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Environmental impact of concrete

The environmental impact of concrete, its manufacture, and its applications, are complex, driven in part by direct impacts of construction and infrastructure, as well as by CO2 emissions; between 4-8% of total global CO2 emissions come from concrete.[1] Many depend on circumstances. A major component is cement, which has its own environmental and social impacts and contributes largely to those of concrete.

The cement industry is one of the main producers of carbon dioxide, a greenhouse gas.[2] Concrete causes damage to the most fertile layer of the earth, the topsoil. Concrete is used to create hard surfaces which contribute to surface runoff that may cause soil erosion, water pollution and flooding. Conversely, concrete is one of the most powerful tools for proper flood control, by means of damming, diversion, and deflection of flood waters, mud flows, and the like. Light-colored concrete can reduce the urban heat island effect, due to its higher albedo.[3] However, original vegetation results in even greater benefit. Concrete dust released by building demolition and natural disasters can be a major source of dangerous air pollution. The presence of some substances in concrete, including useful and unwanted additives, can cause health concerns due to toxicity and (usually naturally occurring) radioactivity.[4] Wet concrete is highly alkaline and should always be handled with proper protective equipment. Concrete recycling is increasing in response to improved environmental awareness, legislation, and economic considerations. Conversely, the use of concrete mitigates the use of alternative building materials such as wood, which is a natural form of carbon sequestering.

Concrete dust edit

 
Demolition of the cooling towers of a power station, Athlone, Cape Town, South Africa, 2010

Building demolition and natural disasters such as earthquakes often release a large amount of concrete dust into the local atmosphere. Concrete dust was concluded to be the major source of dangerous air pollution following the Great Hanshin earthquake.[5]

Toxic and radioactive contamination edit

Substantial amount of construction dust emitted and rising up from a building under rehabilitation in Hong Kong.[6][7][8]

The presence of some substances in concrete, including useful and unwanted additives, can cause health concerns. Natural radioactive elements (K, U, Th, and Rn) can be present in various concentration in concrete dwellings, depending on the source of the raw materials used.[9] For example, some stones naturally emit Radon, and Uranium was once common in mine refuse.[10] Toxic substances may also be unintentionally used as the result of contamination from a nuclear accident.[11] Dust from rubble or broken concrete upon demolition or crumbling may cause serious health concerns depending also on what had been incorporated in the concrete. However, embedding harmful materials in concrete is not always dangerous and may in fact be beneficial.[citation needed] In some cases, incorporating certain compounds such as metals in the hydration process of cement immobilizes them in a harmless state and prevents them from being released freely elsewhere.[12]

Carbon dioxide emissions and climate change edit

The cement industry is one of the two largest producers of carbon dioxide (CO2), creating up to 5% of worldwide man-made emissions of this gas, of which 50% is from the chemical process and 40% from burning fuel.[2][13] The CO2 produced for the manufacture of structural concrete (using ~14% cement) is estimated at 410 kg/m3 (~180 kg/tonne @ density of 2.3 g/cm3) (reduced to 290 kg/m3 with 30% fly ash replacement of cement).[14] The CO2 emission from the concrete production is directly proportional to the cement content used in the concrete mix; 900 kg of CO2 are emitted for the fabrication of every ton of cement, accounting for 88% of the emissions associated with the average concrete mix.[15][16] Cement manufacture contributes greenhouse gases both directly through the production of carbon dioxide when calcium carbonate is thermally decomposed, producing lime and carbon dioxide,[17] and also through the use of energy, particularly from the combustion of fossil fuels.

One area of the concrete life cycle worth noting is its very low embodied energy per unit mass. This is primarily because the materials used in concrete construction, such as aggregates, pozzolans, and water, are relatively plentiful and can often be drawn from local sources.[18] This means that transportation only accounts for 7% of the embodied energy of concrete, while cement production accounts for 70%. Concrete has a total embodied energy of 1.69 GJ/tonne, lower per unit mass than most common building materials besides wood. However, concrete structures often have high masses, so this comparison is not always directly relevant to decision making. Additionally, this value is based only on mix proportions of up to 20% fly ash. It is estimated that a 1% replacement of cement with fly ash represents a 0.7% reduction in energy consumption. With some proposed mixes containing as much as 80% fly ash, this could represent a considerable energy saving.[16]

A 2022 report from the Boston Consulting Group found that investments in greener forms of cement would lead to greater greenhouse gas reductions, per dollar, than investments in many other green technologies—though investments in plant-based meat alternatives would reap considerably greater reductions than even this.[19]

Mitigation edit

Design improvements edit

There is a growing interest in reducing carbon emissions related to concrete from both the academic and industrial sectors, especially with the possibility of future carbon tax implementation. Several approaches to reducing emissions have been suggested.

Cement production and use edit

One reason why the carbon emissions are so high is because cement has to be heated to very high temperatures in order for clinker to form. A major culprit of this is alite (Ca3SiO5), a mineral in concrete that cures within hours of pouring and is therefore responsible for much of its initial strength. However, alite also has to be heated to 1,500 °C in the clinker-forming process. Some research suggests that alite can be replaced by a different mineral, such as belite (Ca2SiO4). Belite is also a mineral already used in concrete. It has a roasting temperature of 1,200 °C, which is significantly lower than that of alite. Furthermore, belite is actually stronger once concrete cures. However, belite takes on the order of days or months to set completely, which leaves concrete weak for longer. Current research is focusing on finding possible impurity additives, like magnesium, that might speed up the curing process. It is also worthwhile to consider that belite takes more energy to grind, which may make its full life of impact similar to or even higher than alite.[20]

Another approach has been the partial replacement of conventional clinker with such alternatives as fly ash, bottom ash, and slag, all of which are by-products of other industries that would otherwise end up in landfills. Fly ash and bottom ash come from thermoelectric power plants, while slag is a waste from blast furnaces in the ironworks industry. These materials are slowly gaining popularity as additives, especially since they can potentially increase strength, decrease density, and prolong durability of concrete.[21]

The main obstacle to wider implementation of fly ash and slag may be largely due to the risk of construction with new technology that has not been exposed to long field testing. Until a carbon tax is implemented, companies are unwilling to take the chance with new concrete mix recipes even if this reduces carbon emissions. However, there are some examples of "green" concrete and its implementation. One instance is a concrete company called Ceratech that has started manufacturing concrete with 95% fly ash and 5% liquid additives.[20] Another is the I-35W Saint Anthony Falls Bridge, which was constructed with a novel mixture of concrete that included different compositions of Portland cement, fly ash, and slag depending on the portion of the bridge and its material properties requirements.[22] Several startup companies are developing and testing alternative cement production methods. Sublime of Somerville, Massachusetts uses a no-kiln electrochemical process, and Fortera captures carbon dioxide from conventional plants to make a new kind of cement.[23] Blue Planet of Los Gatos, California captures emitted carbon dioxide to produce synthetic concrete. CarbonCure Technologies of Halifax, Nova Scotia has retrofitted its carbon mineralization systems at hundreds of concrete plants around the world, injecting and permanently storing carbon dioxide in concrete as it is being mixed.[24]

Furthermore, the production of concrete requires large amounts of water, and global production accounts for almost a tenth of worldwide industrial water use.[25] This amounts to 1.7 percent of total global water withdrawal. A study that appeared in Nature Sustainability in 2018 predicts that concrete production will in the future increase pressure on water resources in regions susceptible to drought conditions, writing, "In 2050, 75% of the water demand for concrete production will likely occur in regions that are expected to experience water stress".[26]

Carbon concrete edit

Carbonatation, sometimes called carbonation, is the formation of calcium carbonate (CaCO3) by chemical reaction, which, if used in concrete, can sequester carbon dioxide.[27] The speed of carbonation depends primarily on the porosity of the concrete and its moisture content. Carbonation in concrete pores happens only at a relative humidity (RH) of 40-90%—when RH is higher than 90%, carbon dioxide cannot enter the concrete pores, and when RH is lower than 40%, CO2 cannot be dissolved in water.[28]

