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Enriched uranium

Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written 235U) has been increased through the process of isotope separation. Naturally-occurring uranium is composed of three major isotopes: uranium-238 (238U with 99.2739–99.2752% natural abundance), uranium-235 (235U, 0.7198–0.7202%), and uranium-234 (234U, 0.0050–0.0059%).[citation needed] 235U is the only nuclide existing in nature (in any appreciable amount) that is fissile with thermal neutrons.[1]

Proportions of uranium-238 (blue) and uranium-235 (red) found naturally versus enriched grades

Enriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons. The International Atomic Energy Agency attempts to monitor and control enriched uranium supplies and processes in its efforts to ensure nuclear power generation safety and curb nuclear weapons proliferation.

There are about 2,000 tonnes of highly enriched uranium in the world,[2] produced mostly for nuclear power, nuclear weapons, naval propulsion, and smaller quantities for research reactors.

The 238U remaining after enrichment is known as depleted uranium (DU), and is considerably less radioactive than even natural uranium, though still very dense. Depleted uranium is used as a radiation shielding material and for armor-penetrating weapons.

Grades edit

Uranium as it is taken directly from the Earth is not suitable as fuel for most nuclear reactors and requires additional processes to make it usable (CANDU design is a notable exception). Uranium is mined either underground or in an open pit depending on the depth at which it is found. After the uranium ore is mined, it must go through a milling process to extract the uranium from the ore.

This is accomplished by a combination of chemical processes with the end product being concentrated uranium oxide, which is known as "yellowcake", contains roughly 80% uranium whereas the original ore typically contains as little as 0.1% uranium.[3]

After the milling process is complete, the uranium must next undergo a process of conversion, "to either uranium dioxide, which can be used as the fuel for those types of reactors that do not require enriched uranium, or into uranium hexafluoride, which can be enriched to produce fuel for the majority of types of reactors".[4] Naturally-occurring uranium is made of a mixture of 235U and 238U. The 235U is fissile, meaning it is easily split with neutrons while the remainder is 238U, but in nature, more than 99% of the extracted ore is 238U. Most nuclear reactors require enriched uranium, which is uranium with higher concentrations of 235U ranging between 3.5% and 4.5% (although a few reactor designs using a graphite or heavy water moderator, such as the RBMK and CANDU, are capable of operating with natural uranium as fuel). There are two commercial enrichment processes: gaseous diffusion and gas centrifugation. Both enrichment processes involve the use of uranium hexafluoride and produce enriched uranium oxide.

 
A drum of yellowcake (a mixture of uranium precipitates)

Reprocessed uranium (RepU) edit

Reprocessed uranium (RepU) is a product of nuclear fuel cycles involving nuclear reprocessing of spent fuel. RepU recovered from light water reactor (LWR) spent fuel typically contains slightly more 235U than natural uranium, and therefore could be used to fuel reactors that customarily use natural uranium as fuel, such as CANDU reactors. It also contains the undesirable isotope uranium-236, which undergoes neutron capture, wasting neutrons (and requiring higher 235U enrichment) and creating neptunium-237, which would be one of the more mobile and troublesome radionuclides in deep geological repository disposal of nuclear waste.

Low-enriched uranium (LEU) edit

Low-enriched uranium (LEU) has a lower than 20% concentration of 235U; for instance, in commercial LWR, the most prevalent power reactors in the world, uranium is enriched to 3 to 5% 235U. Slightly enriched uranium (SEU) has a concentration of under 2% 235U.[5]

High-assay LEU (HALEU) is enriched between 5% and 20%.[6] Fresh LEU used in research reactors is usually enriched between 12% and 19.75% 235U; the latter concentration is used to replace HEU fuels when converting to LEU.[7]

Highly enriched uranium (HEU) edit

 
A billet of highly enriched uranium metal

Highly enriched uranium (HEU) has a 20% or higher concentration of 235U. The fissile uranium in nuclear weapon primaries usually contains 85% or more of 235U known as weapons grade, though theoretically for an implosion design, a minimum of 20% could be sufficient (called weapon-usable) although it would require hundreds of kilograms of material and "would not be practical to design";[8][9] even lower enrichment is hypothetically possible, but as the enrichment percentage decreases the critical mass for unmoderated fast neutrons rapidly increases, with for example, an infinite mass of 5.4% 235U being required.[8] For criticality experiments, enrichment of uranium to over 97% has been accomplished.[10]

The very first uranium bomb, Little Boy, dropped by the United States on Hiroshima in 1945, used 64 kilograms (141 lb) of 80% enriched uranium. Wrapping the weapon's fissile core in a neutron reflector (which is standard on all nuclear explosives) can dramatically reduce the critical mass. Because the core was surrounded by a good neutron reflector, at explosion it comprised almost 2.5 critical masses. Neutron reflectors, compressing the fissile core via implosion, fusion boosting, and "tamping", which slows the expansion of the fissioning core with inertia, allow nuclear weapon designs that use less than what would be one bare-sphere critical mass at normal density. The presence of too much of the 238U isotope inhibits the runaway nuclear chain reaction that is responsible for the weapon's power. The critical mass for 85% highly enriched uranium is about 50 kilograms (110 lb), which at normal density would be a sphere about 17 centimetres (6.7 in) in diameter.

Later U.S. nuclear weapons usually use plutonium-239 in the primary stage, but the jacket or tamper secondary stage, which is compressed by the primary nuclear explosion often uses HEU with enrichment between 40% and 80%[11] along with the fusion fuel lithium deuteride. For the secondary of a large nuclear weapon, the higher critical mass of less-enriched uranium can be an advantage as it allows the core at explosion time to contain a larger amount of fuel. The 238U is not said to be fissile but still is fissionable by fast neutrons (>2 MeV) such as the ones produced during D-T fusion.

HEU is also used in fast neutron reactors, whose cores require about 20% or more of fissile material, as well as in naval reactors, where it often contains at least 50% 235U, but typically does not exceed 90%. The Fermi-1 commercial fast reactor prototype used HEU with 26.5% 235U. Significant quantities of HEU are used in the production of medical isotopes, for example molybdenum-99 for technetium-99m generators.[12]

Enrichment methods edit

Isotope separation is difficult because two isotopes of the same element have nearly identical chemical properties, and can only be separated gradually using small mass differences. (235U is only 1.26% lighter than 238U.) This problem is compounded because uranium is rarely separated in its atomic form, but instead as a compound (235UF6 is only 0.852% lighter than 238UF6). A cascade of identical stages produces successively higher concentrations of 235U. Each stage passes a slightly more concentrated product to the next stage and returns a slightly less concentrated residue to the previous stage.

There are currently two generic commercial methods employed internationally for enrichment: gaseous diffusion (referred to as first generation) and gas centrifuge (second generation), which consumes only 2% to 2.5%[13] as much energy as gaseous diffusion (at least a "factor of 20" more efficient).[14] Some work is being done that would use nuclear resonance; however, there is no reliable evidence that any nuclear resonance processes have been scaled up to production.

Diffusion techniques edit

Gaseous diffusion edit

 
Gaseous diffusion uses semi-permeable membranes to separate enriched uranium.

