other cultures. In modern use, the precious stones are emerald, ruby, sapphire and diamond, with all other gemstones being semi-precious.[9] This distinction reflects the rarity of the respective stones in ancient times, as well as their quality: all are translucent, with fine color in their purest forms (except for the colorless diamond), and very hard with a hardness score of 8 to 10 on the Mohs scale.[10] Other stones are classified by their color, translucency, and hardness. The traditional distinction does not necessarily reflect modern values; for example, while garnets are relatively inexpensive, a green garnet called tsavorite can be far more valuable than a mid-quality emerald.[11] Another traditional term for semi-precious gemstones used in art history and archaeology is hardstone. Use of the terms 'precious' and 'semi-precious' in a commercial context is, arguably, misleading in that it suggests certain stones are more valuable than others when this is not reflected in the actual market value, although it would generally be correct if referring to desirability.

In modern times gemstones are identified by gemologists, who describe gems and their characteristics using technical terminology specific to the field of gemology. The first characteristic a gemologist uses to identify a gemstone is its chemical composition. For example, diamonds are made of carbon (C) and rubies of aluminium oxide (Al
2
O
3
). Many gems are crystals which are classified by their crystal system such as cubic or trigonal or monoclinic. Another term used is habit, the form the gem is usually found in.[12] For example, diamonds, which have a cubic crystal system, are often found as octahedrons.[13]

Gemstones are classified into different groups, species, and varieties.[14][15] For example, ruby is the red variety of the species corundum, while any other color of corundum is considered sapphire. Other examples are the emerald (green), aquamarine (blue), red beryl (red), goshenite (colorless), heliodor (yellow), and morganite (pink), which are all varieties of the mineral species beryl.

Gems are characterized in terms of their color (hue, tone and saturation), optical phenomena, luster, refractive index, birefringence, dispersion, specific gravity, hardness, cleavage, and fracture.[16][17] They may exhibit pleochroism or double refraction. They may have luminescence and a distinctive absorption spectrum. Gemstones may also be classified in terms of their "water". This is a recognized grading of the gem's luster, transparency, or "brilliance".[18] Very transparent gems are considered "first water", while "second" or "third water" gems are those of a lesser transparency.[19] Additionally, material or flaws within a stone may be present as inclusions.[20]

Value edit

 
Spanish emerald and gold pendant at Victoria and Albert Museum
 
Enamelled gold, amethyst, and pearl pendant, about 1880, Pasquale Novissimo (1844–1914), V&A Museum number M.36-1928

Gemstones have no universally accepted grading system. Diamonds are graded using a system developed by the Gemological Institute of America (GIA) in the early 1950s. Historically, all gemstones were graded using the naked eye. The GIA system included a major innovation: the introduction of 10x magnification as the standard for grading clarity. Other gemstones are still graded using the naked eye (assuming 20/20 vision).[21]

A mnemonic device, the "four Cs" (color, cut, clarity, and carats), has been introduced to help describe the factors used to grade a diamond. With modification, these categories can be useful in understanding the grading of all gemstones. The four criteria carry different weights depending upon whether they are applied to colored gemstones or to colorless diamonds. In diamonds, the cut is the primary determinant of value, followed by clarity and color. An ideally cut diamond will sparkle, to break down light into its constituent rainbow colors (dispersion), chop it up into bright little pieces (scintillation), and deliver it to the eye (brilliance). In its rough crystalline form, a diamond will do none of these things; it requires proper fashioning and this is called "cut". In gemstones that have color, including colored diamonds, the purity, and beauty of that color is the primary determinant of quality.[22]

Physical characteristics that make a colored stone valuable are color, clarity to a lesser extent (emeralds will always have a number of inclusions), cut, unusual optical phenomena within the stone such as color zoning (the uneven distribution of coloring within a gem)[23] and asteria (star effects).

Apart from the more generic and commonly used gemstones such as from diamonds, rubies, sapphires, and emeralds, pearls and opal[24] have also been defined as precious in the jewellery trade. Up to the discoveries of bulk amethyst in Brazil in the 19th century, amethyst was considered a "precious stone" as well, going back to ancient Greece. Even in the last century certain stones such as aquamarine, peridot and cat's eye (cymophane) have been popular and hence been regarded as precious, thus reinforcing the notion that a mineral's rarity may have been implicated in its classification as a precious stone and thus contribute to its value.

Today the gemstone trade no longer makes such a distinction.[25] Many gemstones are used in even the most expensive jewelry, depending on the brand-name of the designer, fashion trends, market supply, treatments, etc. Nevertheless, diamonds, rubies, sapphires, and emeralds still have a reputation that exceeds those of other gemstones.[26]

Rare or unusual gemstones, generally understood to include those gemstones which occur so infrequently in gem quality that they are scarcely known except to connoisseurs, include andalusite, axinite, cassiterite, clinohumite, painite and red beryl.[27]

Gemstone pricing and value are governed by factors and characteristics in the quality of the stone. These characteristics include clarity, rarity, freedom from defects, the beauty of the stone, as well as the demand for such stones. There are different pricing influencers for both colored gemstones, and for diamonds. The pricing on colored stones is determined by market supply-and-demand, but diamonds are more intricate.[28] Diamond value can change based on location, time, and on the evaluations of diamond vendors, especially since most of the diamond supply in the world is strongly and exclusive controlled by a single authority, DeBeers.[29]

In the addition to the aesthetic and adorning/ornamental purpose of gemstones, there are many proponents of energy medicine who also value gemstones on the basis of their alleged healing powers.[30]

A gemstone that has been rising in popularity is Cuprian Elbaite Tourmaline which is also called "Paraiba Tourmaline". It was first discovered in the late 1980s in Paraíba, Brazil and later in Mozambique and Nigeria.[31] It is famous for its glowing neon blue color. Paraiba Tourmaline has become one of the most popular gemstones in recent times thanks to its color and is considered to be one of the important gemstones after rubies, emeralds, and sapphires according to Gübelin Gemlab. Even though it is a tourmaline, Paraiba Tourmaline is one of the most expensive gemstones.[32]

Grading edit

There are a number of laboratories which grade and provide reports on gemstones.[25]

  • Gemological Institute of America (GIA), the main provider of education services and diamond grading reports
  • International Gemological Institute (IGI), independent laboratory for grading and evaluation of diamonds, jewelry, and colored stones
  • Hoge Raad Voor Diamant (HRD Antwerp), The Diamond High Council, Belgium is one of Europe's oldest laboratories; its main stakeholder is the Antwerp World Diamond Centre
  • American Gemological Society (AGS) is not as widely recognized nor as old as the GIA
  • American Gem Trade Laboratory which is part of the American Gem Trade Association (AGTA), a trade organization of jewelers and dealers of colored stones
  • American Gemological Laboratories (AGL), owned by Christopher P. Smith
  • European Gemological Laboratory (EGL), founded in 1974 by Guy Margel in Belgium
  • Gemmological Association of All Japan (GAAJ-ZENHOKYO), Zenhokyo, Japan, active in gemological research
  • The Gem and Jewelry Institute of Thailand (Public Organization) or GIT, Thailand's national institute for gemological research and gem testing, Bangkok[33]
  • Gemmology Institute of Southern Africa, Africa's premium gem laboratory
  • Asian Institute of Gemological Sciences (AIGS), the oldest gemological institute in South East Asia, involved in gemological education and gem testing
  • Swiss Gemmological Institute (SSEF), founded by Henry Hänni, focusing on colored gemstones and the identification of natural pearls
  • Gübelin Gem Lab, the traditional Swiss lab founded by Eduard Gübelin
  • Institute for Gems and Gold Research of VINAGEMS (Vietnam), founded by Van Long Pham[citation needed]

Each laboratory has its own methodology to evaluate gemstones. A stone can be called "pink" by one lab while another lab calls it "padparadscha". One lab can conclude a stone is untreated, while another lab might conclude that it is heat-treated.[25] To minimize such differences, seven of the most respected labs, AGTA-GTL (New York), CISGEM (Milano), GAAJ-ZENHOKYO (Tokyo), GIA (Carlsbad), GIT (Bangkok), Gübelin (Lucerne) and SSEF (Basel), have established the Laboratory Manual Harmonisation Committee (LMHC), for the standardization of wording reports, promotion of certain analytical methods and interpretation of results. Country of origin has sometimes been difficult to determine, due to the constant discovery of new source locations. Determining a "country of origin" is thus much more difficult than determining other aspects of a gem (such as cut, clarity, etc.).[34]

