Technetium(VII) oxide is the chemical compound with the formula Tc2O7. This yellow volatile solid is a rare example of a molecular binary metal oxide, the other examples being RuO4, OsO4, and the unstable Mn2O7. It adopts a centrosymmetric corner-shared bi-tetrahedral structure in which the terminal and bridging Tc−O bonds are 167pm and 184 pm respectively and the Tc−O−Tc angle is 180°.[2]
^ abKrebs, Bernt (1971). "Technetium(VII)-oxid: Ein Übergangsmetalloxid mit Molekülstruktur im festen Zustand". Zeitschrift für anorganische und allgemeine Chemie. 380 (2): 146–159. doi:10.1002/zaac.19713800205.
^Krebs, Bernt (1969). "Technetium(VII)-oxid: Ein Übergangsmetalloxid mit Molekülstruktur im festen Zustand". Angewandte Chemie. 81 (9): 328–329. Bibcode:1969AngCh..81..328K. doi:10.1002/ange.19690810905.
^Herrell, A. Y.; Busey, R. H.; Gayer, K. H. (1977). Technetium(VII) Oxide, in Inorganic Syntheses. Vol. XVII. pp. 155–158. doi:10.1002/9780470132487.ch41. ISBN0-07-044327-0.
January 06, 2023
technetium, oxide, chemical, compound, with, formula, tc2o7, this, yellow, volatile, solid, rare, example, molecular, binary, metal, oxide, other, examples, being, ruo4, oso4, unstable, mn2o7, adopts, centrosymmetric, corner, shared, tetrahedral, structure, wh. Technetium VII oxide is the chemical compound with the formula Tc2O7 This yellow volatile solid is a rare example of a molecular binary metal oxide the other examples being RuO4 OsO4 and the unstable Mn2O7 It adopts a centrosymmetric corner shared bi tetrahedral structure in which the terminal and bridging Tc O bonds are 167pm and 184 pm respectively and the Tc O Tc angle is 180 2 Technetium VII oxide Structural formula of technetium VII oxide Unit cell of technetium VII oxide NamesIUPAC name Technetium VII oxideOther names Technetium heptoxideIdentifiersCAS Number 12165 21 8 N3D model JSmol Interactive imagePubChem CID 22227441CompTox Dashboard EPA DTXSID70153330InChI InChI 1S 7O 2Tc q7 2 2 7SMILES O 2 O 2 O 2 O 2 O 2 O 2 O 2 Tc 7 Tc 7 PropertiesChemical formula Tc2O7Molar mass 307 810 g molAppearance light yellow solidDensity 3 5 g cm3Melting point 119 5 C 247 1 F 392 6 K Boiling point 310 6 C 591 1 F 583 8 K Solubility in water hydrolysis to HTcO4Magnetic susceptibility x 40 0 10 6 cm3 molStructure 1 Crystal structure Primitive orthorhombicSpace group Pbca No 61Lattice constant a 1375 6 pm b 743 9 pm c 561 7 pm 1 HazardsOccupational safety and health OHS OSH Main hazards radioactiveExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references Technetium VII oxide is prepared by the oxidation of technetium at 450 500 C 3 4 Tc 7 O2 2 Tc2O7It is the anhydride of pertechnetic acid and the precursor to sodium pertechnetate Tc2O7 2 H2O 2 HTcO4 Tc2O7 2 NaOH 2 NaTcO4 H2OReferences Edit a b Krebs Bernt 1971 Technetium VII oxid Ein Ubergangsmetalloxid mit Molekulstruktur im festen Zustand Zeitschrift fur anorganische und allgemeine Chemie 380 2 146 159 doi 10 1002 zaac 19713800205 Krebs Bernt 1969 Technetium VII oxid Ein Ubergangsmetalloxid mit Molekulstruktur im festen Zustand Angewandte Chemie 81 9 328 329 Bibcode 1969AngCh 81 328K doi 10 1002 ange 19690810905 Herrell A Y Busey R H Gayer K H 1977 Technetium VII Oxide in Inorganic Syntheses Vol XVII pp 155 158 doi 10 1002 9780470132487 ch41 ISBN 0 07 044327 0 Retrieved from https en wikipedia org w index php title Technetium VII oxide amp oldid 1097167613, wikipedia, wiki, book, books, library,
