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Fluoromethane

Fluoromethane, also known as methyl fluoride, Freon 41, Halocarbon-41 and HFC-41, is a non-toxic, liquefiable, and flammable gas at standard temperature and pressure. It is made of carbon, hydrogen, and fluorine. The name stems from the fact that it is methane (CH4) with a fluorine atom substituted for one of the hydrogen atoms. It is used in semiconductor manufacturing processes as an etching gas in plasma etch reactors.[2]

Fluoromethane
Stick model of fluoromethane
Spacefill model of fluoromethane
Names
IUPAC name
Fluoromethane
Other names
Freon 41

Methyl fluoride
Halocarbon 41

Monofluoromethane
Identifiers
  • 593-53-3 Y
3D model (JSmol)
  • Interactive image
Abbreviations R41
1730725
ChEBI
  • CHEBI:28826 Y
ChEMBL
  • ChEMBL116838 Y
ChemSpider
  • 11148 Y
ECHA InfoCard 100.008.907
EC Number
  • 209-796-6
391
KEGG
  • C11147 Y
MeSH Fluoromethane
  • 11638
UNII
  • 54A9X6F0CM Y
UN number UN 2454
  • DTXSID6060474
  • InChI=1S/CH3F/c1-2/h1H3 Y
    Key: NBVXSUQYWXRMNV-UHFFFAOYSA-N Y
  • InChI=1/CH3F/c1-2/h1H3
    Key: NBVXSUQYWXRMNV-UHFFFAOYAF
  • FC
Properties
CH3F
Molar mass 34.03 g/mol
Appearance Colourless gas
Odor pleasant, ether-like odour at high concentrations
Density 1.4397 g/L

0.557 g/cm3 (liquid) at saturation pressure at 25 °C

Melting point −137.8 °C (−216.0 °F; 135.3 K)[1]
Boiling point −78.4 °C (−109.1 °F; 194.8 K)[1]
1.66 L/kg (2.295 g/L)
Vapor pressure 3.3 MPa
Hazards
GHS labelling:
Danger
H220, H280
P210, P377, P381, P403, P410+P403
NFPA 704 (fire diamond)
Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
4
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

Composition edit

The compound is the lowest mass member of the hydrofluorocarbon (HFC) family, compounds which contain only hydrogen, fluorine, and carbon. These compounds are related to the chlorofluorocarbons (CFC), but since they do not contain chlorine, are not destructive to the ozone layer.[3] Fluorocarbons are, however, potent greenhouse gasses, and the Kigali Amendment to the Montreal Protocol is an attempt to phase them out due to their contribution to global warming.[4]

The C−F bond energy is 552 kJ/mol and its length is 0.139 nm. Its molecular geometry is tetrahedral.

Its specific heat capacity (Cp) is 38.171 J·mol−1·K−1 at 25 °C. The critical point of fluoromethane is at 44.9 °C (318.1 K) and 6.280 MPa.

See also edit

References edit

  1. ^ a b Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
  2. ^ Siegemund, Günter; Schwertfeger, Werner; Feiring, Andrew; Smart, Bruce; Behr, Fred; Vogel, Herward; McKusick, Blaine (2002). "Fluorine Compounds, Organic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a11_349. ISBN 978-3527306732.
  3. ^ Fluoromethane CH3F
  4. ^ "Explainer: hydrofluorocarbons saved the ozone layer, so why are we banning them?". 2 November 2017.

External links edit

fluoromethane, also, known, methyl, fluoride, freon, halocarbon, toxic, liquefiable, flammable, standard, temperature, pressure, made, carbon, hydrogen, fluorine, name, stems, from, fact, that, methane, with, fluorine, atom, substituted, hydrogen, atoms, used,. Fluoromethane also known as methyl fluoride Freon 41 Halocarbon 41 and HFC 41 is a non toxic liquefiable and flammable gas at standard temperature and pressure It is made of carbon hydrogen and fluorine The name stems from the fact that it is methane CH4 with a fluorine atom substituted for one of the hydrogen atoms It is used in semiconductor manufacturing processes as an etching gas in plasma etch reactors 2 Fluoromethane Stick model of fluoromethane Spacefill model of fluoromethaneNamesIUPAC name FluoromethaneOther names Freon 41Methyl fluoride Halocarbon 41 MonofluoromethaneIdentifiersCAS Number 593 53 3 Y3D model JSmol Interactive imageAbbreviations R41Beilstein Reference 1730725ChEBI CHEBI 28826 YChEMBL ChEMBL116838 YChemSpider 11148 YECHA InfoCard 100 008 907EC Number 209 796 6Gmelin Reference 391KEGG C11147 YMeSH FluoromethanePubChem CID 11638UNII 54A9X6F0CM YUN number UN 2454CompTox Dashboard EPA DTXSID6060474InChI InChI 1S CH3F c1 2 h1H3 YKey NBVXSUQYWXRMNV UHFFFAOYSA N YInChI 1 CH3F c1 2 h1H3Key NBVXSUQYWXRMNV UHFFFAOYAFSMILES FCPropertiesChemical formula CH3FMolar mass 34 03 g molAppearance Colourless gasOdor pleasant ether like odour at high concentrationsDensity 1 4397 g L0 557 g cm3 liquid at saturation pressure at 25 CMelting point 137 8 C 216 0 F 135 3 K 1 Boiling point 78 4 C 109 1 F 194 8 K 1 Solubility in water 1 66 L kg 2 295 g L Vapor pressure 3 3 MPaHazardsGHS labelling PictogramsSignal word DangerHazard statements H220 H280Precautionary statements P210 P377 P381 P403 P410 P403NFPA 704 fire diamond 140Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references Contents 1 Composition 2 See also 3 References 4 External linksComposition editThe compound is the lowest mass member of the hydrofluorocarbon HFC family compounds which contain only hydrogen fluorine and carbon These compounds are related to the chlorofluorocarbons CFC but since they do not contain chlorine are not destructive to the ozone layer 3 Fluorocarbons are however potent greenhouse gasses and the Kigali Amendment to the Montreal Protocol is an attempt to phase them out due to their contribution to global warming 4 The C F bond energy is 552 kJ mol and its length is 0 139 nm Its molecular geometry is tetrahedral Its specific heat capacity Cp is 38 171 J mol 1 K 1 at 25 C The critical point of fluoromethane is at 44 9 C 318 1 K and 6 280 MPa See also editOrganofluorine chemistry HalomethanesReferences edit a b Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health Siegemund Gunter Schwertfeger Werner Feiring Andrew Smart Bruce Behr Fred Vogel Herward McKusick Blaine 2002 Fluorine Compounds Organic Ullmann s Encyclopedia of Industrial Chemistry Weinheim Wiley VCH doi 10 1002 14356007 a11 349 ISBN 978 3527306732 Fluoromethane CH3F Explainer hydrofluorocarbons saved the ozone layer so why are we banning them 2 November 2017 External links editMSDS at Chemblink com permanent dead link Data at Airliquide Encyclopedia permanent dead link Thermochemical data at chemnet ru CAS DataBase List METHYL FLUORIDE at ChemicalBook Retrieved from https en wikipedia org w index php title Fluoromethane amp oldid 1195062647, wikipedia, wiki, book, books, library,

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