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Plutonium(III) chloride

Plutonium(III) chloride is a chemical compound with the formula PuCl3. This ionic plutonium salt can be prepared by reacting the metal with hydrochloric acid.

Plutonium(III) chloride
Names
IUPAC name
Plutonium(III) chloride
Other names
Plutonium trichloride
Identifiers
3D model (JSmol)
  • Interactive image
ChemSpider
  • 14483818 Y
  • 19902959
  • DTXSID90601161
  • InChI=1S/3ClH.Pu/h3*1H;/q;;;+3/p-3 Y
    Key: CYMMZQWRMUVJRR-UHFFFAOYSA-K Y
  • InChI=1S/3ClH.Pu/h3*1H;/q;;;+3/p-3
    Key: CYMMZQWRMUVJRR-DFZHHIFOAR
  • Key: CYMMZQWRMUVJRR-UHFFFAOYSA-K
  • [Pu+3].[Cl-].[Cl-].[Cl-]
Properties
Cl3Pu
Molar mass 350.322 g/mol
Appearance Green solid
Density 5.71 g/cm3, solid[1]
Melting point 767 °C (1,413 °F; 1,040 K)[1]
Boiling point 1,767 °C (3,213 °F; 2,040 K)[1]
Related compounds
Other anions
PuCl4, PuBr3, SmCl3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

Structure

Plutonium atoms in crystalline PuCl3 are 9 coordinate, and the structure is tricapped trigonal prismatic. It crystallizes as the trihydrate, and forms lavender-blue solutions in water.[2]

Safety

As with all plutonium compounds, it is subject to control under the Nuclear Non-Proliferation Treaty. Due to the radioactivity of plutonium, all of its compounds, PuCl3 included, are warm to the touch. Such contact is not recommended, since touching the material may result in serious injury.

References

  1. ^ a b c www.webelements.com: Plutonium(III) chloride.
  2. ^ John H. Burns, J. R. Peterson, J. N. Stevenson: "Crystallographic Studies of some Transuranic Trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3", Journal of Inorganic and Nuclear Chemistry 1975, 37 (3), 743–749; doi:10.1016/0022-1902(75)80532-X.


plutonium, chloride, chemical, compound, with, formula, pucl3, this, ionic, plutonium, salt, prepared, reacting, metal, with, hydrochloric, acid, namesiupac, name, other, names, plutonium, trichlorideidentifierscas, number, 13569, pubchem, model, jsmol, intera. Plutonium III chloride is a chemical compound with the formula PuCl3 This ionic plutonium salt can be prepared by reacting the metal with hydrochloric acid Plutonium III chloride NamesIUPAC name Plutonium III chlorideOther names Plutonium trichlorideIdentifiersCAS Number 13569 62 5 Y PubChem 3D model JSmol Interactive imageChemSpider 14483818 YPubChem CID 19902959CompTox Dashboard EPA DTXSID90601161InChI InChI 1S 3ClH Pu h3 1H q 3 p 3 YKey CYMMZQWRMUVJRR UHFFFAOYSA K YInChI 1S 3ClH Pu h3 1H q 3 p 3Key CYMMZQWRMUVJRR DFZHHIFOARKey CYMMZQWRMUVJRR UHFFFAOYSA KSMILES Pu 3 Cl Cl Cl PropertiesChemical formula Cl 3PuMolar mass 350 322 g molAppearance Green solidDensity 5 71 g cm3 solid 1 Melting point 767 C 1 413 F 1 040 K 1 Boiling point 1 767 C 3 213 F 2 040 K 1 Related compoundsOther anions PuCl4 PuBr3 SmCl3Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox referencesStructure EditPlutonium atoms in crystalline PuCl3 are 9 coordinate and the structure is tricapped trigonal prismatic It crystallizes as the trihydrate and forms lavender blue solutions in water 2 Safety EditSee also Dual fluid reactor As with all plutonium compounds it is subject to control under the Nuclear Non Proliferation Treaty Due to the radioactivity of plutonium all of its compounds PuCl3 included are warm to the touch Such contact is not recommended since touching the material may result in serious injury References Edit a b c www webelements com Plutonium III chloride John H Burns J R Peterson J N Stevenson Crystallographic Studies of some Transuranic Trihalides 239PuCl3 244CmBr3 249BkBr3 and 249CfBr3 Journal of Inorganic and Nuclear Chemistry 1975 37 3 743 749 doi 10 1016 0022 1902 75 80532 X This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Plutonium III chloride amp oldid 1120770951, wikipedia, wiki, book, books, library,

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