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Gas to liquids

January 01, 1970

Gas to liquids (GTL) is a refinery process to convert natural gas or other gaseous hydrocarbons into longer-chain hydrocarbons, such as gasoline or diesel fuel. Methane-rich gases are converted into liquid synthetic fuels. Two general strategies exist: (i) direct partial combustion of methane to methanol and (ii) Fischer–Tropsch-like processes that convert carbon monoxide and hydrogen into hydrocarbons. Strategy ii is followed by diverse methods to convert the hydrogen-carbon monoxide mixtures to liquids. Direct partial combustion has been demonstrated in nature but not replicated commercially. Technologies reliant on partial combustion have been commercialized mainly in regions where natural gas is inexpensive.[1][2]

LNG tankers are used to transport methane.

The motivation for GTL is to produce liquid fuels, which are more readily transported than methane. Methane must be cooled below its critical temperature of -82.3 °C in order to be liquified under pressure. Because of the associated cryogenic apparatus, LNG tankers are used for transport. Methanol is a conveniently handled combustible liquid, but its energy density is half of that of gasoline.[3]

Fischer–Tropsch process edit

Main article: Fischer–Tropsch process
 
GTL process using the Fischer Tropsch method

A GtL process may be established via the Fischer–Tropsch process which comprises several chemical reactions that convert a mixture of carbon monoxide (CO) and hydrogen (H2) into long chained hydrocarbons. These hydrocarbons are typically liquid or semi-liquid and ideally have the formula (CnH2n+2).

In order to obtain the mixture of CO and H2 required for the Fischer–Tropsch process, methane (main component of natural gas) may be subjected to partial oxidation which yields a raw synthesis gas mixture of mostly carbon dioxide, carbon monoxide, hydrogen gas (and sometimes water and nitrogen).[4] The ratio of carbon monoxide to hydrogen in the raw synthesis gas mixture can be adjusted e.g. using the water gas shift reaction. Removing impurities, particularly nitrogen, carbon dioxide and water, from the raw synthesis gas mixture yields pure synthesis gas (syngas).

The pure syngas is routed into the Fischer–Tropsch process, where the syngas reacts over an iron or cobalt catalyst to produce synthetic hydrocarbons, including alcohols.

Methane to methanol process edit

Methanol is made from methane (natural gas) in a series of three reactions:

Steam reforming
CH4 + H2O → CO + 3 H2   ΔrH = +206 kJ mol−1
Water shift reaction
CO + H2O → CO2 + H2   ΔrH = -41 kJ mol−1
Synthesis
2 H2 + CO → CH3OH   ΔrH = -92 kJ mol−1

The methanol thus formed may be converted to gasoline by the Mobil process and methanol-to-olefins.

Methanol to gasoline (MTG) and methanol to olefins edit

In the early 1970s, Mobil developed an alternative procedure in which natural gas is converted to syngas, and then methanol. The methanol reacts in the presence of a zeolite catalyst to form alkanes. In terms of mechanism, methanol is partially dehydrated to give dimethyl ether:

2 CH3OH → CH3OCH3 + H2O

The mixture of dimethyl ether and methanol is then further dehydrated over a zeolite catalyst such as ZSM-5, which in practice is polymerized and hydrogenated to give a gasoline with hydrocarbons of five or more carbon atoms making up 80% of the fuel by weight. The Mobil MTG process is practiced from coal-derived methanol in China by JAMG. A more modern implementation of MTG is the Topsøe improved gasoline synthesis (TiGAS).[5]

Methanol can be converted to olefins using zeolite and SAPO-based heterogeneous catalysts. Depending on the catalyst pore size, this process can afford either C2 or C3 products, which are important monomers.[6][7]

Syngas to gasoline plus process (STG+) edit

Main article: Syngas to gasoline plus
 
The STG+ Process

A third gas-to-liquids process builds on the MTG technology by converting natural gas-derived syngas into drop-in gasoline and jet fuel via a thermochemical single-loop process.[8]

The STG+ process follows four principal steps in one continuous process loop. This process consists of four fixed bed reactors in series in which a syngas is converted to synthetic fuels. The steps for producing high-octane synthetic gasoline are as follows:[9]

