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Rheology

Rheology (/rˈɒləi/; from Greek ῥέω (rhéō) 'flow', and -λoγία (-logia) 'study of') is the study of the flow of matter, primarily in a fluid (liquid or gas) state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is a branch of physics, and it is the science that deals with the deformation and flow of materials, both solids and liquids.[1]

The term rheology was coined by Eugene C. Bingham, a professor at Lafayette College, in 1920, from a suggestion by a colleague, Markus Reiner.[2][3] The term was inspired by the aphorism of Heraclitus (often mistakenly attributed to Simplicius), panta rhei (πάντα ῥεῖ, 'everything flows'[4][5]) and was first used to describe the flow of liquids and the deformation of solids. It applies to substances that have a complex microstructure, such as muds, sludges, suspensions, polymers and other glass formers (e.g., silicates), as well as many foods and additives, bodily fluids (e.g., blood) and other biological materials, and to other materials that belong to the class of soft matter such as food.

Newtonian fluids can be characterized by a single coefficient of viscosity for a specific temperature. Although this viscosity will change with temperature, it does not change with the strain rate. Only a small group of fluids exhibit such constant viscosity. The large class of fluids whose viscosity changes with the strain rate (the relative flow velocity) are called non-Newtonian fluids.

Rheology generally accounts for the behavior of non-Newtonian fluids by characterizing the minimum number of functions that are needed to relate stresses with rate of change of strain or strain rates. For example, ketchup can have its viscosity reduced by shaking (or other forms of mechanical agitation, where the relative movement of different layers in the material actually causes the reduction in viscosity) but water cannot. Ketchup is a shear-thinning material, like yogurt and emulsion paint (US terminology latex paint or acrylic paint), exhibiting thixotropy, where an increase in relative flow velocity will cause a reduction in viscosity, for example, by stirring. Some other non-Newtonian materials show the opposite behavior, rheopecty: viscosity increasing with relative deformation, and are called shear-thickening or dilatant materials. Since Sir Isaac Newton originated the concept of viscosity, the study of liquids with strain-rate-dependent viscosity is also often called Non-Newtonian fluid mechanics.[1]

The experimental characterisation of a material's rheological behaviour is known as rheometry, although the term rheology is frequently used synonymously with rheometry, particularly by experimentalists. Theoretical aspects of rheology are the relation of the flow/deformation behaviour of material and its internal structure (e.g., the orientation and elongation of polymer molecules), and the flow/deformation behaviour of materials that cannot be described by classical fluid mechanics or elasticity.

Scope

In practice, rheology is principally concerned with extending continuum mechanics to characterize the flow of materials that exhibit a combination of elastic, viscous and plastic behavior by properly combining elasticity and (Newtonian) fluid mechanics. It is also concerned with predicting mechanical behavior (on the continuum mechanical scale) based on the micro- or nanostructure of the material, e.g. the molecular size and architecture of polymers in solution or the particle size distribution in a solid suspension. Materials with the characteristics of a fluid will flow when subjected to a stress, which is defined as the force per area. There are different sorts of stress (e.g. shear, torsional, etc.), and materials can respond differently under different stresses. Much of theoretical rheology is concerned with associating external forces and torques with internal stresses, internal strain gradients, and flow velocities.[1][6][7][8]

Continuum mechanics
The study of the physics of continuous materials
Solid mechanics
The study of the physics of continuous materials with a defined rest shape.
Elasticity
Describes materials that return to their rest shape after applied stresses are removed.
Plasticity
Describes materials that permanently deform after a sufficient applied stress.
Rheology
The study of materials with both solid and fluid characteristics.
Fluid mechanics
The study of the physics of continuous materials which deform when subjected to a force.
Non-Newtonian fluid
Do not undergo strain rates proportional to the applied shear stress.
Newtonian fluids undergo strain rates proportional to the applied shear stress.

Rheology unites the seemingly unrelated fields of plasticity and non-Newtonian fluid dynamics by recognizing that materials undergoing these types of deformation are unable to support a stress (particularly a shear stress, since it is easier to analyze shear deformation) in static equilibrium. In this sense, a solid undergoing plastic deformation is a fluid, although no viscosity coefficient is associated with this flow. Granular rheology refers to the continuum mechanical description of granular materials.

One of the major tasks of rheology is to establish by measurement the relationships between strains (or rates of strain) and stresses, although a number of theoretical developments (such as assuring frame invariants) are also required before using the empirical data. These experimental techniques are known as rheometry and are concerned with the determination of well-defined rheological material functions. Such relationships are then amenable to mathematical treatment by the established methods of continuum mechanics.

The characterization of flow or deformation originating from a simple shear stress field is called shear rheometry (or shear rheology). The study of extensional flows is called extensional rheology. Shear flows are much easier to study and thus much more experimental data are available for shear flows than for extensional flows.

Viscoelasticity

  • Fluid and solid character are relevant at long times:
    We consider the application of a constant stress (a so-called creep experiment):
    • if the material, after some deformation, eventually resists further deformation, it is considered a solid
    • if, by contrast, the material flows indefinitely, it is considered a fluid
  • By contrast, elastic and viscous (or intermediate, viscoelastic) behaviour is relevant at short times (transient behaviour):
    We again consider the application of a constant stress:[9]
    • if the material deformation strain increases linearly with increasing applied stress, then the material is linear elastic within the range it shows recoverable strains. Elasticity is essentially a time independent processes, as the strains appear the moment the stress is applied, without any time delay.
    • if the material deformation strain rate increases linearly with increasing applied stress, then the material is viscous in the Newtonian sense. These materials are characterized due to the time delay between the applied constant stress and the maximum strain.
    • if the materials behaves as a combination of viscous and elastic components, then the material is viscoelastic. Theoretically such materials can show both instantaneous deformation as elastic material and a delayed time dependent deformation as in fluids.
  • Plasticity is the behavior observed after the material is subjected to a yield stress:
    A material that behaves as a solid under low applied stresses may start to flow above a certain level of stress, called the yield stress of the material. The term plastic solid is often used when this plasticity threshold is rather high, while yield stress fluid is used when the threshold stress is rather low. However, there is no fundamental difference between the two concepts.