Gaseous diffusion is a technology used to produce enriched uranium by forcing gaseous uranium hexafluoride (hex) through semi-permeable membranes. This produces a slight separation between the molecules containing 235U and 238U. Throughout the Cold War, gaseous diffusion played a major role as a uranium enrichment technique, and as of 2008 accounted for about 33% of enriched uranium production,[15] but in 2011 was deemed an obsolete technology that is steadily being replaced by the later generations of technology as the diffusion plants reach their ends of life.[16] In 2013, the Paducah facility in the U.S. ceased operating, it was the last commercial 235U gaseous diffusion plant in the world.[17]

Thermal diffusion edit

Thermal diffusion uses the transfer of heat across a thin liquid or gas to accomplish isotope separation. The process exploits the fact that the lighter 235U gas molecules will diffuse toward a hot surface, and the heavier 238U gas molecules will diffuse toward a cold surface. The S-50 plant at Oak Ridge, Tennessee was used during World War II to prepare feed material for the Electromagnetic isotope separation (EMIS) process, explained later in this article. It was abandoned in favor of gaseous diffusion.

Centrifuge techniques edit

Gas centrifuge edit

 
A cascade of gas centrifuges at a U.S. enrichment plant

The gas centrifuge process uses a large number of rotating cylinders in series and parallel formations. Each cylinder's rotation creates a strong centripetal force so that the heavier gas molecules containing 238U move tangentially toward the outside of the cylinder and the lighter gas molecules rich in 235U collect closer to the center. It requires much less energy to achieve the same separation than the older gaseous diffusion process, which it has largely replaced and so is the current method of choice and is termed second generation. It has a separation factor per stage of 1.3 relative to gaseous diffusion of 1.005,[15] which translates to about one-fiftieth of the energy requirements. Gas centrifuge techniques produce close to 100% of the world's enriched uranium. The cost per separative work unit is approximately 100 dollars per Separative Work Units (SWU), making it about 40% cheaper than standard gaseous diffusion techniques.[18]

Zippe centrifuge edit

 
Diagram of the principles of a Zippe-type gas centrifuge with U-238 represented in dark blue and U-235 represented in light blue

The Zippe-type centrifuge is an improvement on the standard gas centrifuge, the primary difference being the use of heat. The bottom of the rotating cylinder is heated, producing convection currents that move the 235U up the cylinder, where it can be collected by scoops. This improved centrifuge design is used commercially by Urenco to produce nuclear fuel and was used by Pakistan in their nuclear weapons program.

Laser techniques edit

Laser processes promise lower energy inputs, lower capital costs and lower tails assays, hence significant economic advantages. Several laser processes have been investigated or are under development. Separation of isotopes by laser excitation (SILEX) is well developed and is licensed for commercial operation as of 2012. Separation of isotopes by laser excitation is a very effective and cheap method of uranium separation, able to be done in small facilities requiring much less energy and space than previous separation techniques. The cost of uranium enrichment using laser enrichment technologies is approximately $30 per SWU[18] which is less than a third of the price of gas centrifuges, the current standard of enrichment. Separation of isotopes by laser excitation could be done in facilities virtually undetectable by satellites.[19] More than 20 countries have worked with laser separation over the past two decades, the most notable of these countries being Iran and North Korea, though all countries have had very limited success up to this point.

Atomic vapor laser isotope separation (AVLIS) edit

Atomic vapor laser isotope separation employs specially tuned lasers[20] to separate isotopes of uranium using selective ionization of hyperfine transitions. The technique uses lasers tuned to frequencies that ionize 235U atoms and no others. The positively charged 235U ions are then attracted to a negatively charged plate and collected.

Molecular laser isotope separation (MLIS) edit

Molecular laser isotope separation uses an infrared laser directed at UF6, exciting molecules that contain a 235U atom. A second laser frees a fluorine atom, leaving uranium pentafluoride, which then precipitates out of the gas.

Separation of isotopes by laser excitation (SILEX) edit

Separation of isotopes by laser excitation is an Australian development that also uses UF6. After a protracted development process involving U.S. enrichment company USEC acquiring and then relinquishing commercialization rights to the technology, GE Hitachi Nuclear Energy (GEH) signed a commercialization agreement with Silex Systems in 2006.[21] GEH has since built a demonstration test loop and announced plans to build an initial commercial facility.[22] Details of the process are classified and restricted by intergovernmental agreements between United States, Australia, and the commercial entities. SILEX has been projected to be an order of magnitude more efficient than existing production techniques but again, the exact figure is classified.[15] In August, 2011 Global Laser Enrichment, a subsidiary of GEH, applied to the U.S. Nuclear Regulatory Commission (NRC) for a permit to build a commercial plant.[23] In September 2012, the NRC issued a license for GEH to build and operate a commercial SILEX enrichment plant, although the company had not yet decided whether the project would be profitable enough to begin construction, and despite concerns that the technology could contribute to nuclear proliferation.[24] The fear of nuclear proliferation arose in part due to laser separation technology requiring less than 25% of the space of typical separation techniques, as well as requiring only the energy that would power 12 typical houses, putting a laser separation plant that works by means of laser excitation well below the detection threshold of existing surveillance technologies.[19] Due to these concerns the American Physical Society filed a petition with the NRC, asking that before any laser excitation plants are built that they undergo a formal review of proliferation risks. The APS even went as far as calling the technology a "game changer"[18] due to the ability for it to be hidden from any type of detection.

Other techniques edit

Aerodynamic processes edit

 
Schematic diagram of an aerodynamic nozzle. Many thousands of these small foils would be combined in an enrichment unit.
 
The X-ray-based LIGA manufacturing process was originally developed at the Forschungszentrum Karlsruhe, Germany, to produce nozzles for isotope enrichment.[25]

Aerodynamic enrichment processes include the Becker jet nozzle techniques developed by E. W. Becker and associates using the LIGA process and the vortex tube separation process. These aerodynamic separation processes depend upon diffusion driven by pressure gradients, as does the gas centrifuge. They in general have the disadvantage of requiring complex systems of cascading of individual separating elements to minimize energy consumption. In effect, aerodynamic processes can be considered as non-rotating centrifuges. Enhancement of the centrifugal forces is achieved by dilution of UF6 with hydrogen or helium as a carrier gas achieving a much higher flow velocity for the gas than could be obtained using pure uranium hexafluoride. The Uranium Enrichment Corporation of South Africa (UCOR) developed and deployed the continuous Helikon vortex separation cascade for high production rate low-enrichment and the substantially different semi-batch Pelsakon low production rate high enrichment cascade both using a particular vortex tube separator design, and both embodied in industrial plant.[26] A demonstration plant was built in Brazil by NUCLEI, a consortium led by Industrias Nucleares do Brasil that used the separation nozzle process. However, all methods have high energy consumption and substantial requirements for removal of waste heat; none is currently still in use.

Electromagnetic isotope separation edit

 
Schematic diagram of uranium isotope separation in a calutron shows how a strong magnetic field is used to redirect a stream of uranium ions to a target, resulting in a higher concentration of uranium-235 (represented here in dark blue) in the inner fringes of the stream.