 
Pore structures in fresh concrete and air entrained in concrete

Concrete can be carbonated by two main methods: weathering carbonation and early age carbonation.[29]

Weathering carbonation occurs in concrete when calcium compounds react with carbon dioxide ( ) from the atmosphere and water ( ) in the concrete pores. The reaction is as follows. First, through chemical weathering, CO2 reacts with water in the concrete pores to form carbonic acid:

 

Carbonic acid then reacts with calcium hydroxide to form calcium carbonate and water:

 

Once the calcium hydroxide (Ca(OH)2) has sufficiently carbonated, the main component of cement, calcium silicate hydrate gel (C-S-H), can be decalcified, i.e., liberated calcium oxide ( ) can carbonate:

 

Early age carbonation is when CO2 is introduced to the early stages of fresh premix concrete or upon initial curing, which can occur both naturally through exposure or be artificially accelerated by augmenting a direct intake of CO2.[29] Gaseous carbon dioxide is converted to solid carbonates and can be permanently stored in concrete. The reactions of CO2 and calcium silicate hydrate (C-S-H) in cement was described in 1974 in cement chemist notation (CCN) as:[30]

 
 
A Canadian company patented and commercialized a novel technology that uses early age carbonation to sequester CO2. This is achieved by directly injecting recycled liquid carbon dioxide from third-party industrial emitters into the concrete wet-mix stage during the manufacturing process. CO2 is then chemically mineralized, sequestering the greenhouse gas pollutant in concrete infrastructure, buildings, roads, etc. for long periods of time.

In a study published in the Journal of Cleaner Production, the authors created a model showing that sequestered CO2 improved the compressive strength of concrete while reducing CO2 emissions, thus allowing for a cement loading reduction while also having a "4.6% reduction in the carbon footprint".[31]

Another proposed method of capturing emissions is to absorb CO2 in the curing process through the use of an admixture—specifically, a dicalcium silicate in 𝛾 phase—as the concrete cures. The use of fly ash or another suitable substitute could theoretically bring CO2 emissions below 0 kg/m3, compared to Portland cement concrete emissions of 400 kg/m3. The most effective method of production of this concrete would use the exhaust gas of a power plant, where an isolated chamber could control temperature and humidity.[32]

In August 2019, reduced CO2 cement was announced which "reduces the overall carbon footprint in precast concrete by 70%".[33] The base of the cement is primarily wollastonite ( ) and rankinite ( ), in contrast to traditional Portland cement, based on alite ( ) and belite ( ). The patented process of reduced-emissions concrete manufacture begins with the bonding of particles through liquid phase sintering, also referred to as reactive hydrothermal liquid-phase densification (rHLPD).[34] A solution of water and CO2 penetrates the particles, reacting in ambient conditions to form a bond which creates reduced-lime, non-hydraulic calcium silicate cement (CSC). The difference between traditional Portland concrete and these carbonated calcium silicate concrete (CSC-C) lies in the final curing process reaction between a water-CO2 solution and a family of calcium-silicate. According to a study of one reduced-emissions cement, called Solidia, "CSC-C curing is a mildly exothermic reaction in which the low-lime calcium silicates in the CSC react with CO2 in the presence of water to produce calcite (CaCO3) and silica (SiO2) as follows:

 "[35]

However, as early age carbonation methods have gained recognition due to their substantial carbon sequestration proficiencies, some authors have argued that the effect of early-age carbonation curing may succumb to weathering carbonation later on. For example, a 2020 article writes, "Experimental results suggest that early-age carbonated concretes with high w/c ratios (>0.65) are more likely to be affected by weathering carbonation".[36] The article cautions that this may weaken its strength abilities in the corrosion stages during life service.

Italian company Italcementi designed a kind of cement that is supposedly alleviating air pollution by breaking down pollutants that come in contact with the concrete, through the use of titanium dioxide absorbing ultraviolet light. Some environmental experts nevertheless remain skeptical and wonder if the special material can "eat" enough pollutants to make it financially viable. Jubilee Church in Rome is built from this kind of concrete.[37]

Another aspect to consider in carbon concrete is surface scaling due to cold climatic conditions and exposure to de-icing salt and freeze-thaw cycles (frost weathering). Concrete produced by carbonation curing also shows superior performance when subject to physical degradations, e.g., freeze-thaw damage, particularly due to a pore densification effect enabled by the precipitation of carbonation products[38]

The vast majority of CO2 emissions from concrete come from cement manufacturing. Therefore, methods to reduce cement materials in each concrete mix are the only known methods to reduce the emissions.[citation needed]

Photocatalysis to reduce smog edit

Titanium dioxide (TiO2), a semiconductor material shown to exhibit photocatalytic behavior, has been used to remove nitrogen oxides (denoted NOx) from the atmosphere. NOx species, i.e., nitric oxide and nitrogen dioxide, are atmospheric gases that contribute to acid rain and smog formation, both of which are the result of urban pollution. Since NOx formation only occurs at high temperatures, nitrogen oxides are typically produced as a byproduct of hydrocarbon combustion. In addition to contributing to urban pollution events, NOx has been demonstrated to cause a wide variety of adverse health and environmental effects, including triggering respiratory distress, reacting with other atmospheric chemicals to form harmful products such as ozone, nitroarenes, and nitrate radicals, and contributing to the greenhouse effect. The World Health Organization (WHO) has recommended a maximum NOx concentration of 40 μg/m3.[39] One proposed route of decreasing NOx concentrations, especially in urban settings, is to use photocatalytic TiO2 mixed into concrete to oxidize NO and NO2 to form nitrate. In the presence of light, TiO2 generates electrons and holes that allow for NO to oxidize into NO2 and NO2 to then form HNO3 (nitric acid) via a hydroxyl radical attack. The molecule adsorption reactions are given below:

O2 + ⬚ → Oads
H2O + ⬚ → H2Oads
NO + ⬚ → NOads
NO2 + ⬚ → NO2ads

Generation of holes and electrons via TiO2 activation is described below:

TiO2 + → e + h+

Trapping of electron/hole:

h+ + H2Oads → OH· + H+
e + O2ads → O2

Hydroxyl radical attack:

NOads + OH· → HNO2
HNO2 + OH· → NO2ads + H2O
NO2ads + OH· → NO3 + H+

Electron and hole recombination:

e + h+ → heat

Another pathway for the oxidation of nitrogen uses UV irradiation to form NO3.[40]

Embedded solar cells edit

Dye-sensitized solar cells embedded in concrete has been proposed as a method of reducing the carbon and energy footprints of buildings. The usage of embedded solar cells allows for on-site energy generation, which when coupled with batteries, would provide constant power throughout the day. The top layer of the concrete would be a thin layer of dye-sensitized solar cells. Dye-sensitized solar cells are particularly attractive due to its ease of mass production, either via roll-printing or painting, and a reasonably high efficiency of 10%.[41] One example of the commercialization of this concept is the German company Discrete, which produces a dye-sensitized solar cell embedded concrete product. Their process uses a spray-coating method to apply organic dyes that generate electricity onto concrete.[42]

Energy storage edit

Energy storage has become an important consideration for many renewable energy generation methods, especially for popular methods such as solar or wind energy, both of which are intermittent energy producers that require storage for constant use. Currently, 96% of the world’s energy storage comes from pumped hydro, which uses excess generated electricity to pump water up a dam and then allowed to fall and turn turbines that produce electricity when the demand exceeds generation. The problem with pumped hydro, however, is that the setup requires specific geographies that can be difficult to find. A similar concept that uses cement instead of water has been realized by Energy Vault, a Swiss startup. They created a setup that uses an electric crane surrounded by stacks of 35-ton concrete blocks, which can be produced using waste products, to store energy by using excess energy generation to power the crane to lift and stack the concrete blocks. When energy is needed, the blocks are allowed to fall and the rotated motor would send energy back to the grid. The setup would have a storage capacity of 25-80 MWh.[43]

Other improvements edit

There are many other improvements to concrete that do not deal directly with emissions. Recently, much research has gone into "smart" concretes: concretes that use electrical and mechanical signals to respond to changes in loading conditions. One variety uses carbon fiber reinforcement which provides an electrical response that can be used to measure strain. This allows for monitoring the structural integrity of the concrete without installing sensors.[44]

The road construction and maintenance industry consumes tons of carbon-intensive concrete every day to secure road-side and urban infrastructure. As populations grow this infrastructure is becoming increasingly vulnerable to impact from vehicles, creating an ever increasing cycle of damage and waste and ever increasing consumption of concrete for repairs (roadworks are now seen around our cities on almost a daily basis). A major development in the infrastructure industry involves the use of recycled petroleum waste to protect the concrete from damage and enable infrastructure to become dynamic, able to be easily maintained and updated without disturbance to the existing foundations. This simple innovation preserves the foundations for the entire lifespan of a development.

