Copper selenide is an inorganicbinary compound between copper and selenium. The chemical formula depends on the ratio between the two elements, such as CuSe or Cu2Se.
The crystalline structure and electronic behavior is determined by its elemental composition.[2]Stoichiometric copper selenide is a zero bandgap material with metal-like behavior.[3] Copper-deficient Cu2-xSe (non-stoichiometric) is an intrinsic p-type semiconductor with direct and indirect bandgap energies in the range of 2.1–2.3 eV and 1.2–1.4 eV, respectively.[4] It is frequently grown as nanoparticles or other nanostructures.[5][6][7]
Copper selenide is produced in-situ to form a protective black coating on iron or steel parts in some cold-bluing processes.[8] Bluing solutions that operate in this manner will typically be labeled as containing selenous acid or selenium dioxide.[9][10] It has also been investigated for use in the treatment of colon cancer.[6]
Natural occurrencesedit
Copper selenides are the most common selenium minerals. CuSe is known in mineralogy as klockmannite,[11] while Cu2Se occurs as two polymorphs, berzelianite[12] (isometric, more common) and bellidoite (tetragonal). There are more natural Cu selenides to date, including umangite, Cu3Se2 and athabascaite, Cu5Se4.[13]
^"Copper (I) selenide". Sigma-Aldrich. Retrieved 12 April 2016.
^Lanling, Zhao; Wang, Xiaolin; F. Yun, Frank (5 February 2015). "The Effects of Te2− and I− Substitutions on the Electronic Structures, Thermoelectric Performance, and Hardness in Melt-Quenched Highly Dense Cu2-xSe". Advanced Electronic Materials. 1 (3). doi:10.1002/aelm.201400015. S2CID 137099918. Retrieved 28 June 2021.
^Tyagi, Kriti; Gahtori, Bhasker (June 2015). "Enhanced thermoelectric performance of spark plasma sintered copper-deficient nanostructured copper selenide". Journal of Physics and Chemistry of Solids. 81: 100–105. Bibcode:2015JPCS...81..100T. doi:10.1016/j.jpcs.2015.01.018.
^C. Singh, Subhash (September 2018). "Structural and compositional control in copper selenide nanocrystals for light-induced self-repairable electrodes". Nano Energy. 51: 774–785. doi:10.1016/j.nanoen.2018.07.020. PMC6100260. PMID 30177955.
^Xiao, Guanjun; Ning, Jiajia; Liu, Zhaoyang; Sui, Yongming; Wang, Yingnan; Dong, Qingfeng; Tian, Wenjing; Liu, Bingbing; Zou, Guangtian (2012). "Solution synthesis of copper selenide nanocrystals and their electrical transport properties". CrystEngComm. 14 (6): 2139. doi:10.1039/c2ce06270d.
^ abHessel, Colin M.; Pattani, Varun P.; Rasch, Michael; Panthani, Matthew G.; Koo, Bonil; Tunnell, James W.; Korgel, Brian A. (2011-05-10). "Copper Selenide Nanocrystals for Photothermal Therapy". Nano Letters. 11 (6): 2560–2566. Bibcode:2011NanoL..11.2560H. doi:10.1021/nl201400z. PMC3111000. PMID 21553924.
^Patidar, D.; Saxena, N. S. (2012-03-15). "Characterization of single phase copper selenide nanoparticles and their growth mechanism". Journal of Crystal Growth. 343 (1): 68–72. Bibcode:2012JCrGr.343...68P. doi:10.1016/j.jcrysgro.2012.01.026.
^. Archived from the original on 28 April 2016. Retrieved 12 April 2016.
^(PDF). Archived from the original (PDF) on 23 April 2016. Retrieved 12 April 2016.
^"Oxpho-Blue MSDS" (PDF). Retrieved 12 April 2016.
^Berry, L. G. (1954). "The crystal structure of covellite, cuse and klockmannite, cuse". American Mineralogist. 39 (5–6): 504–509.
^Harris, D. C.; Cabri, L. J.; Murray, E. J. (1970). "An occurrence of a sulphur-bearing berzelianite" (PDF). The Canadian Mineralogist: 737–740.
^Harris, D. C.; Cabri, L. J.; Kaiman, S. (1970). "Athabascaite: A New Copper Selenide Mineral from Martin Lake, Saskatchewan". The Canadian Mineralogist. 10 (2): 207–215.