  1. Methanol Synthesis: Syngas is fed to Reactor 1, the first of four reactors, which converts most of the syngas (CO and H2) to methanol (CH3OH) when passing through the catalyst bed.
  2. Dimethyl Ether (DME) Synthesis: The methanol-rich gas from Reactor 1 is next fed to Reactor 2, the second STG+ reactor. The methanol is exposed to a catalyst and much of it is converted to DME, which involves a dehydration from methanol to form DME (CH3OCH3).
  3. Gasoline synthesis: The Reactor 2 product gas is next fed to Reactor 3, the third reactor containing the catalyst for conversion of DME to hydrocarbons including paraffins (alkanes), aromatics, naphthenes (cycloalkanes) and small amounts of olefins (alkenes), mostly from C6 (number of carbon atoms in the hydrocarbon molecule) to C10.
  4. Gasoline Treatment: The fourth reactor provides transalkylation and hydrogenation treatment to the products coming from Reactor 3. The treatment reduces durene (tetramethylbenzene)/isodurene and trimethylbenzene components that have high freezing points and must be minimized in gasoline. As a result, the synthetic gasoline product has high octane and desirable viscometric properties.
  5. Separator: Finally, the mixture from Reactor 4 is condensed to obtain gasoline. The non-condensed gas and gasoline are separated in a conventional condenser/separator. Most of the non-condensed gas from the product separator becomes recycled gas and is sent back to the feed stream to Reactor 1, leaving the synthetic gasoline product composed of paraffins, aromatics and naphthenes.

Biological gas-to-liquids (Bio-GTL) edit

With methane as the predominant target for GTL, much attention has focused on the three enzymes that process methane. These enzymes support the existence of methanotrophs, microorganisms that metabolize methane as their only source of carbon and energy. Aerobic methanotrophs harbor enzymes that oxygenate methane to methanol. The relevant enzymes are methane monooxygenases, which are found both in soluble and particulate (i.e. membrane-bound) varieties. They catalyze the oxygenation according to the following stoichiometry:

CH4 + O2 + NADPH + H+ → CH3OH + H2O + NAD+

Anaerobic methanotrophs rely on the bioconversion of methane using the enzymes called methyl-coenzyme M reductases. These organisms effect reverse methanogenesis. Strenuous efforts have been made to elucidate the mechanisms of these methane-converting enzymes, which would enable their catalysis to be replicated in vitro.[10]

Biodiesel can be made from CO2 using the microbes Moorella thermoacetica and Yarrowia lipolytica. This process is known as biological gas-to-liquids.[11]

Commercial uses edit

 
INFRA M100 GTL Plant

Using gas-to-liquids processes, refineries can convert some of their gaseous waste products (flare gas) into valuable fuel oils, which can be sold as is or blended only with diesel fuel. The World Bank estimates that over 150 billion cubic metres (5.3×10^12 cu ft) of natural gas are flared or vented annually, an amount worth approximately $30.6 billion, equivalent to 25% of the United States' gas consumption or 30% of the European Union's annual gas consumption,[12] a resource that could be useful using GTL. Gas-to-liquids processes may also be used for the economic extraction of gas deposits in locations where it is not economical to build a pipeline. This process will be increasingly significant as crude oil resources are depleted.

Royal Dutch Shell produces a diesel from natural gas in a factory in Bintulu, Malaysia. Another Shell GTL facility is the Pearl GTL plant in Qatar, the world's largest GTL facility.[13][14] SASOL has recently built the Oryx GTL facility in Ras Laffan Industrial City, Qatar and together with Uzbekneftegaz and Petronas builds the Uzbekistan GTL plant.[15][16][17] Chevron Corporation, in a joint venture with the Nigerian National Petroleum Corporation is commissioning the Escravos GTL in Nigeria, which uses Sasol technology. PetroSA,  South Africa's national oil company,  owns and operates a 22,000 barrels/day (capacity) GTL plant in Mossel Bay, using Sasol GTL technology.[18]  

