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Dolomite (mineral)

Dolomite (/ˈdɒl.əˌmt, ˈd.lə-/) is an anhydrous carbonate mineral composed of calcium magnesium carbonate, ideally CaMg(CO3)2. The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite. An alternative name sometimes used for the dolomitic rock type is dolostone.

Dolomite
Dolomite (white) on talc
General
CategoryCarbonate minerals
Formula
(repeating unit)
CaMg(CO3)2
IMA symbolDol[1]
Strunz classification5.AB.10
Crystal systemTrigonal
Crystal classRhombohedral (3)
H-M symbol: (3)
Space groupR3
Unit cella = 4.8012(1), c = 16.002 [Å]; Z = 3
Identification
ColorWhite, grey to pink, reddish-white, brownish-white; colourless in transmitted light
Crystal habitTabular crystals, often with curved faces, also columnar, stalactitic, granular, massive.
TwinningCommon as simple contact twins
Cleavage3 directions of cleavage not at right angles
FractureConchoidal
TenacityBrittle
Mohs scale hardness3.5-4
LusterVitreous to pearly
StreakWhite
Specific gravity2.84–2.86
Optical propertiesUniaxial (-)
Refractive indexnω = 1.679–1.681 nε = 1.500
Birefringenceδ = 0.179–0.181
SolubilityPoorly soluble in dilute HCl
Other characteristicsMay fluoresce white to pink under UV; triboluminescent.
Ksp values vary between 1x10−19 to 1x10−17
References[2][3][4][5][6]
Dolomite and calcite look similar under a microscope, but thin sections can be etched and stained in order to identify the minerals. Photomicrograph of a thin section in cross and plane polarised light: the brighter mineral grains in the picture are dolomite, and the darker grains are calcite.

History

 
Cristallo in the Dolomites mountain range near Cortina d'Ampezzo, Italy. The Dolomite Mountains were named after the mineral.

As stated by Nicolas-Théodore de Saussure[7] the mineral dolomite was probably first described by Carl Linnaeus in 1768.[8] In 1791, it was described as a rock by the French naturalist and geologist Déodat Gratet de Dolomieu (1750–1801), first in buildings of the old city of Rome, and later as samples collected in the Tyrolean Alps. Nicolas-Théodore de Saussure first named the mineral (after Dolomieu) in March 1792.

Properties

The mineral dolomite crystallizes in the trigonal-rhombohedral system. It forms white, tan, gray, or pink crystals. Dolomite is a double carbonate, having an alternating structural arrangement of calcium and magnesium ions. Unless it is in fine powder form, it does not rapidly dissolve or effervesce (fizz) in cold dilute hydrochloric acid as calcite does.[9] Crystal twinning is common.

Solid solution exists between dolomite, the iron-dominant ankerite and the manganese-dominant kutnohorite.[10] Small amounts of iron in the structure give the crystals a yellow to brown tint. Manganese substitutes in the structure also up to about three percent MnO. A high manganese content gives the crystals a rosy pink color. Lead, zinc, and cobalt also substitute in the structure for magnesium. The mineral dolomite is closely related to huntite Mg3Ca(CO3)4.

Because dolomite can be dissolved by slightly acidic water, areas where dolomite is an abundant rock-forming mineral are important as aquifers and contribute to karst terrain formation.[11]

Formation

Modern dolomite formation has been found to occur under anaerobic conditions in supersaturated saline lagoons such as those at the Rio de Janeiro coast of Brazil, namely, Lagoa Vermelha and Brejo do Espinho. There are many other localities where modern dolomite forms, notably along sabkhas in the Persian Gulf,[12] but also in sedimentary basins bearing gas hydrates[13] and hypersaline lakes.[14] It is often thought that dolomite nucleates with the help of sulfate-reducing bacteria (e.g. Desulfovibrio brasiliensis),[15] but other microbial metabolisms have been also found to mediate in dolomite formation.[12] In general, low-temperature dolomite may occur in natural supersaturated environments rich in extracelullar polymeric substances (EPS) and microbial cell surfaces.[12] This is likely result from complexation of both magnesium and calcium by carboxylic acids comprising EPS.[16]

