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Vitreous enamel

Vitreous enamel, also called porcelain enamel, is a material made by fusing powdered glass to a substrate by firing, usually between 750 and 850 °C (1,380 and 1,560 °F). The powder melts, flows, and then hardens to a smooth, durable vitreous coating. The word comes from the Latin vitreum, meaning "glass".

Gothic châsse; 1185–1200; champlevé enamel over copper gilded; height: 17.7 cm, width: 17.4 cm, depth: 10.1 cm

Enamel can be used on metal, glass, ceramics, stone, or any material that will withstand the fusing temperature. In technical terms fired enamelware is an integrated layered composite of glass and another material (or more glass). The term "enamel" is most often restricted to work on metal, which is the subject of this article. Essentially the same technique used with other bases is known by different terms: on glass as enamelled glass, or "painted glass", and on pottery it is called overglaze decoration, "overglaze enamels" or "enamelling". The craft is called "enamelling", the artists "enamellers" and the objects produced can be called "enamels".

Chinese dish with scalloped rim, from the Ming Dynasty; early 15th century; cloisonné enamel; height: 2.5 cm, diameter: 15.2 cm

Enamelling is an old and widely adopted technology, for most of its history mainly used in jewellery and decorative art. Since the 18th century, enamels have also been applied to many metal consumer objects, such as some cooking vessels, steel sinks, and cast-iron bathtubs. It has also been used on some appliances, such as dishwashers, laundry machines, and refrigerators, and on marker boards and signage.

The term "enamel" has also sometimes been applied to industrial materials other than vitreous enamel, such as enamel paint and the polymers coating enameled wire; these actually are very different in materials science terms.

The word enamel comes from the Old High German word smelzan (to smelt) via the Old French esmail,[1] or from a Latin word smaltum, first found in a 9th-century Life of Leo IV.[2] Used as a noun, "an enamel" is usually a small decorative object coated with enamel. "Enamelled" and "enamelling" are the preferred spellings in British English, while "enameled" and "enameling" are preferred in American English.

History

 
Staffordshire Moorlands Pan, 2nd-century Roman Britain

Ancient

The earliest enamel all used the cloisonné technique, placing the enamel within small cells with gold walls. This had been used as a technique to hold pieces of stone and gems tightly in place since the 3rd millennium BC, for example in Mesopotamia, and then Egypt. Enamel seems likely to have developed as a cheaper method of achieving similar results.[3]

The earliest undisputed objects known to use enamel are a group of Mycenaean rings from Cyprus, dated to the 13th century BC.[3] Although Egyptian pieces, including jewellery from the Tomb of Tutankhamun of c. 1325 BC, are frequently described as using "enamel", many scholars doubt the glass paste was sufficiently melted to be properly so described, and use terms such as "glass-paste". It seems possible that in Egyptian conditions the melting point of the glass and gold were too close to make enamel a viable technique. Nonetheless, there appear to be a few actual examples of enamel, perhaps from the Third Intermediate Period of Egypt (beginning 1070 BC) on.[4] But it remained rare in both Egypt and Greece.

The technique appears in the Koban culture of the northern and central Caucasus, and was perhaps carried by the Sarmatians to the ancient Celts.[3] Red enamel is used in 26 places on the Battersea Shield (c.350–50 BC), probably as an imitation of the red Mediterranean coral, which is used on the Witham Shield (400-300 BC). Pliny the Elder mentions the Celts' use of the technique on metal, which the Romans in his day hardly knew. The Staffordshire Moorlands Pan is a 2nd-century AD souvenir of Hadrian's Wall, made for the Roman military market, which has swirling enamel decoration in a Celtic style. In Britain, probably through preserved Celtic craft skills, enamel survived until the hanging bowls of early Anglo-Saxon art.

A problem that adds to the uncertainty over early enamel is artefacts (typically excavated) that appear to have been prepared for enamel, but have now lost whatever filled the cloisons or backing to a champlevé piece.[3] This occurs in several different regions, from ancient Egypt to Anglo-Saxon England. Once enamel becomes more common, as in medieval Europe after about 1000, the assumption that enamel was originally used becomes safer.

Medieval and Renaissance Europe

 
Detail of painted Limoges enamel dish, mid-16th century, attributed to Jean de Court

In European art history, enamel was at its most important in the Middle Ages, beginning with the Late Romans and then the Byzantine, who began to use cloisonné enamel in imitation of cloisonné inlays of precious stones. The Byzantine enamel style was widely adopted by the peoples of Migration Period northern Europe. The Byzantines then began to use cloisonné more freely to create images; this was also copied in Western Europe.