Another area of concrete research involves the creation of certain “waterless” concretes for use in extraplanetary colonization. Most commonly, these concretes use sulfur to act as a non-reactive binder, allowing for construction of concrete structures in environments with no or very little water. These concretes are in many ways indistinguishable from normal hydraulic concrete: they have similar densities, can be used with currently existing metal reinforcement, and they actually gain strength faster than normal concrete[45] This application has yet to be explored on Earth, but with concrete production representing as much as two-thirds of the total energy usage of some developing countries,[18] any improvement is worth considering.

Changes in use edit

Concrete is one of the world's oldest man-made building materials. Over the years, significant environmental limitations have been placed on the creation and use of concrete due to its carbon footprint. Manufacturers responded to these limitations by altering concrete's production processes, and recycling old concrete rubble to use as aggregate in new concrete mixtures to reduce these emissions. Concrete has immersed from natural resources into man-made processes; evidence of the use of concrete dates back over 8,000 years ago. Today, many construction companies and concrete manufacturers have cut the use of Portland cement in their mixtures due to its production process emitting significant amounts of greenhouse gases into the atmosphere.

Alternatives to concrete edit

There are in fact many alternatives to concrete. One being Green concrete that is produced by recycled waste materials from various industries , another being Ashcrete, a material made from a mix of lime and water that acts similar to cement. Black furnace slag is also a strong alternative made from molten iron slag into water, along with Micro Silica, Papercrete, composite cement, and post-consumer glass.[46]

Depending on the amounts required or used overall and the amounts needed, in combination with other materials, for structural stability per building, many other materials also have a substantial negative impact on the environment. For instance, while research and development to reduce these emissions are ongoing, steel accounted for ~8 % of the world's total greenhouse gas emissions as of 2021.[47][48]

Clay edit

 
The Tecla eco-house as of 2021

Mixtures of clay are an alternative construction material to concrete that have a lower environmental footprint. In 2021, the first prototype 3D printed house, Tecla, printed from locally-sourced soil and water as well as fibers from rice husks and a binder was completed.[49][50][51] Such buildings could be very inexpensive, well-insulated, stable and weatherproof, climate-adaptable, customizable, get produced rapidly, require only very little easily-learnable manual labor, require less energy, produce very little waste and reduce carbon emissions from concrete.[citation needed]

Surface runoff edit

Surface runoff, when water runs off impervious surfaces, such as non-porous concrete, can cause severe soil erosion and flooding. Urban runoff tends to pick up gasoline, motor oil, heavy metals, trash and other pollutants from sidewalks, roadways and parking lots.[52][53] Without attenuation, the impervious cover in a typical urban area limits groundwater percolation and causes five times the amount of runoff generated by a typical woodland of the same size.[54] A 2008 report by the United States National Research Council identified urban runoff as a leading source of water quality problems.[55]

In an attempt to counteract the negative effects of impervious concrete, many new paving projects have begun to use pervious concrete, which provides a level of automatic stormwater management. Pervious concrete is created by careful laying of concrete with specifically designed aggregate proportions, which allows for surface runoff to seep through and return to the groundwater. This both prevents flooding and contributes to groundwater replenishment.[56] If designed and layered properly, pervious concrete and other discreetly paved areas can also function as an automatic water filter by preventing certain harmful substances like oils and other chemicals from passing through.[57] Unfortunately there are still downsides to large scale applications of pervious concrete: its reduced strength relative to conventional concrete limits use to low-load areas, and it must be laid properly to reduce susceptibility to freeze-thaw damage and sediment buildup.[56]

Urban heat edit

Both concrete and asphalt are the primary contributors to what is known as the urban heat island effect.[25] According to the United Nations Department of Economic and Social Affairs 55% of the world’s population reside in urban areas and 68% of the world’s population is projected to be urban by 2050; also, "the world is projected to add 230 billion m2 (2.5 trillion ft2) of buildings by 2060, or an area equal to the entire current global building stock. This is the equivalent of adding an entire New York City to the planet every 34 days for the next 40 years".[58] As a result, paved surfaces represent a major concern because of the additional energy consumption and air pollution they cause.[59]

The potential of energy saving within an area is also high. With lower temperatures, the demand for air conditioning theoretically decreases, saving energy. However, research into the interaction between reflective pavements and buildings has found that, unless the nearby buildings are fitted with reflective glass, solar radiation reflected off pavements can increase building temperatures, increasing air conditioning demands.[60]

Moreover, heat transfer from pavements, which cover about one-third of a typical U.S. city,[3] can also influence local temperatures and air quality. Hot surfaces warm the city air through convection, so using materials that absorb less solar energy, such as high-albedo pavements, can reduce the flow of heat into the urban environment and moderate the UHIE.[61] Albedos range from about 0.05 to about 0.35 for currently used pavement material surfaces. Over a typical life service, pavement materials that begin with high albedo tend to lose reflectance, while those with low initial albedo may gain reflectance[62]

The Design Trust for Public Space found that by slightly raising the albedo value in New York City, beneficial effects such as energy savings could be achieved.,[63] by replacement of black asphalt with light-colored concrete. However, in winter this may be a disadvantage as ice will form more easily and remain longer on light colored surfaces as they will be colder due to less energy absorbed from the reduced amount of sunlight in winter.[64]

Another aspect to consider is thermal comfort effect, as well as the need for more mitigation strategies, which don’t threat the health and wellbeing of pedestrians particularly during heat waves.[65] A study that appeared in Building and Environment in 2019 performed experiments to project the impact of heat waves and high albedo materials interactions in the northern Italian city of Milan. By calculating the "Mediterranean Outdoor Comfort Index" (MOCI) in presence of a heat wave, where high albedo materials was used in all surfaces. The study identified a deterioration of the microclimate where high amounts of high albedo materials were located. The use of the high albedo materials was found to "lead to the establishment of multiple inter-reflections and a consequent increase in micrometeorological variables such as average radiant temperatures and air temperatures. To be more detailed, these changes lead to an increase in the MOCI that in the afternoon hours can even reach 0.45 units".[66]

Overall urban configurations should remain of concern when making decisions as people are exposed to weather and thermal confort conditions. The use of high albedo materials within an urban environment can be of positive effect with proper combination of other technologies and strategies such as: vegetation, reflective materials, etc. Urban heat mitigation measures could minimize impacts on microclimate as well as human and wildlife habitats.[67]


Handling precautions edit

Handling of wet concrete must always be done with proper protective equipment. Contact with wet concrete can cause skin chemical burns due to the caustic nature of the mixture of cement and water (including rainwater). Indeed, the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution (pH ~ 13.5). Eyes, hands and feet must be correctly protected to avoid any direct contact with wet concrete and washed without delay if necessary.

Concrete recycling edit

 
Recycled crushed concrete being loaded into a semi-dump truck to be used as granular fill

Concrete recycling is an increasingly common method of disposing of concrete structures. Concrete debris was once routinely shipped to landfills for disposal, but recycling is increasing due to improved environmental awareness, governmental laws and economic benefits.

Concrete, which must be free of trash, wood, paper and other such materials, is collected from demolition sites and put through a crushing machine, often along with asphalt, bricks and rocks.