Vast deposits of dolomite are present in the geological record, but the mineral is relatively rare in modern environments. Reproducible, inorganic low-temperature syntheses of dolomite are yet to be performed. Usually, the initial inorganic precipitation of a metastable "precursor" (such as magnesium calcite) can easily be achieved. The precursor phase will theoretically change gradually into a more stable phase (such as partially ordered dolomite) during periodical intervals of dissolution and re-precipitation. The general principle governing the course of this irreversible geochemical reaction has been coined "breaking Ostwald's step rule".[17] High diagenetic temperatures, such as those of groundwater flowing along deeply rooted fault systems affecting some sedimentary successions or deeply buried limestone rocks allocate dolomitization.[18] But the mineral is also volumetrically important in some Neogene platforms never subjected to elevated temperatures. Under such conditions of diagenesis the long-term activity of the deep biosphere could play a key role in dolomitization, since diagenetic fluids of contrasting composition are mixed as a response to Milankovitch cycles.[19]

A recent biotic synthetic experiment claims to have precipitated ordered dolomite when anoxygenic photosynthesis proceeds in the presence of manganese(II).[20] A still perplexing example of an organogenic origin is that of the reported formation of dolomite in the urinary bladder of a Dalmatian dog, possibly as the result of an illness or infection.[21]

Uses

Dolomite is used as an ornamental stone, a concrete aggregate, and a source of magnesium oxide, as well as in the Pidgeon process for the production of magnesium. It is an important petroleum reservoir rock, and serves as the host rock for large strata-bound Mississippi Valley-Type (MVT) ore deposits of base metals such as lead, zinc, and copper. Where calcite limestone is uncommon or too costly, dolomite is sometimes used in its place as a flux for the smelting of iron and steel. Large quantities of processed dolomite are used in the production of float glass.

In horticulture, dolomite and dolomitic limestone are added to soils and soilless potting mixes as a pH buffer and as a magnesium source.

Dolomite is also used as the substrate in marine (saltwater) aquariums to help buffer changes in the pH of the water.

Calcined dolomite is also used as a catalyst for destruction of tar in the gasification of biomass at high temperature.[22] Particle physics researchers like to build particle detectors under layers of dolomite to enable the detectors to detect the highest possible number of exotic particles. Because dolomite contains relatively minor quantities of radioactive materials, it can insulate against interference from cosmic rays without adding to background radiation levels.[23]

In addition to being an industrial mineral, dolomite is highly valued by collectors and museums when it forms large, transparent crystals. The specimens that appear in the magnesite quarry exploited in Eugui, Esteribar, Navarra (Spain) are considered among the best in the world.[24]