Aspirational and emerging ventures edit

New generation of GTL technology is being pursued for the conversion of unconventional, remote and problem gas into valuable liquid fuels.[19][20] GTL plants based on innovative Fischer–Tropsch catalysts have been built by INFRA Technology. Other mainly U.S. companies include Velocys, ENVIA Energy, Waste Management, NRG Energy, ThyssenKrupp Industrial Solutions, Liberty GTL, Petrobras,[21] Greenway Innovative Energy,[22] Primus Green Energy,[23] Compact GTL,[24] and Petronas.[25] Several of these processes have proven themselves with demonstration flights using their jet fuels.[26][27]

Another proposed solution to stranded gas involves use of novel FPSO for offshore conversion of gas to liquids such as methanol, diesel, petrol, synthetic crude, and naphtha.[28]

Economics of GTL edit

GTL using natural gas is more economical when there is wide gap between the prevailing natural gas price and crude oil price on a Barrel of oil equivalent (BOE) basis. A coefficient of 0.1724 results in full oil parity.[29] GTL is a mechanism to bring down the diesel/gasoline/crude oil international prices at par with the natural gas price in an expanding global natural gas production at cheaper than crude oil price. When natural gas is converted in to GTL, the liquid products are easier to export at cheaper price rather than converting in to LNG and further conversion to liquid products in an importing country.[30][31]

However, GTL fuels are much more expensive to produce than conventional fuels.[32]

See also edit

Bibliography edit

  • Boogaard, P. J., Carrillo, J. C., Roberts, L. G., & Whale, G. F. (2017) Toxicological and ecotoxicological properties of gas-to-liquid (GTL) products. 1. Mammalian toxicology. Critical reviews in toxicology, 47(2), 121-144.

References edit

  1. ^ Höök, Mikael; Fantazzini, Dean; Angelantoni, André; Snowden, Simon (2013). "Hydrocarbon liquefaction: viability as a peak oil mitigation strategy". Philosophical Transactions of the Royal Society A. 372 (2006): 20120319. Bibcode:2013RSPTA.37220319H. doi:10.1098/rsta.2012.0319. PMID 24298075. Retrieved 2009-06-03.
  2. ^ Kaneko, Takao; Derbyshire, Frank; Makino, Eiichiro; Gray, David; Tamura, Masaaki (2001). "Coal Liquefaction". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a07_197. ISBN 978-3-527-30673-2.
  3. ^ "Alternative Fuels Data Center: Fuel Properties Comparison".
  4. ^ "Gas POX - Natural Gas Partial Oxidation". Air Liquide. 2016-03-18. Retrieved 2021-02-18.
  5. ^ Olsbye, U.; Svelle, S.; Bjorgen, M.; Beato, P.; Janssens, T. V. W.; Joensen, F.; Bordiga, S.; Lillerud, K. P. (2012). "Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity". Angew. Chem. Int. Ed. 51 (24): 5810–5831. doi:10.1002/anie.201103657. hdl:2318/122770. PMID 22511469. S2CID 26585752.
  6. ^ Tian, P.; Wei, Y.; Ye, M.; Liu, Z. (2015). "Methanol to Olefins (MTO): From Fundamentals to Commercialization". ACS Catal. 5 (3): 1922–1938. doi:10.1021/acscatal.5b00007.
