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Dutch process cocoa

Dutch processed cocoa, Dutch cocoa, or alkalized cocoa, is cocoa solids that have been treated with an alkalizing agent to reduce the natural acidity of cocoa, giving it a less bitter taste (and darker colour) compared to "natural cocoa" extracted with the Broma process. It forms the basis for much of modern chocolate, and is used in ice cream, hot chocolate, and baking.

Dutch processed cocoa
Dutch process cocoa (left) compared to natural cocoa (right)
Alternative namesDutched cocoa
TypeCocoa
Place of originNetherlands
Created byCoenraad Johannes van Houten
Main ingredientsCocoa powder, alkalizing agent

Alkalizing agents employed vary, but include potassium carbonate (E501), sodium carbonate (E500), and/or sodium hydroxide (E525).

Dutching greatly reduces the levels of certain phytochemicals in cocoa.

Baking chocolate, unsweetened, squares
Nutritional value per 100 g (3.5 oz)
Energy922 kJ (220 kcal)
58.3 g
Sugars1.76
Dietary fiber29.8 g
13.1 g
18.1 g
Other constituentsQuantity
Water2.7 g
Caffeine78 mg
Theobromine2630 mg

Link to USDA Database entry
Percentages estimated using US recommendations for adults,[1] except for potassium, which is estimated based on expert recommendation from the National Academies.[2]

History edit

The Dutch process was developed in the early 19th century by Dutch chocolate maker Coenraad Johannes van Houten, whose father Casparus was responsible for the development of the method of removing fat from cocoa beans by hydraulic press around 1828, forming the basis for cocoa powder. These developments greatly expanded the use of cocoa, and reduced the oiliness that was previously associated with cocoa.[3]

Colour edit

The quantity of alkalizing agent is not specified on the ingredients on cocoa powder. However, this may be figured out by comparing the brown shades between different products. Higher quantities of alkalizing agents will produce cocoa that is darker than cocoa with lower quantities.

Cooking properties edit

Dutch processed cocoa has a neutral pH, and is not acidic like natural cocoa, so in recipes that use sodium bicarbonate (baking soda) as the leavening agent (which relies on the acidity of the cocoa to activate it), an acid must be added to the recipe, such as cream of tartar or the use of buttermilk instead of fresh milk. There is no need to add acidity when Dutch process cocoa (or natural cocoa) is used in recipes that use baking powder instead of soda for leavening.[4]

Reduction of phytochemicals edit

Caffeine edit

Dutch cocoa contains 3 times less caffeine:

  • 100 grams unsweetened cocoa powder processed with alkali contains 78 mg.[5]
  • 100 grams unsweetened cocoa powder without alkali contains 230 mg.[6]

Antioxidants and flavonols edit

Compared to other processes, Dutch process cocoa contains lower amounts of flavonols (antioxidants).[7] The effect this has on nutritional value is disputed. Professor Irmgard Bitsch of the Institut für Ernährungswissenschaft, Justus-Liebig-University Giessen claims that the reduction of antioxidants due to the process is not significant and enough polyphenols and procyanidins remain in the cocoa.[8] One study determined that 60% of natural cocoa's original antioxidants were destroyed by light dutching and 90% were destroyed by heavy dutching.[9] Natural cocoa has such high levels of antioxidants that even a 60% reduction leaves it high on the list of antioxidant-rich foods.[10]

References edit

  1. ^ United States Food and Drug Administration (2024). "Daily Value on the Nutrition and Supplement Facts Labels". Retrieved 28 March 2024.
  2. ^ National Academies of Sciences, Engineering, and Medicine; Health and Medicine Division; Food and Nutrition Board; Committee to Review the Dietary Reference Intakes for Sodium and Potassium (2019). Oria, Maria; Harrison, Meghan; Stallings, Virginia A. (eds.). Dietary Reference Intakes for Sodium and Potassium. The National Academies Collection: Reports funded by National Institutes of Health. Washington (DC): National Academies Press (US). ISBN 978-0-309-48834-1. PMID 30844154.{{cite book}}: CS1 maint: multiple names: authors list (link)
  3. ^ Goldstein, D. (2015). The Oxford Companion to Sugar and Sweets. Oxford Companions. Oxford University Press. p. 762-763. ISBN 978-0-19-931339-6. Retrieved 26 May 2023.
  4. ^ "Cocoa Powder". Joyofbaking.com. Retrieved 27 May 2013.
  5. ^ "FoodData Central". fdc.nal.usda.gov.
  6. ^ "FoodData Central". fdc.nal.usda.gov.
  7. ^ "Chocolate Terms". Thenibble.com. Retrieved 27 May 2013.
  8. ^ . medizinauskunft.de. Archived from the original on 14 May 2016. Retrieved 1 October 2016.
  9. ^ "New study re-emphasizes natural cocoa powder has high antioxidant content". Eurekalert.org. 8 October 2008. Retrieved 27 May 2013.
  10. ^ Crozier, S. J.; Preston, A. G.; Hurst, J. W.; Payne, M. J.; Mann, J.; Hainly, L.; Miller, D. L. (7 February 2011). "Cacao seeds are a "Super Fruit": A comparative analysis of various fruit powders and products". Chemistry Central Journal. 5 (5). Chem Cent J.: 5. doi:10.1186/1752-153X-5-5. PMC 3038885. PMID 21299842.