Gem dealers are aware of the differences between gem laboratories and will make use of the discrepancies to obtain the best possible certificate.[25]

Cutting and polishing edit

 
A diamond cutter in Amsterdam

A few gemstones are used as gems in the crystal or other forms in which they are found. Most, however, are cut and polished for usage as jewelry. The two main classifications are as follows:

  • Stones cut as smooth, dome-shaped stones called cabochons or simply cab. These have been a popular shape since ancient time and is more durable than faceted gems.[35]
  • Stones which are cut with a faceting machine by polishing small flat windows called facets at regular intervals at exact angles.[35]

Stones which are opaque or semi-opaque such as opal, turquoise, variscite, etc. are commonly cut as cabochons. These gems are designed to show the stone's color, luster and other surface properties as opposed to internal reflection properties like brilliance.[36] Grinding wheels and polishing agents are used to grind, shape, and polish the smooth dome shape of the stones.[37]

Gems that are transparent are normally faceted, a method that shows the optical properties of the stone's interior to its best advantage by maximizing reflected light which is perceived by the viewer as sparkle. There are many commonly used shapes for faceted stones. The facets must be cut at the proper angles, which varies depending on the optical properties of the gem. If the angles are too steep or too shallow, the light will pass through and not be reflected back toward the viewer. The faceting machine is used to hold the stone onto a flat lap for cutting and polishing the flat facets.[38] Rarely, some cutters use special curved laps to cut and polish curved facets.

Colors edit

 
Nearly 300 variations of diamond color exhibited at the Aurora display at the Natural History Museum in London
 
A variety of semiprecious stones in a piece of jewellery

The color of any material is due to the nature of light itself. Daylight, often called white light, is all of the colors of the spectrum combined. When light strikes a material, most of the light is absorbed while a smaller amount of a particular frequency or wavelength is reflected. The part that is reflected reaches the eye as the perceived color.[39] A ruby appears red because it absorbs all other colors of white light while reflecting red.

A material which is mostly the same can exhibit different colors. For example, ruby and sapphire have the same primary chemical composition (both are corundum)[40] but exhibit different colors because of impurities which absorb and reflect different wavelengths of light depending on their individual compositions. Even the same named gemstone can occur in many different colors: sapphires show different shades of blue and pink and "fancy sapphires" exhibit a whole range of other colors from yellow to orange-pink, the latter called "padparadscha sapphire".[41]

This difference in color is based on the atomic structure of the stone. Although the different stones formally have the same chemical composition and structure, they are not exactly the same. Every now and then an atom is replaced by a completely different atom, sometimes as few as one in a million atoms. These so-called impurities are sufficient to absorb certain colors and leave the other colors unaffected. For example, beryl, which is colorless in its pure mineral form, becomes emerald with chromium impurities. If manganese is added instead of chromium, beryl becomes pink morganite. With iron, it becomes aquamarine.Some gemstone treatments make use of the fact that these impurities can be "manipulated", thus changing the color of the gem.

Treatment edit

Gemstones are often treated to enhance the color or clarity of the stone.[42] In some cases, the treatment applied to the gemstone can also increase its durability. Even though natural gemstones can be transformed using the traditional method of cutting and polishing, other treatment options allow the stone's appearance to be enhanced.[43] Depending on the type and extent of treatment, they can affect the value of the stone. Some treatments are used widely because the resulting gem is stable, while others are not accepted most commonly because the gem color is unstable and may revert to the original tone.[44]

Early history edit

Before the innovation of modern-day tools, thousands of years ago, people were recorded to use a variety of techniques to treat and enhance gemstones. Some of the earliest methods of gemstone treatment date back to the Minoan Age, for example foiling, which is where metal foil is used to enhance a gemstone's colour.[45] Other methods recorded 2000 years ago in the book Natural History by Pliny the Elder include oiling and dyeing/staining.

Heat edit

Heat can either improve or spoil gemstone color or clarity. The heating process has been well known to gem miners and cutters for centuries, and in many stone types heating is a common practice. Most citrine is made by heating amethyst, and partial heating with a strong gradient results in "ametrine" – a stone partly amethyst and partly citrine. Aquamarine is often heated to remove yellow tones, or to change green colors into the more desirable blue, or enhance its existing blue color to a deeper blue.[44]

Nearly all tanzanite is heated at low temperatures to remove brown undertones and give a more desirable blue / purple color.[46] A considerable portion of all sapphire and ruby is treated with a variety of heat treatments to improve both color and clarity.

When jewelry containing diamonds is heated for repairs, the diamond should be protected with boric acid; otherwise, the diamond, which is pure carbon, could be burned on the surface or even burned completely up. When jewelry containing sapphires or rubies is heated, those stones should not be coated with boric acid (which can etch the surface) or any other substance. They do not have to be protected from burning, like a diamond (although the stones do need to be protected from heat stress fracture by immersing the part of the jewelry with stones in the water when metal parts are heated).

Radiation edit

The irradiation process is widely practiced in jewelry industry[47] and enabled the creation of gemstone colors that do not exist or are extremely rare in nature.[48] However, particularly when done in a nuclear reactor, the processes can make gemstones radioactive. Health risks related to the residual radioactivity of the treated gemstones have led to government regulations in many countries.[48][49]

Virtually all blue topaz, both the lighter and the darker blue shades such as "London" blue, has been irradiated to change the color from white to blue. Most green quartz (Oro Verde) are also irradiated to achieve the yellow-green color. Diamonds are mainly irradiated to become blue-green or green, although other colors are possible. When light-to-medium-yellow diamonds are treated with gamma rays they may become green; with a high-energy electron beam, blue.[50]

Waxing/oiling edit

Emeralds containing natural fissures are sometimes filled with wax or oil to disguise them. This wax or oil is also colored to make the emerald appear of better color as well as clarity. Turquoise is also commonly treated in a similar manner.

Fracture filling edit

 
The foreign material inside this fracture-filled emerald appears rainbow-colored under darkfield illumination.

Fracture filling has been in use with different gemstones such as diamonds, emeralds, and sapphires. In 2006 "glass-filled rubies" received publicity. Rubies over 10 carats (2 g) with large fractures were filled with lead glass, thus dramatically improving the appearance (of larger rubies in particular). Such treatments are fairly easy to detect.

Bleaching edit

 
Pearls are a gemstone that is commonly treated with hydrogen peroxide to remove unwanted colours

Another treatment method that is commonly used to treat gemstones is bleaching. This method uses a chemical in order to reduce the colour of the gem. After bleaching, a combination treatment can be done by dying the gemstone once the unwanted colours are removed. Hydrogen peroxide is the most commonly used product used to alter gemstones and have notably been used to treat jade and pearls. The treatment of bleaching can also be followed by impregnation, which allows the gemstone's durability to be increased.[43]

Socioeconomic issues in the gemstone industry edit

The socio-economic dynamics of the gemstone industry are shaped by market forces and consumer preferences and typically go undiscussed. Changes in demand and prices can significantly affect the livelihoods of those involved in gemstone mining and trade, particularly in developing countries where the industry serves as a crucial source of income.[51]

A situation that arises as a result of this is the exploitation of natural resources and labor within gemstone mining operations. Many mines, particularly in developing countries, face challenges such as inadequate safety measures, low wages, and poor working conditions.[51] Miners, often from disadvantaged backgrounds, endure hazardous working conditions and receive meager wages, contributing to cycles of poverty and exploitation.[52] Gemstone mining operations are frequently conducted in remote or underdeveloped areas, lacking proper infrastructure and access to essential services such as healthcare and education. This further contributes to the pre-existing socio-economic disparities and obstructs community development such that the benefits of gemstone extraction may not adequately reach those directly involved in the process.[53]

Another such issue revolves around environmental degradation resulting from mining activities. Environmental degradation can pose long-term threats to ecosystems and biodiversity, further worsening the socio-economic state in affected regions.[54] Unregulated mining practices often result in deforestation, soil erosion, and water contamination thus threatening ecosystems and biodiversity.[55] Unregulated mining activity can also cause depletion of natural resources, thus diminishing the prospects for sustainable development.[56] The environmental impact of gemstone mining not only poses a threat to ecosystems but also undermines the long-term viability of the industry by diminishing the quality and quantity of available resources.