Mosan metalwork often included enamel plaques of the highest quality in reliquaries and other large works of goldsmithing. Limoges enamel was made in Limoges, France, the most famous centre of vitreous enamel production in Western Europe, though Spain also made a good deal. Limoges became famous for champlevé enamels from the 12th century onwards, producing on a large scale, and then (after a period of reduced production) from the 15th century retained its lead by switching to painted enamel on flat metal plaques. The champlevé technique was considerably easier and very widely practiced in the Romanesque period. In Gothic art the finest work is in basse-taille and ronde-bosse techniques, but cheaper champlevé works continued to be produced in large numbers for a wider market.

Painted enamel remained in fashion for over a century, and in France developed into a sophisticated Renaissance and the Mannerist style, seen on objects such as large display dishes, ewers, inkwells and in small portraits. After it fell from fashion it continued as a medium for portrait miniatures, spreading to England and other countries. This continued until the early 19th century.

A Russian school developed, which used the technique on other objects, as in the Renaissance, and for relatively cheap religious pieces such as crosses and small icons.

China

 
Chinese cloisonné enamel bronze wine pot, 18th century

From either Byzantium or the Islamic world, the cloisonné technique reached China in the 13–14th centuries. The first written reference to cloisonné is in a book from 1388, where it is called "Dashi ('Muslim') ware".[5] No Chinese pieces that are clearly from the 14th century are known; the earliest datable pieces are from the reign of the Xuande Emperor (1425–35), which, since they show a full use of Chinese styles, suggest considerable experience in the technique.

Cloisonné remained very popular in China until the 19th century and is still produced today. The most elaborate and most highly valued Chinese pieces are from the early Ming Dynasty, especially the reigns of the Xuande Emperor and Jingtai Emperor (1450–57), although 19th century or modern pieces are far more common.[5]

Japan

 
Imperial vases by Ando Jubei, with the chrysanthemum crests of the Imperial family, using moriage to slightly raise the design; Khalili Collection of Japanese Art

Japanese artists did not make three-dimensional enamelled objects until the 1830s but, once the technique took hold based on analysis of Chinese objects, it developed very rapidly, reaching a peak in the Meiji and Taishō eras (late 19th/ early 20th century).[6] Enamel had been used as decoration for metalwork since about 1600,[7][6] and Japanese cloisonné was already exported to Europe before the start of the Meiji era in 1868.[6] Cloisonné is known in Japan as shippo, literally "seven treasures".[8] This refers to richly coloured substances mentioned in Buddhist texts.[9] The term was initially used for colourful objects imported from China. According to legend, in the 1830s Kaji Tsunekichi broke open a Chinese enamel object to examine it, then trained many artists, starting off Japan's own enamel industry.[9][7]

Early Japanese enamels were cloudy and opaque, with relatively clumsy shapes. This changed rapidly from 1870 onwards.[6] The Nagoya cloisonné company (Nagoya shippo kaisha existed from 1871 to 1884, to sell the output of many small workshops and help them improve their work.[6] In 1874, the government created the Kiriu kosho kaisha company to sponsor the creation of a wide range of decorative arts at international exhibitions. This was part of a programme to promote Japan as a modern, industrial nation.[6]

Gottfried Wagener was a German scientist brought in by the government to advise Japanese industry and improve production processes. Along with Namikawa Yasuyuki he developed a transparent black enamel which was used for backgrounds. Translucent enamels in various other colours followed during this period.[6] Along with Tsukamoto Kaisuke, Wagener transformed the firing processes used by Japanese workshops, improving the quality of finishes and extending the variety of colours.[6] Kawade Shibatarō introduced a variety of techniques, including nagare-gusuri (drip-glaze) which produces a rainbow-coloured glaze and uchidashi (repoussé) technique, in which the metal foundation is hammered outwards to create a relief effect.[10] Together with Hattori Tadasaburō he developed the moriage ("piling up") technique which places layers of enamel upon each other to create a three-dimensional effect.[11] Namikawa Sōsuke developed a pictorial style that imitated paintings. He is known for shosen (minimised wires) and musen (wireless cloisonné): techniques developed with Wagener in which the wire cloisons are minimised or burned away completely with acid.[12][7] This contrasts with the Chinese style which used thick metal cloisons.[6] Ando Jubei introduced the shōtai-jippō (plique-à-jour) technique which burns away the metal substrate to leave translucent enamel, producing an effect resembling stained glass.[13] The Ando Cloisonné Company which he co-founded is one of the few makers from this era still active.[6] Distinctively Japanese designs, in which flowers, birds and insects were used as themes, became popular. Designs also increasingly used areas of blank space.[7] With the greater subtlety these techniques allowed, Japanese enamels were regarded as unequalled in the world[14] and won many awards at national and international exhibitions.[12][15]

India and Islamic world

 
Meenakaari art from Iran

Enamel was established in the Mughal Empire by around 1600 for decorating gold and silver objects, and became a distinctive feature of Mughal jewellery. The Mughal court was known to employ mīnākār (enamelers).[16] These craftsmen reached a peak of during the reign of Shah Jahan in the mid-17th century. Transparent enamels were popular during this time.[16] Both cloissoné and champlevé were produced in Mughal, with champlevé used for the finest pieces.[16] Modern industrial production began in Calcutta in 1921, with the Bengal Enamel Works Limited.