Reinforced concrete contains rebar and other metallic reinforcements, which are removed with magnets and recycled elsewhere. The remaining aggregate chunks are sorted by size. Larger chunks may go through the crusher again. Smaller pieces of concrete are used as gravel for new construction projects. Aggregate base gravel is laid down as the lowest layer in a road, with fresh concrete or asphalt placed over it. Crushed recycled concrete can sometimes be used as the dry aggregate for brand new concrete if it is free of contaminants, though the use of recycled concrete limits strength and is not allowed in many jurisdictions. On 3 March 1983, a government-funded research team (the VIRL research.codep)[citation needed] approximated that almost 17% of worldwide landfill was by-products of concrete-based waste.

See also edit

References edit

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environmental, impact, concrete, environmental, impact, concrete, manufacture, applications, complex, driven, part, direct, impacts, construction, infrastructure, well, emissions, between, total, global, emissions, come, from, concrete, many, depend, circumsta. The environmental impact of concrete its manufacture and its applications are complex driven in part by direct impacts of construction and infrastructure as well as by CO2 emissions between 4 8 of total global CO2 emissions come from concrete 1 Many depend on circumstances A major component is cement which has its own environmental and social impacts and contributes largely to those of concrete The cement industry is one of the main producers of carbon dioxide a greenhouse gas 2 Concrete causes damage to the most fertile layer of the earth the topsoil Concrete is used to create hard surfaces which contribute to surface runoff that may cause soil erosion water pollution and flooding Conversely concrete is one of the most powerful tools for proper flood control by means of damming diversion and deflection of flood waters mud flows and the like Light colored concrete can reduce the urban heat island effect due to its higher albedo 3 However original vegetation results in even greater benefit Concrete dust released by building demolition and natural disasters can be a major source of dangerous air pollution The presence of some substances in concrete including useful and unwanted additives can cause health concerns due to toxicity and usually naturally occurring radioactivity 4 Wet concrete is highly alkaline and should always be handled with proper protective equipment Concrete recycling is increasing in response to improved environmental awareness legislation and economic considerations Conversely the use of concrete mitigates the use of alternative building materials such as wood which is a natural form of carbon sequestering Contents 1 Concrete dust 2 Toxic and radioactive contamination 3 Carbon dioxide emissions and climate change 4 Mitigation 4 1 Design improvements 4 1 1 Cement production and use 4 1 2 Carbon concrete 4 1 3 Photocatalysis to reduce smog 4 1 4 Embedded solar cells 4 1 5 Energy storage 4 1 6 Other improvements 4 2 Changes in use 4 3 Alternatives to concrete 4 3 1 Clay 5 Surface runoff 6 Urban heat 7 Handling precautions 8 Concrete recycling 9 See also 10 ReferencesConcrete dust editThis section needs expansion You can help by adding to it January 2024 nbsp Demolition of the cooling towers of a power station Athlone Cape Town South Africa 2010 Building demolition and natural disasters such as earthquakes often release a large amount of concrete dust into the local atmosphere Concrete dust was concluded to be the major source of dangerous air pollution following the Great Hanshin earthquake 5 Toxic and radioactive contamination editThis section needs expansion You can help by adding to it January 2024 source source source source source source source source Substantial amount of construction dust emitted and rising up from a building under rehabilitation in Hong Kong 6 7 8 The presence of some substances in concrete including useful and unwanted additives can cause health concerns Natural radioactive elements K U Th and Rn can be present in various concentration in concrete dwellings depending on the source of the raw materials used 9 For example some stones naturally emit Radon and Uranium was once common in mine refuse 10 Toxic substances may also be unintentionally used as the result of contamination from a nuclear accident 11 Dust from rubble or broken concrete upon demolition or crumbling may cause serious health concerns depending also on what had been incorporated in the concrete However embedding harmful materials in concrete is not always dangerous and may in fact be beneficial citation needed In some cases incorporating certain compounds such as metals in the hydration process of cement immobilizes them in a harmless state and prevents them from being released freely elsewhere 12 Carbon dioxide emissions and climate change editThe cement industry is one of the two largest producers of carbon dioxide CO2 creating up to 5 of worldwide man made emissions of this gas of which 50 is from the chemical process and 40 from burning fuel 2 13 The CO2 produced for the manufacture of structural concrete using 14 cement is estimated at 410 kg m3 180 kg tonne density of 2 3 g cm3 reduced to 290 kg m3 with 30 fly ash replacement of cement 14 The CO2 emission from the concrete production is directly proportional to the cement content used in the concrete mix 900 kg of CO2 are emitted for the fabrication of every ton of cement accounting for 88 of the emissions associated with the average concrete mix 15 16 Cement manufacture contributes greenhouse gases both directly through the production of carbon dioxide when calcium carbonate is thermally decomposed producing lime and carbon dioxide 17 and also through the use of energy particularly from the combustion of fossil fuels One area of the concrete life cycle worth noting is its very low embodied energy per unit mass This is primarily because the materials used in concrete construction such as aggregates pozzolans and water are relatively plentiful and can often be drawn from local sources 18 This means that transportation only accounts for 7 of the embodied energy of concrete while cement production accounts for 70 Concrete has a total embodied energy of 1 69 GJ tonne lower per unit mass than most common building materials besides wood However concrete structures often have high masses so this comparison is not always directly relevant to decision making Additionally this value is based only on mix proportions of up to 20 fly ash It is estimated that a 1 replacement of cement with fly ash represents a 0 7 reduction in energy consumption With some proposed mixes containing as much as 80 fly ash this could represent a considerable energy saving 16 A 2022 report from the Boston Consulting Group found that investments in greener forms of cement would lead to greater greenhouse gas reductions per dollar than investments in many other green technologies though investments in plant based meat alternatives would reap considerably greater reductions than even this 19 Mitigation editDesign improvements edit There is a growing interest in reducing carbon emissions related to concrete from both the academic and industrial sectors especially with the possibility of future carbon tax implementation Several approaches to reducing emissions have been suggested Cement production and use edit One reason why the carbon emissions are so high is because cement has to be heated to very high temperatures in order for clinker to form A major culprit of this is alite Ca3SiO5 a mineral in concrete that cures within hours of pouring and is therefore responsible for much of its initial strength However alite also has to be heated to 1 500 C in the clinker forming process Some research suggests that alite can be replaced by a different mineral such as belite Ca2SiO4 Belite is also a mineral already used in concrete It has a roasting temperature of 1 200 C which is significantly lower than that of alite Furthermore belite is actually stronger once concrete cures However belite takes on the order of days or months to set completely which leaves concrete weak for longer Current research is focusing on finding possible impurity additives like magnesium that might speed up the curing process It is also worthwhile to consider that belite takes more energy to grind which may make its full life of impact similar to or even higher than alite 20 Another approach has been the partial replacement of conventional clinker with such alternatives as fly ash bottom ash and slag all of which are by products of other industries that would otherwise end up in landfills Fly ash and bottom ash come from thermoelectric power plants while slag is a waste from blast furnaces in the ironworks industry These materials are slowly gaining popularity as additives