Indium(III) nitrate is a nitrate salt of indium which forms various hydrates. Only the pentahydrate has been crystallographically verified. Other hydrates are also reported in literature, such as the trihydrate.[1][2][3]
Indium(III) nitrate hydrate is produced by the dissolution of indium metal in concentrated nitric acid followed by evaporation of the solution:[1][2][3]
In the presence of excess nitrate ions, indium(III) nitrate converts to the [In(NO3)4]− ion.[1][2]
The hydrolysis of indium(III) nitrate yields indium(III) hydroxide. It also reacts with sodium tungstate to form In(OH)WO4, [In(OH)2]2WO4, NaInWO4 or In2(WO4)3 depending on pH.[5][6]
Structureedit
Only the pentahydrate has been structurally elucidated. The pentahydrate consists of octahedral [In(NO3)(H2O)5]2+ centers as well as two nitrates and is monoclinic.[1]
Referencesedit
^ abcdefM. A. Malyarik; S. P. Petrosyants; A. B. Ilyukhin; Yu. A. Buslaev (1993). "Polyfunctionality of the nitrate group, coordination numbers of trivalent indium in nitrates complexes, and crystal structures of [In(NO3)(H2O)5](NO3)2 and HK6[In(NO3)4(H2O)2]3(NO3)4". Russian Journal of Inorganic Chemistry. 38 (12): 1849–1854. ISSN 0036-0236.
^ abcdD. G. Tuck; E. J. Woodhouse; P. Carty (1966). "Co-ordination compounds of indium. Part III. Indium(III) nitrate species". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 1077–1080. doi:10.1039/J19660001077.
^ abGalina V. Kozhevnikova; Gábor Keresztury (1985). "The state of indium ions in nitrate solutions: A Raman spectroscopic study". Inorganica Chimica Acta. 98 (1): 59–65. doi:10.1016/S0020-1693(00)90751-5.
^B. O. Field; C. J. Hardy (1964). "Volatile and anhydrous nitrato-complexes of metals: preparation by the use of dinitrogen pentroxide, and measurement of infrared spectra". Journal of the Chemical Society: 4428–4434. doi:10.1039/JR9640004428.
^Keita Yura; Karl C. Fredrikson; Egon Matijević (1990). "Preparation and properties of uniform colloidal indium compounds of different morphologies". Colloids and Surfaces. 50: 281–293. doi:10.1016/0166-6622(90)80270-E.
^Shcherbina, K. G.; Mokhosoev, M. V.; Gruba, A. I. (1974). "Reaction of aluminum and indium nitrates with sodium tungstate in hot solutions". Zhurnal Neorganicheskoi Khimii (in Russian). 19 (2): 396–399. ISSN 0044-457X.{{cite journal}}: CS1 maint: multiple names: authors list (link)
April 10, 2024
indium, nitrate, nitrate, salt, indium, which, forms, various, hydrates, only, pentahydrate, been, crystallographically, verified, other, hydrates, also, reported, literature, such, trihydrate, identifierscas, number, anhydrous, 13770, ymonohydrate, 13465, 0tr. Indium III nitrate is a nitrate salt of indium which forms various hydrates Only the pentahydrate has been crystallographically verified Other hydrates are also reported in literature such as the trihydrate 1 2 3 Indium III nitrate IdentifiersCAS Number anhydrous 13770 61 1 Ymonohydrate 13465 14 0trihydrate 15650 88 13D model JSmol anhydrous Interactive imagemonohydrate Interactive imagetrihydrate Interactive imagetetrahydrate Interactive imageChemSpider anhydrous 24472monohydrate 2341257trihydrate 26948018ECHA InfoCard 100 033 979EC Number anhydrous 237 393 5PubChem CID anhydrous 26265monohydrate 3084148trihydrate 91886655tetrahydrate 138753438pentahydrate 22446589RTECS number anhydrous NL1750000UNII anhydrous WOP84073FA YCompTox Dashboard EPA anhydrous DTXSID7065621InChI InChI 1S In 3NO3 c 3 2 1 3 4 q 3 3 1Key LKRFCKCBYVZXTC UHFFFAOYSA Nmonohydrate InChI 1S In 3NO3 H2O c 3 