See also

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Deer, W. A., R. A. Howie and J. Zussman (1966) An Introduction to the Rock Forming Minerals, Longman, pp. 489–493. ISBN 0-582-44210-9.
  3. ^ Dolomite 2008-04-09 at the Wayback Machine. Handbook of Mineralogy. (PDF) . Retrieved on 2011-10-10.
  4. ^ Dolomite 2005-08-27 at the Wayback Machine. Webmineral. Retrieved on 2011-10-10.
  5. ^ Dolomite 2015-11-18 at the Wayback Machine. Mindat.org. Retrieved on 2011-10-10.
  6. ^ Krauskopf, Konrad Bates; Bird, Dennis K. (1995). Introduction to geochemistry (3rd ed.). New York: McGraw-Hill. ISBN 9780070358201. from the original on 2017-02-26.
  7. ^ Saussure le fils, M. de (1792): Analyse de la dolomie. Journal de Physique, vol.40, pp.161-173.
  8. ^ Linnaeus, C. (1768): Systema naturae per regnum tria naturae, secundum classes, ordines, genera, species cum characteribus & differentiis. Tomus III. Laurentii Salvii, Holmiae, 236 p. On p.41 of this very book, Linnaeus stated (in Latin): "Marmor tardum - Marmor paticulis subimpalpabilibus album diaphanum. Hoc simile quartzo durum, distinctum quod cum aqua forti non, nisi post aliquot minuta & fero, effervescens." In translation: "Slow marble - Marble, white and transparent with barely discernable particles. This is as hard as quartz, but it is different in that it does not, unless after a few minutes, effervesce with "aqua forti"".
  9. ^ "Dolomite Mineral - Uses and Properties". geology.com.
  10. ^ Klein, Cornelis and Cornelius S. Hurlbut Jr., Manual of Mineralogy, Wiley, 20th ed., p. 339-340 ISBN 0-471-80580-7
  11. ^ Kaufmann, James. Sinkholes 2013-06-04 at the Wayback Machine. USGS Fact Sheet. Retrieved on 2013-9-10.
  12. ^ a b c Petrash, Daniel A.; Bialik, Or M.; Bontognali, Tomaso R.R.; Vasconcelos, Crisógono; Roberts, Jennifer A.; McKenzie, Judith A.; Konhauser, Kurt O. (2017-08-01). "Microbially catalyzed dolomite formation: From near-surface to burial". Earth-Science Reviews. 171: 558–582. Bibcode:2017ESRv..171..558P. doi:10.1016/j.earscirev.2017.06.015. ISSN 0012-8252.
  13. ^ Snyder, Glen T.; Matsumoto, Ryo; Suzuki, Yohey; Kouduka, Mariko; Kakizaki, Yoshihiro; Zhang, Naizhong; Tomaru, Hitoshi; Sano, Yuji; Takahata, Naoto; Tanaka, Kentaro; Bowden, Stephen A. (2020-02-05). "Evidence in the Japan Sea of microdolomite mineralization within gas hydrate microbiomes". Scientific Reports. 10 (1): 1876. Bibcode:2020NatSR..10.1876S. doi:10.1038/s41598-020-58723-y. ISSN 2045-2322. PMC 7002378. PMID 32024862.
  14. ^ Last, William M. (1990-05-01). "Lacustrine dolomite—an overview of modern, Holocene, and Pleistocene occurrences". Earth-Science Reviews. 27 (3): 221–263. Bibcode:1990ESRv...27..221L. doi:10.1016/0012-8252(90)90004-F. ISSN 0012-8252.
  15. ^ Vasconcelos C.; McKenzie J. A.; Bernasconi S.; Grujic D.; Tien A. J. (1995). "Microbial mediation as a possible mechanism for natural dolomite formation at low temperatures". Nature. 337 (6546): 220–222. Bibcode:1995Natur.377..220V. doi:10.1038/377220a0. S2CID 4371495.
  16. ^ Roberts, J. A.; Kenward, P. A.; Fowle, D. A.; Goldstein, R. H.; Gonzalez, L. A. & Moore, D. S. (1980). "Surface chemistry allows for abiotic precipitation of dolomite at low temperature". Proceedings of the National Academy of Sciences of the United States of America. 110 (36): 14540–5. Bibcode:2013PNAS..11014540R. doi:10.1073/pnas.1305403110. PMC 3767548. PMID 23964124.
  17. ^ Deelman, J.C. (1999): "Low-temperature nucleation of magnesite and dolomite" 2008-04-09 at the Wayback Machine, Neues Jahrbuch für Mineralogie, Monatshefte, pp. 289–302.
  18. ^ Warren, J. (2000-11-01). "Dolomite: occurrence, evolution and economically important associations". Earth-Science Reviews. 52 (1–3): 1–81. Bibcode:2000ESRv...52....1W. doi:10.1016/S0012-8252(00)00022-2. ISSN 0012-8252.
  19. ^ Petrash, Daniel A.; Bialik, Or M.; Staudigel, Philip T.; Konhauser, Kurt O.; Budd, David A. (2021). "Biogeochemical reappraisal of the freshwater–seawater mixing-zone diagenetic model". Sedimentology. 68 (5): 1797–1830. doi:10.1111/sed.12849. ISSN 1365-3091. S2CID 234012426.
  20. ^ Daye, Mirna; Higgins, John; Bosak, Tanja (2019-06-01). "Formation of ordered dolomite in anaerobic photosynthetic biofilms". Geology. 47 (6): 509–512. Bibcode:2019Geo....47..509D. doi:10.1130/G45821.1. hdl:1721.1/126802. ISSN 0091-7613. S2CID 146426700.
  21. ^ Mansfield, Charles F. (1980). "A urolith of biogenic dolomite – another clue in the dolomite mystery". Geochimica et Cosmochimica Acta. 44 (6): 829–839. Bibcode:1980GeCoA..44..829M. doi:10.1016/0016-7037(80)90264-1.
  22. ^ A Review of the Literature on Catalytic Biomass Tar Destruction 2015-02-04 at the Wayback Machine National Renewable Energy Laboratory.
  23. ^ Short Sharp Science: Particle quest: Hunting for Italian WIMPs underground 2017-05-17 at the Wayback Machine. Newscientist.com (2011-09-05). Retrieved on 2011-10-10.
  24. ^ Calvo M.; Sevillano, E. (1991). "The Eugui quarries, Navarra, Spain". The Mineralogical Record. 22: 137–142.