Dimensionless numbers

Deborah number

On one end of the spectrum we have an inviscid or a simple Newtonian fluid and on the other end, a rigid solid; thus the behavior of all materials fall somewhere in between these two ends. The difference in material behavior is characterized by the level and nature of elasticity present in the material when it deforms, which takes the material behavior to the non-Newtonian regime. The non-dimensional Deborah number is designed to account for the degree of non-Newtonian behavior in a flow. The Deborah number is defined as the ratio of the characteristic time of relaxation (which purely depends on the material and other conditions like the temperature) to the characteristic time of experiment or observation.[3][10] Small Deborah numbers represent Newtonian flow, while non-Newtonian (with both viscous and elastic effects present) behavior occurs for intermediate range Deborah numbers, and high Deborah numbers indicate an elastic/rigid solid. Since Deborah number is a relative quantity, the numerator or the denominator can alter the number. A very small Deborah number can be obtained for a fluid with extremely small relaxation time or a very large experimental time, for example.

Reynolds number

In fluid mechanics, the Reynolds number is a measure of the ratio of inertial forces ( ) to viscous forces ( ) and consequently it quantifies the relative importance of these two types of effect for given flow conditions. Under low Reynolds numbers viscous effects dominate and the flow is laminar, whereas at high Reynolds numbers inertia predominates and the flow may be turbulent. However, since rheology is concerned with fluids which do not have a fixed viscosity, but one which can vary with flow and time, calculation of the Reynolds number can be complicated.

It is one of the most important dimensionless numbers in fluid dynamics and is used, usually along with other dimensionless numbers, to provide a criterion for determining dynamic similitude. When two geometrically similar flow patterns, in perhaps different fluids with possibly different flow rates, have the same values for the relevant dimensionless numbers, they are said to be dynamically similar.

Typically it is given as follows:

 

where:

  • us – mean flow velocity, [m s−1]
  • L – characteristic length, [m]
  • μ – (absolute) dynamic fluid viscosity, [N s m−2] or [Pa s]
  • ν – kinematic fluid viscosity:  , [m2 s−1]
  • ρ – fluid density, [kg m−3].

Measurement

Rheometers are instruments used to characterize the rheological properties of materials, typically fluids that are melts or solution. These instruments impose a specific stress field or deformation to the fluid, and monitor the resultant deformation or stress. Instruments can be run in steady flow or oscillatory flow, in both shear and extension.

Applications

Rheology has applications in materials science, engineering, geophysics, physiology, human biology and pharmaceutics. Materials science is utilized in the production of many industrially important substances, such as cement, paint, and chocolate, which have complex flow characteristics. In addition, plasticity theory has been similarly important for the design of metal forming processes. The science of rheology and the characterization of viscoelastic properties in the production and use of polymeric materials has been critical for the production of many products for use in both the industrial and military sectors. Study of flow properties of liquids is important for pharmacists working in the manufacture of several dosage forms, such as simple liquids, ointments, creams, pastes etc. The flow behavior of liquids under applied stress is of great relevance in the field of pharmacy. Flow properties are used as important quality control tools to maintain the superiority of the product and reduce batch to batch variations.

Materials science

Polymers

Examples may be given to illustrate the potential applications of these principles to practical problems in the processing[11] and use of rubbers, plastics, and fibers. Polymers constitute the basic materials of the rubber and plastic industries and are of vital importance to the textile, petroleum, automobile, paper, and pharmaceutical industries. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production.

In viscoelastic materials, such as most polymers and plastics, the presence of liquid-like behaviour depends on the properties of and so varies with rate of applied load, i.e., how quickly a force is applied. The silicone toy 'Silly Putty' behaves quite differently depending on the time rate of applying a force. Pull on it slowly and it exhibits continuous flow, similar to that evidenced in a highly viscous liquid. Alternatively, when hit hard and directly, it shatters like a silicate glass.

In addition, conventional rubber undergoes a glass transition (often called a rubber-glass transition). E.g. The Space Shuttle Challenger disaster was caused by rubber O-rings that were being used well below their glass transition temperature on an unusually cold Florida morning, and thus could not flex adequately to form proper seals between sections of the two solid-fuel rocket boosters.

Biopolymers

 
Linear structure of cellulose — the most common component of all organic plant life on Earth. * Note the evidence of hydrogen bonding which increases the viscosity at any temperature and pressure. This is an effect similar to that of polymer crosslinking, but less pronounced.

Sol-gel

 
Polymerization process of tetraethylorthosilicate (TEOS) and water to form amorphous hydrated silica particles (Si-OH) can be monitored rheologically by a number of different methods.

With the viscosity of a sol adjusted into a proper range, both optical quality glass fiber and refractory ceramic fiber can be drawn which are used for fiber-optic sensors and thermal insulation, respectively. The mechanisms of hydrolysis and condensation, and the rheological factors that bias the structure toward linear or branched structures are the most critical issues of sol-gel science and technology.

Geophysics

The scientific discipline of geophysics includes study of the flow of molten lava and study of debris flows (fluid mudslides). This disciplinary branch also deals with solid Earth materials which only exhibit flow over extended time-scales. Those that display viscous behaviour are known as rheids. For example, granite can flow plastically with a negligible yield stress at room temperatures (i.e. a viscous flow). Long-term creep experiments (~10 years) indicate that the viscosity of granite and glass under ambient conditions are on the order of 1020 poises.[12][13]

Physiology

Physiology includes the study of many bodily fluids that have complex structure and composition, and thus exhibit a wide range of viscoelastic flow characteristics. In particular there is a specialist study of blood flow called hemorheology. This is the study of flow properties of blood and its elements (plasma and formed elements, including red blood cells, white blood cells and platelets). Blood viscosity is determined by plasma viscosity, hematocrit (volume fraction of red blood cell, which constitute 99.9% of the cellular elements) and mechanical behaviour of red blood cells. Therefore, red blood cell mechanics is the major determinant of flow properties of blood.[14]

The leading characteristic for hemorheology has been shear thinning in steady shear flow. Other non-Newtonian rheological characteristics that blood can demonstrate includes pseudoplasticity, viscoelasticity, and thixotropy.[15]