especially since they can potentially increase strength decrease density and prolong durability of concrete 21 The main obstacle to wider implementation of fly ash and slag may be largely due to the risk of construction with new technology that has not been exposed to long field testing Until a carbon tax is implemented companies are unwilling to take the chance with new concrete mix recipes even if this reduces carbon emissions However there are some examples of green concrete and its implementation One instance is a concrete company called Ceratech that has started manufacturing concrete with 95 fly ash and 5 liquid additives 20 Another is the I 35W Saint Anthony Falls Bridge which was constructed with a novel mixture of concrete that included different compositions of Portland cement fly ash and slag depending on the portion of the bridge and its material properties requirements 22 Several startup companies are developing and testing alternative cement production methods Sublime of Somerville Massachusetts uses a no kiln electrochemical process and Fortera captures carbon dioxide from conventional plants to make a new kind of cement 23 Blue Planet of Los Gatos California captures emitted carbon dioxide to produce synthetic concrete CarbonCure Technologies of Halifax Nova Scotia has retrofitted its carbon mineralization systems at hundreds of concrete plants around the world injecting and permanently storing carbon dioxide in concrete as it is being mixed 24 Furthermore the production of concrete requires large amounts of water and global production accounts for almost a tenth of worldwide industrial water use 25 This amounts to 1 7 percent of total global water withdrawal A study that appeared in Nature Sustainability in 2018 predicts that concrete production will in the future increase pressure on water resources in regions susceptible to drought conditions writing In 2050 75 of the water demand for concrete production will likely occur in regions that are expected to experience water stress 26 Carbon concrete edit Carbonatation sometimes called carbonation is the formation of calcium carbonate CaCO3 by chemical reaction which if used in concrete can sequester carbon dioxide 27 The speed of carbonation depends primarily on the porosity of the concrete and its moisture content Carbonation in concrete pores happens only at a relative humidity RH of 40 90 when RH is higher than 90 carbon dioxide cannot enter the concrete pores and when RH is lower than 40 CO2 cannot be dissolved in water 28 nbsp Pore structures in fresh concrete and air entrained in concrete Concrete can be carbonated by two main methods weathering carbonation and early age carbonation 29 Weathering carbonation occurs in concrete when calcium compounds react with carbon dioxide CO 2 displaystyle ce CO2 nbsp from the atmosphere and water H 2 O displaystyle ce H2O nbsp in the concrete pores The reaction is as follows First through chemical weathering CO2 reacts with water in the concrete pores to form carbonic acid CO 2 H 2 O H 2 CO 3 displaystyle ce CO2 H2O lt gt H2CO3 nbsp Carbonic acid then reacts with calcium hydroxide to form calcium carbonate and water Ca OH 2 H 2 CO 3 CaCO 3 2 H 2 O displaystyle ce Ca OH 2 H2CO3 lt gt CaCO3 2H2O nbsp Once the calcium hydroxide Ca OH 2 has sufficiently carbonated the main component of cement calcium silicate hydrate gel C S H can be decalcified i e liberated calcium oxide CaO displaystyle ce CaO nbsp can carbonate H 2 CO 3 CaO CaCO 3 H 2 O displaystyle ce H2CO3 CaO lt gt CaCO3 H2O nbsp Early age carbonation is when CO2 is introduced to the early stages of fresh premix concrete or upon initial curing which can occur both naturally through exposure or be artificially accelerated by augmenting a direct intake of CO2 29 Gaseous carbon dioxide is converted to solid carbonates and can be permanently stored in concrete The reactions of CO2 and calcium silicate hydrate C S H in cement was described in 1974 in cement chemist notation CCN as 30 C 3 S 3 CO 2 H 2 O CSH 3 CaCO 3 347 kJ mol displaystyle ce C3S 3CO2 H2O gt CSH 3CaCO3 347 kJ mol nbsp C 2 S 2 CO 2 H 2 O CSH 2 CaCO 3 184 kJ mol displaystyle ce C2S 2CO2 H2O gt CSH 2CaCO3 184 kJ mol nbsp A Canadian company patented and commercialized a novel technology that uses early age carbonation to sequester CO2 This is achieved by directly injecting recycled liquid carbon dioxide from third party industrial emitters into the concrete wet mix stage during the manufacturing process CO2 is then chemically mineralized sequestering the greenhouse gas pollutant in concrete infrastructure buildings roads etc for long periods of time In a study published in the Journal of Cleaner Production the authors created a model showing that sequestered CO2 improved the compressive strength of concrete while reducing CO2 emissions thus allowing for a cement loading reduction while also having a 4 6 reduction in the carbon footprint 31 Another proposed method of capturing emissions is to absorb CO2 in the curing process through the use of an admixture specifically a dicalcium silicate in 𝛾 phase as the concrete cures The use of fly ash or another suitable substitute could theoretically bring CO2 emissions below 0 kg m3 compared to Portland cement concrete emissions of 400 kg m3 The most effective method of production of this concrete would use the exhaust gas of a power plant where an isolated chamber could control temperature and humidity 32 In August 2019 reduced CO2 cement was announced which reduces the overall carbon footprint in precast concrete by 70 33 The base of the cement is primarily wollastonite CaSiO 3 displaystyle ce CaSiO3 nbsp and rankinite 3 CaO 2 SiO 2 displaystyle ce 3CaO 2SiO2 nbsp in contrast to traditional Portland cement based on alite 3 CaO SiO 2 displaystyle ce 3CaO SiO2 nbsp and belite 2 CaO SiO 2 displaystyle ce 2CaO SiO2 nbsp The patented process of reduced emissions concrete manufacture begins with the bonding of particles through liquid phase sintering also referred to as reactive hydrothermal liquid phase densification rHLPD 34 A solution of water and CO2 penetrates the particles reacting in ambient conditions to form a bond which creates reduced lime non hydraulic calcium silicate cement CSC The difference between traditional Portland concrete and these carbonated calcium silicate concrete CSC C lies in the final curing process reaction between a water CO2 solution and a family of calcium silicate According to a study of one reduced emissions cement called Solidia CSC C curing is a mildly exothermic reaction in which the low lime calcium silicates in the CSC react with CO2 in the presence of water to produce calcite CaCO3 and silica SiO2 as follows CaSiO 3 CO 2 CaCO 3 SiO 2 displaystyle ce CaSiO3 CO2 gt CaCO3 SiO2 nbsp 35 However as early age carbonation methods have gained recognition due to their substantial carbon sequestration proficiencies some authors have argued that the effect of early age carbonation curing may succumb to weathering carbonation later on For example a 2020 article writes Experimental results suggest that early age carbonated concretes with high w c ratios gt 0 65 are more likely to be affected by weathering carbonation 36 The article cautions that this may weaken its strength abilities in the corrosion stages during life service Italian company Italcementi designed a kind of cement that is supposedly alleviating air pollution by breaking down pollutants that come in contact with the concrete through the use of titanium dioxide absorbing ultraviolet light Some environmental experts nevertheless remain skeptical and wonder if the special material can eat enough pollutants to make it financially viable Jubilee Church in Rome is built from this kind of concrete 37 Another aspect to consider in carbon concrete is surface scaling due to cold climatic conditions and exposure to de icing salt and freeze thaw cycles frost weathering Concrete produced by carbonation curing also shows superior performance when subject to physical degradations e g freeze thaw damage particularly due to a pore densification effect enabled by the precipitation of carbonation products 38 The vast majority of CO2 emissions from concrete come from cement manufacturing Therefore methods to reduce cement materials in each concrete mix are the only known methods to reduce the emissions citation needed Photocatalysis to reduce smog edit Titanium dioxide TiO2 a semiconductor material shown to exhibit photocatalytic behavior has been used to remove nitrogen oxides denoted NOx from the atmosphere NOx species i e nitric oxide and nitrogen dioxide are atmospheric gases that contribute to acid rain and smog formation both of which are the result of urban pollution Since NOx formation only occurs at high temperatures nitrogen oxides are typically produced as a byproduct of hydrocarbon combustion In addition to contributing to urban pollution events NOx has been demonstrated to