In the electromagnetic isotope separation process (EMIS), metallic uranium is first vaporized, and then ionized to positively charged ions. The cations are then accelerated and subsequently deflected by magnetic fields onto their respective collection targets. A production-scale mass spectrometer named the Calutron was developed during World War II that provided some of the 235U used for the Little Boy nuclear bomb, which was dropped over Hiroshima in 1945. Properly the term 'Calutron' applies to a multistage device arranged in a large oval around a powerful electromagnet. Electromagnetic isotope separation has been largely abandoned in favour of more effective methods.

Chemical methods edit

One chemical process has been demonstrated to pilot plant stage but not used for production. The French CHEMEX process exploited a very slight difference in the two isotopes' propensity to change valency in oxidation/reduction, using immiscible aqueous and organic phases. An ion-exchange process was developed by the Asahi Chemical Company in Japan that applies similar chemistry but effects separation on a proprietary resin ion-exchange column.

Plasma separation edit

Plasma separation process (PSP) describes a technique that makes use of superconducting magnets and plasma physics. In this process, the principle of ion cyclotron resonance is used to selectively energize the 235U isotope in a plasma containing a mix of ions. France developed its own version of PSP, which it called RCI. Funding for RCI was drastically reduced in 1986, and the program was suspended around 1990, although RCI is still used for stable isotope separation.

Separative work unit edit

"Separative work"—the amount of separation done by an enrichment process—is a function of the concentrations of the feedstock, the enriched output, and the depleted tailings; and is expressed in units that are so calculated as to be proportional to the total input (energy / machine operation time) and to the mass processed. Separative work is not energy. The same amount of separative work will require different amounts of energy depending on the efficiency of the separation technology. Separative work is measured in Separative work units SWU, kg SW, or kg UTA (from the German Urantrennarbeit – literally uranium separation work).

  • 1 SWU = 1 kg SW = 1 kg UTA
  • 1 kSWU = 1 tSW = 1 t UTA
  • 1 MSWU = 1 ktSW = 1 kt UTA

Cost issues edit

In addition to the separative work units provided by an enrichment facility, the other important parameter to be considered is the mass of natural uranium (NU) that is needed to yield a desired mass of enriched uranium. As with the number of SWUs, the amount of feed material required will also depend on the level of enrichment desired and upon the amount of 235U that ends up in the depleted uranium. However, unlike the number of SWUs required during enrichment, which increases with decreasing levels of 235U in the depleted stream, the amount of NU needed will decrease with decreasing levels of 235U that end up in the DU.

For example, in the enrichment of LEU for use in a light water reactor it is typical for the enriched stream to contain 3.6% 235U (as compared to 0.7% in NU) while the depleted stream contains 0.2% to 0.3% 235U. In order to produce one kilogram of this LEU it would require approximately 8 kilograms of NU and 4.5 SWU if the DU stream was allowed to have 0.3% 235U. On the other hand, if the depleted stream had only 0.2% 235U, then it would require just 6.7 kilograms of NU, but nearly 5.7 SWU of enrichment. Because the amount of NU required and the number of SWUs required during enrichment change in opposite directions, if NU is cheap and enrichment services are more expensive, then the operators will typically choose to allow more 235U to be left in the DU stream whereas if NU is more expensive and enrichment is less so, then they would choose the opposite.

When converting uranium (hexafluoride, hex for short) to metal, 0.3% is lost during manufacturing.[27][28]

Downblending edit

The opposite of enriching is downblending; surplus HEU can be downblended to LEU to make it suitable for use in commercial nuclear fuel.

The HEU feedstock can contain unwanted uranium isotopes: 234U is a minor isotope contained in natural uranium (primarily as a product of alpha decay of 238
U
—because the half-life of 238
U
is much larger than that of 234
U
, it'll be produced and destroyed at the same rate in a constant steady state equilibrium, bringing any sample with sufficient 238
U
content to a stable ratio of 234
U
to 238
U
over long enough timescales); during the enrichment process, its concentration increases but remains well below 1%. High concentrations of 236U are a byproduct from irradiation in a reactor and may be contained in the HEU, depending on its manufacturing history. 236
U
is produced primarily when 235
U
absorbs a neutron and does not fission. The production of 236
U
is thus unavoidable in any thermal neutron reactor with 235
U
fuel. HEU reprocessed from nuclear weapons material production reactors (with an 235U assay of approximately 50%) may contain 236U concentrations as high as 25%, resulting in concentrations of approximately 1.5% in the blended LEU product. 236U is a neutron poison; therefore the actual 235U concentration in the LEU product must be raised accordingly to compensate for the presence of 236U. While 234
U
also absorbs neutrons, it is a fertile material that is turned into fissile 235
U
upon neutron absorption. If 236
U
absorbs a neutron, the resulting short-lived 237
U
beta decays to 237
Np
, which is not usable in thermal neutron reactors but can be chemically separated from spent fuel to be disposed of as waste or to be transmutated into 238
Pu
(for use in nuclear batteries) in special reactors.

The blendstock can be NU or DU; however, depending on feedstock quality, SEU at typically 1.5 wt% 235U may be used as a blendstock to dilute the unwanted byproducts that may be contained in the HEU feed. Concentrations of these isotopes in the LEU product in some cases could exceed ASTM specifications for nuclear fuel if NU or DU were used. So, the HEU downblending generally cannot contribute to the waste management problem posed by the existing large stockpiles of depleted uranium. At present, 95 percent of the world's stocks of depleted uranium remain in secure storage.[citation needed]

A major downblending undertaking called the Megatons to Megawatts Program converts ex-Soviet weapons-grade HEU to fuel for U.S. commercial power reactors. From 1995 through mid-2005, 250 tonnes of high-enriched uranium (enough for 10,000 warheads) was recycled into low-enriched uranium. The goal is to recycle 500 tonnes by 2013. The decommissioning programme of Russian nuclear warheads accounted for about 13% of total world requirement for enriched uranium leading up to 2008.[15]

The United States Enrichment Corporation has been involved in the disposition of a portion of the 174.3 tonnes of highly enriched uranium (HEU) that the U.S. government declared as surplus military material in 1996. Through the U.S. HEU Downblending Program, this HEU material, taken primarily from dismantled U.S. nuclear warheads, was recycled into low-enriched uranium (LEU) fuel, used by nuclear power plants to generate electricity.[29][30]

Global enrichment facilities edit

The following countries are known to operate enrichment facilities: Argentina, Brazil, China, France, Germany, India, Iran, Japan, the Netherlands, North Korea, Pakistan, Russia, the United Kingdom, and the United States.[31][32] Belgium, Iran, Italy, and Spain hold an investment interest in the French Eurodif enrichment plant, with Iran's holding entitling it to 10% of the enriched uranium output. Countries that had enrichment programs in the past include Libya and South Africa, although Libya's facility was never operational.[33] The Australian company Silex Systems has developed a laser enrichment process known as SILEX (separation of isotopes by laser excitation), which it intends to pursue through financial investment in a U.S. commercial venture by General Electric,[34] Although SILEX has been granted a license to build a plant, the development is still in its early stages as laser enrichment has yet to be proven to be economically viable, and there is a petition being filed to review the license given to SILEX over nuclear proliferation concerns.[35] It has also been claimed that Israel has a uranium enrichment program housed at the Negev Nuclear Research Center site near Dimona.[36]

Codename edit

During the Manhattan Project, weapons-grade highly enriched uranium was given the codename oralloy, a shortened version of Oak Ridge alloy, after the location of the plants where the uranium was enriched.[37] The term oralloy is still occasionally used to refer to enriched uranium.