Furthermore, the gemstone industry is also susceptible to issues related to transparency and ethics, which impact both producers and consumers. The lack of standardized certification processes and the prevalence of illicit practices undermine market integrity and trust.[57] The lack of transparency and accountability in the supply chain aggravates pre-existing inequalities, as middlemen and corporations often capture a disproportionate share of the profits. As a result the unequal distribution of profits along the supply chain does little to improve socio-economic inequalities, particularly in regions where gemstones are mined.

Addressing these socio-economic challenges requires intensive effort from various stakeholders, including governments, industry executives, and society, to promote sustainable practices and ensure equitable outcomes for all involved parties. Implementing and enforcing regulations to ensure fair labor practices, environmental sustainability, and ethical sourcing is essential. Additionally, investing in community development projects, such as education and healthcare initiatives, can help alleviate poverty and empower marginalized communities dependent on the gemstone industry. Collaboration across sectors is crucial for fostering a more equitable and sustainable gemstone trade that benefits both producers and consumers while respecting human rights and environmental integrity.

Synthetic and artificial gemstones edit

Synthetic gemstones are distinct from imitation or simulated gems.

Synthetic gems are physically, optically, and chemically identical to the natural stone, but are created in a laboratory.[58] Imitation or simulated stones are chemically different from the natural stone, but may appear quite similar to it; they can be more easily manufactured synthetic gemstones of a different mineral (spinel), glass, plastic, resins, or other compounds.

Examples of simulated or imitation stones include cubic zirconia, composed of zirconium oxide, synthetic moissanite, and uncolored, synthetic corundum or spinels; all of which are diamond simulants. The simulants imitate the look and color of the real stone but possess neither their chemical nor physical characteristics. In general, all are less hard than diamond. Moissanite actually has a higher refractive index than diamond, and when presented beside an equivalently sized and cut diamond will show more "fire".

Cultured, synthetic, or "lab-created" gemstones are not imitations: The bulk mineral and trace coloring elements are the same in both. For example, diamonds, rubies, sapphires, and emeralds have been manufactured in labs that possess chemical and physical characteristics identical to the naturally occurring variety. Synthetic (lab created) corundum, including ruby and sapphire, is very common and costs much less than the natural stones. Small synthetic diamonds have been manufactured in large quantities as industrial abrasives, although larger gem-quality synthetic diamonds are becoming available in multiple carats.[59]

Whether a gemstone is a natural stone or synthetic, the chemical, physical, and optical characteristics are the same: They are composed of the same mineral and are colored by the same trace materials, have the same hardness and density and strength, and show the same color spectrum, refractive index, and birefringence (if any). Lab-created stones tend to have a more vivid color since impurities common in natural stones are not present in the synthetic stone. Synthetics are made free of common naturally occurring impurities that reduce gem clarity or color unless intentionally added in order to provide a more drab, natural appearance, or to deceive an assayer.[citation needed] On the other hand, synthetics often show flaws not seen in natural stones, such as minute particles of corroded metal from lab trays used during synthesis.[citation needed]

Types edit

Some gemstones are more difficult to synthesize than others and not all stones are commercially viable to attempt to synthesize. These are the most common on the market currently.[60]

Synthetic corundum edit

Synthetic corundum includes ruby (red variation) and sapphire (other color variations), both of which are considered highly desired and valued.[60] Ruby was the first gemstone to be synthesized by Auguste Verneuil with his development of the flame-fusion process in 1902.[61] Synthetic corundum continues to be made typically by flame-fusion as it is most cost-effective, but can also be produced through flux growth and hydrothermal growth.[62]

Synthetic beryls edit

The most common synthesized beryl is emerald (green). Yellow, red and blue beryls are possible but much more rare. Synthetic emerald became possible with the development of the flux growth process and is produced in this way and well as hydrothermal growth.[63]

Synthetic quartz edit

Types of synthetic quartz include citrine, rose quartz, and amethyst. Natural occurring quartz is not rare is synthetically produced as it has practical application outside of aesthetic purposes. Quartz generates an electric current when under pressure and is used in watches, clocks, and oscillators.[64]

Synthetic spinel edit

Synthetic spinel was first produced by accident.[clarification needed] It can be created in any color making it popular to simulate various natural gemstones. It is created through flux growth and hydrothermal growth.[60]

Creation process edit

There are two main categories for creation of these minerals: melt or solution processes.[60]

Verneuil flame fusion process (melt process) edit

 
Verneuil furnace

The flame fusion process was the first process used which successfully created large quantities of synthetic gemstones to be sold on the market.[65] This remains the most cost effective and common method of creating corundums today.

The flame fusion process is completed in a Verneuil furnace. The furnace consists of an inverted blowpipe burner which produces an extremely hot oxyhydrogen flame, a powder dispenser, and a ceramic pedestal.[66] A chemical powder which corresponds to the desired gemstone is passed through this flames. This melts the ingredients which drop on to a plate and solidify into a crystal called a boule.[66] For corundum the flame must be 2000 °C. This process takes hours and yields a crystal with the same properties as its natural counterpart.

To produce corundum, a pure aluminium powder is used with different additives to achieve different colors.[66]

  • Chromic oxide for ruby
  • Iron and titanium oxide for blue sapphire
  • Nickel oxide for yellow sapphire
  • Nickel, chromium and iron for orange sapphire
  • Manganese for pink sapphire
  • Copper for blue-green sapphire
  • Cobalt for dark blue sapphire

Czochralski process (melt process) edit

In 1918 this process was developed by J. Czocharalski[66] and is also referred to as the "crystal pulling" method. In this process, the required gemstone materials are added to a crucible. A seed stone is placed into the melt in the crucible. As the gem begins to crystallize on the seed, the seed is pulled away and the gem continues to grow.[60] This is used for corundum but is currently the least popular method.[65]

Flux growth (solution process) edit

The flux growth process was the first process able to synthesize emerald.[63] Flux growth begins with a crucible which can withstand high heat; either graphite or platinum which is filled with a molten liquid referred to as flux.[67] The specific gem ingredients are added and dissolved in this fluid and recrystallize to form the desired gemstone.This is a longer process compared to the flame fusion process and can take two months up to a year depending on the desired final size.[68]

Hydrothermal growth (solution process) edit

The hydrothermal growth process attempts to imitate the natural growth process of minerals. The required gem materials are sealed in a container of water and placed under extreme pressure. The water is heated beyond its boiling point which allows normally insoluble materials to dissolve. As more material cannot be added once the container is sealed, in order to create a larger gem the process would begin with a "seed" stone from a previous batch which the new material will crystallize on. This process takes a few weeks to complete.

Characteristics edit

Synthetic gemstones share chemical and physical properties with natural gemstones, but there are some slight differences that can be used to discern synthetic from natural.[69] These differences are slight and often require microscopy as a tool to distinguish differences. Undetectable synthetics pose a threat to the market if they are able to be sold as rare natural gemstones.[citation needed] Because of this there are certain characteristic gemologists look for. Each crystal is characteristic to the environment and growth process under which it was created.

 
Visible banding in an apatite gemstone

Gemstones created from the flame-fusion process may have

  • small air bubbles which were trapped inside the boule during formation process
  • visible banding from formation of the boule
  • chatter marks which on the surface which appear crack like which are caused from damage during polishing of the gemstone

Gemstones created from flux melt process may have

  • small cavities which are filled with flux solution
  • inclusions in the gemstone from crucible used[70]

Gemstones created from hydrothermal growth may have

  • inclusions from container used[70]

History edit

 
Auguste Verneuil – creator of flame-fusion process 1902

Prior to development of synthesising processes the alternatives on the market to natural gemstones were imitations or fake. In 1837, the first successful synthesis of ruby occurred.[65] French chemist Marc Gaudin managed to produce small crystals of ruby from melting together potassium aluminium sulphate and potassium chromate through what would later be known as the flux melt process.[66] Following this, another French chemist Fremy was able to grow large quantities of small ruby crystals using a lead flux.[67]

A few years later an alternative to flux melt was developed which led to the introduction of what was labeled "reconstructed ruby" to the market. Reconstructed ruby was sold as a process which produced larger rubies from melting together bits of natural ruby.[68] In later attempts to recreate this process it was found to not be possible and is believed reconstructed rubies were most likely created using a multi-step method of melting of ruby powder.[66]

Auguste Verneuil, a student of Fremy, went on to develop flame-fusion as an alternative to the flux-melt method. He developed large furnaces which were able to produce large quantities of corundums more efficiently and shifted the gemstone market dramatically.[71] This process is still used today and the furnaces have not changed much from the original design.[72] World production of corundum using this method reaches 1000 million carats a year.