  7. ^ Ismaël Amghizar; Laurien A. Vandewalle; Kevin M. Van Geem; Guy B. Marin (2017). "New Trends in Olefin Production". Engineering. 3 (2): 171–178. doi:10.1016/J.ENG.2017.02.006.
  8. ^ LaMonica, Martin. Natural Gas Tapped as Bridge to Biofuels MIT Technology Review, 27 June 2012. Retrieved: 7 March 2013.
  9. ^ Introduction to Primus' STG+ Technology Primus Green Energy, undated. Retrieved: 5 March 2013.
  10. ^ Lawton, T. J.; Rosenzweig, A. C. (2016). "Biocatalysts for methane conversion: big progress on breaking a small substrate". Curr. Opin. Chem. Biol. 35: 142–149. doi:10.1016/j.cbpa.2016.10.001. PMC 5161620. PMID 27768948.
  11. ^ Microbes paired for biological gas-to-liquids (Bio-GTL) process
  12. ^ World Bank, GGFR Partners Unlock Value of Wasted Gas", World Bank 14 December 2009. Retrieved 17 March 2010.
  13. ^ "Pearl Gas-to-Liquids Plant, Ras Laffan, Qatar". Retrieved 2009-06-22.
  14. ^ Gold, Russell (4 April 2012). "Shell Weighs Natural Gas-to-Diesel Processing Facility for Louisiana". Wall Street Journal. Retrieved 2012-05-05.
  15. ^ "Petronas signs Uzbek GTL pact". Upstream Online. NHST Media Group. 2009-04-08. Retrieved 2009-07-18.
  16. ^ "Malaysia's Petronas in Uzbekistan oil-production deal". Reuters. 2009-05-14. Retrieved 2009-07-18.
  17. ^ "Contract let for GTL plant in Uzbekistan". Oil & Gas Journal. PennWell Corporation. 2010-03-08. Retrieved 2010-03-14.
  18. ^ Wood, D.A.; et al. (November 2021). "A review of an industry offering several routes for monetizing natural gas". Journal of Natural Gas Science and Engineering. 9: 196–209. doi:10.1016/j.jngse.2012.07.001.
  19. ^ "Smaller-scale and modular technologies drive GTL industry forward".
  20. ^ Popov, Dmitry. "Unlocking the value of stranded and remote offshore gas assets".
  21. ^ Chetwynd, Gareth (20 January 2012). "Petrobras puts gas flares out of fashion with GTL" (PDF). CompactGTL.
  22. ^ "Greenway Technologies Inc. Marks Milestone, Completes First Commercial G-Reformer®" (Press release). 7 March 2018.
  23. ^ . Primus Green Energy. November 7, 2013. Archived from the original on 2015-09-24.
  24. ^ Fairley, Peter (15 March 2010). "Turning Gas Flares into Fuel". MIT Technology Review.
  25. ^ "UPDATE 2-Malaysia's Petronas in Uzbekistan oil-production deal". Reuters. 14 May 2008.
  26. ^ "Qatar Airways Makes GTL History".
  27. ^ "A380 makes test flight on alternative fuel". Reuters. February 2008.
  28. ^ "Innovative Engineering in Energy Technologies". Bpp-Tech. Retrieved 2014-04-12.
  29. ^ Hecht, Andrew (6 January 2020). "Crude Oil vs Natural Gas". The Balance.
  30. ^ "Turkmenistan gas-to-liquids refinery ships first synthetic gasoline to Afghanistan". Retrieved 25 December 2019.
  31. ^ "Uzbekistan borrows $2.3 billion for gas-to-liquids plant project". Retrieved 25 December 2019.
  32. ^ Qatar Airways Flies Plane With New Fuel, The Wall Street Journal, Wednesday, October 14, 2009, p.B2