See also edit

References edit

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  3. ^ Nuclear Fuel Cycle Overview, Uranium milling. World Nuclear Association, update April 2021
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  7. ^ Glaser, Alexander (6 November 2005). About the Enrichment Limit for Research Reactor Conversion : Why 20%? (PDF). The 27th International Meeting on Reduced Enrichment for Research and Test Reactors (RERTR. Princeton University. Archived (PDF) from the original on 9 October 2022. Retrieved 18 April 2014.
  8. ^ a b Forsberg, C. W.; Hopper, C. M.; Richter, J. L.; Vantine, H. C. (March 1998). (PDF). ORNL/TM-13517. Oak Ridge National Laboratories. Archived from the original (PDF) on 2 November 2013. Retrieved 30 October 2013.
  9. ^ Sublette, Carey (4 October 1996). "Nuclear Weapons FAQ, Section 4.1.7.1: Nuclear Design Principles – Highly Enriched Uranium". Nuclear Weapons FAQ. Retrieved 2 October 2010.
  10. ^ Mosteller, R.D. (1994). "Detailed Reanalysis of a Benchmark Critical Experiment: Water-Reflected Enriched-Uranium Sphere" (PDF). Los Alamos Technical Paper (LA–UR–93–4097): 2. doi:10.2172/10120434. Archived (PDF) from the original on 9 October 2022. Retrieved 19 December 2007. The enrichment of the pin and of one of the hemispheres was 97.67 w/o, while the enrichment of the other hemisphere was 97.68 w/o.
  11. ^ "Nuclear Weapons FAQ". Retrieved 26 January 2013.
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  13. ^ . world-nuclear.org. Archived from the original on 1 July 2013. Retrieved 14 April 2013.
  14. ^ Economic Perspective for Uranium Enrichment (PDF), archived (PDF) from the original on 9 October 2022, The throughput per centrifuge unit is very small compared to that of a diffusion unit so small, in fact, that it is not compensated by the higher enrichment per unit. To produce the same amount of reactor-grade fuel requires a considerably larger number (approximately 50,000 to 500,000) of centrifuge units than diffusion units. This disadvantage, however, is outweighed by the considerably lower (by a factor of 20) energy consumption per SWU for the gas centrifuge
  15. ^ a b c d "Lodge Partners Mid-Cap Conference 11 April 2008" (PDF). Silex Ltd. 11 April 2008. Archived (PDF) from the original on 9 October 2022.
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  17. ^ "Paducah enrichment plant to be closed - World Nuclear News". www.world-nuclear-news.org.
  18. ^ a b c Weinberger, Sharon (28 September 2012). "US grants licence for uranium laser enrichment". Nature: nature.2012.11502. doi:10.1038/nature.2012.11502. S2CID 100862135.
  19. ^ a b Slakey, Francis; Cohen, Linda R. (March 2010). "Stop laser uranium enrichment". Nature. 464 (7285): 32–33. Bibcode:2010Natur.464...32S. doi:10.1038/464032a. PMID 20203589. S2CID 205053626. ProQuest 204555310.
  20. ^ F. J. Duarte and L. W. Hillman (Eds.), Dye Laser Principles (Academic, New York, 1990) Chapter 9.
  21. ^ (Press release). GE Energy. 22 May 2006. Archived from the original on 14 June 2006.
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  23. ^ Broad, William J. (20 August 2011). "Laser Advances in Nuclear Fuel Stir Terror Fear". The New York Times. Retrieved 21 August 2011.
  24. ^ Associated Press (27 September 2012). "Uranium Plant Using Laser Technology Wins U.S. Approval". The New York Times.
  25. ^ Becker, E. W.; Ehrfeld, W.; Münchmeyer, D.; Betz, H.; Heuberger, A.; Pongratz, S.; Glashauser, W.; Michel, H. J.; Siemens, R. (1982). "Production of Separation-Nozzle Systems for Uranium Enrichment by a Combination of X-Ray Lithography and Galvanoplastics". Naturwissenschaften. 69 (11): 520–523. Bibcode:1982NW.....69..520B. doi:10.1007/BF00463495. S2CID 44245091.
  26. ^ Smith, Michael; Jackson A G M (2000). "Dr". South African Institution of Chemical Engineers – Conference 2000: 280–289.
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  29. ^ . USEC.com. 1 May 2000. Archived from the original on 6 April 2001.
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  32. ^ Australia's uranium - Greenhouse friendly fuel for an energy hungry world (PDF). Standing Committee on Industry and Resources (Report). The Parliament of the Commonwealth of Australia. November 2006. p. 730. Archived (PDF) from the original on 9 October 2022. Retrieved 3 April 2015.
  33. ^ "Q&A: Uranium enrichment". BBC News. BBC. 1 September 2006. Retrieved 3 January 2010.
  34. ^ "Laser enrichment could cut cost of nuclear power". The Sydney Morning Herald. 26 May 2006.
  35. ^ Weinberger, Sharon (28 September 2012). "US grants licence for uranium laser enrichment". Nature. doi:10.1038/nature.2012.11502. ISSN 1476-4687. S2CID 100862135.
  36. ^ "Israel's Nuclear Weapons Program". Nuclear Weapon Archive. 10 December 1997. Retrieved 7 October 2007.
  37. ^ Burr, William (22 December 2015). "Strategic Air Command Declassifies Nuclear Target List from 1950s". nsarchive2.gwu.edu. Retrieved 27 November 2020. Oralloy [Oak Ridge alloy] was a term of art for highly enriched uranium.