External links

dolomite, mineral, dolomite, anhydrous, carbonate, mineral, composed, calcium, magnesium, carbonate, ideally, camg, term, also, used, sedimentary, carbonate, rock, composed, mostly, mineral, dolomite, alternative, name, sometimes, used, dolomitic, rock, type, . Dolomite ˈ d ɒ l e ˌ m aɪ t ˈ d oʊ l e is an anhydrous carbonate mineral composed of calcium magnesium carbonate ideally CaMg CO3 2 The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite An alternative name sometimes used for the dolomitic rock type is dolostone DolomiteDolomite white on talcGeneralCategoryCarbonate mineralsFormula repeating unit CaMg CO3 2IMA symbolDol 1 Strunz classification5 AB 10Crystal systemTrigonalCrystal classRhombohedral 3 H M symbol 3 Space groupR3Unit cella 4 8012 1 c 16 002 A Z 3IdentificationColorWhite grey to pink reddish white brownish white colourless in transmitted lightCrystal habitTabular crystals often with curved faces also columnar stalactitic granular massive TwinningCommon as simple contact twinsCleavage3 directions of cleavage not at right anglesFractureConchoidalTenacityBrittleMohs scale hardness3 5 4LusterVitreous to pearlyStreakWhiteSpecific gravity2 84 2 86Optical propertiesUniaxial Refractive indexnw 1 679 1 681 ne 1 500Birefringenced 0 179 0 181SolubilityPoorly soluble in dilute HClOther characteristicsMay fluoresce white to pink under UV triboluminescent Ksp values vary between 1x10 19 to 1x10 17References 2 3 4 5 6 Dolomite and calcite look similar under a microscope but thin sections can be etched and stained in order to identify the minerals Photomicrograph of a thin section in cross and plane polarised light the brighter mineral grains in the picture are dolomite and the darker grains are calcite Contents 1 History 2 Properties 3 Formation 4 Uses 5 See also 6 References 7 External linksHistory Edit Cristallo in the Dolomites mountain range near Cortina d Ampezzo Italy The Dolomite Mountains were named after the mineral As stated by Nicolas Theodore de Saussure 7 the mineral dolomite was probably first described by Carl Linnaeus in 1768 8 In 1791 it was described as a rock by the French naturalist and geologist Deodat Gratet de Dolomieu 1750 1801 first in buildings of the old city of Rome and later as samples collected in the Tyrolean Alps Nicolas Theodore de Saussure first named the mineral after Dolomieu in March 1792 Properties EditThe mineral dolomite crystallizes in the trigonal rhombohedral system It forms white tan gray or pink crystals Dolomite is a double carbonate having an alternating structural arrangement of calcium and magnesium ions Unless it is in fine powder form it does not rapidly dissolve or effervesce fizz in cold dilute hydrochloric acid as calcite does 9 Crystal twinning is common Solid solution exists between dolomite the iron dominant ankerite and the manganese dominant kutnohorite 10 Small amounts of iron in the structure give the crystals a yellow to brown tint Manganese substitutes in the structure also up to about three percent MnO A high manganese content gives the crystals a rosy pink color Lead zinc and cobalt also substitute in the structure for magnesium The mineral dolomite is closely related to huntite Mg3Ca CO3 4 Because dolomite can be dissolved by slightly acidic water areas where dolomite is an abundant rock forming mineral are important as aquifers and contribute to karst terrain formation 11 Formation EditModern dolomite formation has been found to occur under anaerobic conditions in supersaturated saline lagoons such as those at the Rio de Janeiro coast of Brazil namely Lagoa Vermelha and Brejo do Espinho There are many other localities where modern dolomite forms notably along sabkhas in the Persian Gulf 12 but also in sedimentary basins bearing gas hydrates 13 and hypersaline lakes 14 It is often thought that dolomite nucleates with the help of sulfate reducing bacteria e g Desulfovibrio brasiliensis 15 but other microbial metabolisms have been also found to mediate in dolomite formation 12 In general low temperature dolomite may occur in natural supersaturated environments rich in extracelullar polymeric substances EPS and microbial cell surfaces 12 This is