Bauxite
Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (Y-AlO(OH)) and diaspore (α-AlO(OH)), mixed with the two iron oxides goethite (FeO(OH)) and haematite (Fe2O3), the aluminium clay mineral kaolinite (Al2Si2O5(OH)4) and small amounts of anatase (TiO2) and ilmenite (FeTiO3 or FeO.TiO2).[1] Bauxite appears dull in luster and is reddish-brown, white, or tan.[2]
In 1821, the French geologist Pierre Berthier discovered bauxite near the village of Les Baux in Provence, southern France.[3][4]
Formation
Numerous classification schemes have been proposed for bauxite but, as of 1982[update], there was no consensus.[5]
Vadász (1951) distinguished lateritic bauxites (silicate bauxites) from karst bauxite ores (carbonate bauxites):[5]
- The carbonate bauxites occur predominantly in Europe, Guyana, Suriname, and Jamaica above carbonate rocks (limestone and dolomite), where they were formed by lateritic weathering and residual accumulation of intercalated clay layers – dispersed clays which were concentrated as the enclosing limestones gradually dissolved during chemical weathering.
- The lateritic bauxites are found mostly in the countries of the tropics. They were formed by lateritization of various silicate rocks such as granite, gneiss, basalt, syenite, and shale. In comparison with the iron-rich laterites, the formation of bauxites depends even more on intense weathering conditions in a location with very good drainage. This enables the dissolution of the kaolinite and the precipitation of the gibbsite. Zones with highest aluminium content are frequently located below a ferruginous surface layer. The aluminium hydroxide in the lateritic bauxite deposits is almost exclusively gibbsite.
In the case of Jamaica, recent analysis of the soils showed elevated levels of cadmium, suggesting that the bauxite originates from Miocene volcanic ash deposits from episodes of significant volcanism in Central America.[citation needed]
Production and reserves
Australia is the largest producer of bauxite, followed by Guinea and China.[6] Increased aluminium recycling, which requires less electric power than producing aluminium from ores, will considerably extend the world's bauxite reserves.
| Country | Production | Reserves |
|---|---|---|
| World | 327,000 | 30,000,000 |
| Australia | 110,000 | 6,000,000 |
| Guinea | 82,000 | 7,400,000 |
| China | 60,000 | 1,000,000 |
| Brazil | 35,000 | 2,600,000 |
| Indonesia | 23,000 | 1,200,000 |
| India | 22,000 | 660,000 |
| Jamaica | 7,700 | 2,000,000 |
| Russia | 6,100 | 500,000 |
| Kazakhstan | 5,800 | 160,000 |
| Vietnam | 4,000 | 3,700,000 |
| Saudi Arabia | 4,000 | 200,000 |
| Greece | 1,800 | 250,000 |
| Guyana | 1,700 | 850,000 |
| Other countries | 9,000 | 3,740,000 |
Processing
Bauxite is usually strip mined because it is almost always found near the surface of the terrain, with little or no overburden. As of 2010[update], approximately 70% to 80% of the world's dry bauxite production is processed first into alumina and then into aluminium by electrolysis.[9] Bauxite rocks are typically classified according to their intended commercial application: metallurgical, abrasive, cement, chemical, and refractory.
Bauxite ore is usually heated in a pressure vessel along with a sodium hydroxide solution at a temperature of 150 to 200 °C (300 to 390 °F). At these temperatures, the aluminium is dissolved as sodium aluminate (the Bayer process). The aluminium compounds in the bauxite may be present as gibbsite(Al(OH)3), boehmite(AlOOH) or diaspore(AlOOH); the different forms of the aluminium component will dictate the extraction conditions. The undissolved waste, bauxite tailings, after the aluminium compounds are extracted contains iron oxides, silica, calcia, titania and some un-reacted alumina. After separation of the residue by filtering, pure gibbsite is precipitated when the liquid is cooled, and then seeded with fine-grained aluminium hydroxide. The gibbsite is usually converted into aluminium oxide, Al2O3, by heating in rotary kilns or fluid flash calciners to a temperature in excess of 1,000 °C (1,830 °F). This aluminium oxide is dissolved at a temperature of about 960 °C (1,760 °F) in molten cryolite. Next, this molten substance can yield metallic aluminium by passing an electric current through it in the process of electrolysis, which is called the Hall–Héroult process, named after its American and French discoverers.
Prior to the invention of this process, and prior to the Deville process, aluminium ore was refined by heating ore along with elemental sodium or potassium in a vacuum. The method was complicated and consumed materials that were themselves expensive at that time. This made early elemental aluminium more expensive than gold.[10]
Maritime safety
As a bulk cargo, Bauxite is a Group A cargo that may liquefy if excessively moist.[11] Liquefaction and the Free surface effect can cause the cargo to shift rapidly inside the hold and make the ship unstable, potentially sinking the ship. One vessel suspected to have been sunk in this way was the MS Bulk Jupiter in 2015.[12] One method which can demonstrate this effect is the Can test, in which a sample of the material is placed in a cylindrical can and struck against a surface many times.[13] If a moist slurry forms in the can, then there is a likelihood for the cargo to liquefy; although conversely, even if the sample remains dry it does not conclusively prove that it will remain that way, or that it is safe for loading.