External links edit

enriched, uranium, type, uranium, which, percent, composition, uranium, written, 235u, been, increased, through, process, isotope, separation, naturally, occurring, uranium, composed, three, major, isotopes, uranium, 238u, with, 2739, 2752, natural, abundance,. Enriched uranium is a type of uranium in which the percent composition of uranium 235 written 235U has been increased through the process of isotope separation Naturally occurring uranium is composed of three major isotopes uranium 238 238U with 99 2739 99 2752 natural abundance uranium 235 235U 0 7198 0 7202 and uranium 234 234U 0 0050 0 0059 citation needed 235U is the only nuclide existing in nature in any appreciable amount that is fissile with thermal neutrons 1 Proportions of uranium 238 blue and uranium 235 red found naturally versus enriched gradesEnriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons The International Atomic Energy Agency attempts to monitor and control enriched uranium supplies and processes in its efforts to ensure nuclear power generation safety and curb nuclear weapons proliferation There are about 2 000 tonnes of highly enriched uranium in the world 2 produced mostly for nuclear power nuclear weapons naval propulsion and smaller quantities for research reactors The 238U remaining after enrichment is known as depleted uranium DU and is considerably less radioactive than even natural uranium though still very dense Depleted uranium is used as a radiation shielding material and for armor penetrating weapons Contents 1 Grades 1 1 Reprocessed uranium RepU 1 2 Low enriched uranium LEU 1 3 Highly enriched uranium HEU 2 Enrichment methods 2 1 Diffusion techniques 2 1 1 Gaseous diffusion 2 1 2 Thermal diffusion 2 2 Centrifuge techniques 2 2 1 Gas centrifuge 2 2 2 Zippe centrifuge 2 3 Laser techniques 2 3 1 Atomic vapor laser isotope separation AVLIS 2 3 2 Molecular laser isotope separation MLIS 2 3 3 Separation of isotopes by laser excitation SILEX 2 4 Other techniques 2 4 1 Aerodynamic processes 2 4 2 Electromagnetic isotope separation 2 4 3 Chemical methods 2 4 4 Plasma separation 3 Separative work unit 4 Cost issues 5 Downblending 6 Global enrichment facilities 7 Codename 8 See also 9 References 10 External linksGrades editUranium as it is taken directly from the Earth is not suitable as fuel for most nuclear reactors and requires additional processes to make it usable CANDU design is a notable exception Uranium is mined either underground or in an open pit depending on the depth at which it is found After the uranium ore is mined it must go through a milling process to extract the uranium from the ore This is accomplished by a combination of chemical processes with the end product being concentrated uranium oxide which is known as yellowcake contains roughly 80 uranium whereas the original ore typically contains as little as 0 1 uranium 3 After the milling process is complete the uranium must next undergo a process of conversion to either uranium dioxide which can be used as the fuel for those types of reactors that do not require enriched uranium or into uranium hexafluoride which can be enriched to produce fuel for the majority of types of reactors 4 Naturally occurring uranium is made of a mixture of 235U and 238U The 235U is fissile meaning it is easily split with neutrons while the remainder is 238U but in nature more than 99 of the extracted ore is 238U Most nuclear reactors require enriched uranium which is uranium with higher concentrations of 235U ranging between 3 5 and 4 5 although a few reactor designs using a graphite or heavy water moderator such as the RBMK and CANDU are capable of operating with natural uranium as fuel There are two commercial enrichment processes gaseous diffusion and gas centrifugation Both enrichment processes involve the use of uranium hexafluoride and produce enriched uranium oxide nbsp A drum of yellowcake a mixture of uranium precipitates Reprocessed uranium RepU edit Main article Reprocessed uranium Reprocessed uranium RepU is a product of nuclear fuel cycles involving nuclear reprocessing of spent fuel RepU recovered from light water reactor LWR spent fuel typically contains slightly more 235U than natural uranium and therefore could be used to fuel reactors that customarily use natural uranium as fuel such as CANDU reactors It also contains the undesirable isotope uranium 236 which undergoes neutron capture wasting neutrons and requiring higher 235U enrichment and creating neptunium 237 which would be one of the more mobile and troublesome radionuclides in deep geological repository disposal of nuclear waste Low enriched uranium LEU edit Low enriched uranium LEU has a lower than 20 concentration of 235U for instance in commercial LWR the most prevalent power reactors in the world uranium is enriched to 3 to 5 235U Slightly enriched uranium SEU has a concentration of under 2 235U 5 High assay LEU HALEU is enriched between 5 and 20 6 Fresh LEU used in research reactors is usually enriched between 12 and 19 75 235U the latter concentration is used to replace HEU fuels when converting to LEU 7 Highly enriched uranium HEU edit nbsp A billet of highly enriched uranium metalHighly enriched uranium HEU has a 20 or higher concentration of 235U The fissile uranium in nuclear weapon primaries usually contains 85 or more of 235U known as weapons grade though theoretically for an implosion design a minimum of 20 could be sufficient called weapon usable although it would require hundreds of kilograms of material and would not be practical to design 8 9 even lower enrichment is hypothetically possible but as the enrichment percentage decreases the critical mass for unmoderated fast neutrons rapidly increases with for example an infinite mass of 5 4 235U being required 8 For criticality experiments enrichment of uranium to over 97 has been accomplished 10 The very first uranium bomb Little Boy dropped by the United States on Hiroshima in 1945 used 64 kilograms 141 lb of 80 enriched uranium Wrapping the weapon s fissile core in a neutron reflector which is standard on all nuclear explosives can dramatically reduce the critical mass Because the core was surrounded by a good neutron reflector at explosion it comprised almost 2 5 critical masses Neutron reflectors compressing the fissile core via implosion fusion boosting and tamping which slows the expansion of the fissioning core with inertia allow nuclear weapon designs that use less than what would be one bare sphere critical mass at normal density The presence of too much of the 238U isotope inhibits the runaway nuclear chain reaction that is responsible for the weapon s power The critical mass for 85 highly enriched uranium is about 50 kilograms 110 lb which at normal density would be a sphere about 17 centimetres 6 7 in in diameter Later U S nuclear weapons usually use plutonium 239 in the primary stage but the jacket or tamper secondary stage which is compressed by the primary nuclear explosion often uses HEU with enrichment between 40 and 80 11 along with the fusion fuel lithium deuteride For the secondary of a large nuclear weapon the higher critical mass of less enriched uranium can be an advantage as it allows the core at explosion time to contain a larger amount of fuel The 238U is not said to be fissile but still is fissionable by fast neutrons gt 2 MeV such as the ones produced during D T fusion HEU is also used in fast neutron reactors whose cores require about 20 or more of fissile material as well as in naval reactors where it often contains at least 50 235U but typically does not exceed 90 The Fermi 1 commercial fast reactor prototype used HEU with 26 5 235U Significant quantities of HEU are used in the production of medical isotopes for example molybdenum 99 for technetium 99m generators 12 Enrichment methods editIsotope separation is difficult because two isotopes of the same element have nearly identical chemical properties and can only be separated gradually using small mass differences 235U is only 1 26 lighter than 238U This problem is compounded because uranium is rarely separated in its atomic form but instead as a compound 235UF6 is only 0 852 lighter than 238UF6 A cascade of identical stages produces successively higher concentrations of 235U Each stage passes a slightly more concentrated product to the next stage and returns a slightly less concentrated residue to the previous stage There are currently two generic commercial methods employed internationally for enrichment