likely result from complexation of both magnesium and calcium by carboxylic acids comprising EPS 16 Vast deposits of dolomite are present in the geological record but the mineral is relatively rare in modern environments Reproducible inorganic low temperature syntheses of dolomite are yet to be performed Usually the initial inorganic precipitation of a metastable precursor such as magnesium calcite can easily be achieved The precursor phase will theoretically change gradually into a more stable phase such as partially ordered dolomite during periodical intervals of dissolution and re precipitation The general principle governing the course of this irreversible geochemical reaction has been coined breaking Ostwald s step rule 17 High diagenetic temperatures such as those of groundwater flowing along deeply rooted fault systems affecting some sedimentary successions or deeply buried limestone rocks allocate dolomitization 18 But the mineral is also volumetrically important in some Neogene platforms never subjected to elevated temperatures Under such conditions of diagenesis the long term activity of the deep biosphere could play a key role in dolomitization since diagenetic fluids of contrasting composition are mixed as a response to Milankovitch cycles 19 A recent biotic synthetic experiment claims to have precipitated ordered dolomite when anoxygenic photosynthesis proceeds in the presence of manganese II 20 A still perplexing example of an organogenic origin is that of the reported formation of dolomite in the urinary bladder of a Dalmatian dog possibly as the result of an illness or infection 21 Uses EditDolomite is used as an ornamental stone a concrete aggregate and a source of magnesium oxide as well as in the Pidgeon process for the production of magnesium It is an important petroleum reservoir rock and serves as the host rock for large strata bound Mississippi Valley Type MVT ore deposits of base metals such as lead zinc and copper Where calcite limestone is uncommon or too costly dolomite is sometimes used in its place as a flux for the smelting of iron and steel Large quantities of processed dolomite are used in the production of float glass In horticulture dolomite and dolomitic limestone are added to soils and soilless potting mixes as a pH buffer and as a magnesium source Dolomite is also used as the substrate in marine saltwater aquariums to help buffer changes in the pH of the water Calcined dolomite is also used as a catalyst for destruction of tar in the gasification of biomass at high temperature 22 Particle physics researchers like to build particle detectors under layers of dolomite to enable the detectors to detect the highest possible number of exotic particles Because dolomite contains relatively minor quantities of radioactive materials it can insulate against interference from cosmic rays without adding to background radiation levels 23 In addition to being an industrial mineral dolomite is highly valued by collectors and museums when it forms large transparent crystals The specimens that appear in the magnesite quarry exploited in Eugui Esteribar Navarra Spain are considered among the best in the world 24 See also EditDolomitization Geological process producing dolomite Evaporite Water soluble mineral deposit formed by evaporation from an aqueous solution List of minerals List of minerals for which there are articles on Wikipedia Magnesian Limestone Suite of carbonate rocks in England Main Dolomite Rock formation in the Alps of EuropeReferences Edit Warr L N 2021 IMA CNMNC approved mineral symbols Mineralogical Magazine 85 3 291 320 Bibcode 2021MinM 85 291W doi 10 1180 mgm 2021 43 S2CID 235729616 Deer W A R A Howie and J Zussman 1966 An Introduction to the Rock Forming Minerals Longman pp 489 493 ISBN 0 582 44210 9 Dolomite Archived 2008 04 09 at the Wayback Machine Handbook of Mineralogy PDF Retrieved on 2011 10 10 Dolomite Archived 2005 08 27 at the Wayback Machine Webmineral Retrieved on 2011 10 10 Dolomite Archived 2015 11 18 at the Wayback Machine Mindat org Retrieved on 2011 10 10 Krauskopf Konrad Bates Bird Dennis K 1995 Introduction to geochemistry 3rd ed New York McGraw Hill ISBN 9780070358201 