Source of gallium
Bauxite is the main source of the rare metal gallium.[14]
During the processing of bauxite to alumina in the Bayer process, gallium accumulates in the sodium hydroxide liquor. From this it can be extracted by a variety of methods. The most recent is the use of ion-exchange resin.[15] Achievable extraction efficiencies critically depend on the original concentration in the feed bauxite. At a typical feed concentration of 50 ppm, about 15 percent of the contained gallium is extractable.[15] The remainder reports to the red mud and aluminium hydroxide streams.[16]
See also
References
- ^ . Archived from the original on 2016-04-16.
- ^ "Aluminum". Minerals Education Coalition.
- ^ P. Berthier (1821) "Analyse de l'alumine hydratée des Beaux, département des Bouches-du-Rhóne" (Analysis of hydrated alumina from Les Beaux, department of the Mouths-of-the-Rhone), Annales des mines, 1st series, 6 : 531-534. Notes:
- In 1847, in the cumulative index of volume 3 of his series, Traité de minéralogie, French mineralogist Armand Dufrénoy listed the hydrated alumina from Les Beaux as "beauxite". (See: A. Dufrénoy, Traité de minéralogie, volume 3 (Paris, France: Carilian-Goeury et Vor Dalmont, 1847), p. 799.)
- In 1861, H. Sainte-Claire Deville credits Berthier with naming "bauxite", on p. 309, "Chapitre 1. Minerais alumineux ou bauxite" of: H. Sainte-Claire Deville (1861) "De la présence du vanadium dans un minerai alumineux du midi de la France. Études analytiques sur les matières alumineuses." (On the presence of vanadium in an alumina mineral from the Midi of France. Analytical studies of aluminous substances.), Annales de Chimie et de Physique, 3rd series, 61 : 309-342.
- ^ Burgess, N. (October 26, 2015). "March 23, 1821: Bauxite Discovered". Earth. Retrieved 2021-07-31.
- ^ a b Bárdossy, G. (1982). Karst Bauxites. Amsterdam: Elsevier. p. 16. ISBN 978-0-444-99727-2.
- ^ "Bauxite and Alumina 2020 Annual Publication" (PDF). U.S. Geological Survey. January 2020. Archived (PDF) from the original on 2022-10-09. Retrieved 29 June 2020.
- ^ "World's Biggest Bauxite Producing Countries in 2018". AssetCharts.com. January 2020. Retrieved 10 September 2021.
- ^ "Bauxite and Alumina 2021 Annual Publication" (PDF). U.S. Geological Survey. January 2020. Retrieved 2 August 2021.
- ^ . Archived from the original on 2018-02-25. Retrieved 2018-04-01.
- ^ Michael Quinion (2006-01-23). "Aluminium versus aluminum". Worldwidewords.org. Retrieved 2011-12-19.
- ^ "IMSBC CODE GROUP A CARGOES". Baltic and International Maritime Council. Retrieved 21 November 2021.
- ^ "Bulk Jupiter sinking: A stark reminder of bauxite cargo risks". September 20, 2019. Retrieved 21 November 2021.
- ^ "What a Can Test Can Do". 8 February 2021. Retrieved 21 November 2021.
- ^ "Compilation of Gallium Resource Data for Bauxite Deposits Author: USGS" (PDF). Archived (PDF) from the original on 2022-10-09. Retrieved 2017-12-01.
- ^ a b Frenzel, Max; Ketris, Marina P.; Seifert, Thomas; Gutzmer, Jens (March 2016). "On the current and future availability of gallium". Resources Policy. 47: 38–50. doi:10.1016/j.resourpol.2015.11.005.
- ^ Moskalyk, R. R. (2003). "Gallium: the backbone of the electronics industry". Minerals Engineering. 16 (10): 921–929. doi:10.1016/j.mineng.2003.08.003.
Further reading
- Bárdossy, G. (1982): Karst Bauxites: Bauxite deposits on carbonate rocks. Elsevier Sci. Publ. 441 p.
- Bárdossy, G. and Aleva, G.J.J. (1990): Lateritic Bauxites. Developments in Economic Geology 27, Elsevier Sci. Publ. 624 p. ISBN 0-444-98811-4
- Grant, C.; Lalor, G. and Vutchkov, M. (2005) Comparison of bauxites from Jamaica, the Dominican Republic and Suriname. Journal of Radioanalytical and Nuclear Chemistry p. 385–388 Vol.266, No.3
- Hanilçi, N. (2013). Geological and geochemical evolution of the Bolkardaği bauxite deposits, Karaman, Turkey: Transformation from shale to bauxite. Journal of Geochemical Exploration
External links
- USGS Minerals Information: Bauxite
- . New International Encyclopedia. 1905.