List of rare gemstones edit

  • Painite was discovered in 1956 in Ohngaing in Myanmar. The mineral was named in honor of the British gemologist Arthur Charles Davy Pain. At one point it was considered the rarest mineral on Earth.[73]
  • Tanzanite was discovered in 1967 in Northern Tanzania. With its supply possibly declining in the next 30 years, this gemstone is considered to be more rare than a diamond. This type of gemstone receives its vibrant blue from being heated.[74]
  • Hibonite was discovered in 1956 in Madagascar. It was named after the discoverer, French geologist Paul Hibon. Gem quality hibonite has been found only in Myanmar.[75]
 
Red Beryl - discovered in 1940
  • Red beryl or bixbite was discovered in an area near Beaver, Utah in 1904 and named after the American mineralogist Maynard Bixby.
  • Jeremejevite was discovered in 1883 in Russia and named after its discoverer, Pawel Wladimirowich Jeremejew (1830–1899).
  • Chambersite was discovered in 1957 in Chambers County, Texas, US, and named after the deposit's location.
  • Taaffeite was discovered in 1945. It was named after the discoverer, the Irish gemologist Count Edward Charles Richard Taaffe.
  • Musgravite was discovered in 1967 in the Musgrave Mountains in South Australia and named for the location.
 
Black Opal – the rarest type of opal
  • Black opal is directly mined in New South Wales, Australia, making it the rarest type of opal. Having a darker composition, this gemstone can be in a variety of colours.[74]
  • Grandidierite was discovered by Antoine François Alfred Lacroix (1863–1948) in 1902 in Tuléar Province, Madagascar. It was named in honor of the French naturalist and explorer Alfred Grandidier (1836–1912).
  • Poudretteite was discovered in 1965 at the Poudrette Quarry in Canada and named after the quarry's owners and operators, the Poudrette family.
  • Serendibite was discovered in Sri Lanka by Sunil Palitha Gunasekera in 1902 and named after Serendib, the old Arabic name for Sri Lanka.
  • Zektzerite was discovered by Bart Cannon in 1968 on Kangaroo Ridge near Washington Pass in Okanogan County, Washington, USA. The mineral was named in honor of mathematician and geologist Jack Zektzer, who presented the material for study in 1976.

In popular culture edit

French singer-songwriter Nolwenn Leroy was inspired by the gemstones for her 2017 album Gemme (meaning gemstone in French) and the single of the same name.[76]

Land of the Lustrous is an anime and manga series whose main characters are depicted as humanoid gemstones.

Steven Universe is an American animated television series whose main characters are magical gemstones who project themselves as feminine humanoids.

See also edit

References edit

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External links edit

  •   Quotations related to Gemstone at Wikiquote
  •   Media related to Gemstones at Wikimedia Commons
  •   The dictionary definition of gemstones at Wiktionary
  •   Gemstone travel guide from Wikivoyage