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Dutch processed cocoa Dutch cocoa or alkalized cocoa is cocoa solids that have been treated with an alkalizing agent to reduce the natural acidity of cocoa giving it a less bitter taste and darker colour compared to natural cocoa extracted with the Broma process It forms the basis for much of modern chocolate and is used in ice cream hot chocolate and baking Dutch processed cocoaDutch process cocoa left compared to natural cocoa right Alternative namesDutched cocoaTypeCocoaPlace of originNetherlandsCreated byCoenraad Johannes van HoutenMain ingredientsCocoa powder alkalizing agentAlkalizing agents employed vary but include potassium carbonate E501 sodium carbonate E500 and or sodium hydroxide E525 Dutching greatly reduces the levels of certain phytochemicals in cocoa Baking chocolate unsweetened squaresNutritional value per 100 g 3 5 oz Energy922 kJ 220 kcal Carbohydrates58 3 gSugars1 76Dietary fiber29 8 gFat13 1 gProtein18 1 gOther constituentsQuantityWater2 7 gCaffeine78 mgTheobromine2630 mgLink to USDA Database entry Percentages estimated using US recommendations for adults 1 except for potassium which is estimated based on expert recommendation from the National Academies 2 Contents 1 History 2 Colour 3 Cooking properties 4 Reduction of phytochemicals 4 1 Caffeine 4 2 Antioxidants and flavonols 5 ReferencesHistory editThe Dutch process was developed in the early 19th century by Dutch chocolate maker Coenraad Johannes van Houten whose father Casparus was responsible for the development of the method of removing fat from cocoa beans by hydraulic press around 1828 forming the basis for cocoa powder These developments greatly expanded the use of cocoa and reduced the oiliness that was previously associated with cocoa 3 Colour editThe quantity of alkalizing agent is not specified on the ingredients on cocoa powder However this may be figured out by comparing the brown shades between different products Higher quantities of alkalizing agents will produce cocoa that is darker than cocoa with lower quantities Cooking properties editDutch processed cocoa has a neutral pH and is not acidic like natural cocoa so in recipes that use sodium bicarbonate baking soda as the leavening agent which relies on the acidity of the cocoa to activate it an acid must be added to the recipe such as cream of tartar or the use of buttermilk instead of fresh milk There is no need to add acidity when Dutch process cocoa or natural cocoa is used in recipes that use baking powder instead of soda for leavening 4 Reduction of phytochemicals editCaffeine edit Dutch cocoa contains 3 times less caffeine 100 grams unsweetened cocoa powder processed with alkali contains 78 mg 5 100 grams unsweetened cocoa powder without alkali contains 230 mg 6 Antioxidants and flavonols edit Compared to other processes Dutch process cocoa contains lower amounts of flavonols antioxidants 7 The effect this has on nutritional value is disputed Professor Irmgard Bitsch of the Institut fur Ernahrungswissenschaft Justus Liebig University Giessen claims that the reduction of antioxidants due to the process is not significant and enough polyphenols and procyanidins remain in the cocoa 8 One study determined that 60 of natural cocoa s original antioxidants were destroyed by light dutching and 90 were destroyed by heavy dutching 9 Natural cocoa has such high levels of antioxidants that even a 60 reduction leaves it high on the list of antioxidant rich foods 10 References edit United States Food and Drug Administration 2024 Daily Value on the Nutrition and Supplement Facts Labels Retrieved 28 March 2024 National Academies of Sciences Engineering and Medicine Health and Medicine Division Food and Nutrition Board Committee to Review the Dietary Reference Intakes for Sodium and Potassium 2019 Oria Maria Harrison Meghan Stallings Virginia A eds Dietary Reference Intakes for Sodium and Potassium The National Academies Collection Reports funded by National Institutes of Health Washington DC National Academies Press US ISBN 978 0 309 48834 1 PMID 30844154 a href Template Cite book html title Template Cite book cite book a CS1 maint multiple names authors list link Goldstein D 2015 The Oxford Companion to Sugar and Sweets Oxford Companions Oxford University Press p 762 763 ISBN 978 0 19 931339 6 Retrieved 26 May 2023 Cocoa Powder Joyofbaking com Retrieved 27 May 2013 FoodData Central fdc nal usda gov FoodData Central fdc nal usda gov Chocolate Terms Thenibble com Retrieved 27 May 2013 Kakao und Schokolade Die geheimen Gesundmacher medizinauskunft de Archived from the original on 14 May 2016 Retrieved 1 October 2016 New study re emphasizes natural cocoa powder has high antioxidant content Eurekalert org 8 October 2008 Retrieved 27 May 2013 Crozier S J Preston A G Hurst J W Payne M J Mann J Hainly L Miller D L 7 February 2011 Cacao seeds are a Super Fruit A comparative analysis of various fruit powders and products Chemistry Central Journal 5 5 Chem Cent J 5 doi 10 1186 1752 153X 5 5 PMC 3038885 PMID 21299842 Retrieved from https en wikipedia org w index php title Dutch process cocoa amp oldid 1196425108, wikipedia, wiki, book, books, library,

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