Red Blood Cell Aggregation

There are two current major hypotheses to explain blood flow predictions and shear thinning responses. The two models also attempt to demonstrate the drive for reversible red blood cell aggregation, although the mechanism is still being debated. There is a direct effect of red blood cell aggregation on blood viscosity and circulation.[16] The foundation of hemorheology can also provide information for modeling of other biofluids.[15] The bridging or "cross-bridging" hypothesis suggests that macromolecules physically crosslink adjacent red blood cells into rouleaux structures. This occurs through adsorption of macromolecules onto the red blood cell surfaces.[15][16] The depletion layer hypothesis suggests the opposite mechanism. The surfaces of the red blood cells are bound together by an osmotic pressure gradient that is created by depletion layers overlapping.[15] The effect of rouleaux aggregation tendency can be explained by hematocrit and fibrinogen concentration in whole blood rheology.[15] Some techniques researchers use are optical trapping and microfluidics to measure cell interaction in vitro.[16]

Disease and Diagnostics

Changes to viscosity has been shown to be linked with diseases like hyperviscosity, hypertension, sickle cell anemia, and diabetes.[15] Hemorheological measurements and genomic testing technologies that act as preventative measures and diagnostic tools.[15][17]

Hemorheology has also been correlated with aging effects, especially with impaired blood fluidity, and studies have shown that physical activity may improve the thickening of blood rheology.[18]

Zoology

Many animals make use of rheological phenomena, for example sandfish that exploit the granular rheology of dry sand to "swim" in it or land gastropods that use snail slime for adhesive locomotion. Certain animals produce specialized endogenous complex fluids, such as the sticky slime produced by velvet worms to immobilize prey or the fast-gelling underwater slime secreted by hagfish to deter predators.[19]

Food rheology

Food rheology is important in the manufacture and processing of food products, such as cheese[20] and gelato.[21] An adequate rheology is important for the indulgence of many common foods, particularly in the case of sauces,[22] dressings,[23] yogurt,[24] or fondue.[25]

Thickening agents, or thickeners, are substances which, when added to an aqueous mixture, increase its viscosity without substantially modifying its other properties, such as taste. They provide body, increase stability, and improve suspension of added ingredients. Thickening agents are often used as food additives and in cosmetics and personal hygiene products. Some thickening agents are gelling agents, forming a gel. The agents are materials used to thicken and stabilize liquid solutions, emulsions, and suspensions. They dissolve in the liquid phase as a colloid mixture that forms a weakly cohesive internal structure. Food thickeners frequently are based on either polysaccharides (starches, vegetable gums, and pectin), or proteins.[26][27]

Concrete rheology

Concrete's and mortar's workability is related to the rheological properties of the fresh cement paste. The mechanical properties of hardened concrete increase if less water is used in the concrete mix design, however reducing the water-to-cement ratio may decrease the ease of mixing and application. To avoid these undesired effects, superplasticizers are typically added to decrease the apparent yield stress and the viscosity of the fresh paste. Their addition highly improves concrete and mortar properties.[28]

Filled polymer rheology

The incorporation of various types of fillers into polymers is a common means of reducing cost and to impart certain desirable mechanical, thermal, electrical and magnetic properties to the resulting material. The advantages that filled polymer systems have to offer come with an increased complexity in the rheological behavior.[29]

Usually when the use of fillers is considered, a compromise has to be made between the improved mechanical properties in the solid state on one side and the increased difficulty in melt processing, the problem of achieving uniform dispersion of the filler in the polymer matrix and the economics of the process due to the added step of compounding on the other. The rheological properties of filled polymers are determined not only by the type and amount of filler, but also by the shape, size and size distribution of its particles. The viscosity of filled systems generally increases with increasing filler fraction. This can be partially ameliorated via broad particle size distributions via the Farris effect. An additional factor is the stress transfer at the filler-polymer interface. The interfacial adhesion can be substantially enhanced via a coupling agent that adheres well to both the polymer and the filler particles. The type and amount of surface treatment on the filler are thus additional parameters affecting the rheological and material properties of filled polymeric systems.

It is important to take into consideration wall slip when performing the rheological characterization of highly filled materials, as there can be a large difference between the actual strain and the measured strain.[30]

Rheologist

A rheologist is an interdisciplinary scientist or engineer who studies the flow of complex liquids or the deformation of soft solids. It is not a primary degree subject; there is no qualification of rheologist as such. Most rheologists have a qualification in mathematics, the physical sciences (e.g. chemistry, physics, geology, biology), engineering (e.g. mechanical, chemical, materials science, plastics engineering and engineering or civil engineering), medicine, or certain technologies, notably materials or food. Typically, a small amount of rheology may be studied when obtaining a degree, but a person working in rheology will extend this knowledge during postgraduate research or by attending short courses and by joining a professional association.