gemstone, several, terms, redirect, here, other, uses, disambiguation, gems, disambiguation, disambiguation, jewels, disambiguation, precious, stone, disambiguation, gemstone, also, called, fine, jewel, precious, stone, semiprecious, stone, simply, piece, mine. Several terms redirect here For other uses see Gemstone disambiguation Gems disambiguation Gem disambiguation Jewels disambiguation and Precious stone disambiguation A gemstone also called a fine gem jewel precious stone semiprecious stone or simply gem is a piece of mineral crystal which when cut or polished is used to make jewelry or other adornments 1 2 3 Certain rocks such as lapis lazuli opal and obsidian and occasionally organic materials that are not minerals such as amber jet and pearl may also be used for jewelry and are therefore often considered to be gemstones as well 4 5 Most gemstones are hard but some softer minerals such as brazilianite may be used in jewelry 6 because of their color or luster or other physical properties that have aesthetic value However generally speaking soft minerals are not typically used as gemstones by virtue of their brittleness and lack of durability 7 Group of precious and semiprecious stones both uncut and faceted including clockwise from top left diamond uncut synthetic sapphire ruby uncut emerald and amethyst crystal cluster Found all over the world the industry of coloured gemstones i e anything other than diamonds is currently estimated at around US 1 55 billion as of 2023 and is projected to steadily increase to a value of US 4 46 billion by 2033 8 A gem expert is a gemologist a gem maker is called a lapidarist or gemcutter a diamond cutter is called a diamantaire Contents 1 Characteristics and classification 2 Value 3 Grading 4 Cutting and polishing 5 Colors 6 Treatment 6 1 Early history 6 2 Heat 6 3 Radiation 6 4 Waxing oiling 6 5 Fracture filling 6 6 Bleaching 7 Socioeconomic issues in the gemstone industry 8 Synthetic and artificial gemstones 8 1 Types 8 1 1 Synthetic corundum 8 1 2 Synthetic beryls 8 1 3 Synthetic quartz 8 1 4 Synthetic spinel 8 2 Creation process 8 2 1 Verneuil flame fusion process melt process 8 2 2 Czochralski process melt process 8 2 3 Flux growth solution process 8 2 4 Hydrothermal growth solution process 8 3 Characteristics 8 4 History 9 List of rare gemstones 10 In popular culture 11 See also 12 References 13 External linksCharacteristics and classification edit nbsp A collection of gemstone pebbles made by tumbling the rough stones except the ruby and tourmaline with abrasive grit inside a rotating barrel The largest pebble here is 40 mm 1 6 in long The traditional classification in the West which goes back to the ancient Greeks begins with a distinction between precious and semi precious similar distinctions are made in other cultures In modern use the precious stones are emerald ruby sapphire and diamond with all other gemstones being semi precious 9 This distinction reflects the rarity of the respective stones in ancient times as well as their quality all are translucent with fine color in their purest forms except for the colorless diamond and very hard with a hardness score of 8 to 10 on the Mohs scale 10 Other stones are classified by their color translucency and hardness The traditional distinction does not necessarily reflect modern values for example while garnets are relatively inexpensive a green garnet called tsavorite can be far more valuable than a mid quality emerald 11 Another traditional term for semi precious gemstones used in art history and archaeology is hardstone Use of the terms precious and semi precious in a commercial context is arguably misleading in that it suggests certain stones are more valuable than others when this is not reflected in the actual market value although it would generally be correct if referring to desirability In modern times gemstones are identified by gemologists who describe gems and their characteristics using technical terminology specific to the field of gemology The first characteristic a gemologist uses to identify a gemstone is its chemical composition For example diamonds are made of carbon C and rubies of aluminium oxide Al2 O3 Many gems are crystals which are classified by their crystal system such as cubic or trigonal or monoclinic Another term used is habit the form the gem is usually found in 12 For example diamonds which have a cubic crystal system are often found as octahedrons 13 Gemstones are classified into different groups species and varieties 14 15 For example ruby is the red variety of the species corundum while any other color of corundum is considered sapphire Other examples are the emerald green aquamarine blue red beryl red goshenite colorless heliodor yellow and morganite pink which are all varieties of the mineral species beryl Gems are characterized in terms of their color hue tone and saturation optical phenomena luster refractive index birefringence dispersion specific gravity hardness cleavage and fracture 16 17 They may exhibit pleochroism or double refraction They may have luminescence and a distinctive absorption spectrum Gemstones may also be classified in terms of their water This is a recognized grading of the gem s luster transparency or brilliance 18 Very transparent gems are considered first water while second or third water gems are those of a lesser transparency 19 Additionally material or flaws within a stone may be present as inclusions 20 Value edit nbsp Spanish emerald and gold pendant at Victoria and Albert Museum nbsp Enamelled gold amethyst and pearl pendant about 1880 Pasquale Novissimo 1844 1914 V amp A Museum number M 36 1928 Gemstones have no universally accepted grading system Diamonds are graded using a system developed by the Gemological Institute of America GIA in the early 1950s Historically all gemstones were graded using the naked eye The GIA system included a major innovation the introduction of 10x magnification as the standard for grading clarity Other gemstones are still graded using the naked eye assuming 20 20 vision 21 A mnemonic device the four Cs color cut clarity and carats has been introduced to help describe the factors used to grade a diamond With modification these categories can be useful in understanding the grading of all gemstones The four criteria carry different weights depending upon whether they are applied to colored gemstones or to colorless diamonds In diamonds the cut is the primary determinant of value followed by clarity and color An ideally cut diamond will sparkle to break down light into its constituent rainbow colors dispersion chop it up into bright little pieces scintillation and deliver it to the eye brilliance In its rough crystalline form a diamond will do none of these things it requires proper fashioning and this is called cut In gemstones that have color including colored diamonds the purity and beauty of that color is the primary determinant of quality 22 Physical characteristics that make a colored stone valuable are color clarity to a lesser extent emeralds will always have a number of inclusions cut unusual optical phenomena within the stone such as color zoning the uneven distribution of coloring within a gem 23 and asteria star effects Apart from the more generic and commonly used gemstones such as from diamonds rubies sapphires and emeralds pearls and opal 24 have also been defined as precious in the jewellery trade Up to the discoveries of bulk amethyst in Brazil in the 19th century amethyst was considered a precious stone as well going back to ancient Greece Even in the last century certain stones such as aquamarine peridot and cat s eye cymophane have been popular and hence been regarded as precious thus reinforcing the notion that a mineral s rarity may have been implicated in its classification as a precious stone and thus contribute to its value Today the gemstone trade no longer makes such a distinction 25 Many gemstones are used in even the most expensive jewelry depending on the brand name of the designer fashion trends market supply treatments etc Nevertheless diamonds rubies sapphires and emeralds still have a reputation that exceeds those of other gemstones 26 Rare or unusual gemstones generally understood to include those gemstones which occur so infrequently in gem quality that they are scarcely known except to connoisseurs include andalusite axinite cassiterite clinohumite painite and red beryl 27 Gemstone pricing and value are governed by factors and characteristics in the quality of the stone These characteristics include clarity rarity freedom from defects the beauty of the stone as well as the demand for such stones There are different pricing influencers for both colored gemstones and for diamonds The pricing on colored stones is determined by market supply and demand but diamonds are more intricate 28 Diamond value can change based on location time and on the evaluations of diamond vendors especially since most of the diamond supply in the world is strongly and exclusive controlled by a single authority DeBeers 29 In the addition to the aesthetic and adorning ornamental purpose of gemstones there are many proponents of energy medicine who also value gemstones on the basis of their alleged healing powers 30 A gemstone that has been rising in popularity is Cuprian Elbaite Tourmaline which is also called Paraiba Tourmaline It was first discovered in the late 1980s in Paraiba Brazil and later in Mozambique and Nigeria 31 It is famous for its glowing neon blue color Paraiba Tourmaline has become one of the most popular gemstones in recent times thanks to its color and is considered to be one of the important gemstones after rubies emeralds and sapphires according to Gubelin Gemlab Even though it is a tourmaline Paraiba Tourmaline is one of the most expensive gemstones 32 Grading editThere are a number of laboratories which grade and provide reports on gemstones 25 Gemological Institute of America GIA the main provider of education services and diamond grading reports International Gemological Institute IGI independent laboratory for grading and evaluation of diamonds jewelry and colored stones Hoge Raad Voor Diamant HRD Antwerp The Diamond High Council Belgium is one of Europe s oldest laboratories its main stakeholder is the Antwerp World Diamond Centre American Gemological Society AGS is not as widely recognized nor as old as the GIA American Gem Trade Laboratory which is part of the American Gem Trade Association AGTA a trade organization of jewelers and dealers of colored stones American Gemological Laboratories AGL owned by Christopher P Smith European Gemological Laboratory EGL founded in 1974 by Guy Margel in Belgium Gemmological Association of All Japan GAAJ ZENHOKYO Zenhokyo Japan active in gemological research The Gem and Jewelry Institute of Thailand Public Organization or GIT Thailand s national institute for gemological research and gem testing Bangkok 33 Gemmology Institute of Southern Africa Africa s premium gem laboratory Asian Institute of Gemological Sciences AIGS the oldest gemological institute in South East Asia involved in gemological education and gem testing Swiss Gemmological Institute SSEF founded by Henry Hanni focusing on colored gemstones and the identification of natural pearls Gubelin Gem Lab the traditional Swiss lab founded by Eduard Gubelin Institute