Silicon monosulfide is a chemical compound of silicon and sulfur. The chemical formula is SiS. Molecular SiS has been detected at high temperature in the gas phase.[1] The gas phase molecule has an Si-S bondlength of 192.93 pm, this compares to the normal single bond length of 216 pm,[1][2] and is shorter than the Si=S bond length of around 201 pm reported in an organosilanethione.[1] Historically a pale yellow-red amorphous solid compound has been reported.[3] The behavior of silicon can be contrasted with germanium which forms a stable solid monosulfide.
Müller, H. S. P.; McCarthy, M. C.; Bizzocchi, L.; Gupta, H.; Esser, S.; Lichau, H.; Caris, M.; Lewen, F.; et al. (2007). "Rotational spectroscopy of the isotopic species of silicon monosulfide, SiS". Physical Chemistry Chemical Physics. 9 (13): 1579–86. Bibcode:2007PCCP....9.1579M. doi:10.1039/B618799D. PMID 17429551.
Chattopadhyaya, Surya; Chattopadhyay, Anjan; Das, Kalyan Kumar (2002). "Electronic Spectrum of Silicon Monosulfide: Configuration Interaction Study". The Journal of Physical Chemistry A. 106 (5): 833. Bibcode:2002JPCA..106..833C. doi:10.1021/jp013332e.
Birk, Helmut; Jones, Harold (1990). "Diode laser measurement of the infrared spectrum of silicon monosulfide". Chemical Physics Letters. 175 (5): 536. Bibcode:1990CPL...175..536B. doi:10.1016/0009-2614(90)85577-Y.
silicon, monosulfide, chemical, compound, silicon, sulfur, chemical, formula, molecular, been, detected, high, temperature, phase, phase, molecule, bondlength, this, compares, normal, single, bond, length, shorter, than, bond, length, around, reported, organos. Silicon monosulfide is a chemical compound of silicon and sulfur The chemical formula is SiS Molecular SiS has been detected at high temperature in the gas phase 1 The gas phase molecule has an Si S bondlength of 192 93 pm this compares to the normal single bond length of 216 pm 1 2 and is shorter than the Si S bond length of around 201 pm reported in an organosilanethione 1 Historically a pale yellow red amorphous solid compound has been reported 3 The behavior of silicon can be contrasted with germanium which forms a stable solid monosulfide Silicon monosulfide NamesIUPAC name silicon II sulfideIdentifiersCAS Number 12504 41 53D model JSmol Interactive imagePubChem CID 21538250InChI InChI 1S SSi c1 2Key DWFFKGPZNGKUPH UHFFFAOYSA NSMILES Si SPropertiesChemical formula SiSMolar mass 60 150 g molExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesFurther reading EditMuller H S P McCarthy M C Bizzocchi L Gupta H Esser S Lichau H Caris M Lewen F et al 2007 Rotational spectroscopy of the isotopic species of silicon monosulfide SiS Physical Chemistry Chemical Physics 9 13 1579 86 Bibcode 2007PCCP 9 1579M doi 10 1039 B618799D PMID 17429551 Chattopadhyaya Surya Chattopadhyay Anjan Das Kalyan Kumar 2002 Electronic Spectrum of Silicon Monosulfide Configuration Interaction Study The Journal of Physical Chemistry A 106 5 833 Bibcode 2002JPCA 106 833C doi 10 1021 jp013332e Birk Helmut Jones Harold 1990 Diode laser measurement of the infrared spectrum of silicon monosulfide Chemical Physics Letters 175 5 536 Bibcode 1990CPL 175 536B doi 10 1016 0009 2614 90 85577 Y References Edit a b c Greenwood Norman N Earnshaw Alan 1997 Chemistry of the Elements 2nd ed Butterworth Heinemann ISBN 978 0 08 037941 8 Lide David R ed 2006 CRC Handbook of Chemistry and Physics 87th ed Boca Raton FL CRC Press ISBN 0 8493 0487 3 E G Rochow E W Abel 1973 The Chemistry of Germanium Tin and Lead Pergamon Press ISBN 0 08 018854 0 This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Silicon monosulfide amp oldid 1001098061, wikipedia, wiki, book, books, library,
