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Plutonium(III) bromide

Plutonium(III) bromide is an inorganic salt of bromine and plutonium with the formula PuBr3. This radioactive green solid has few uses, however its crystal structure is often used as a structural archetype in crystallography.

Plutonium(III) bromide
Names
IUPAC name
Plutonium tribromide
Other names
Plutonium(III) bromide
Identifiers
3D model (JSmol)
  • Interactive image
  • 101943065
  • InChI=1S/3BrH.Pu/h3*1H;/p-3
    Key: LNRFBKZOZNXTON-UHFFFAOYSA-K
  • [Br-].[Br-].[Br-].[Pu]
Properties
Br3Pu
Molar mass 484 g·mol−1
Appearance Green[1]
Melting point 767 °C (1,413 °F; 1,040 K)[1]
Boiling point 1,463 °C (2,665 °F; 1,736 K)
Water soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Crystal structure edit

 
Crystal structure
 
Unit cell
PuBr3:   Pu3+   Br

The PuBr3 crystal structure was first published in 1948 by William Houlder Zachariasen.[2] The compound forms orthorhombic crystals, a type of square antiprism, within which the Pu atoms adopt an 8-coordinate bicapped trigonal prismatic arrangement. Its Pearson symbol is oS16 with the corresponding space group No. 63 (in International Union of Crystallography classification) or Cmcm (in Hermann–Mauguin notation). The majority of trivalent chloride and bromide salts of lanthanide and actinides crystallise in the PuBr3 structure.

References edit

  1. ^ a b Greenwood, N. N. (2001). Chemistry of the elements (2nd ed.). Boston, Mass. p. 1270. ISBN 0750633654.{{cite book}}: CS1 maint: location missing publisher (link)
  2. ^ Zachariasen, W. H. (2 November 1948). "Crystal chemical studies of the 5f-series of elements. I. New structure types". Acta Crystallographica. 1 (5): 265–268. Bibcode:1948AcCry...1..265Z. doi:10.1107/S0365110X48000703.

plutonium, bromide, inorganic, salt, bromine, plutonium, with, formula, pubr3, this, radioactive, green, solid, uses, however, crystal, structure, often, used, structural, archetype, crystallography, names, iupac, name, plutonium, tribromide, other, names, ide. Plutonium III bromide is an inorganic salt of bromine and plutonium with the formula PuBr3 This radioactive green solid has few uses however its crystal structure is often used as a structural archetype in crystallography Plutonium III bromide Names IUPAC name Plutonium tribromide Other names Plutonium III bromide Identifiers CAS Number 15752 46 220737 00 2 hexahydrate 3D model JSmol Interactive image PubChem CID 101943065 InChI InChI 1S 3BrH Pu h3 1H p 3Key LNRFBKZOZNXTON UHFFFAOYSA K SMILES Br Br Br Pu Properties Chemical formula Br 3Pu Molar mass 484 g mol 1 Appearance Green 1 Melting point 767 C 1 413 F 1 040 K 1 Boiling point 1 463 C 2 665 F 1 736 K Solubility in water Water soluble Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesCrystal structure edit nbsp Crystal structure nbsp Unit cellPuBr3 Pu3 Br The PuBr3 crystal structure was first published in 1948 by William Houlder Zachariasen 2 The compound forms orthorhombic crystals a type of square antiprism within which the Pu atoms adopt an 8 coordinate bicapped trigonal prismatic arrangement Its Pearson symbol is oS16 with the corresponding space group No 63 in International Union of Crystallography classification or Cmcm in Hermann Mauguin notation The majority of trivalent chloride and bromide salts of lanthanide and actinides crystallise in the PuBr3 structure References edit a b Greenwood N N 2001 Chemistry of the elements 2nd ed Boston Mass p 1270 ISBN 0750633654 a href Template Cite book html title Template Cite book cite book a CS1 maint location missing publisher link Zachariasen W H 2 November 1948 Crystal chemical studies of the 5f series of elements I New structure types Acta Crystallographica 1 5 265 268 Bibcode 1948AcCry 1 265Z doi 10 1107 S0365110X48000703 nbsp This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Plutonium III bromide amp oldid 1196695782, wikipedia, wiki, book, books, library,

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