for Gems and Gold Research of VINAGEMS Vietnam founded by Van Long Pham citation needed Each laboratory has its own methodology to evaluate gemstones A stone can be called pink by one lab while another lab calls it padparadscha One lab can conclude a stone is untreated while another lab might conclude that it is heat treated 25 To minimize such differences seven of the most respected labs AGTA GTL New York CISGEM Milano GAAJ ZENHOKYO Tokyo GIA Carlsbad GIT Bangkok Gubelin Lucerne and SSEF Basel have established the Laboratory Manual Harmonisation Committee LMHC for the standardization of wording reports promotion of certain analytical methods and interpretation of results Country of origin has sometimes been difficult to determine due to the constant discovery of new source locations Determining a country of origin is thus much more difficult than determining other aspects of a gem such as cut clarity etc 34 Gem dealers are aware of the differences between gem laboratories and will make use of the discrepancies to obtain the best possible certificate 25 Cutting and polishing edit nbsp A diamond cutter in Amsterdam A few gemstones are used as gems in the crystal or other forms in which they are found Most however are cut and polished for usage as jewelry The two main classifications are as follows Stones cut as smooth dome shaped stones called cabochons or simply cab These have been a popular shape since ancient time and is more durable than faceted gems 35 Stones which are cut with a faceting machine by polishing small flat windows called facets at regular intervals at exact angles 35 Stones which are opaque or semi opaque such as opal turquoise variscite etc are commonly cut as cabochons These gems are designed to show the stone s color luster and other surface properties as opposed to internal reflection properties like brilliance 36 Grinding wheels and polishing agents are used to grind shape and polish the smooth dome shape of the stones 37 Gems that are transparent are normally faceted a method that shows the optical properties of the stone s interior to its best advantage by maximizing reflected light which is perceived by the viewer as sparkle There are many commonly used shapes for faceted stones The facets must be cut at the proper angles which varies depending on the optical properties of the gem If the angles are too steep or too shallow the light will pass through and not be reflected back toward the viewer The faceting machine is used to hold the stone onto a flat lap for cutting and polishing the flat facets 38 Rarely some cutters use special curved laps to cut and polish curved facets Colors edit nbsp Nearly 300 variations of diamond color exhibited at the Aurora display at the Natural History Museum in London nbsp A variety of semiprecious stones in a piece of jewellery The color of any material is due to the nature of light itself Daylight often called white light is all of the colors of the spectrum combined When light strikes a material most of the light is absorbed while a smaller amount of a particular frequency or wavelength is reflected The part that is reflected reaches the eye as the perceived color 39 A ruby appears red because it absorbs all other colors of white light while reflecting red A material which is mostly the same can exhibit different colors For example ruby and sapphire have the same primary chemical composition both are corundum 40 but exhibit different colors because of impurities which absorb and reflect different wavelengths of light depending on their individual compositions Even the same named gemstone can occur in many different colors sapphires show different shades of blue and pink and fancy sapphires exhibit a whole range of other colors from yellow to orange pink the latter called padparadscha sapphire 41 This difference in color is based on the atomic structure of the stone Although the different stones formally have the same chemical composition and structure they are not exactly the same Every now and then an atom is replaced by a completely different atom sometimes as few as one in a million atoms These so called impurities are sufficient to absorb certain colors and leave the other colors unaffected For example beryl which is colorless in its pure mineral form becomes emerald with chromium impurities If manganese is added instead of chromium beryl becomes pink morganite With iron it becomes aquamarine Some gemstone treatments make use of the fact that these impurities can be manipulated thus changing the color of the gem Treatment editGemstones are often treated to enhance the color or clarity of the stone 42 In some cases the treatment applied to the gemstone can also increase its durability Even though natural gemstones can be transformed using the traditional method of cutting and polishing other treatment options allow the stone s appearance to be enhanced 43 Depending on the type and extent of treatment they can affect the value of the stone Some treatments are used widely because the resulting gem is stable while others are not accepted most commonly because the gem color is unstable and may revert to the original tone 44 Early history edit Before the innovation of modern day tools thousands of years ago people were recorded to use a variety of techniques to treat and enhance gemstones Some of the earliest methods of gemstone treatment date back to the Minoan Age for example foiling which is where metal foil is used to enhance a gemstone s colour 45 Other methods recorded 2000 years ago in the book Natural History by Pliny the Elder include oiling and dyeing staining Heat edit Heat can either improve or spoil gemstone color or clarity The heating process has been well known to gem miners and cutters for centuries and in many stone types heating is a common practice Most citrine is made by heating amethyst and partial heating with a strong gradient results in ametrine a stone partly amethyst and partly citrine Aquamarine is often heated to remove yellow tones or to change green colors into the more desirable blue or enhance its existing blue color to a deeper blue 44 Nearly all tanzanite is heated at low temperatures to remove brown undertones and give a more desirable blue purple color 46 A considerable portion of all sapphire and ruby is treated with a variety of heat treatments to improve both color and clarity When jewelry containing diamonds is heated for repairs the diamond should be protected with boric acid otherwise the diamond which is pure carbon could be burned on the surface or even burned completely up When jewelry containing sapphires or rubies is heated those stones should not be coated with boric acid which can etch the surface or any other substance They do not have to be protected from burning like a diamond although the stones do need to be protected from heat stress fracture by immersing the part of the jewelry with stones in the water when metal parts are heated Radiation edit Main article Gemstone irradiation The irradiation process is widely practiced in jewelry industry 47 and enabled the creation of gemstone colors that do not exist or are extremely rare in nature 48 However particularly when done in a nuclear reactor the processes can make gemstones radioactive Health risks related to the residual radioactivity of the treated gemstones have led to government regulations in many countries 48 49 Virtually all blue topaz both the lighter and the darker blue shades such as London blue has been irradiated to change the color from white to blue Most green quartz Oro Verde are also irradiated to achieve the yellow green color Diamonds are mainly irradiated to become blue green or green although other colors are possible When light to medium yellow diamonds are treated with gamma rays they may become green with a high energy electron beam blue 50 Waxing oiling edit Emeralds containing natural fissures are sometimes filled with wax or oil to disguise them This wax or oil is also colored to make the emerald appear of better color as well as clarity Turquoise is also commonly treated in a similar manner Fracture filling edit nbsp The foreign material inside this fracture filled emerald appears rainbow colored under darkfield illumination Fracture filling has been in use with different gemstones such as diamonds emeralds and sapphires In 2006 glass filled rubies received publicity Rubies over 10 carats 2 g with large fractures were filled with lead glass thus dramatically improving the appearance of larger rubies in particular Such treatments are fairly easy to detect Bleaching edit nbsp Pearls are a gemstone that is commonly treated with hydrogen peroxide to remove unwanted colours Another treatment method that is commonly used to treat gemstones is bleaching This method uses a chemical in order to reduce the colour of the gem After bleaching a combination treatment can be done by dying the gemstone once the unwanted colours are removed Hydrogen peroxide is the most commonly used product used to alter gemstones and have notably been used to treat jade and pearls The treatment of bleaching can also be followed by impregnation which allows the gemstone s durability to be increased 43 Socioeconomic issues in the gemstone industry editThe socio economic dynamics of the gemstone industry are shaped by market forces and consumer preferences and typically go undiscussed Changes in demand and prices can significantly affect the livelihoods of those involved in gemstone mining and trade particularly in developing countries where the industry serves as a crucial source of income 51 A situation that arises as a result of this is the exploitation of natural resources and labor within gemstone mining operations Many mines particularly in developing countries face challenges such as inadequate safety measures low wages and poor working conditions 51 Miners often from disadvantaged backgrounds endure hazardous working conditions and receive meager wages contributing to cycles of poverty and exploitation 52 Gemstone mining operations are frequently conducted in remote or underdeveloped areas lacking proper infrastructure and access to essential services such as healthcare and education This further contributes to the pre existing socio economic disparities and obstructs community development such that the benefits of gemstone extraction may not adequately reach those directly involved in the process 53 Another such issue revolves around environmental degradation resulting from mining activities Environmental degradation can pose long term threats to ecosystems and biodiversity further worsening the socio economic state in affected regions 54 Unregulated mining practices often result in deforestation soil erosion and water contamination thus threatening ecosystems and biodiversity 55 Unregulated mining activity can also cause depletion of natural resources thus diminishing the prospects for sustainable development 56 The environmental impact of gemstone mining not only poses a threat to ecosystems but also undermines the long term viability of the industry by diminishing the quality and quantity of available resources Furthermore the gemstone industry is also susceptible to issues related to transparency and ethics which impact both producers and consumers The lack of standardized certification processes and the prevalence of illicit