See also

References

  1. ^ a b c W. R. Schowalter (1978) Mechanics of Non-Newtonian Fluids Pergamon ISBN 0-08-021778-8
  2. ^ James Freeman Steffe (1 January 1996). Rheological Methods in Food Process Engineering. Freeman Press. ISBN 978-0-9632036-1-8.
  3. ^ a b The Deborah Number 2011-04-13 at the Wayback Machine
  4. ^ Barnes, Jonathan (1982). The presocratic philosophers. ISBN 978-0-415-05079-1.
  5. ^ Beris, A. N.; Giacomin, A. J. (2014). "πάντα ῥεῖ : Everything Flows". Applied Rheology. 24: 52918. doi:10.3933/ApplRheol-24-52918. S2CID 195789095.
  6. ^ R. B. Bird, W. E. Stewart, E. N. Lightfoot (1960), Transport Phenomena, John Wiley & Sons, ISBN 0-471-07392-X
  7. ^ R. Byrin Bird, Charles F. Curtiss, Robert C. Armstrong (1989), Dynamics of Polymeric Liquids, Vol 1 & 2, Wiley Interscience, ISBN 0-471-51844-1 and 978-0471518440
  8. ^ Faith A. Morrison (2001), Understanding Rheology, Oxford University Press, ISBN 0-19-514166-0 and 978-0195141665
  9. ^ William N. Findley, James S. Lai, Kasif Onaran (1989), Creep and Relaxation of Nonlinear Viscoelastic Materials, Dover Publications
  10. ^ Reiner, M. (1964). "The Deborah Number". Physics Today. 17 (1): 62. Bibcode:1964PhT....17a..62R. doi:10.1063/1.3051374. ISSN 0031-9228.
  11. ^ Shenoy, Aroon V.; Saini, D. R. (1996). Thermoplastic melt rheology and processing. New York: Marcel Dekker Inc. ISBN 9780824797232.
  12. ^ Kumagai, N., Sasajima, S., Ito, H., Long-term Creep of Rocks, J. Soc. Mat. Sci. (Japan), Vol. 27, p. 157 (1978) Online
  13. ^ Vannoni, M.; Sordoni, A.; Molesini, G. (2011). "Relaxation time and viscosity of fused silica glass at room temperature". Eur. Phys. J. E. 34 (9): 9–14. doi:10.1140/epje/i2011-11092-9. PMID 21947892. S2CID 2246471.
  14. ^ The ocular Vitreous humor is subject to rheologic observations, particularly during studies of age-related vitreous liquefaction, or synaeresis. Baskurt OK, Meiselman HJ; Meiselman (2003). "Blood rheology and hemodynamics". Seminars in Thrombosis and Hemostasis. 29 (5): 435–450. doi:10.1055/s-2003-44551. PMID 14631543. S2CID 17873138.
  15. ^ a b c d e f g Beris, Antony N.; Horner, Jeffrey S.; Jariwala, Soham; Armstrong, Matthew J.; Wagner, Norman J. (2021). "Recent advances in blood rheology: a review". Soft Matter. 17 (47): 10591–10613. arXiv:2109.05088. Bibcode:2021SMat...1710591B. doi:10.1039/D1SM01212F. ISSN 1744-683X. PMID 34787149. S2CID 237492003.
  16. ^ a b c Lee, Kisung; Wagner, Christian; Priezzhev, Alexander V. (2017). "Assessment of the "cross-bridge"-induced interaction of red blood cells by optical trapping combined with microfluidics". Journal of Biomedical Optics. 22 (9): 091516. Bibcode:2017JBO....22i1516L. doi:10.1117/1.JBO.22.9.091516. ISSN 1083-3668. PMID 28636066. S2CID 27534435.
  17. ^ Hurst, Anna C. E.; Robin, Nathaniel H. (2020). "Dysmorphology in the Era of Genomic Diagnosis". Journal of Personalized Medicine. 10 (1): 18. doi:10.3390/jpm10010018. ISSN 2075-4426. PMC 7151624. PMID 32192103.
  18. ^ Simmonds, Michael J.; Meiselman, Herbert J.; Baskurt, Oguz K. (2013). "Blood rheology and aging". Journal of Geriatric Cardiology. 10 (3): 291–301. doi:10.3969/j.issn.1671-5411.2013.03.010. PMC 3796705. PMID 24133519.
  19. ^ Rühs, Patrick A.; Bergfreund, Jotam; Bertsch, Pascal; Gstöhl, Stefan J.; Fischer, Peter (2021). "Complex fluids in animal survival strategies". Soft Matter. 17 (11): 3022–3036. arXiv:2005.00773. Bibcode:2021SMat...17.3022R. doi:10.1039/D1SM00142F. PMID 33729256. S2CID 232260738.
  20. ^ S. Gunasekaran, M. Mehmet (2003), Cheese rheology and texture, CRC Press, ISBN 1-58716-021-8
  21. ^ Silaghi, Florina; et al. (July 2010). "Estimation of rheological properties of gelato by FT-NIR spectroscopy". Food Research International. 43 (6): 1624–1628. doi:10.1016/j.foodres.2010.05.007.
  22. ^ Okonkwo, Valentine C.; Mba, Ogan I.; Kwofie, Ebenezer M.; Ngadi, Michael O. (November 2021). "Rheological Properties of Meat Sauces as Influenced by Temperature". Food and Bioprocess Technology. 14 (11): 2146–2160. doi:10.1007/s11947-021-02709-9. S2CID 238223322.
  23. ^ Franco, Jose Maria; Guerrero, Antonio; Gallegos, Crispulo (1995). "Rheology and processing of salad dressing emulsions". Rheologica Acta. 34 (6): 513–524. doi:10.1007/BF00712312. S2CID 94776693.
  24. ^ Benezech, T.; Maingonnat, J.F. (January 1994). "Characterization of the rheological properties of yoghurt—A review". Journal of Food Engineering. 21 (4): 447–472. doi:10.1016/0260-8774(94)90066-3.
  25. ^ Bertsch, Pascal; Savorani, Laura; Fischer, Peter (31 January 2019). "Rheology of Swiss Cheese Fondue". ACS Omega. 4 (1): 1103–1109. doi:10.1021/acsomega.8b02424. PMC 6648832. PMID 31459386.
  26. ^ B.M. McKenna, and J.G. Lyng (2003). Texture in food – Introduction to food rheology and its measurement. ISBN 978-1-85573-673-3. Retrieved 2009-09-18.
  27. ^ Nikolaev L.K., Nikolaev B.L., "EXPERIMENTAL STUDY OF RHEOLOGICAL CHARACTERISTICS OF MELTED CHEESE «MILK»", Processes and equipment for food production, Number 4(18), 2013
  28. ^ Ferrari, L; Kaufmann, J; Winnefeld, F; Plank, J (2011). "Multi-method approach to study influence of superplasticizers on cement suspensions". Cement and Concrete Research. 41 (10): 1058. doi:10.1016/j.cemconres.2011.06.010.
  29. ^ Shenoy, Aroon V. (1999). Rheology of Filled Polymer Systems. doi:10.1007/978-94-015-9213-0. ISBN 978-90-481-4029-9.
  30. ^ C. Feger, M. McGlashan-Powell, I. Nnebe, D.M. Kalyon, Rheology and Stability of Highly Filled Thermal Pastes, IBM Research Report, RC23869 (W0602-065) 2006. http://domino.research.ibm.com/library/cyberdig.nsf/papers/7AAC28E89CA36CC785257116005F824E/$File/rc23869.pdf