cause a wide variety of adverse health and environmental effects including triggering respiratory distress reacting with other atmospheric chemicals to form harmful products such as ozone nitroarenes and nitrate radicals and contributing to the greenhouse effect The World Health Organization WHO has recommended a maximum NOx concentration of 40 mg m3 39 One proposed route of decreasing NOx concentrations especially in urban settings is to use photocatalytic TiO2 mixed into concrete to oxidize NO and NO2 to form nitrate In the presence of light TiO2 generates electrons and holes that allow for NO to oxidize into NO2 and NO2 to then form HNO3 nitric acid via a hydroxyl radical attack The molecule adsorption reactions are given below O2 Oads H2O H2Oads NO NOads NO2 NO2ads dd dd Generation of holes and electrons via TiO2 activation is described below TiO2 hn e h dd dd Trapping of electron hole h H2Oads OH H e O2ads O2 dd dd Hydroxyl radical attack NOads OH HNO2 HNO2 OH NO2ads H2O NO2ads OH NO3 H dd dd Electron and hole recombination e h heat dd dd Another pathway for the oxidation of nitrogen uses UV irradiation to form NO3 40 Embedded solar cells edit Dye sensitized solar cells embedded in concrete has been proposed as a method of reducing the carbon and energy footprints of buildings The usage of embedded solar cells allows for on site energy generation which when coupled with batteries would provide constant power throughout the day The top layer of the concrete would be a thin layer of dye sensitized solar cells Dye sensitized solar cells are particularly attractive due to its ease of mass production either via roll printing or painting and a reasonably high efficiency of 10 41 One example of the commercialization of this concept is the German company Discrete which produces a dye sensitized solar cell embedded concrete product Their process uses a spray coating method to apply organic dyes that generate electricity onto concrete 42 Energy storage edit Energy storage has become an important consideration for many renewable energy generation methods especially for popular methods such as solar or wind energy both of which are intermittent energy producers that require storage for constant use Currently 96 of the world s energy storage comes from pumped hydro which uses excess generated electricity to pump water up a dam and then allowed to fall and turn turbines that produce electricity when the demand exceeds generation The problem with pumped hydro however is that the setup requires specific geographies that can be difficult to find A similar concept that uses cement instead of water has been realized by Energy Vault a Swiss startup They created a setup that uses an electric crane surrounded by stacks of 35 ton concrete blocks which can be produced using waste products to store energy by using excess energy generation to power the crane to lift and stack the concrete blocks When energy is needed the blocks are allowed to fall and the rotated motor would send energy back to the grid The setup would have a storage capacity of 25 80 MWh 43 Other improvements edit There are many other improvements to concrete that do not deal directly with emissions Recently much research has gone into smart concretes concretes that use electrical and mechanical signals to respond to changes in loading conditions One variety uses carbon fiber reinforcement which provides an electrical response that can be used to measure strain This allows for monitoring the structural integrity of the concrete without installing sensors 44 The road construction and maintenance industry consumes tons of carbon intensive concrete every day to secure road side and urban infrastructure As populations grow this infrastructure is becoming increasingly vulnerable to impact from vehicles creating an ever increasing cycle of damage and waste and ever increasing consumption of concrete for repairs roadworks are now seen around our cities on almost a daily basis A major development in the infrastructure industry involves the use of recycled petroleum waste to protect the concrete from damage and enable infrastructure to become dynamic able to be easily maintained and updated without disturbance to the existing foundations This simple innovation preserves the foundations for the entire lifespan of a development Another area of concrete research involves the creation of certain waterless concretes for use in extraplanetary colonization Most commonly these concretes use sulfur to act as a non reactive binder allowing for construction of concrete structures in environments with no or very little water These concretes are in many ways indistinguishable from normal hydraulic concrete they have similar densities can be used with currently existing metal reinforcement and they actually gain strength faster than normal concrete 45 This application has yet to be explored on Earth but with concrete production representing as much as two thirds of the total energy usage of some developing countries 18 any improvement is worth considering Changes in use edit This section is empty You can help by adding to it May 2021 Concrete is one of the world s oldest man made building materials Over the years significant environmental limitations have been placed on the creation and use of concrete due to its carbon footprint Manufacturers responded to these limitations by altering concrete s production processes and recycling old concrete rubble to use as aggregate in new concrete mixtures to reduce these emissions Concrete has immersed from natural resources into man made processes evidence of the use of concrete dates back over 8 000 years ago Today many construction companies and concrete manufacturers have cut the use of Portland cement in their mixtures due to its production process emitting significant amounts of greenhouse gases into the atmosphere See also Infrastructure and Road surface Alternatives to concrete edit See also Thermal insulation and Structural engineering Materials This section needs expansion You can help by adding to it May 2021 There are in fact many alternatives to concrete One being Green concrete that is produced by recycled waste materials from various industries another being Ashcrete a material made from a mix of lime and water that acts similar to cement Black furnace slag is also a strong alternative made from molten iron slag into water along with Micro Silica Papercrete composite cement and post consumer glass 46 Depending on the amounts required or used overall and the amounts needed in combination with other materials for structural stability per building many other materials also have a substantial negative impact on the environment For instance while research and development to reduce these emissions are ongoing steel accounted for 8 of the world s total greenhouse gas emissions as of 2021 47 48 Clay edit nbsp source source source source source source source source The Tecla eco house as of 2021 Mixtures of clay are an alternative construction material to concrete that have a lower environmental footprint In 2021 the first prototype 3D printed house Tecla printed from locally sourced soil and water as well as fibers from rice husks and a binder was completed 49 50 51 Such buildings could be very inexpensive well insulated stable and weatherproof climate adaptable customizable get produced rapidly require only very little easily learnable manual labor require less energy produce very little waste and reduce carbon emissions from concrete citation needed Surface runoff editSurface runoff when water runs off impervious surfaces such as non porous concrete can cause severe soil erosion and flooding Urban runoff tends to pick up gasoline motor oil heavy metals trash and other pollutants from sidewalks roadways and parking lots 52 53 Without attenuation the impervious cover in a typical urban area limits groundwater percolation and causes five times the amount of runoff generated by a typical woodland of the same size 54 A 2008 report by the United States National Research Council identified urban runoff as a leading source of water quality problems 55 In an attempt to counteract the negative effects of impervious concrete many new paving projects have begun to use pervious concrete which provides a level of automatic stormwater management Pervious concrete is created by careful laying of concrete with specifically designed aggregate proportions which allows for surface runoff to seep through and return to the groundwater This both prevents flooding and contributes to groundwater replenishment 56 If designed and layered properly pervious concrete and other discreetly paved areas can also function as an automatic water filter by preventing certain harmful substances like oils and other chemicals from passing through 57 Unfortunately there are still downsides to large scale applications of pervious concrete its reduced strength relative to