January 01, 1970
liquids, refinery, process, convert, natural, other, gaseous, hydrocarbons, into, longer, chain, hydrocarbons, such, gasoline, diesel, fuel, methane, rich, gases, converted, into, liquid, synthetic, fuels, general, strategies, exist, direct, partial, combustio. Gas to liquids GTL is a refinery process to convert natural gas or other gaseous hydrocarbons into longer chain hydrocarbons such as gasoline or diesel fuel Methane rich gases are converted into liquid synthetic fuels Two general strategies exist i direct partial combustion of methane to methanol and ii Fischer Tropsch like processes that convert carbon monoxide and hydrogen into hydrocarbons Strategy ii is followed by diverse methods to convert the hydrogen carbon monoxide mixtures to liquids Direct partial combustion has been demonstrated in nature but not replicated commercially Technologies reliant on partial combustion have been commercialized mainly in regions where natural gas is inexpensive 1 2 LNG tankers are used to transport methane The motivation for GTL is to produce liquid fuels which are more readily transported than methane Methane must be cooled below its critical temperature of 82 3 C in order to be liquified under pressure Because of the associated cryogenic apparatus LNG tankers are used for transport Methanol is a conveniently handled combustible liquid but its energy density is half of that of gasoline 3 Contents 1 Fischer Tropsch process 2 Methane to methanol process 3 Methanol to gasoline MTG and methanol to olefins 4 Syngas to gasoline plus process STG 5 Biological gas to liquids Bio GTL 6 Commercial uses 6 1 Aspirational and emerging ventures 7 Economics of GTL 8 See also 9 Bibliography 10 ReferencesFischer Tropsch process editMain article Fischer Tropsch process nbsp GTL process using the Fischer Tropsch method A GtL process may be established via the Fischer Tropsch process which comprises several chemical reactions that convert a mixture of carbon monoxide CO and hydrogen H2 into long chained hydrocarbons These hydrocarbons are typically liquid or semi liquid and ideally have the formula CnH2n 2 In order to obtain the mixture of CO and H2 required for the Fischer Tropsch process methane main component of natural gas may be subjected to partial oxidation which yields a raw synthesis gas mixture of mostly carbon dioxide carbon monoxide hydrogen gas and sometimes water and nitrogen 4 The ratio of carbon monoxide to hydrogen in the raw synthesis gas mixture can be adjusted e g using the water gas shift reaction Removing impurities particularly nitrogen carbon dioxide and water from the raw synthesis gas mixture yields pure synthesis gas syngas The pure syngas is routed into the Fischer Tropsch process where the syngas reacts over an iron or cobalt catalyst to produce synthetic hydrocarbons including alcohols Methane to methanol process editMethanol is made from methane natural gas in a series of three reactions Steam reforming CH4 H2O CO 3 H2 DrH 206 kJ mol 1 Water shift reaction CO H2O CO2 H2 DrH 41 kJ mol 1 Synthesis 2 H2 CO CH3OH DrH 92 kJ mol 1 The methanol thus formed may be converted to gasoline by the Mobil process and methanol to olefins Methanol to gasoline MTG and methanol to olefins editIn the early 1970s Mobil developed an alternative procedure in which natural gas is converted to syngas and then methanol The methanol reacts in the presence of a zeolite catalyst to form alkanes In terms of mechanism methanol is partially dehydrated to give dimethyl ether 2 CH3OH CH3OCH3 H2O The mixture of dimethyl ether and methanol is then further dehydrated over a zeolite catalyst such as ZSM 5 which in practice is polymerized and hydrogenated to give a gasoline with hydrocarbons of five or more carbon atoms making up 80 of the fuel by weight The Mobil MTG process is practiced from coal derived methanol in China by JAMG A more modern implementation of MTG is the Topsoe improved gasoline synthesis TiGAS 5 Methanol can be converted to olefins using zeolite and SAPO based heterogeneous catalysts Depending on the catalyst pore size this process can afford either C2 or C3 products which are important monomers 6 7 Syngas to gasoline plus process STG editMain article Syngas to gasoline plus nbsp The STG Process A third gas to liquids process builds on the MTG technology by converting natural gas derived syngas into drop in gasoline and jet fuel via a thermochemical single loop process 8 The STG process follows four principal steps in one continuous process loop This process consists of four fixed bed reactors in series in which a syngas is converted to synthetic fuels The steps for producing high octane synthetic gasoline are as follows 9 Methanol Synthesis Syngas is fed to Reactor 1 the first of four reactors which converts most of the syngas