External links

  • "The Origins of Rheology: A short historical excursion" 2019-08-19 at the Wayback Machine by Deepak Doraiswamy, DuPont iTechnologies
  • – Short history and collection of rheological instruments from the time of Fritz Höppler
  • [1] 2018-12-20 at the Wayback Machine - On the Rheology of Cats
Societies
  • American Society of Rheology
  • Australian Society of Rheology
  • British Society of Rheology
  • European Society of Rheology
  • French Society of Rheology
  • Nordic Rheology Society
  • Romanian Society of Rheology
  • Korean Society of Rheology
Journals
  • Applied Rheology
  • Journal of Non-Newtonian Fluid Mechanics
  • Journal of Rheology
  • Rheologica Acta

rheology, from, greek, ῥέω, rhéō, flow, λoγία, logia, study, study, flow, matter, primarily, fluid, liquid, state, also, soft, solids, solids, under, conditions, which, they, respond, with, plastic, flow, rather, than, deforming, elastically, response, applied. Rheology r iː ˈ ɒ l e dʒ i from Greek ῥew rheō flow and logia logia study of is the study of the flow of matter primarily in a fluid liquid or gas state but also as soft solids or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force Rheology is a branch of physics and it is the science that deals with the deformation and flow of materials both solids and liquids 1 The term rheology was coined by Eugene C Bingham a professor at Lafayette College in 1920 from a suggestion by a colleague Markus Reiner 2 3 The term was inspired by the aphorism of Heraclitus often mistakenly attributed to Simplicius panta rhei panta ῥeῖ everything flows 4 5 and was first used to describe the flow of liquids and the deformation of solids It applies to substances that have a complex microstructure such as muds sludges suspensions polymers and other glass formers e g silicates as well as many foods and additives bodily fluids e g blood and other biological materials and to other materials that belong to the class of soft matter such as food Newtonian fluids can be characterized by a single coefficient of viscosity for a specific temperature Although this viscosity will change with temperature it does not change with the strain rate Only a small group of fluids exhibit such constant viscosity The large class of fluids whose viscosity changes with the strain rate the relative flow velocity are called non Newtonian fluids Rheology generally accounts for the behavior of non Newtonian fluids by characterizing the minimum number of functions that are needed to relate stresses with rate of change of strain or strain rates For example ketchup can have its viscosity reduced by shaking or other forms of mechanical agitation where the relative movement of different layers in the material actually causes the reduction in viscosity but water cannot Ketchup is a shear thinning material like yogurt and emulsion paint US terminology latex paint or acrylic paint exhibiting thixotropy where an increase in relative flow velocity will cause a reduction in viscosity for example by stirring Some other non Newtonian materials show the opposite behavior rheopecty viscosity increasing with relative deformation and are called shear thickening or dilatant materials Since Sir Isaac Newton originated the concept of viscosity the study of liquids with strain rate dependent viscosity is also often called Non Newtonian fluid mechanics 1 The experimental characterisation of a material s rheological behaviour is known as rheometry although the term rheology is frequently used synonymously with rheometry particularly by experimentalists Theoretical aspects of rheology are the relation of the flow deformation behaviour of material and its internal structure e g the orientation and elongation of polymer molecules and the flow deformation behaviour of materials that cannot be described by classical fluid mechanics or elasticity Contents 1 Scope 2 Viscoelasticity 3 Dimensionless numbers 3 1 Deborah number 3 2 Reynolds number 4 Measurement 5 Applications 5 1 Materials science 5 1 1 Polymers 5 1 2 Biopolymers 5 1 3 Sol gel 5 2 Geophysics 5 3 Physiology 5 3 1 Red Blood Cell Aggregation 5 3 2 Disease and Diagnostics 5 4 Zoology 5 5 Food rheology 5 6 Concrete rheology 5 7 Filled polymer rheology 6 Rheologist 7 See also 8 References 9 External linksScope EditIn practice rheology is principally concerned with extending continuum mechanics to characterize the flow of materials that exhibit a combination of elastic viscous and plastic behavior by properly combining elasticity and Newtonian fluid mechanics It is also concerned with predicting mechanical behavior on the continuum mechanical scale based on the micro or nanostructure of the material e g the molecular size and architecture of polymers in solution or the particle size distribution in a solid suspension Materials with the characteristics of a fluid will flow when subjected to a stress which is defined as the force per area There are different sorts of stress e g shear torsional etc and materials can respond differently under different stresses Much of theoretical rheology is concerned with associating external forces and torques with internal stresses internal strain gradients and flow velocities 1 6 7 8 Continuum mechanicsThe study of the physics of continuous materials Solid mechanicsThe study of the physics of continuous materials with a defined rest shape ElasticityDescribes materials that return to their rest shape after applied stresses are removed PlasticityDescribes materials that permanently deform after a sufficient applied stress RheologyThe study of materials with both solid and fluid characteristics Fluid mechanicsThe study of the physics of continuous materials which deform when subjected to a force Non Newtonian fluidDo not undergo strain rates proportional to the applied shear stress Newtonian fluids undergo strain rates proportional to the applied shear stress Rheology unites the seemingly unrelated fields of plasticity and non Newtonian fluid dynamics by recognizing that materials undergoing these types of deformation are unable to support a stress particularly a shear stress since it is easier to analyze shear deformation in static equilibrium In this sense a solid undergoing plastic deformation is a fluid although no viscosity coefficient is associated with this flow Granular rheology refers to the continuum mechanical description of granular materials One of the major tasks of rheology is to establish by measurement the relationships between strains or rates of strain and stresses although a number of theoretical developments such as assuring frame invariants are also required before using the empirical data These experimental techniques are known as rheometry and are concerned with the determination of well defined rheological material functions Such relationships are then amenable to mathematical treatment by the established methods of continuum mechanics The characterization of flow or deformation originating from a simple shear stress field is called shear rheometry or shear rheology The study of extensional flows is called extensional rheology Shear flows are much easier to study and thus much more experimental data are available for shear flows than