conventional concrete limits use to low load areas and it must be laid properly to reduce susceptibility to freeze thaw damage and sediment buildup 56 Urban heat editBoth concrete and asphalt are the primary contributors to what is known as the urban heat island effect 25 According to the United Nations Department of Economic and Social Affairs 55 of the world s population reside in urban areas and 68 of the world s population is projected to be urban by 2050 also the world is projected to add 230 billion m2 2 5 trillion ft2 of buildings by 2060 or an area equal to the entire current global building stock This is the equivalent of adding an entire New York City to the planet every 34 days for the next 40 years 58 As a result paved surfaces represent a major concern because of the additional energy consumption and air pollution they cause 59 The potential of energy saving within an area is also high With lower temperatures the demand for air conditioning theoretically decreases saving energy However research into the interaction between reflective pavements and buildings has found that unless the nearby buildings are fitted with reflective glass solar radiation reflected off pavements can increase building temperatures increasing air conditioning demands 60 Moreover heat transfer from pavements which cover about one third of a typical U S city 3 can also influence local temperatures and air quality Hot surfaces warm the city air through convection so using materials that absorb less solar energy such as high albedo pavements can reduce the flow of heat into the urban environment and moderate the UHIE 61 Albedos range from about 0 05 to about 0 35 for currently used pavement material surfaces Over a typical life service pavement materials that begin with high albedo tend to lose reflectance while those with low initial albedo may gain reflectance 62 The Design Trust for Public Space found that by slightly raising the albedo value in New York City beneficial effects such as energy savings could be achieved 63 by replacement of black asphalt with light colored concrete However in winter this may be a disadvantage as ice will form more easily and remain longer on light colored surfaces as they will be colder due to less energy absorbed from the reduced amount of sunlight in winter 64 Another aspect to consider is thermal comfort effect as well as the need for more mitigation strategies which don t threat the health and wellbeing of pedestrians particularly during heat waves 65 A study that appeared in Building and Environment in 2019 performed experiments to project the impact of heat waves and high albedo materials interactions in the northern Italian city of Milan By calculating the Mediterranean Outdoor Comfort Index MOCI in presence of a heat wave where high albedo materials was used in all surfaces The study identified a deterioration of the microclimate where high amounts of high albedo materials were located The use of the high albedo materials was found to lead to the establishment of multiple inter reflections and a consequent increase in micrometeorological variables such as average radiant temperatures and air temperatures To be more detailed these changes lead to an increase in the MOCI that in the afternoon hours can even reach 0 45 units 66 Overall urban configurations should remain of concern when making decisions as people are exposed to weather and thermal confort conditions The use of high albedo materials within an urban environment can be of positive effect with proper combination of other technologies and strategies such as vegetation reflective materials etc Urban heat mitigation measures could minimize impacts on microclimate as well as human and wildlife habitats 67 Handling precautions editFurther information on safety issues associated with cement Cement Safety issues Handling of wet concrete must always be done with proper protective equipment Contact with wet concrete can cause skin chemical burns due to the caustic nature of the mixture of cement and water including rainwater Indeed the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution pH 13 5 Eyes hands and feet must be correctly protected to avoid any direct contact with wet concrete and washed without delay if necessary Concrete recycling editMain article Concrete recycling nbsp Recycled crushed concrete being loaded into a semi dump truck to be used as granular fill Concrete recycling is an increasingly common method of disposing of concrete structures Concrete debris was once routinely shipped to landfills for disposal but recycling is increasing due to improved environmental awareness governmental laws and economic benefits Concrete which must be free of trash wood paper and other such materials is collected from demolition sites and put through a crushing machine often along with asphalt bricks and rocks Reinforced concrete contains rebar and other metallic reinforcements which are removed with magnets and recycled elsewhere The remaining aggregate chunks are sorted by size Larger chunks may go through the crusher again Smaller pieces of concrete are used as gravel for new construction projects Aggregate base gravel is laid down as the lowest layer in a road with fresh concrete or asphalt placed over it Crushed recycled concrete can sometimes be used as the dry aggregate for brand new concrete if it is free of contaminants though the use of recycled concrete limits strength and is not allowed in many jurisdictions On 3 March 1983 a government funded research team the VIRL research codep citation needed approximated that almost 17 of worldwide landfill was by products of concrete based waste See also editLongship a CCS project storing CO2 emissions from a cement factory Greenhouse gas emissions Buildings and constructionReferences edit Concrete the most destructive material on Earth the Guardian 25 February 2019 Retrieved 13 July 2022 a b The Cement Sustainability Initiative Our agenda for action World Business Council for Sustainable Development page 20 published 1 June 2002 a b Cool Pavement Report PDF Environmental Protection Agency June 2005 Retrieved 6 February 2009 CDC 7 December 2015 Radiation from Building Materials Centers for Disease Control and Prevention Retrieved 25 February 2019 Yamamoto Ryoji Nobuhiko Nagai Koizumi Naoko Ninomiya Ruriko 1999 Dust concentration around the sites of demolition work after the Great Hanshin Awaji Earthquake Environmental Health and Preventive Medicine 3 4 207 214 Bibcode 1999EHPM 3 207Y doi 10 1007 BF02932260 PMC 2723556 PMID 21432527 Integrated Building Rehabilitation Assistance Scheme Operation Building Bright 2 0 Hong Kong watchdog arrests 49 suspects in housing renovation scam involving contracts worth HK 500 million 6 January 2023 Gavela Stamatia Papadakos Georgios 20 November 2023 Activity Concentration Index Values for Concrete Multistory Residences in Greece Due to Fly Ash Addition in Cement Eng 4 4 2926 2940 doi 10 3390 eng4040164 ISSN 2673 4117 Ademola J A Oguneletu P O 2005 Radionuclide content of concrete building blocks and radiation dose rates in some dwellings in Ibadan Nigeria Journal of Environmental Radioactivity 81 1 107 113 doi 10 1016 j jenvrad 2004 12 002 PMID 15748664 Fujita Akiko 16 January 2012 Radioactive Concrete is Latest Scare for Fukushima Survivors P K Mehta Concrete technology for sustainable development overview of essential elements O E Gjorv K Sakai Eds Concrete technology for a sustainable development in the 21st century E amp FN Spon London 2000 pp 83 94 Lehne Johanna Preston Felix June 2018 Making Concrete Change Innovation in Low Carbon Cement and Concrete PDF Chatham House Report ISBN 9781784132729 Retrieved 17 April 2021 a href Template Cite book html title Template Cite book cite book a website ignored help A Samarin 7 September 1999 Wastes in Concrete Converting Liabilities into Assets in Ravindra K Dhir Trevor G Jappy eds Exploiting wastes in concrete proceedings of the international seminar held at the University of Dundee Scotland UK Thomas Telford p 8 ISBN 9780727728210 Mahasenan Natesan Steve Smith Kenneth Humphreys Y Kaya 2003 The Cement Industry and Global Climate Change Current and Potential Future Cement Industry CO2 Emissions Greenhouse Gas Control Technologies 6th International Conference Oxford Pergamon pp 995 1000 doi 10 1016 B978 008044276 1 50157 4 ISBN 978 0 08 044276 1 a b Nisbet Michael A Marceau Medgar L VanGeem Martha G 2002 Environmental Life Cycle Inventory of Portland Cement Concrete PDF National Ready Mixed Concrete Association PCA R amp D Serial No 2137a Portland Cement Association Archived from the original PDF on 16 May 2017 Retrieved 17 April 2021 EIA Emissions of Greenhouse Gases in the U S 2006 Carbon Dioxide Emissions Archived 2011 05 23 at the Wayback Machine a b Building Green 1993 Cement and Concrete Environmental Considerations Retrieved 2 November 2015 http www wbcsdcement org pdf tf2 cementconc pdf Carrington