Archived from the original on 2017 02 26 Saussure le fils M de 1792 Analyse de la dolomie Journal de Physique vol 40 pp 161 173 Linnaeus C 1768 Systema naturae per regnum tria naturae secundum classes ordines genera species cum characteribus amp differentiis Tomus III Laurentii Salvii Holmiae 236 p On p 41 of this very book Linnaeus stated in Latin Marmor tardum Marmor paticulis subimpalpabilibus album diaphanum Hoc simile quartzo durum distinctum quod cum aqua forti non nisi post aliquot minuta amp fero effervescens In translation Slow marble Marble white and transparent with barely discernable particles This is as hard as quartz but it is different in that it does not unless after a few minutes effervesce with aqua forti Dolomite Mineral Uses and Properties geology com Klein Cornelis and Cornelius S Hurlbut Jr Manual of Mineralogy Wiley 20th ed p 339 340 ISBN 0 471 80580 7 Kaufmann James Sinkholes Archived 2013 06 04 at the Wayback Machine USGS Fact Sheet Retrieved on 2013 9 10 a b c Petrash Daniel A Bialik Or M Bontognali Tomaso R R Vasconcelos Crisogono Roberts Jennifer A McKenzie Judith A Konhauser Kurt O 2017 08 01 Microbially catalyzed dolomite formation From near surface to burial Earth Science Reviews 171 558 582 Bibcode 2017ESRv 171 558P doi 10 1016 j earscirev 2017 06 015 ISSN 0012 8252 Snyder Glen T Matsumoto Ryo Suzuki Yohey Kouduka Mariko Kakizaki Yoshihiro Zhang Naizhong Tomaru Hitoshi Sano Yuji Takahata Naoto Tanaka Kentaro Bowden Stephen A 2020 02 05 Evidence in the Japan Sea of microdolomite mineralization within gas hydrate microbiomes Scientific Reports 10 1 1876 Bibcode 2020NatSR 10 1876S doi 10 1038 s41598 020 58723 y ISSN 2045 2322 PMC 7002378 PMID 32024862 Last William M 1990 05 01 Lacustrine dolomite an overview of modern Holocene and Pleistocene occurrences Earth Science Reviews 27 3 221 263 Bibcode 1990ESRv 27 221L doi 10 1016 0012 8252 90 90004 F ISSN 0012 8252 Vasconcelos C McKenzie J A Bernasconi S Grujic D Tien A J 1995 Microbial mediation as a possible mechanism for natural dolomite formation at low temperatures Nature 337 6546 220 222 Bibcode 1995Natur 377 220V doi 10 1038 377220a0 S2CID 4371495 Roberts J A Kenward P A Fowle D A Goldstein R H Gonzalez L A amp Moore D S 1980 Surface chemistry allows for abiotic precipitation of dolomite at low temperature Proceedings of the National Academy of Sciences of the United States of America 110 36 14540 5 Bibcode 2013PNAS 11014540R doi 10 1073 pnas 1305403110 PMC 3767548 PMID 23964124 Deelman J C 1999 Low temperature nucleation of magnesite and dolomite Archived 2008 04 09 at the Wayback Machine Neues Jahrbuch fur Mineralogie Monatshefte pp 289 302 Warren J 2000 11 01 Dolomite occurrence evolution and economically important associations Earth Science Reviews 52 1 3 1 81 Bibcode 2000ESRv 52 1W doi 10 1016 S0012 8252 00 00022 2 ISSN 0012 8252 Petrash Daniel A Bialik Or M Staudigel Philip T Konhauser Kurt O Budd David A 2021 Biogeochemical reappraisal of the freshwater seawater mixing zone diagenetic model Sedimentology 68 5 1797 1830 doi 10 1111 sed 12849 ISSN 1365 3091 S2CID 234012426 Daye Mirna Higgins John Bosak Tanja 2019 06 01 Formation of ordered dolomite in anaerobic photosynthetic biofilms Geology 47 6 509 512 Bibcode 2019Geo 47 509D doi 10 1130 G45821 1 hdl 1721 1 126802 ISSN 0091 7613 S2CID 146426700 Mansfield Charles F 1980 A urolith of biogenic dolomite another clue in the dolomite mystery Geochimica et Cosmochimica Acta 44 6 829 839 Bibcode 1980GeCoA 44 829M doi 10 1016 0016 7037 80 90264 1 A Review of the Literature on Catalytic Biomass Tar Destruction Archived 2015 02 04 at the Wayback Machine National Renewable Energy Laboratory Short Sharp Science Particle quest Hunting for Italian WIMPs underground Archived 2017 05 17 at the Wayback Machine Newscientist com 2011 09 05 Retrieved on 2011 10 10 Calvo M Sevillano E 1991 The Eugui quarries Navarra Spain The Mineralogical Record 22 137 142 External links Edit Wikimedia Commons has media related to Dolomite mineral Retrieved from https en wikipedia org w index php title Dolomite mineral amp oldid 1129866679, wikipedia, wiki, book, books, library,

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