for extensional flows Viscoelasticity EditMain article Viscoelasticity Fluid and solid character are relevant at long times We consider the application of a constant stress a so called creep experiment if the material after some deformation eventually resists further deformation it is considered a solid if by contrast the material flows indefinitely it is considered a fluid By contrast elastic and viscous or intermediate viscoelastic behaviour is relevant at short times transient behaviour We again consider the application of a constant stress 9 if the material deformation strain increases linearly with increasing applied stress then the material is linear elastic within the range it shows recoverable strains Elasticity is essentially a time independent processes as the strains appear the moment the stress is applied without any time delay if the material deformation strain rate increases linearly with increasing applied stress then the material is viscous in the Newtonian sense These materials are characterized due to the time delay between the applied constant stress and the maximum strain if the materials behaves as a combination of viscous and elastic components then the material is viscoelastic Theoretically such materials can show both instantaneous deformation as elastic material and a delayed time dependent deformation as in fluids Plasticity is the behavior observed after the material is subjected to a yield stress A material that behaves as a solid under low applied stresses may start to flow above a certain level of stress called the yield stress of the material The term plastic solid is often used when this plasticity threshold is rather high while yield stress fluid is used when the threshold stress is rather low However there is no fundamental difference between the two concepts Dimensionless numbers EditDeborah number Edit Main article Deborah number On one end of the spectrum we have an inviscid or a simple Newtonian fluid and on the other end a rigid solid thus the behavior of all materials fall somewhere in between these two ends The difference in material behavior is characterized by the level and nature of elasticity present in the material when it deforms which takes the material behavior to the non Newtonian regime The non dimensional Deborah number is designed to account for the degree of non Newtonian behavior in a flow The Deborah number is defined as the ratio of the characteristic time of relaxation which purely depends on the material and other conditions like the temperature to the characteristic time of experiment or observation 3 10 Small Deborah numbers represent Newtonian flow while non Newtonian with both viscous and elastic effects present behavior occurs for intermediate range Deborah numbers and high Deborah numbers indicate an elastic rigid solid Since Deborah number is a relative quantity the numerator or the denominator can alter the number A very small Deborah number can be obtained for a fluid with extremely small relaxation time or a very large experimental time for example Reynolds number Edit Main article Reynolds number In fluid mechanics the Reynolds number is a measure of the ratio of inertial forces v s r displaystyle v s rho to viscous forces m L displaystyle frac mu L and consequently it quantifies the relative importance of these two types of effect for given flow conditions Under low Reynolds numbers viscous effects dominate and the flow is laminar whereas at high Reynolds numbers inertia predominates and the flow may be turbulent However since rheology is concerned with fluids which do not have a fixed viscosity but one which can vary with flow and time calculation of the Reynolds number can be complicated It is one of the most important dimensionless numbers in fluid dynamics and is used usually along with other dimensionless numbers to provide a criterion for determining dynamic similitude When two geometrically similar flow patterns in perhaps different fluids with possibly different flow rates have the same values for the relevant dimensionless numbers they are said to be dynamically similar Typically it is given as follows R e r u s 2 L m u s L 2 r u s L m u s L n displaystyle mathrm Re frac rho frac u s 2 L mu frac u s L 2 frac rho u s L mu frac u s L nu where us mean flow velocity m s 1 L characteristic length m m absolute dynamic fluid viscosity N s m 2 or Pa s n kinematic fluid viscosity v m r displaystyle v frac mu rho m2 s 1 r fluid density kg m 3 Measurement EditRheometers are instruments used to characterize the rheological properties of materials typically fluids that are melts or solution These instruments impose a specific stress field or deformation to the fluid and monitor the resultant deformation or stress Instruments can be run in steady flow or oscillatory flow in both shear and extension Applications EditRheology has applications in materials science engineering geophysics physiology human biology and pharmaceutics Materials science is utilized in the production of many industrially important substances such as cement paint and chocolate which have complex flow characteristics In addition plasticity theory has been similarly important for the design of metal forming processes The science of rheology and the characterization of viscoelastic properties in the production and use of polymeric materials has been critical for the production of many products for use in both the industrial and military sectors Study of flow properties of liquids is important for pharmacists working in the manufacture of several dosage forms such as simple liquids ointments creams pastes etc The flow behavior of liquids under applied stress is of great relevance in the field of pharmacy Flow properties are used as important quality control tools to maintain the superiority of the product and reduce batch to batch variations Materials science Edit Polymers Edit Examples may be given to illustrate the potential applications of these principles to practical problems in the processing 11 and use of rubbers plastics and fibers Polymers constitute the basic materials of the rubber and plastic industries and are of vital importance to the textile petroleum automobile paper and pharmaceutical industries Their viscoelastic properties determine the mechanical performance of the final products of these industries and also the success of processing methods at intermediate stages of production In viscoelastic materials such as most polymers and plastics the presence of liquid like behaviour depends on the properties of and so varies with rate of applied load i e how quickly a force is applied The silicone toy Silly Putty behaves quite differently depending on the time rate of applying a force Pull on it slowly and it exhibits continuous flow similar to that evidenced in a highly viscous liquid Alternatively when hit hard and directly it shatters like a silicate glass In addition conventional rubber undergoes a glass transition often called a rubber glass transition E g The Space Shuttle Challenger disaster was caused by rubber O rings that were being used well below their glass transition temperature on an unusually cold Florida morning and thus could not flex adequately