gaseous diffusion referred to as first generation and gas centrifuge second generation which consumes only 2 to 2 5 13 as much energy as gaseous diffusion at least a factor of 20 more efficient 14 Some work is being done that would use nuclear resonance however there is no reliable evidence that any nuclear resonance processes have been scaled up to production Diffusion techniques edit Gaseous diffusion edit Main article Gaseous diffusion nbsp Gaseous diffusion uses semi permeable membranes to separate enriched uranium Gaseous diffusion is a technology used to produce enriched uranium by forcing gaseous uranium hexafluoride hex through semi permeable membranes This produces a slight separation between the molecules containing 235U and 238U Throughout the Cold War gaseous diffusion played a major role as a uranium enrichment technique and as of 2008 accounted for about 33 of enriched uranium production 15 but in 2011 was deemed an obsolete technology that is steadily being replaced by the later generations of technology as the diffusion plants reach their ends of life 16 In 2013 the Paducah facility in the U S ceased operating it was the last commercial 235U gaseous diffusion plant in the world 17 Thermal diffusion edit Thermal diffusion uses the transfer of heat across a thin liquid or gas to accomplish isotope separation The process exploits the fact that the lighter 235U gas molecules will diffuse toward a hot surface and the heavier 238U gas molecules will diffuse toward a cold surface The S 50 plant at Oak Ridge Tennessee was used during World War II to prepare feed material for the Electromagnetic isotope separation EMIS process explained later in this article It was abandoned in favor of gaseous diffusion Centrifuge techniques edit Gas centrifuge edit Main article Gas centrifuge nbsp A cascade of gas centrifuges at a U S enrichment plantThe gas centrifuge process uses a large number of rotating cylinders in series and parallel formations Each cylinder s rotation creates a strong centripetal force so that the heavier gas molecules containing 238U move tangentially toward the outside of the cylinder and the lighter gas molecules rich in 235U collect closer to the center It requires much less energy to achieve the same separation than the older gaseous diffusion process which it has largely replaced and so is the current method of choice and is termed second generation It has a separation factor per stage of 1 3 relative to gaseous diffusion of 1 005 15 which translates to about one fiftieth of the energy requirements Gas centrifuge techniques produce close to 100 of the world s enriched uranium The cost per separative work unit is approximately 100 dollars per Separative Work Units SWU making it about 40 cheaper than standard gaseous diffusion techniques 18 Zippe centrifuge edit Main article Zippe type centrifuge nbsp Diagram of the principles of a Zippe type gas centrifuge with U 238 represented in dark blue and U 235 represented in light blueThe Zippe type centrifuge is an improvement on the standard gas centrifuge the primary difference being the use of heat The bottom of the rotating cylinder is heated producing convection currents that move the 235U up the cylinder where it can be collected by scoops This improved centrifuge design is used commercially by Urenco to produce nuclear fuel and was used by Pakistan in their nuclear weapons program Laser techniques edit Laser processes promise lower energy inputs lower capital costs and lower tails assays hence significant economic advantages Several laser processes have been investigated or are under development Separation of isotopes by laser excitation SILEX is well developed and is licensed for commercial operation as of 2012 Separation of isotopes by laser excitation is a very effective and cheap method of uranium separation able to be done in small facilities requiring much less energy and space than previous separation techniques The cost of uranium enrichment using laser enrichment technologies is approximately 30 per SWU 18 which is less than a third of the price of gas centrifuges the current standard of enrichment Separation of isotopes by laser excitation could be done in facilities virtually undetectable by satellites 19 More than 20 countries have worked with laser separation over the past two decades the most notable of these countries being Iran and North Korea though all countries have had very limited success up to this point Atomic vapor laser isotope separation AVLIS edit Atomic vapor laser isotope separation employs specially tuned lasers 20 to separate isotopes of uranium using selective ionization of hyperfine transitions The technique uses lasers tuned to frequencies that ionize 235U atoms and no others The positively charged 235U ions are then attracted to a negatively charged plate and collected Molecular laser isotope separation MLIS edit Molecular laser isotope separation uses an infrared laser directed at UF6 exciting molecules that contain a 235U atom A second laser frees a fluorine atom leaving uranium pentafluoride which then precipitates out of the gas Separation of isotopes by laser excitation SILEX edit Separation of isotopes by laser excitation is an Australian development that also uses UF6 After a protracted development process involving U S enrichment company USEC acquiring and then relinquishing commercialization rights to the technology GE Hitachi Nuclear Energy GEH signed a commercialization agreement with Silex Systems in 2006 21 GEH has since built a demonstration test loop and announced plans to build an initial commercial facility 22 Details of the process are classified and restricted by intergovernmental agreements between United States Australia and the commercial entities SILEX has been projected to be an order of magnitude more efficient than existing production techniques but again the exact figure is classified 15 In August 2011 Global Laser Enrichment a subsidiary of GEH applied to the U S Nuclear Regulatory Commission NRC for a permit to build a commercial plant 23 In September 2012 the NRC issued a license for GEH to build and operate a commercial SILEX enrichment plant although the company had not yet decided whether the project would be profitable enough to begin construction and despite concerns that the technology could contribute to nuclear proliferation 24 The fear of nuclear proliferation arose in part due to laser separation technology requiring less than 25 of the space of typical separation techniques as well as requiring only the energy that would power 12 typical houses putting a laser separation plant that works by means of laser excitation well below the detection threshold of existing surveillance technologies 19 Due to these concerns the American Physical Society filed a petition with the NRC asking that before any laser excitation plants are built that they undergo a formal review of proliferation risks The APS even went as far as calling the technology a game changer 18 due to the ability for it to be hidden from any type of detection Other techniques edit Aerodynamic processes edit nbsp Schematic diagram of an aerodynamic nozzle Many thousands of these small foils would be combined in an enrichment unit nbsp The X ray based LIGA manufacturing process was originally developed at the Forschungszentrum Karlsruhe Germany to produce nozzles for isotope enrichment 25 Aerodynamic enrichment processes include the Becker jet nozzle techniques developed by E W Becker and associates using the LIGA process and the vortex tube separation process These aerodynamic separation processes depend upon diffusion driven by pressure gradients as does the gas centrifuge They in general have the disadvantage of requiring complex systems of cascading of individual separating elements to minimize energy consumption In effect aerodynamic processes can be considered as non rotating centrifuges Enhancement of the centrifugal forces is achieved by dilution of UF6 with hydrogen or helium as a carrier gas achieving a much higher flow velocity for the gas than could be obtained using pure uranium hexafluoride The Uranium Enrichment Corporation of South Africa UCOR developed and deployed the continuous Helikon vortex separation cascade for high production rate low enrichment and the substantially different semi batch Pelsakon low production rate high enrichment cascade both using a particular vortex tube separator design and both embodied in industrial plant 26 A demonstration plant was built in