practices undermine market integrity and trust 57 The lack of transparency and accountability in the supply chain aggravates pre existing inequalities as middlemen and corporations often capture a disproportionate share of the profits As a result the unequal distribution of profits along the supply chain does little to improve socio economic inequalities particularly in regions where gemstones are mined Addressing these socio economic challenges requires intensive effort from various stakeholders including governments industry executives and society to promote sustainable practices and ensure equitable outcomes for all involved parties Implementing and enforcing regulations to ensure fair labor practices environmental sustainability and ethical sourcing is essential Additionally investing in community development projects such as education and healthcare initiatives can help alleviate poverty and empower marginalized communities dependent on the gemstone industry Collaboration across sectors is crucial for fostering a more equitable and sustainable gemstone trade that benefits both producers and consumers while respecting human rights and environmental integrity Synthetic and artificial gemstones editSynthetic gemstones are distinct from imitation or simulated gems Synthetic gems are physically optically and chemically identical to the natural stone but are created in a laboratory 58 Imitation or simulated stones are chemically different from the natural stone but may appear quite similar to it they can be more easily manufactured synthetic gemstones of a different mineral spinel glass plastic resins or other compounds Examples of simulated or imitation stones include cubic zirconia composed of zirconium oxide synthetic moissanite and uncolored synthetic corundum or spinels all of which are diamond simulants The simulants imitate the look and color of the real stone but possess neither their chemical nor physical characteristics In general all are less hard than diamond Moissanite actually has a higher refractive index than diamond and when presented beside an equivalently sized and cut diamond will show more fire Cultured synthetic or lab created gemstones are not imitations The bulk mineral and trace coloring elements are the same in both For example diamonds rubies sapphires and emeralds have been manufactured in labs that possess chemical and physical characteristics identical to the naturally occurring variety Synthetic lab created corundum including ruby and sapphire is very common and costs much less than the natural stones Small synthetic diamonds have been manufactured in large quantities as industrial abrasives although larger gem quality synthetic diamonds are becoming available in multiple carats 59 Whether a gemstone is a natural stone or synthetic the chemical physical and optical characteristics are the same They are composed of the same mineral and are colored by the same trace materials have the same hardness and density and strength and show the same color spectrum refractive index and birefringence if any Lab created stones tend to have a more vivid color since impurities common in natural stones are not present in the synthetic stone Synthetics are made free of common naturally occurring impurities that reduce gem clarity or color unless intentionally added in order to provide a more drab natural appearance or to deceive an assayer citation needed On the other hand synthetics often show flaws not seen in natural stones such as minute particles of corroded metal from lab trays used during synthesis citation needed Types edit Some gemstones are more difficult to synthesize than others and not all stones are commercially viable to attempt to synthesize These are the most common on the market currently 60 Synthetic corundum edit Synthetic corundum includes ruby red variation and sapphire other color variations both of which are considered highly desired and valued 60 Ruby was the first gemstone to be synthesized by Auguste Verneuil with his development of the flame fusion process in 1902 61 Synthetic corundum continues to be made typically by flame fusion as it is most cost effective but can also be produced through flux growth and hydrothermal growth 62 Synthetic beryls edit The most common synthesized beryl is emerald green Yellow red and blue beryls are possible but much more rare Synthetic emerald became possible with the development of the flux growth process and is produced in this way and well as hydrothermal growth 63 Synthetic quartz edit Types of synthetic quartz include citrine rose quartz and amethyst Natural occurring quartz is not rare is synthetically produced as it has practical application outside of aesthetic purposes Quartz generates an electric current when under pressure and is used in watches clocks and oscillators 64 Synthetic spinel edit Synthetic spinel was first produced by accident clarification needed It can be created in any color making it popular to simulate various natural gemstones It is created through flux growth and hydrothermal growth 60 Creation process edit There are two main categories for creation of these minerals melt or solution processes 60 Verneuil flame fusion process melt process edit nbsp Verneuil furnace The flame fusion process was the first process used which successfully created large quantities of synthetic gemstones to be sold on the market 65 This remains the most cost effective and common method of creating corundums today The flame fusion process is completed in a Verneuil furnace The furnace consists of an inverted blowpipe burner which produces an extremely hot oxyhydrogen flame a powder dispenser and a ceramic pedestal 66 A chemical powder which corresponds to the desired gemstone is passed through this flames This melts the ingredients which drop on to a plate and solidify into a crystal called a boule 66 For corundum the flame must be 2000 C This process takes hours and yields a crystal with the same properties as its natural counterpart To produce corundum a pure aluminium powder is used with different additives to achieve different colors 66 Chromic oxide for ruby Iron and titanium oxide for blue sapphire Nickel oxide for yellow sapphire Nickel chromium and iron for orange sapphire Manganese for pink sapphire Copper for blue green sapphire Cobalt for dark blue sapphire Czochralski process melt process edit In 1918 this process was developed by J Czocharalski 66 and is also referred to as the crystal pulling method In this process the required gemstone materials are added to a crucible A seed stone is placed into the melt in the crucible As the gem begins to crystallize on the seed the seed is pulled away and the gem continues to grow 60 This is used for corundum but is currently the least popular method 65 Flux growth solution process edit The flux growth process was the first process able to synthesize emerald 63 Flux growth begins with a crucible which can withstand high heat either graphite or platinum which is filled with a molten liquid referred to as flux 67 The specific gem ingredients are added and dissolved in this fluid and recrystallize to form the desired gemstone This is a longer process compared to the flame fusion process and can take two months up to a year depending on the desired final size 68 Hydrothermal growth solution process edit The hydrothermal growth process attempts to imitate the natural growth process of minerals The required gem materials are sealed in a container of water and placed under extreme pressure The water is heated beyond its boiling point which allows normally insoluble materials to dissolve As more material cannot be added once the container is sealed in order to create a larger gem the process would begin with a seed stone from a previous batch which the new material will crystallize on This process takes a few weeks to complete Characteristics edit Synthetic gemstones share chemical and physical properties with natural gemstones but there are some slight differences that can be used to discern synthetic from natural 69 These differences are slight and often require microscopy as a tool to distinguish differences Undetectable synthetics pose a threat to the market if they are able to be sold as rare natural gemstones citation needed Because of this there are certain characteristic gemologists look for Each crystal is characteristic to the environment and growth process under which it was created nbsp Visible banding in an apatite gemstone Gemstones created from the flame fusion process may have small air bubbles which were trapped inside the boule during formation process visible banding from formation of the boule chatter marks which on the surface which appear crack like which are caused from damage during polishing of the gemstone Gemstones created from flux melt process may have small cavities which are filled with flux solution inclusions in the gemstone from crucible used 70 Gemstones created from hydrothermal growth may have inclusions from container used 70 History edit nbsp Auguste Verneuil creator of flame fusion process 1902 Prior to development of synthesising processes the alternatives on the market to natural gemstones were imitations or fake In 1837 the first successful synthesis of ruby occurred 65 French chemist Marc Gaudin managed to produce small crystals of ruby from melting together potassium aluminium sulphate and potassium chromate through what would later be known as the flux melt process 66 Following this another French chemist Fremy was able to grow large quantities of small ruby crystals using a lead flux 67 A few years later an alternative to flux melt was developed which led to the introduction of what was labeled reconstructed ruby to the market Reconstructed ruby was sold as a process which produced larger rubies from melting together bits of natural ruby 68 In later attempts to recreate this process it was found to not be possible and is believed reconstructed rubies were most likely created using a multi step method of melting of ruby powder 66 Auguste Verneuil a student of Fremy went on to develop flame fusion as an alternative to the flux melt method He developed large furnaces which were able to produce large quantities of corundums more efficiently and shifted the gemstone market dramatically 71 This process is still used today and the furnaces have not changed much from the original design 72 World production of corundum using this method reaches 1000 million carats a year List of rare gemstones editPainite was discovered in 1956 in Ohngaing in Myanmar The mineral was named in honor of the British gemologist Arthur Charles Davy Pain At one point it was considered the rarest mineral on Earth 73 Tanzanite was discovered in 1967 in Northern Tanzania With its supply possibly declining in the next 30 years this gemstone is considered to be more rare than a diamond This type of gemstone receives its vibrant blue from being heated 74 Hibonite was discovered in 1956 in Madagascar It was named after the discoverer French geologist Paul Hibon Gem quality hibonite has been found only in Myanmar 75 nbsp Red Beryl discovered in 1940 Red beryl or bixbite was discovered in an area near Beaver Utah in 1904 and named after the American mineralogist Maynard Bixby Jeremejevite was discovered in 1883 in Russia and named after its discoverer Pawel