CO and H2 to methanol CH3OH when passing through the catalyst bed Dimethyl Ether DME Synthesis The methanol rich gas from Reactor 1 is next fed to Reactor 2 the second STG reactor The methanol is exposed to a catalyst and much of it is converted to DME which involves a dehydration from methanol to form DME CH3OCH3 Gasoline synthesis The Reactor 2 product gas is next fed to Reactor 3 the third reactor containing the catalyst for conversion of DME to hydrocarbons including paraffins alkanes aromatics naphthenes cycloalkanes and small amounts of olefins alkenes mostly from C6 number of carbon atoms in the hydrocarbon molecule to C10 Gasoline Treatment The fourth reactor provides transalkylation and hydrogenation treatment to the products coming from Reactor 3 The treatment reduces durene tetramethylbenzene isodurene and trimethylbenzene components that have high freezing points and must be minimized in gasoline As a result the synthetic gasoline product has high octane and desirable viscometric properties Separator Finally the mixture from Reactor 4 is condensed to obtain gasoline The non condensed gas and gasoline are separated in a conventional condenser separator Most of the non condensed gas from the product separator becomes recycled gas and is sent back to the feed stream to Reactor 1 leaving the synthetic gasoline product composed of paraffins aromatics and naphthenes Biological gas to liquids Bio GTL editWith methane as the predominant target for GTL much attention has focused on the three enzymes that process methane These enzymes support the existence of methanotrophs microorganisms that metabolize methane as their only source of carbon and energy Aerobic methanotrophs harbor enzymes that oxygenate methane to methanol The relevant enzymes are methane monooxygenases which are found both in soluble and particulate i e membrane bound varieties They catalyze the oxygenation according to the following stoichiometry CH4 O2 NADPH H CH3OH H2O NAD Anaerobic methanotrophs rely on the bioconversion of methane using the enzymes called methyl coenzyme M reductases These organisms effect reverse methanogenesis Strenuous efforts have been made to elucidate the mechanisms of these methane converting enzymes which would enable their catalysis to be replicated in vitro 10 Biodiesel can be made from CO2 using the microbes Moorella thermoacetica and Yarrowia lipolytica This process is known as biological gas to liquids 11 Commercial uses edit nbsp INFRA M100 GTL PlantUsing gas to liquids processes refineries can convert some of their gaseous waste products flare gas into valuable fuel oils which can be sold as is or blended only with diesel fuel The World Bank estimates that over 150 billion cubic metres 5 3 10 12 cu ft of natural gas are flared or vented annually an amount worth approximately 30 6 billion equivalent to 25 of the United States gas consumption or 30 of the European Union s annual gas consumption 12 a resource that could be useful using GTL Gas to liquids processes may also be used for the economic extraction of gas deposits in locations where it is not economical to build a pipeline This process will be increasingly significant as crude oil resources are depleted Royal Dutch Shell produces a diesel from natural gas in a factory in Bintulu Malaysia Another Shell GTL facility is the Pearl GTL plant in Qatar the world s largest GTL facility 13 14 SASOL has recently built the Oryx GTL facility in Ras Laffan Industrial City Qatar and together with Uzbekneftegaz and Petronas builds the Uzbekistan GTL plant 15 16 17 Chevron Corporation in a joint venture with the Nigerian National Petroleum Corporation is commissioning the Escravos GTL in Nigeria which uses Sasol technology PetroSA South Africa s national oil company owns and operates a 22 000 barrels day capacity GTL plant in Mossel Bay using Sasol GTL technology 18 Aspirational and emerging ventures edit New generation of GTL technology is being pursued for the conversion of unconventional remote and problem gas into valuable liquid fuels 19 20 GTL plants based on innovative Fischer Tropsch catalysts have been built by INFRA Technology Other mainly U S companies include Velocys ENVIA Energy Waste Management NRG Energy ThyssenKrupp Industrial Solutions Liberty GTL Petrobras 21 Greenway Innovative Energy 22 Primus Green Energy 23 Compact GTL 24 and Petronas 25 Several of these processes have proven themselves with demonstration flights using their jet fuels 26 27 Another proposed solution to stranded gas involves use of novel FPSO for offshore conversion of gas to liquids such as methanol diesel petrol synthetic crude and naphtha 28 Economics of GTL editGTL using natural gas is more economical when there is wide gap between the prevailing natural gas price and crude oil price on a