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Wikipedia

Potassium peroxide

Potassium peroxide is an inorganic compound with the molecular formula K2O2. It is formed as potassium reacts with oxygen in the air, along with potassium oxide (K2O) and potassium superoxide (KO2).

Potassium peroxide
Names
IUPAC name
Potassium peroxide
Identifiers
  • 17014-71-0 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 26237 N
ECHA InfoCard 100.037.339
EC Number
  • 241-089-8
  • 28202
UNII
  • ZHB4ZOE9PU Y
  • DTXSID2066143
  • InChI=1S/2K.O2/c;;1-2/q2*+1;-2 N
    Key: XXQBEVHPUKOQEO-UHFFFAOYSA-N N
  • InChI=1/2K.O2/c;;1-2/q2*+1;-2
    Key: XXQBEVHPUKOQEO-UHFFFAOYAV
  • [O-][O-].[K+].[K+]
Properties
K2O2
Molar mass 110.196 g/mol
Appearance yellow amorphous solid
Melting point 490 °C (914 °F; 763 K)
reacts with water[1]
Structure
Orthorhombic
Cmca, oS16
Thermochemistry
113 J·mol−1·K−1[2]
−496 kJ·mol−1[2]
Hazards
GHS labelling:
Danger
H272, H315, H319
P210, P220, P221, P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, P362, P370+P378, P501
NFPA 704 (fire diamond)
Related compounds
Other anions
Potassium chloride
Other cations
Lithium peroxide
Sodium peroxide
Rubidium peroxide
Caesium peroxide
Potassium oxide
Potassium superoxide
Potassium ozonide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Crystal structure

Potassium peroxide reacts with water to form potassium hydroxide and oxygen:

Properties edit

Potassium peroxide is a highly reactive, oxidizing white to yellowish solid which, while not flammable itself, reacts violently with flammable materials. It decomposes violently on contact with water. [1]

The standard enthalpy of formation of potassium peroxide is ΔH f 0 = −496 kJ/mol.

Usage edit

Potassium Peroxide is used as an oxidizing agent and bleach (due to the peroxide), and to purify air.

References edit

  1. ^ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 477, 520. ISBN 0-8493-0594-2.
  2. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN 978-0-618-94690-7.


potassium, peroxide, inorganic, compound, with, molecular, formula, k2o2, formed, potassium, reacts, with, oxygen, along, with, potassium, oxide, potassium, superoxide, namesiupac, name, identifierscas, number, 17014, model, jsmol, interactive, imagechemspider. Potassium peroxide is an inorganic compound with the molecular formula K2O2 It is formed as potassium reacts with oxygen in the air along with potassium oxide K2O and potassium superoxide KO2 Potassium peroxide NamesIUPAC name Potassium peroxideIdentifiersCAS Number 17014 71 0 Y3D model JSmol Interactive imageChemSpider 26237 NECHA InfoCard 100 037 339EC Number 241 089 8PubChem CID 28202UNII ZHB4ZOE9PU YCompTox Dashboard EPA DTXSID2066143InChI InChI 1S 2K O2 c 1 2 q2 1 2 NKey XXQBEVHPUKOQEO UHFFFAOYSA N NInChI 1 2K O2 c 1 2 q2 1 2Key XXQBEVHPUKOQEO UHFFFAOYAVSMILES O O K K PropertiesChemical formula K2O2Molar mass 110 196 g molAppearance yellow amorphous solidMelting point 490 C 914 F 763 K Solubility in water reacts with water 1 StructureCrystal structure OrthorhombicSpace group Cmca oS16ThermochemistryStd molarentropy S 298 113 J mol 1 K 1 2 Std enthalpy offormation DfH 298 496 kJ mol 1 2 HazardsGHS labelling PictogramsSignal word DangerHazard statements H272 H315 H319Precautionary statements P210 P220 P221 P264 P280 P302 P352 P305 P351 P338 P321 P332 P313 P337 P313 P362 P370 P378 P501NFPA 704 fire diamond 302W OXRelated compoundsOther anions Potassium chlorideOther cations Lithium peroxideSodium peroxideRubidium peroxideCaesium peroxideRelated potassium oxides Potassium oxide Potassium superoxidePotassium ozonideExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references Crystal structurePotassium peroxide reacts with water to form potassium hydroxide and oxygen 2K2O2 2H2O 4KOH O2 displaystyle ce 2K2O2 2H2O gt 4KOH O2 Properties editPotassium peroxide is a highly reactive oxidizing white to yellowish solid which while not flammable itself reacts violently with flammable materials It decomposes violently on contact with water 1 The standard enthalpy of formation of potassium peroxide is DH f 0 496 kJ mol Usage editPotassium Peroxide is used as an oxidizing agent and bleach due to the peroxide and to purify air References edit Lide David R 1998 Handbook of Chemistry and Physics 87 ed Boca Raton Florida CRC Press pp 477 520 ISBN 0 8493 0594 2 a b Zumdahl Steven S 2009 Chemical Principles 6th Ed Houghton Mifflin Company p A22 ISBN 978 0 618 94690 7 nbsp This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Potassium peroxide amp oldid 1146201346, wikipedia, wiki, book, books, library,

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