to form proper seals between sections of the two solid fuel rocket boosters Biopolymers Edit Linear structure of cellulose the most common component of all organic plant life on Earth Note the evidence of hydrogen bonding which increases the viscosity at any temperature and pressure This is an effect similar to that of polymer crosslinking but less pronounced Sol gel Edit Main article sol gel Polymerization process of tetraethylorthosilicate TEOS and water to form amorphous hydrated silica particles Si OH can be monitored rheologically by a number of different methods With the viscosity of a sol adjusted into a proper range both optical quality glass fiber and refractory ceramic fiber can be drawn which are used for fiber optic sensors and thermal insulation respectively The mechanisms of hydrolysis and condensation and the rheological factors that bias the structure toward linear or branched structures are the most critical issues of sol gel science and technology Geophysics Edit The scientific discipline of geophysics includes study of the flow of molten lava and study of debris flows fluid mudslides This disciplinary branch also deals with solid Earth materials which only exhibit flow over extended time scales Those that display viscous behaviour are known as rheids For example granite can flow plastically with a negligible yield stress at room temperatures i e a viscous flow Long term creep experiments 10 years indicate that the viscosity of granite and glass under ambient conditions are on the order of 1020 poises 12 13 Physiology Edit Physiology includes the study of many bodily fluids that have complex structure and composition and thus exhibit a wide range of viscoelastic flow characteristics In particular there is a specialist study of blood flow called hemorheology This is the study of flow properties of blood and its elements plasma and formed elements including red blood cells white blood cells and platelets Blood viscosity is determined by plasma viscosity hematocrit volume fraction of red blood cell which constitute 99 9 of the cellular elements and mechanical behaviour of red blood cells Therefore red blood cell mechanics is the major determinant of flow properties of blood 14 The leading characteristic for hemorheology has been shear thinning in steady shear flow Other non Newtonian rheological characteristics that blood can demonstrate includes pseudoplasticity viscoelasticity and thixotropy 15 Red Blood Cell Aggregation Edit There are two current major hypotheses to explain blood flow predictions and shear thinning responses The two models also attempt to demonstrate the drive for reversible red blood cell aggregation although the mechanism is still being debated There is a direct effect of red blood cell aggregation on blood viscosity and circulation 16 The foundation of hemorheology can also provide information for modeling of other biofluids 15 The bridging or cross bridging hypothesis suggests that macromolecules physically crosslink adjacent red blood cells into rouleaux structures This occurs through adsorption of macromolecules onto the red blood cell surfaces 15 16 The depletion layer hypothesis suggests the opposite mechanism The surfaces of the red blood cells are bound together by an osmotic pressure gradient that is created by depletion layers overlapping 15 The effect of rouleaux aggregation tendency can be explained by hematocrit and fibrinogen concentration in whole blood rheology 15 Some techniques researchers use are optical trapping and microfluidics to measure cell interaction in vitro 16 Disease and Diagnostics Edit Changes to viscosity has been shown to be linked with diseases like hyperviscosity hypertension sickle cell anemia and diabetes 15 Hemorheological measurements and genomic testing technologies that act as preventative measures and diagnostic tools 15 17 Hemorheology has also been correlated with aging effects especially with impaired blood fluidity and studies have shown that physical activity may improve the thickening of blood rheology 18 Zoology Edit Many animals make use of rheological phenomena for example sandfish that exploit the granular rheology of dry sand to swim in it or land gastropods that use snail slime for adhesive locomotion Certain animals produce specialized endogenous complex fluids such as the sticky slime produced by velvet worms to immobilize prey or the fast gelling underwater slime secreted by hagfish to deter predators 19 Food rheology Edit Food rheology is important in the manufacture and processing of food products such as cheese 20 and gelato 21 An adequate rheology is important for the indulgence of many common foods particularly in the case of sauces 22 dressings 23 yogurt 24 or fondue 25 Thickening agents or thickeners are substances which when added to an aqueous mixture increase its viscosity without substantially modifying its other properties such as taste They provide body increase stability and improve suspension of added ingredients Thickening agents are often used as food additives and in cosmetics and personal hygiene products Some thickening agents are gelling agents forming a gel The agents are materials used to thicken and stabilize liquid solutions emulsions and suspensions They dissolve in the liquid phase as a colloid mixture that forms a weakly cohesive internal structure Food thickeners frequently are based on either polysaccharides starches vegetable gums and pectin or proteins 26 27 Concrete rheology Edit Concrete s and mortar s workability is related to the rheological properties of the fresh cement paste The mechanical properties of hardened concrete increase if less water is used in the concrete mix design however reducing the water to cement ratio may decrease the ease of mixing and application To avoid these undesired effects superplasticizers are typically added to decrease the apparent yield stress and the viscosity of the fresh paste Their addition highly improves concrete and mortar properties 28 Filled polymer rheology Edit The incorporation of various types of fillers into polymers is a common means of reducing cost and to impart certain desirable mechanical thermal electrical and magnetic properties to the resulting material The advantages that filled polymer systems have to offer come with an increased complexity in the rheological behavior 29 Usually when the use of fillers is considered a compromise has to be made between the improved mechanical properties in the solid state on one side and the increased difficulty in melt processing the problem of achieving uniform dispersion of the filler in the polymer matrix and the economics of the process due to the added step of compounding on the other The rheological properties of filled polymers are determined not only by the type and amount of filler but also by the shape size and size distribution of its particles The viscosity of filled systems generally increases with increasing filler fraction This can be partially ameliorated via broad particle size distributions via the Farris effect An additional factor is the stress transfer at the filler polymer interface The interfacial adhesion can be substantially enhanced via a coupling agent that adheres