Damian 7 July 2022 Plant based meat by far the best climate investment report finds The Guardian Retrieved 10 July 2022 a b Amato Ivan 2013 Green cement Concrete solutions Nature 494 7437 300 301 Bibcode 2013Natur 494 300A doi 10 1038 494300a PMID 23426307 Kim H Lee H 2013 Effects of High Volumes of Fly Ash Blast Furnace Slag and Bottom Ash on Flow Characteristics Density and Compressive Strength of High Strength Mortar J Mater Civ Eng 25 5 662 665 doi 10 1061 asce mt 1943 5533 0000624 Fountain Henry 30 March 2009 Concrete Is Remixed With Environment in Mind The New York Times Retrieved 26 May 2013 O Malley Isabella 11 April 2024 Making cement is very damaging for the climate One solution is opening in California Yahoo Tech Retrieved 11 April 2024 David Abel 14 June 2023 The high stakes race to reduce emissions from cement The Boston Globe a b Watts Jonathan 25 February 2019 Concrete the most destructive material on Earth The Guardian ISSN 0261 3077 Retrieved 25 February 2019 Miller Sabbie A Horvath Arpad Monteiro Paulo J M January 2018 Impacts of booming concrete production on water resources worldwide Nature Sustainability 1 1 69 76 Bibcode 2018NatSu 1 69M doi 10 1038 s41893 017 0009 5 ISSN 2398 9629 S2CID 134065012 Ahmad Shamsad May 2003 Reinforcement corrosion in concrete structures its monitoring and service life prediction a review Cement and Concrete Composites 25 4 5 459 471 doi 10 1016 S0958 9465 02 00086 0 Non destructive evaluation of reinforced concrete structures Volume 1 Deterioration processes and standard test methods CRC Press 2010 pp 28 56 ISBN 9781845699536 a b Aggarwal Paratibha Aggarwal Yogesh 2020 7 Carbonation and corrosion of SCC Self Compacting Concrete Materials Properties and Applications Woodhead Publishing pp 147 193 doi 10 1016 B978 0 12 817369 5 00007 6 ISBN 978 0 12 817369 5 S2CID 214275549 Young J F Berger R L Breese J 1974 Accelerated Curing of Compacted Calcium Silicate Mortars on Exposure to CO2 Journal of the American Ceramic Society 57 9 394 397 doi 10 1111 j 1151 2916 1974 tb11420 x ISSN 1551 2916 Monkman Sean MacDonald Mark November 2017 On carbon dioxide utilization as a means to improve the sustainability of ready mixed concrete Journal of Cleaner Production 167 365 375 doi 10 1016 j jclepro 2017 08 194 Higuchi Takayuki 30 September 2014 Development of a new ecological concrete with CO2 emissions below zero Construction and Building Materials 67 338 343 doi 10 1016 j conbuildmat 2014 01 029 Alter Lloyd 15 August 2019 LafargeHolcim is selling CO2 sucking cement for precast reduces emissions by 70 percent TreeHugger Retrieved 17 August 2019 Vakifahmetoglu Cekdar Anger Jean Francois Atakan Vahit Quinn Sean Gupta Surojit Li Qinghua Tang Ling Riman Richard E 2016 Reactive Hydrothermal Liquid Phase Densification rHLPD of Ceramics A Study of the BaTiO3 TiO2 Composite System Journal of the American Ceramic Society 99 12 3893 3901 doi 10 1111 jace 14468 ISSN 1551 2916 Meyer Vincent DeCristofaro Nick Bryant Jason Sahu Sada June 2017 Solidia Cement an Example of Carbon Capture and Utilization PDF 6th International Conference on Non Traditional Cement and Concrete Brno Czech Republic via SOLID Life Project Zhang Duo Liu Tianlu Shao Yixin April 2020 Weathering Carbonation Behavior of Concrete Subject to Early Age Carbonation Curing Journal of Materials in Civil Engineering 32 4 04020038 doi 10 1061 ASCE MT 1943 5533 0003087 S2CID 214499382 ABC News Breaking News Latest News and Videos ABC News Archived from the original on 5 December 2022 Zhang Duo Shao Yixin 1 October 2018 Surface scaling of CO2 cured concrete exposed to freeze thaw cycles Journal of CO2 Utilization 27 137 144 doi 10 1016 j jcou 2018 07 012 ISSN 2212 9820 S2CID 139677418 Chen Haihan Nanayakkara Charith E Grassian Vicki H 14 November 2012 Titanium Dioxide Photocatalysis in Atmospheric Chemistry Chemical Reviews 112 11 5919 5948 doi 10 1021 cr3002092 ISSN 0009 2665 PMID 23088691 Ballari M M Yu Q L Brouwers H J H 17 March 2011 Experimental study of the NO and NO2 degradation by photocatalytically active concrete Selected Contributions of the 6th European Meeting on Solar Chemistry and Photocatalysis Environmental Applications SPEA 6 13th to 16th June 2010 161 1 175 180 doi 10 1016 j cattod 2010 09 028 hdl 11336 13551 ISSN 0920 5861 Hosseini T Flores Vivian I Sobolev K Kouklin N 25 September 2013 Concrete Embedded Dye Synthesized Photovoltaic Solar Cell Scientific Reports 3 1 2727 Bibcode 2013NatSR 3E2727H doi 10 1038 srep02727 ISSN 2045 2322 PMC 3782884 PMID 24067664 Dyscrete Heike Klussmann Rathi Akshat 18 August 2018 Stacking concrete blocks is a surprisingly efficient way to store energy Quartz Chen Pu Woei Chung D D L 1996 Carbon Fiber Reinforced Concrete as an Intrinsically Smart Concrete for Damage Assessment during Static and Dynamic Loading PDF ACI Materials Journal Archived PDF from the original on 28 August 2017 Retrieved 17 April 2021 PRODUCTION OF LUNAR CONCRETE USING MOLTEN SULFUR Final Research Report for JoVe NASA Grant NAG8 278 by Dr Husam A Omar Eco Friendly Alternatives to Traditional Concrete Specify Concrete Retrieved 9 November 2021 One order of steel hold the greenhouse gases MIT News Massachusetts Institute of Technology 8 May 2013 Retrieved 27 May 2021 Germany Ready to Spend 6 Billion to Clean Up Steel Production Bloomberg 3 May 2021 Retrieved 27 May 2021 Palumbo Jacqui 12 April 2021 Is This 3D Printed Home Made of Clay the Future of Housing CNN Retrieved 9 May 2021 First 3D printed clay house completed WLNS 6 News 14 April 2021 Retrieved 9 May 2021 Mario Cucinella Architects and WASP creates 3D printed sustainable housing prototype Dezeen 23 April 2021 Retrieved 9 May 2021 Water Environment Federation Alexandria VA and American Society of Civil Engineers Reston VA Urban Runoff Quality Management WEF Manual of Practice No 23 ASCE Manual and Report on Engineering Practice No 87 1998 ISBN 978 1 57278 039 2 Chapter 1 G Allen Burton Jr Robert Pitt 2001 Stormwater Effects Handbook A Toolbox for Watershed Managers Scientists and Engineers New York CRC Lewis Publishers ISBN 978 0 87371 924 7 Archived from the original on 19 May 2009 Retrieved 12 January 2012 Chapter 2 U S Environmental Protection Agency EPA Washington DC Protecting Water Quality from Urban Runoff Document No EPA 841 F 03 003 February 2003 United States National Research Council Washington DC Urban Stormwater Management in the United States 15 October 2008 pp 18 20 a b Pervious Concrete Pavement US EPA 6 August 2014 Atlanta Is Home To Largest Permeable Pavers Project In US news wabe org 2 November 2015 Retrieved 3 November 2015 United Nations 2019 World urbanization prospects the 2018 revision ISBN 978 92 1 148319 2 Akbari Hashem Cartalis Constantinos Kolokotsa Denia Muscio Alberto Pisello Anna Laura Rossi Federico Santamouris Matheos Synnef Afroditi WONG Nyuk Hien Zinzi Michele 18 December 2015 Local Climate Change and Urban Heat Island Mitigation Techniques the State of the Art Journal of Civil Engineering and Management 22 1 1 16 doi 10 3846 13923730 2015 1111934 hdl 11380 1118712 Yaghoobian N Kleissl J 2012 Effect of reflective pavements on building energy use Urban Climate 2 25 42 Bibcode 2012UrbCl 2 25Y doi 10 1016 j uclim 2012 09 002 Pomerantz Melvin 1 June 2018 Are cooler surfaces a cost effect mitigation of urban heat islands Urban Climate 24 393 397 Bibcode 2018UrbCl 24 393P doi 10 1016 j uclim 2017 04 009 ISSN 2212 0955 OSTI 1377539 S2CID 36792486 Gilbert Haley E Rosado Pablo J Ban Weiss George Harvey John T Li Hui Mandel Benjamin H Millstein Dev Mohegh Arash Saboori Arash Levinson Ronnen M 15 December 2017 Energy and environmental consequences of a cool pavement campaign Energy and Buildings 157 53 77 Bibcode 2017EneBu 157 53G doi 10 1016 j enbuild 2017 03 051 ISSN 0378 7788 OSTI 1571936 S2CID 31272343 Sabnis Gajanan M 2015 Green Building with Concrete Sustainable Design and Construction Second Edition CRC Press p 12 ISBN 978 1 4987 0411 3 Steffen Alex April 2011 Worldchanging a user s guide for the 21st century Revised amp updated ed Harry N Abrams ISBN 978 0810997462 Bloch Sam Will L A s Cool Pavements Make Pedestrians Too Hot CityLab Falasca Serena Ciancio Virgilio Salata Ferdinando Golasi Iacopo Rosso Federica Curci Gabriele October 2019 High albedo materials to counteract heat waves in cities An assessment of meteorology buildings energy needs and pedestrian thermal comfort Building and Environment 163 106242 Bibcode 2019BuEnv 16306242F doi 10 1016 j buildenv 2019 106242 S2CID 198482404 Hulley M E 1 January 2012 5 The urban heat island effect causes and potential solutions Metropolitan Sustainability Woodhead Publishing Series in Energy Woodhead Publishing 79 98 doi 10 1533 9780857096463 1 79 ISBN 9780857090461 Retrieved from https en wikipedia org w index php title Environmental impact of concrete amp oldid 1219682601, wikipedia, wiki, book, books, library,

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