2 1 3 4 h 1H2 q 3 3 1 Key YZZFBYAKINKKFM UHFFFAOYSA Ntrihydrate InChI 1S In 3NO3 3H2O c 3 2 1 3 4 h 3 1H2 q 3 3 1 Key HVDZMISZAKTZFP UHFFFAOYSA Ntetrahydrate InChI 1S In 3NO3 4H2O c 3 2 1 3 4 h 4 1H2 q 3 3 1 Key ZYYDOSLSINDXIQ UHFFFAOYSA NSMILES anhydrous N O O O N O O O N O O O In 3 monohydrate N O O O In O N O O O N O O Otrihydrate N O O O In O N O O O N O O O O Otetrahydrate N O O O In O N O O O N O O O O O OPropertiesChemical formula In NO3 3Molar mass 300 83 g molAppearance White solidDensity 2 43 g cm3 pentahydrate 1 Melting point 100 C 212 F 373 K decomposes hydrate Solubility in water SolubleStructure 1 Crystal structure MonoclinicSpace group C2 cLattice constant a 10 35 A b 9 17 A c 11 25 Aa 90 b 91 05 g 90 Lattice volume V 1068 A3HazardsGHS labelling PictogramsSignal word WarningHazard statements H272 H315 H319 H335Precautionary statements P210 P220 P221 P261 P264 P271 P280 P302 P352 P304 P340 P305 P351 P338 P312 P321 P332 P313 P337 P313 P362 P370 P378 P403 P233 P405 P501Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesProduction and reactions editIndium III nitrate hydrate is produced by the dissolution of indium metal in concentrated nitric acid followed by evaporation of the solution 1 2 3 In 4 HNO3 In NO3 3 NO 2 H2OThe hydrate first decomposes to a basic salt and then to indium III oxide at 240 C Anhydrous indium III nitrate is claimed to be produced by the reaction of anhydrous indium III chloride and dinitrogen pentoxide 2 4 In the presence of excess nitrate ions indium III nitrate converts to the In NO3 4 ion 1 2 The hydrolysis of indium III nitrate yields indium III hydroxide It also reacts with sodium tungstate to form In OH WO4 In OH 2 2WO4 NaInWO4 or In2 WO4 3 depending on pH 5 6 Structure editOnly the pentahydrate has been structurally elucidated The pentahydrate consists of octahedral In NO3 H2O 5 2 centers as well as two nitrates and is monoclinic 1 References edit a b c d e f M A Malyarik S P Petrosyants A B Ilyukhin Yu A Buslaev 1993 Polyfunctionality of the nitrate group coordination numbers of trivalent indium in nitrates complexes and crystal structures of In NO3 H2O 5 NO3 2 and HK6 In NO3 4 H2O 2 3 NO3 4 Russian Journal of Inorganic Chemistry 38 12 1849 1854 ISSN 0036 0236 a b c d D G Tuck E J Woodhouse P Carty 1966 Co ordination compounds of indium Part III Indium III nitrate species Journal of the Chemical Society A Inorganic Physical Theoretical 1077 1080 doi 10 1039 J19660001077 a b Galina V Kozhevnikova Gabor Keresztury 1985 The state of indium ions in nitrate solutions A Raman spectroscopic study Inorganica Chimica Acta 98 1 59 65 doi 10 1016 S0020 1693 00 90751 5 B O Field C J Hardy 1964 Volatile and anhydrous nitrato complexes of metals preparation by the use of dinitrogen pentroxide and measurement of infrared spectra Journal of the Chemical Society 4428 4434 doi 10 1039 JR9640004428 Keita Yura Karl C Fredrikson Egon Matijevic 1990 Preparation and properties of uniform colloidal indium compounds of different morphologies Colloids and Surfaces 50 281 293 doi 10 1016 0166 6622 90 80270 E Shcherbina K G Mokhosoev M V Gruba A I 1974 Reaction of aluminum and indium nitrates with sodium tungstate in hot solutions Zhurnal Neorganicheskoi Khimii in Russian 19 2 396 399 ISSN 0044 457X a href Template Cite journal html title Template Cite journal cite journal a CS1 maint multiple names authors list link Retrieved from https en wikipedia org w index php title Indium III nitrate amp oldid 1216905922, wikipedia, wiki, book, books, library,