January 01, 1970
copper, selenide, inorganic, binary, compound, between, copper, selenium, chemical, formula, depends, ratio, between, elements, such, cuse, cu2se, names, iupac, name, copper, selenide, identifiers, number, 20405, model, jsmol, interactive, image, echa, infocar. Copper selenide is an inorganic binary compound between copper and selenium The chemical formula depends on the ratio between the two elements such as CuSe or Cu2Se Copper selenide Names IUPAC name Copper Selenide Identifiers CAS Number 20405 64 5 3D model JSmol Interactive image ECHA InfoCard 100 039 799 EC Number 243 796 7 PubChem CID 6914519 UNII 44P3QN57K9 CompTox Dashboard EPA DTXSID6066606 InChI InChI 1S 2Cu SeKey KTLOQXXVQYUCJU UHFFFAOYSA N SMILES Cu Cu Se Properties Chemical formula Cu 2Se Molar mass 206 063 g mol 1 Appearance Dark blue black Density 6 84 g mL 1 Hazards GHS labelling Pictograms Signal word Danger Hazard statements H201 H331 H373 H410 Precautionary statements P260 P261 P264 P270 P271 P273 P301 P310 P304 P340 P311 P314 P321 P330 P391 P403 P233 P405 P501 Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references The crystalline structure and electronic behavior is determined by its elemental composition 2 Stoichiometric copper selenide is a zero bandgap material with metal like behavior 3 Copper deficient Cu2 xSe non stoichiometric is an intrinsic p type semiconductor with direct and indirect bandgap energies in the range of 2 1 2 3 eV and 1 2 1 4 eV respectively 4 It is frequently grown as nanoparticles or other nanostructures 5 6 7 Contents 1 Uses 2 Natural occurrences 3 See also 4 ReferencesUses editCopper selenide is produced in situ to form a protective black coating on iron or steel parts in some cold bluing processes 8 Bluing solutions that operate in this manner will typically be labeled as containing selenous acid or selenium dioxide 9 10 It has also been investigated for use in the treatment of colon cancer 6 Natural occurrences editCopper selenides are the most common selenium minerals CuSe is known in mineralogy as klockmannite 11 while Cu2Se occurs as two polymorphs berzelianite 12 isometric more common and bellidoite tetragonal There are more natural Cu selenides to date including umangite Cu3Se2 and athabascaite Cu5Se4 13 See also editGallium selenide Indium selenide Copper indium gallium selenide Copper sulfate Selenium dioxide Selenous acidReferences edit Copper I selenide Sigma Aldrich Retrieved 12 April 2016 Lanling Zhao Wang Xiaolin F Yun Frank 5 February 2015 The Effects of Te2 and I Substitutions on the Electronic Structures Thermoelectric Performance and Hardness in Melt Quenched Highly Dense Cu2 xSe Advanced Electronic Materials 1 3 doi 10 1002 aelm 201400015 S2CID 137099918 Retrieved 28 June 2021 Tyagi Kriti Gahtori Bhasker June 2015 Enhanced thermoelectric performance of spark plasma sintered copper deficient nanostructured copper selenide Journal of Physics and Chemistry of Solids 81 100 105 Bibcode 2015JPCS 81 100T doi 10 1016 j jpcs 2015 01 018 C Singh Subhash September 2018 Structural and compositional control in copper selenide nanocrystals for light induced self repairable electrodes Nano Energy 51 774 785 doi 10 1016 j nanoen 2018 07 020 PMC 6100260 PMID 30177955 Xiao Guanjun Ning Jiajia Liu Zhaoyang Sui Yongming Wang Yingnan Dong Qingfeng Tian Wenjing Liu Bingbing Zou Guangtian 2012 Solution synthesis of copper selenide nanocrystals and their electrical transport properties CrystEngComm 14 6 2139 doi 10 1039 c2ce06270d a b Hessel Colin M Pattani Varun P Rasch Michael Panthani Matthew G Koo Bonil Tunnell James W Korgel Brian A 2011 05 10 Copper Selenide Nanocrystals for Photothermal Therapy Nano Letters 11 6 2560 2566 Bibcode 2011NanoL 11 2560H doi 10 1021 nl201400z PMC 3111000 PMID 21553924 Patidar D Saxena N S 2012 03 15 Characterization of single phase copper selenide nanoparticles and their growth mechanism Journal of Crystal Growth 343 1 68 72 Bibcode 2012JCrGr 343 68P doi 10 1016 j jcrysgro 2012 01 026 Room Temperature Black Oxide Archived from the original on 28 April 2016 Retrieved 12 April 2016 Insta Blak 333 MSDS PDF Archived from the original PDF on 23 April 2016 Retrieved 12 April 2016 Oxpho Blue MSDS PDF Retrieved 12 April 2016 Berry L G 1954 The crystal structure of covellite cuse and klockmannite cuse American Mineralogist 39 5 6 504 509 Harris D C Cabri L J Murray E J 1970 An occurrence of a sulphur bearing berzelianite PDF The Canadian Mineralogist 737 740 Harris D C Cabri L J Kaiman S 1970 Athabascaite A New Copper Selenide Mineral from Martin Lake Saskatchewan The Canadian Mineralogist 10 2 207 215 Retrieved from https en wikipedia org w index php title Copper selenide amp oldid 1191390102, wikipedia, wiki, book, books, library,