well to both the polymer and the filler particles The type and amount of surface treatment on the filler are thus additional parameters affecting the rheological and material properties of filled polymeric systems It is important to take into consideration wall slip when performing the rheological characterization of highly filled materials as there can be a large difference between the actual strain and the measured strain 30 Rheologist EditA rheologist is an interdisciplinary scientist or engineer who studies the flow of complex liquids or the deformation of soft solids It is not a primary degree subject there is no qualification of rheologist as such Most rheologists have a qualification in mathematics the physical sciences e g chemistry physics geology biology engineering e g mechanical chemical materials science plastics engineering and engineering or civil engineering medicine or certain technologies notably materials or food Typically a small amount of rheology may be studied when obtaining a degree but a person working in rheology will extend this knowledge during postgraduate research or by attending short courses and by joining a professional association See also EditBingham plastic Die swell Fluid dynamics Glass transition Liquid List of rheologists Microrheology Rheological weldability for thermoplastics Rheopectic Solid Transport phenomena Interfacial rheologyReferences Edit a b c W R Schowalter 1978 Mechanics of Non Newtonian Fluids Pergamon ISBN 0 08 021778 8 James Freeman Steffe 1 January 1996 Rheological Methods in Food Process Engineering Freeman Press ISBN 978 0 9632036 1 8 a b The Deborah Number Archived 2011 04 13 at the Wayback Machine Barnes Jonathan 1982 The presocratic philosophers ISBN 978 0 415 05079 1 Beris A N Giacomin A J 2014 panta ῥeῖ Everything Flows Applied Rheology 24 52918 doi 10 3933 ApplRheol 24 52918 S2CID 195789095 R B Bird W E Stewart E N Lightfoot 1960 Transport Phenomena John Wiley amp Sons ISBN 0 471 07392 X R Byrin Bird Charles F Curtiss Robert C Armstrong 1989 Dynamics of Polymeric Liquids Vol 1 amp 2 Wiley Interscience ISBN 0 471 51844 1 and 978 0471518440 Faith A Morrison 2001 Understanding Rheology Oxford University Press ISBN 0 19 514166 0 and 978 0195141665 William N Findley James S Lai Kasif Onaran 1989 Creep and Relaxation of Nonlinear Viscoelastic Materials Dover Publications Reiner M 1964 The Deborah Number Physics Today 17 1 62 Bibcode 1964PhT 17a 62R doi 10 1063 1 3051374 ISSN 0031 9228 Shenoy Aroon V Saini D R 1996 Thermoplastic melt rheology and processing New York Marcel Dekker Inc ISBN 9780824797232 Kumagai N Sasajima S Ito H Long term Creep of Rocks J Soc Mat Sci Japan Vol 27 p 157 1978 Online Vannoni M Sordoni A Molesini G 2011 Relaxation time and viscosity of fused silica glass at room temperature Eur Phys J E 34 9 9 14 doi 10 1140 epje i2011 11092 9 PMID 21947892 S2CID 2246471 The ocular Vitreous humor is subject to rheologic observations particularly during studies of age related vitreous liquefaction or synaeresis Baskurt OK Meiselman HJ Meiselman 2003 Blood rheology and hemodynamics Seminars in Thrombosis and Hemostasis 29 5 435 450 doi 10 1055 s 2003 44551 PMID 14631543 S2CID 17873138 a b c d e f g Beris Antony N Horner Jeffrey S Jariwala Soham Armstrong Matthew J Wagner Norman J 2021 Recent advances in blood rheology a review Soft Matter 17 47 10591 10613 arXiv 2109 05088 Bibcode 2021SMat 1710591B doi 10 1039 D1SM01212F ISSN 1744 683X PMID 34787149 S2CID 237492003 a b c Lee Kisung Wagner Christian Priezzhev Alexander V 2017 Assessment of the cross bridge induced interaction of red blood cells by optical trapping combined with microfluidics Journal of Biomedical Optics 22 9 091516 Bibcode 2017JBO 22i1516L doi 10 1117 1 JBO 22 9 091516 ISSN 1083 3668 PMID 28636066 S2CID 27534435 Hurst Anna C E Robin Nathaniel H 2020 Dysmorphology in the Era of Genomic Diagnosis Journal of Personalized Medicine 10 1 18 doi 10 3390 jpm10010018 ISSN 2075 4426 PMC 7151624 PMID 32192103 Simmonds Michael J Meiselman Herbert J Baskurt Oguz K 2013 Blood rheology and aging Journal of Geriatric Cardiology 10 3 291 301 doi 10 3969 j issn 1671 5411 2013 03 010 PMC 3796705 PMID 24133519 Ruhs Patrick A Bergfreund Jotam Bertsch Pascal Gstohl Stefan J Fischer Peter 2021 Complex fluids in animal survival strategies Soft Matter 17 11 3022 3036 arXiv 2005 00773 Bibcode 2021SMat 17 3022R doi 10 1039 D1SM00142F PMID 33729256 S2CID 232260738 S Gunasekaran M Mehmet 2003 Cheese rheology and texture CRC Press ISBN 1 58716 021 8 Silaghi Florina et al July 2010 Estimation of rheological properties of gelato by FT NIR spectroscopy Food Research International 43 6 1624 1628 doi 10 1016 j foodres 2010 05 007 Okonkwo Valentine C Mba Ogan I Kwofie Ebenezer M Ngadi Michael O November 2021 Rheological Properties of Meat Sauces as Influenced by Temperature Food and Bioprocess Technology 14 11 2146 2160 doi 10 1007 s11947 021 02709 9 S2CID 238223322 Franco Jose Maria Guerrero Antonio Gallegos Crispulo 1995 Rheology and processing of salad dressing emulsions Rheologica Acta 34 6 513 524 doi 10 1007 BF00712312 S2CID 94776693 Benezech T Maingonnat J F January 1994 Characterization of the rheological properties of yoghurt A review Journal of Food Engineering 21 4 447 472 doi 10 1016 0260 8774 94 90066 3 Bertsch Pascal Savorani Laura Fischer Peter 31 January 2019 Rheology of Swiss Cheese Fondue ACS Omega 4 1 1103 1109 doi 10 1021 acsomega 8b02424 PMC 6648832 PMID 31459386 B M McKenna and J G Lyng 2003 Texture in food Introduction to food rheology and its measurement ISBN 978 1 85573 673 3 Retrieved 2009 09 18 Nikolaev L K Nikolaev B L EXPERIMENTAL STUDY OF RHEOLOGICAL CHARACTERISTICS OF MELTED CHEESE MILK Processes and equipment for food production Number 4 18 2013 Ferrari L Kaufmann J Winnefeld F Plank J 2011 Multi method approach to study influence of superplasticizers on cement suspensions Cement and Concrete Research 41 10 1058 doi 10 1016 j cemconres 2011 06 010 Shenoy Aroon V 1999 Rheology of Filled Polymer Systems doi 10 1007 978 94 015 9213 0 ISBN 978 90 481 4029 9 C Feger M McGlashan Powell I Nnebe D M Kalyon Rheology and Stability of Highly Filled Thermal Pastes IBM Research Report RC23869 W0602 065 2006 http domino research ibm com library cyberdig nsf papers 7AAC28E89CA36CC785257116005F824E File rc23869 pdfExternal links Edit Look up rheology in Wiktionary the free dictionary The Origins of Rheology A short historical excursion Archived 2019 08 19 at the Wayback Machine by Deepak Doraiswamy DuPont iTechnologies RHEOTEST Medingen GmbH Short history and collection of rheological instruments from the time of Fritz Hoppler 1 Archived 2018 12 20 at the Wayback Machine On the Rheology of CatsSocietiesAmerican Society of Rheology Australian Society of Rheology British Society of Rheology European Society of Rheology French Society of Rheology Nordic Rheology Society Romanian Society of Rheology Korean Society of RheologyJournalsApplied Rheology Journal of Non Newtonian Fluid Mechanics Journal of Rheology Rheologica Acta Retrieved from https en wikipedia org w index php title Rheology amp oldid 1149634432, wikipedia, wiki, book, books, library,

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