Barrel of oil equivalent BOE basis A coefficient of 0 1724 results in full oil parity 29 GTL is a mechanism to bring down the diesel gasoline crude oil international prices at par with the natural gas price in an expanding global natural gas production at cheaper than crude oil price When natural gas is converted in to GTL the liquid products are easier to export at cheaper price rather than converting in to LNG and further conversion to liquid products in an importing country 30 31 However GTL fuels are much more expensive to produce than conventional fuels 32 See also editBiomass to liquid Carbon neutral fuel Coal to liquidBibliography editBoogaard P J Carrillo J C Roberts L G amp Whale G F 2017 Toxicological and ecotoxicological properties of gas to liquid GTL products 1 Mammalian toxicology Critical reviews in toxicology 47 2 121 144 References edit Hook Mikael Fantazzini Dean Angelantoni Andre Snowden Simon 2013 Hydrocarbon liquefaction viability as a peak oil mitigation strategy Philosophical Transactions of the Royal Society A 372 2006 20120319 Bibcode 2013RSPTA 37220319H doi 10 1098 rsta 2012 0319 PMID 24298075 Retrieved 2009 06 03 Kaneko Takao Derbyshire Frank Makino Eiichiro Gray David Tamura Masaaki 2001 Coal Liquefaction Ullmann s Encyclopedia of Industrial Chemistry Weinheim Wiley VCH doi 10 1002 14356007 a07 197 ISBN 978 3 527 30673 2 Alternative Fuels Data Center Fuel Properties Comparison Gas POX Natural Gas Partial Oxidation Air Liquide 2016 03 18 Retrieved 2021 02 18 Olsbye U Svelle S Bjorgen M Beato P Janssens T V W Joensen F Bordiga S Lillerud K P 2012 Conversion of Methanol to Hydrocarbons How Zeolite Cavity and Pore Size Controls Product Selectivity Angew Chem Int Ed 51 24 5810 5831 doi 10 1002 anie 201103657 hdl 2318 122770 PMID 22511469 S2CID 26585752 Tian P Wei Y Ye M Liu Z 2015 Methanol to Olefins MTO From Fundamentals to Commercialization ACS Catal 5 3 1922 1938 doi 10 1021 acscatal 5b00007 Ismael Amghizar Laurien A Vandewalle Kevin M Van Geem Guy B Marin 2017 New Trends in Olefin Production Engineering 3 2 171 178 doi 10 1016 J ENG 2017 02 006 LaMonica Martin Natural Gas Tapped as Bridge to Biofuels MIT Technology Review 27 June 2012 Retrieved 7 March 2013 Introduction to Primus STG Technology Primus Green Energy undated Retrieved 5 March 2013 Lawton T J Rosenzweig A C 2016 Biocatalysts for methane conversion big progress on breaking a small substrate Curr Opin Chem Biol 35 142 149 doi 10 1016 j cbpa 2016 10 001 PMC 5161620 PMID 27768948 Microbes paired for biological gas to liquids Bio GTL process World Bank GGFR Partners Unlock Value of Wasted Gas World Bank 14 December 2009 Retrieved 17 March 2010 Pearl Gas to Liquids Plant Ras Laffan Qatar Retrieved 2009 06 22 Gold Russell 4 April 2012 Shell Weighs Natural Gas to Diesel Processing Facility for Louisiana Wall Street Journal Retrieved 2012 05 05 Petronas signs Uzbek GTL pact Upstream Online NHST Media Group 2009 04 08 Retrieved 2009 07 18 Malaysia s Petronas in Uzbekistan oil production deal Reuters 2009 05 14 Retrieved 2009 07 18 Contract let for GTL plant in Uzbekistan Oil amp Gas Journal PennWell Corporation 2010 03 08 Retrieved 2010 03 14 Wood D A et al November 2021 A review of an industry offering several routes for monetizing natural gas Journal of Natural Gas Science and Engineering 9 196 209 doi 10 1016 j jngse 2012 07 001 Smaller scale and modular technologies drive GTL industry forward Popov Dmitry Unlocking the value of stranded and remote offshore gas assets Chetwynd Gareth 20 January 2012 Petrobras puts gas flares out of fashion with GTL PDF CompactGTL Greenway Technologies Inc Marks Milestone Completes First Commercial G Reformer Press release 7 March 2018 Primus Green Energy Demonstration Plant Operating Results Confirm Compelling Performance and Economics According to Independent Engineers Report Primus Green Energy November 7 2013 Archived from the original on 2015 09 24 Fairley Peter 15 March 2010 Turning Gas Flares into Fuel MIT Technology Review UPDATE 2 Malaysia s Petronas in Uzbekistan oil production deal Reuters 14 May 2008 Qatar Airways Makes GTL History A380 makes test flight on alternative fuel Reuters February 2008 Innovative Engineering in Energy Technologies Bpp Tech Retrieved 2014 04 12 Hecht Andrew 6 January 2020 Crude Oil vs Natural Gas The Balance Turkmenistan gas to liquids refinery ships first synthetic gasoline to Afghanistan Retrieved 25 December 2019 Uzbekistan borrows 2 3 billion for gas to liquids plant project Retrieved 25 December 2019 Qatar Airways Flies Plane With New Fuel The Wall Street Journal Wednesday October 14 2009 p B2 Retrieved from https en wikipedia org w index php title Gas to liquids amp oldid 1217200694, wikipedia, wiki, book, books, library,

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