Brazil by NUCLEI a consortium led by Industrias Nucleares do Brasil that used the separation nozzle process However all methods have high energy consumption and substantial requirements for removal of waste heat none is currently still in use Electromagnetic isotope separation edit Main article Calutron nbsp Schematic diagram of uranium isotope separation in a calutron shows how a strong magnetic field is used to redirect a stream of uranium ions to a target resulting in a higher concentration of uranium 235 represented here in dark blue in the inner fringes of the stream In the electromagnetic isotope separation process EMIS metallic uranium is first vaporized and then ionized to positively charged ions The cations are then accelerated and subsequently deflected by magnetic fields onto their respective collection targets A production scale mass spectrometer named the Calutron was developed during World War II that provided some of the 235U used for the Little Boy nuclear bomb which was dropped over Hiroshima in 1945 Properly the term Calutron applies to a multistage device arranged in a large oval around a powerful electromagnet Electromagnetic isotope separation has been largely abandoned in favour of more effective methods Chemical methods edit One chemical process has been demonstrated to pilot plant stage but not used for production The French CHEMEX process exploited a very slight difference in the two isotopes propensity to change valency in oxidation reduction using immiscible aqueous and organic phases An ion exchange process was developed by the Asahi Chemical Company in Japan that applies similar chemistry but effects separation on a proprietary resin ion exchange column Plasma separation edit Plasma separation process PSP describes a technique that makes use of superconducting magnets and plasma physics In this process the principle of ion cyclotron resonance is used to selectively energize the 235U isotope in a plasma containing a mix of ions France developed its own version of PSP which it called RCI Funding for RCI was drastically reduced in 1986 and the program was suspended around 1990 although RCI is still used for stable isotope separation Separative work unit editFurther information Separative work units Separative work the amount of separation done by an enrichment process is a function of the concentrations of the feedstock the enriched output and the depleted tailings and is expressed in units that are so calculated as to be proportional to the total input energy machine operation time and to the mass processed Separative work is not energy The same amount of separative work will require different amounts of energy depending on the efficiency of the separation technology Separative work is measured in Separative work units SWU kg SW or kg UTA from the German Urantrennarbeit literally uranium separation work 1 SWU 1 kg SW 1 kg UTA 1 kSWU 1 tSW 1 t UTA 1 MSWU 1 ktSW 1 kt UTACost issues editIn addition to the separative work units provided by an enrichment facility the other important parameter to be considered is the mass of natural uranium NU that is needed to yield a desired mass of enriched uranium As with the number of SWUs the amount of feed material required will also depend on the level of enrichment desired and upon the amount of 235U that ends up in the depleted uranium However unlike the number of SWUs required during enrichment which increases with decreasing levels of 235U in the depleted stream the amount of NU needed will decrease with decreasing levels of 235U that end up in the DU For example in the enrichment of LEU for use in a light water reactor it is typical for the enriched stream to contain 3 6 235U as compared to 0 7 in NU while the depleted stream contains 0 2 to 0 3 235U In order to produce one kilogram of this LEU it would require approximately 8 kilograms of NU and 4 5 SWU if the DU stream was allowed to have 0 3 235U On the other hand if the depleted stream had only 0 2 235U then it would require just 6 7 kilograms of NU but nearly 5 7 SWU of enrichment Because the amount of NU required and the number of SWUs required during enrichment change in opposite directions if NU is cheap and enrichment services are more expensive then the operators will typically choose to allow more 235U to be left in the DU stream whereas if NU is more expensive and enrichment is less so then they would choose the opposite When converting uranium hexafluoride hex for short to metal 0 3 is lost during manufacturing 27 28 Downblending editThe opposite of enriching is downblending surplus HEU can be downblended to LEU to make it suitable for use in commercial nuclear fuel The HEU feedstock can contain unwanted uranium isotopes 234U is a minor isotope contained in natural uranium primarily as a product of alpha decay of 238 U because the half life of 238 U is much larger than that of 234 U it ll be produced and destroyed at the same rate in a constant steady state equilibrium bringing any sample with sufficient 238 U content to a stable ratio of 234 U to 238 U over long enough timescales during the enrichment process its concentration increases but remains well below 1 High concentrations of 236U are a byproduct from irradiation in a reactor and may be contained in the HEU depending on its manufacturing history 236 U is produced primarily when 235 U absorbs a neutron and does not fission The production of 236 U is thus unavoidable in any thermal neutron reactor with 235 U fuel HEU reprocessed from nuclear weapons material production reactors with an 235U assay of approximately 50 may contain 236U concentrations as high as 25 resulting in concentrations of approximately 1 5 in the blended LEU product 236U is a neutron poison therefore the actual 235U concentration in the LEU product must be raised accordingly to compensate for the presence of 236U While 234 U also absorbs neutrons it is a fertile material that is turned into fissile 235 U upon neutron absorption If 236 U absorbs a neutron the resulting short lived 237 U beta decays to 237 Np which is not usable in thermal neutron reactors but can be chemically separated from spent fuel to be disposed of as waste or to be transmutated into 238 Pu for use in nuclear batteries in special reactors The blendstock can be NU or DU however depending on feedstock quality SEU at typically 1 5 wt 235U may be used as a blendstock to dilute the unwanted byproducts that may be contained in the HEU feed Concentrations of these isotopes in the LEU product in some cases could exceed ASTM specifications for nuclear fuel if NU or DU were used So the HEU downblending generally cannot contribute to the waste management problem posed by the existing large stockpiles of depleted uranium At present 95 percent of the world s stocks of depleted uranium remain in secure storage citation needed A major downblending undertaking called the Megatons to Megawatts Program converts ex Soviet weapons grade HEU to fuel for U S commercial power reactors From 1995 through mid 2005 250 tonnes of high enriched uranium enough for 10 000 warheads was recycled into low enriched uranium The goal is to recycle 500 tonnes by 2013 The decommissioning programme of Russian nuclear warheads accounted for about 13 of total world requirement for enriched uranium leading up to 2008 15 The United States Enrichment Corporation has been involved in the disposition of a portion of the 174 3 tonnes of highly enriched uranium HEU that the U S government declared as surplus military material in 1996 Through the U S HEU Downblending Program this HEU material taken primarily from dismantled U S nuclear warheads was recycled into low enriched uranium LEU fuel used by nuclear power plants to generate electricity 29 30 Global enrichment facilities editThe following countries are known to operate enrichment facilities Argentina Brazil China France Germany India Iran Japan the Netherlands North Korea Pakistan Russia the United Kingdom and the United States 31 32 Belgium Iran Italy and Spain hold an investment interest in the French Eurodif enrichment plant with Iran s holding entitling it to 10 of the enriched uranium output Countries that had enrichment programs in the past include Libya and South Africa although Libya s facility was never operational 33 The Australian company Silex Systems has developed a laser enrichment process known as SILEX separation of isotopes by laser excitation which it intends to pursue through financial investment in a U S commercial venture by General