Wladimirowich Jeremejew 1830 1899 Chambersite was discovered in 1957 in Chambers County Texas US and named after the deposit s location Taaffeite was discovered in 1945 It was named after the discoverer the Irish gemologist Count Edward Charles Richard Taaffe Musgravite was discovered in 1967 in the Musgrave Mountains in South Australia and named for the location nbsp Black Opal the rarest type of opal Black opal is directly mined in New South Wales Australia making it the rarest type of opal Having a darker composition this gemstone can be in a variety of colours 74 Grandidierite was discovered by Antoine Francois Alfred Lacroix 1863 1948 in 1902 in Tulear Province Madagascar It was named in honor of the French naturalist and explorer Alfred Grandidier 1836 1912 Poudretteite was discovered in 1965 at the Poudrette Quarry in Canada and named after the quarry s owners and operators the Poudrette family Serendibite was discovered in Sri Lanka by Sunil Palitha Gunasekera in 1902 and named after Serendib the old Arabic name for Sri Lanka Zektzerite was discovered by Bart Cannon in 1968 on Kangaroo Ridge near Washington Pass in Okanogan County Washington USA The mineral was named in honor of mathematician and geologist Jack Zektzer who presented the material for study in 1976 In popular culture editFrench singer songwriter Nolwenn Leroy was inspired by the gemstones for her 2017 album Gemme meaning gemstone in French and the single of the same name 76 Land of the Lustrous is an anime and manga series whose main characters are depicted as humanoid gemstones Steven Universe is an American animated television series whose main characters are magical gemstones who project themselves as feminine humanoids See also editAssembled gem Gemology List of gemstones by species List of individual gemstones List of diamonds List of emeralds by size List of sapphires by size Luminous gemstonesReferences edit Gemstone Lexico Oxford University Press Archived from the original on March 21 2020 Webster Online Dictionary Archived 2007 06 03 at the Wayback Machine Alden Nancy 2009 Simply Gemstones Designs for Creating Beaded Gemstone Jewelry New York NY Random House p 136 ISBN 978 0 307 45135 4 Pearl Natural Cultured amp Imitation Gemstones Britannica www britannica com January 19 2024 Retrieved March 1 2024 Gemopedia Gemstone Encyclopedia www gemstones com Retrieved March 1 2024 Soft Gemstones and Minerals Gem5 com gem5 com Retrieved March 1 2024 Gemstone Hardness and Wearability Colored Gemstones Market Sales Projection Shows 11 6 CAGR Growth Potential by 2033 Market Research Blog March 1 2024 Retrieved March 1 2024 Bauer Max 1968 Precious Stones Dover Publications p 2 ISBN 9780486219103 What are the differences between precious and semi precious stones Information Leysen Joaillier since 1855 www leysen eu Retrieved February 10 2024 Wise R W 2006 Secrets of The Gem Trade The Connoisseur s Guide to Precious Gemstones Brunswick House Press pp 3 8 ISBN 0 9728223 8 0 Crystal Habits and Forms of Minerals and Gems geology com Retrieved March 1 2024 Diamond www thecanadianencyclopedia ca Retrieved March 1 2024 Hansen Robin April 12 2022 Gemstones A Concise Reference Guide Princeton University Press p 47 ISBN 978 0 691 21448 1 Read Peter G 2005 Gemmology Butterworth Heinemann p 13 ISBN 978 0 7506 6449 3 Hurrell Karen Johnson Mary L 2017 Gemstones a complete color reference for precious and semiprecious stones of the world New York Chartwell Books ISBN 978 0 7858 3498 4 Gemstone Identification How to Identify Gemstones Gemstones com www gemstones com Retrieved March 1 2024 AskOxford com Concise Oxford English dictionary online full citation needed Desirable diamonds The world s most famous gem by Sarah Todd full citation needed Inclusions in Gemstones www gia edu Retrieved March 1 2024 Wise R W 2006 Secrets of The Gem Trade The Connoisseur s Guide to Precious Gemstones Brunswick House Press p 36 ISBN 0 9728223 8 0 Wise R W 2006 Secrets of The Gem Trade The Connoisseur s Guide to Precious Gemstones Brunswick House Press p 15 Zoning Colour Banding www gemporia com Retrieved March 1 2024 Church A H 1905 Definition of Precious Stones Precious Stones considered in their scientific and artistic relations His Majesty s Stationery Office Wyman amp Sons p 11 Archived from the original on September 29 2007 via Farlang com a b c d Wise R W 2003 Secrets of The Gem Trade The Connoisseur s Guide to Precious Gemstones Brunswick House Press Lenox Massachusetts 5 Most Precious Stones HowStuffWorks com November 9 2009 Archived from the original on November 6 2014 A complete guide to Gemstones Jewellery Monthly April 2 2015 Archived from the original on August 28 2017 Pricing of Colored Gemstones Joseph Menzie Inc Archived from the original on October 27 2021 Retrieved October 27 2021 Auer Benjamin R Schuhmacher Frank June 1 2013 Diamonds A precious new asset International Review of Financial Analysis 28 182 189 doi 10 1016 j irfa 2013 03 008 ISSN 1057 5219 Katz Michael 2005 Gemstone Energy Medicine Healing Body Mind and Spirit Natural Healing Press ISBN 9780924700248 Retrieved April 6 2020 Geographic Origin Determination of Paraiba Tourmaline Archived from the original on April 9 2022 Retrieved March 17 2022 International Gem Society LLC The Gem and Jewelry Institute of Thailand Public Organization Bangkok Post Rapaport report of ICA Gemstone Conference in Dubai Diamonds net May 16 2007 Archived from the original on July 26 2011 Retrieved July 30 2010 a b A Guide to Gem Cutting Styles A Guide to Gem Cutting Styles Kraus Pansy D 2007 Introduction to Lapidary Krause Publications ISBN 9780801972669 Vargas Glenn Vargas Martha 2002 Faceting For Amateurs G amp M Vargas ISBN 9780917646096 Seeing Color Ruby and Sapphire Gems of the Mineral Corundum geology com Retrieved March 1 2024 Padparadscha Sapphires 10 Tips On Judging The Rare Gem The Natural Sapphire Company Blog April 6 2015 Archived from the original on January 19 2018 Retrieved January 19 2018 Nassau Kurt 1984 Gemstone enhancement heat irradiation impregnation dyeing and other treatments which alter the appearance of gemstones and the detection of such treatments London u a Butterworths ISBN 978 0 408 01447 2 a b An Introduction to Gem Treatments www gia edu Archived from the original on April 6 2023 Retrieved March 31 2023 a b Nassau Kurt 1994 Gemstone Enhancement History Science and State of the Art 2nd ed Oxford Butterworth Heinemann ISBN 9780750617970 OCLC 28889342 Nassau Kurt 1984 The Early History of Gemstone Treatments PDF Archived PDF from the original on January 2 2023 Retrieved March 31 2023 Tanzanite heating the science Archived from the original on 20 June 2016 Omi Nelson M Rela Paulo R 2007 Gemstone Dedicated Gamma Irradiator Development Proceedings of the INAC 2007 International Nuclear Atlantic Conference PDF Associacao Brasileira de Energia Nuclear p 1 ISBN 978 85 99141 02 1 Archived from the original PDF on October 21 2022 Retrieved October 21 2022 a b Hurlbut Cornelius S Kammerling Robert C 1991 Gemology PDF Wiley Interscience p 170 ISBN 0 471 52667 3 Archived PDF from the original on November 4 2022 Retrieved November 4 2022 via LibreTexts Nuclear Regulatory Commission April 2019 Backgrounder on Irradiated Gemstones The U S Nuclear Regulatory Commission Archived from the original on September 1 2022 Retrieved November 12 2022 nbsp This article incorporates public domain material from websites or documents of the United States Government Rossman George R Summer 1981 Color in Gems The New Technologies PDF Gems amp Gemology 17 2 Gemological Institute of America 70 doi 10 5741 GEMS 17 2 60 ISSN 0016 626X Archived from the original PDF on November 12 2022 a b Hilson Gavin 2016 Artisanal and small scale mining and agriculture Exploring their links in rural sub Saharan Africa Report International Institute for Environment and Development Fisher Eleanor July 2007 Occupying 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Need for and Proposal of the Adoption of a Kimberley Process Styled Legitimacy Certification System for the Global Gemstone Market Research Gate Jewelers circular keystone JCK Chilton Company 1994 full citation needed New process promises bigger better diamond crystals Carnegie Institution for Science Archived from the original on December 1 2010 Retrieved January 7 2011 a b c d e Weldon R An Introduction to Synthetic Gem Materials PDF Archived PDF from the original on April 15 2023 Retrieved April 14 2023 Shigley James 2000 Treated and synthetic gem materials Current Science 79 11 1566 1571 JSTOR 24104849 Elwell Dennis 1981 Nassau Kurt ed Synthetic Gemstones Science 211 4487 1156 doi 10 1126 science 211 4487 1156 a ISSN 0036 8075 JSTOR 1685235 PMID 17755153 S2CID 239860410 Archived from the original on April 15 2023 Retrieved April 15 2023 a b Lefever R 1982 Synthetic emerald pubs geoscienceworld org Retrieved March 15 2023 Hervey P R Foise J W February 1 2001 Synthetic quartz crystal A review Mining Metallurgy amp Exploration 18 1 1 4 doi 10 1007 BF03402862 ISSN 2524 3470 S2CID 140031745 a b c Scheel Hans J April 1 2000 Historical aspects of crystal growth technology Journal of Crystal Growth 211 1 1 12 Bibcode 2000JCrGr 211 1S doi 10 1016 S0022 0248 99 00780 0 ISSN 0022 0248 Archived from the original on April 15 2023 Retrieved April 15 2023 a b c d e f Read Peter G 1999 Gemmology Butterworth Heinemann ISBN 0 7506 4411 7 OCLC 807757024 a b Scheel Hans 2003 Crystal Growth Technology John Wiley amp Sons ISBN 9780470871683 a b Arem Joel Understanding Gem Synthetics Treatments And Imitations Part 4 Synthetic Gemstone Guide International Gem Society Archived from the original on March 22 2023 Retrieved March 30 2023 Jayaraman A December 28 2023 A brief overview of gem materials Natural and synthetic Current Science 79 11 1555 1565 JSTOR 24104848 Archived from the original on April 15 2023 a b Li Zhaolin December 1 2001 Study on inclusions in natural and synthetic gems Chinese Journal of Geochemistry 20 4 324 332 doi 10 1007 BF03166857 ISSN 1993 0364 S2CID 129031255 Nassau Kurt 1990 Synthetic Gem Materials in the 1980s PDF Gems amp Gemology 26 1 50 63 doi 10 5741 GEMS 26 1 50 Archived PDF from the original on November 1 2021 Retrieved April 15 2023 Harris Daniel C September 26 2003 Tustison Randal W ed A peek into the history of sapphire crystal growth Window and Dome Technologies VIII 5078 SPIE 1 11 Bibcode 2003SPIE 5078 1H doi 10 1117 12 501428 S2CID 109528895 Hansen 2022 p 206 a b 10 Gems Rarer and More Valuable Than Diamonds The Spruce Crafts Archived from the original on March 31 2023 Retrieved March 31 2023 Hainschwang Thomas Notari Franck Massi Laurent Armbruster Thomas Rondeau Benjamin Fritsch Emmanuel Nagashima Mariko Summer 2010 Hibonite A New Gem Mineral PDF Gems amp Gemology 46 2 135 138 doi 10 5741 GEMS 46 2 135 Archived PDF from the original on December 13 2017 in French Video Nolwenn Leroy lumineuse et enceinte dans le clip de Gemme RTL 19 July 2017 External links edit nbsp Quotations related to Gemstone at Wikiquote nbsp Media related to Gemstones at Wikimedia Commons nbsp The dictionary definition of gemstones at Wiktionary nbsp Gemstone travel guide from Wikivoyage Retrieved from https en wikipedia org w index php title Gemstone amp oldid 1220635890, wikipedia, wiki, book, books, library,

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