Electric 34 Although SILEX has been granted a license to build a plant the development is still in its early stages as laser enrichment has yet to be proven to be economically viable and there is a petition being filed to review the license given to SILEX over nuclear proliferation concerns 35 It has also been claimed that Israel has a uranium enrichment program housed at the Negev Nuclear Research Center site near Dimona 36 Codename editDuring the Manhattan Project weapons grade highly enriched uranium was given the codename oralloy a shortened version of Oak Ridge alloy after the location of the plants where the uranium was enriched 37 The term oralloy is still occasionally used to refer to enriched uranium See also editList of laser articles MOX fuel Nuclear fuel bank Orano Uranium market Uranium miningReferences edit OECD Nuclear Energy Agency 2003 Nuclear Energy Today OECD Publishing p 25 ISBN 9789264103283 Cochran Natural Resources Defense Council Thomas B 12 June 1997 Safeguarding Nuclear Weapon Usable Materials in Russia PDF Proceedings of international forum on illegal nuclear traffic Archived from the original PDF on 22 July 2012 Nuclear Fuel Cycle Overview Uranium milling World Nuclear Association update April 2021 Radiological Sources of Potential Exposure and or Contamination U S Army Center for Health Promotion and Preventive Medicine June 1999 p 27 Retrieved 1 July 2019 Carter John P Borrelli R A August 2020 Integral molten salt reactor neutron physics study using Monte Carlo N particle code Nuclear Engineering and Design 365 110718 doi 10 1016 j nucengdes 2020 110718 S2CID 225435681 Retrieved 22 December 2022 Herczeg John W 28 March 2019 High assay low enriched uranium PDF energy gov Archived PDF from the original on 9 October 2022 Glaser Alexander 6 November 2005 About the Enrichment Limit for Research Reactor Conversion Why 20 PDF The 27th International Meeting on Reduced Enrichment for Research and Test Reactors RERTR Princeton University Archived PDF from the original on 9 October 2022 Retrieved 18 April 2014 a b Forsberg C W Hopper C M Richter J L Vantine H C March 1998 Definition of Weapons Usable Uranium 233 PDF ORNL TM 13517 Oak Ridge National Laboratories Archived from the original PDF on 2 November 2013 Retrieved 30 October 2013 Sublette Carey 4 October 1996 Nuclear Weapons FAQ Section 4 1 7 1 Nuclear Design Principles Highly Enriched Uranium Nuclear Weapons FAQ Retrieved 2 October 2010 Mosteller R D 1994 Detailed Reanalysis of a Benchmark Critical Experiment Water Reflected Enriched Uranium Sphere PDF Los Alamos Technical Paper LA UR 93 4097 2 doi 10 2172 10120434 Archived PDF from the original on 9 October 2022 Retrieved 19 December 2007 The enrichment of the pin and of one of the hemispheres was 97 67 w o while the enrichment of the other hemisphere was 97 68 w o Nuclear Weapons FAQ Retrieved 26 January 2013 Von Hippel Frank N Kahn Laura H December 2006 Feasibility of Eliminating the Use of Highly Enriched Uranium in the Production of Medical Radioisotopes Science amp Global Security 14 2 amp 3 151 162 Bibcode 2006S amp GS 14 151V doi 10 1080 08929880600993071 S2CID 122507063 Uranium Enrichment world nuclear org Archived from the original on 1 July 2013 Retrieved 14 April 2013 Economic Perspective for Uranium Enrichment PDF archived PDF from the original on 9 October 2022 The throughput per centrifuge unit is very small compared to that of a diffusion unit so small in fact that it is not compensated by the higher enrichment per unit To produce the same amount of reactor grade fuel requires a considerably larger number approximately 50 000 to 500 000 of centrifuge units than diffusion units This disadvantage however is outweighed by the considerably lower by a factor of 20 energy consumption per SWU for the gas centrifuge a b c d Lodge Partners Mid Cap Conference 11 April 2008 PDF Silex Ltd 11 April 2008 Archived PDF from the original on 9 October 2022 Adams Rod 24 May 2011 McConnell asks DOE to keep using 60 year old enrichment plant to save jobs Atomic Insights Archived from the original on 28 January 2013 Retrieved 26 January 2013 Paducah enrichment plant to be closed World Nuclear News www world nuclear news org a b c Weinberger Sharon 28 September 2012 US grants licence for uranium laser enrichment Nature nature 2012 11502 doi 10 1038 nature 2012 11502 S2CID 100862135 a b Slakey Francis Cohen Linda R March 2010 Stop laser uranium enrichment Nature 464 7285 32 33 Bibcode 2010Natur 464 32S doi 10 1038 464032a PMID 20203589 S2CID 205053626 ProQuest 204555310 F J Duarte and L W Hillman Eds Dye Laser Principles Academic New York 1990 Chapter 9 GE Signs Agreement With Silex Systems of Australia To Develop Uranium Enrichment Technology Press release GE Energy 22 May 2006 Archived from the original on 14 June 2006 GE Hitachi Nuclear Energy Selects Wilmington N C as Site for Potential Commercial Uranium Enrichment Facility Business Wire 30 April 2008 Retrieved 30 September 2012 Broad William J 20 August 2011 Laser Advances in Nuclear Fuel Stir Terror Fear The New York Times Retrieved 21 August 2011 Associated Press 27 September 2012 Uranium Plant Using Laser Technology Wins U S Approval The New York Times Becker E W Ehrfeld W Munchmeyer D Betz H Heuberger A Pongratz S Glashauser W Michel H J Siemens R 1982 Production of Separation Nozzle Systems for Uranium Enrichment by a Combination of X Ray Lithography and Galvanoplastics Naturwissenschaften 69 11 520 523 Bibcode 1982NW 69 520B doi 10 1007 BF00463495 S2CID 44245091 Smith Michael Jackson A G M 2000 Dr South African Institution of Chemical Engineers Conference 2000 280 289 Balakrishnan M R 1971 Economics of blending a case study PDF Bombay India Government of India Atomic Energy Commission p 6 Archived PDF from the original on 9 October 2022 Retrieved 7 November 2021 US Atomic Energy Commission January 1961 Costs of nuclear power Washington DC Office of Technical Services Dept of Commerce p 29 Retrieved 7 November 2021 Status Report USEC DOE Megatons to Megawatts Program USEC com 1 May 2000 Archived from the original on 6 April 2001 Megatons to Megawatts centrusenergy com December 2013 Makhijani Arjun Chalmers Lois Smith Brice 15 October 2004 Uranium enrichment PDF Institute for Energy and Environmental Research Archived PDF from the original on 9 October 2022 Retrieved 21 November 2009 Australia s uranium Greenhouse friendly fuel for an energy hungry world PDF Standing Committee on Industry and Resources Report The Parliament of the Commonwealth of Australia November 2006 p 730 Archived PDF from the original on 9 October 2022 Retrieved 3 April 2015 Q amp A Uranium enrichment BBC News BBC 1 September 2006 Retrieved 3 January 2010 Laser enrichment could cut cost of nuclear power The Sydney Morning Herald 26 May 2006 Weinberger Sharon 28 September 2012 US grants licence for uranium laser enrichment Nature doi 10 1038 nature 2012 11502 ISSN 1476 4687 S2CID 100862135 Israel s Nuclear Weapons Program Nuclear Weapon Archive 10 December 1997 Retrieved 7 October 2007 Burr William 22 December 2015 Strategic Air Command Declassifies Nuclear Target List from 1950s nsarchive2 gwu edu Retrieved 27 November 2020 Oralloy Oak Ridge alloy was a term of art for highly enriched uranium External links edit nbsp Look up enriched uranium in Wiktionary the free dictionary Annotated bibliography on enriched uranium from the Alsos Digital Library for Nuclear Issues Silex Systems Ltd Uranium Enrichment Archived 2 December 2010 at the Wayback Machine World Nuclear Association Overview and history of U S HEU production News Resource on Uranium Enrichment Nuclear Chemistry Uranium Enrichment Archived 15 October 2008 at the Wayback Machine A busy year for SWU a 2008 review of the commercial enrichment marketplace Nuclear Engineering International 1 September 2008 Uranium Enrichment and Nuclear Weapon Proliferation by Allan S Krass Peter Boskma Boelie Elzen and Wim A Smit 296 pp published for SIPRI by Taylor and Francis Ltd London 1983 Poliakoff Martyn 2009 How do you enrich Uranium The Periodic Table of Videos University of Nottingham Gilinsky V Hoehn W December 1969 The Military Significance of Small Uranium Enrichment Facilities Fed with Low Enrichment Uranium Redacted Defense Technical Information Center RAND Corporation OCLC 913595660 DTIC ADA613260 Retrieved from https en wikipedia org w index php title Enriched uranium amp oldid 1207640545, wikipedia, wiki, book, books, library,

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