Enamel was used in Iran for colouring and ornamenting the surface of metals by fusing over it brilliant colours that are decorated in an intricate design called Meenakari. The French traveller Jean Chardin, who toured Iran during the Safavid period, made a reference to an enamel work of Isfahan, which comprised a pattern of birds and animals on a floral background in light blue, green, yellow and red. Gold has been used traditionally for Meenakari jewellery as it holds the enamel better, lasts longer and its lustre brings out the colours of the enamels. Silver, a later introduction, is used for artifacts like boxes, bowls, spoons, and art pieces. Copper began to be used for handicraft products after the Gold Control Act, was enforced in India which compelled the Meenakars to look for an alternative material. Initially, the work of Meenakari often went unnoticed as this art was traditionally used on the back of pieces of kundan or gem-studded jewellery, allowing pieces to be reversible.[17]

Modern

 
Grey clouds, typical enamel cooking gear from the Dutch DRU factory, popular in the 1950s

More recently, the bright, jewel-like colours have made enamel a favoured choice for jewellery designers, including the Art Nouveau jewellers, for designers of bibelots such as the eggs of Peter Carl Fabergé and the enameled copper boxes of the Battersea enamellers,[18] and for artists such as George Stubbs and other painters of portrait miniatures.

A resurgence in enamel-based art took place near the end of the 20th century in the Soviet Union, led by artists like Alexei Maximov and Leonid Efros. In Australia, abstract artist Bernard Hesling brought the style into prominence with his variously sized steel plates.[19]

Enamel was first applied commercially to sheet iron and steel in Austria and Germany in about 1850.[20]: 5  Industrialization increased as the purity of raw materials increased and costs decreased. The wet application process started with the discovery of the use of clay to suspend frit in water. Developments that followed during the 20th century include enamelling-grade steel, cleaned-only surface preparation, automation, and ongoing improvements in efficiency, performance, and quality.[20]: 5 

Properties

 
Glass vials with ground vitreous enamel powder in different colors

Vitreous enamel can be applied to most metals. Most modern industrial enamel is applied to steel in which the carbon content is controlled to prevent unwanted reactions at the firing temperatures. Enamel can also be applied to gold, silver, copper, aluminium,[21] stainless steel,[22] and cast iron.[23]

Vitreous enamel has many useful properties: it is smooth, hard, chemically resistant, durable, scratch resistant (5–6 on the Mohs scale), has long-lasting colour fastness, is easy to clean, and cannot burn. Enamel is glass, not paint, so it does not fade under ultraviolet light.[24] A disadvantage of enamel is a tendency to crack or shatter when the substrate is stressed or bent, but modern enamels are relatively chip- and impact-resistant because of good thickness control and coefficients of thermal expansion well-matched to the metal.

The Buick automobile company was founded by David Dunbar Buick with wealth earned by his development of improved enamelling processes, c. 1887, for sheet steel and cast iron. Such enameled ferrous material had, and still has, many applications: early 20th century and some modern advertising signs, interior oven walls, cooking pots, housing and interior walls of major kitchen appliances, housing and drums of clothes washers and dryers, sinks and cast iron bathtubs, farm storage silos, and processing equipment such as chemical reactors and pharmaceutical process tanks. Structures such as filling stations, bus stations and Lustron Houses had walls, ceilings and structural elements made of enamelled steel.

One of the most widespread modern uses of enamel is in the production of quality chalk-boards and marker-boards (typically called 'blackboards' or 'whiteboards') where the resistance of enamel to wear and chemicals ensures that 'ghosting', or unerasable marks, do not occur, as happens with polymer boards. Since standard enamelling steel is magnetically attractive, it may also be used for magnet boards. Some new developments in the last ten years include enamel/non-stick hybrid coatings, sol-gel functional top-coats for enamels, enamels with a metallic appearance, and easy-to-clean enamels.[25]

The key ingredient of vitreous enamel is finely ground glass called frit. Frit for enamelling steel is typically an alkali borosilicate glass with a thermal expansion and glass temperature suitable for coating steel. Raw materials are smelted together between 2,100 and 2,650 °F (1,150 and 1,450 °C) into a liquid glass that is directed out of the furnace and thermal shocked with either water or steel rollers into frit.[26]

Colour in enamel is obtained by the addition of various minerals, often metal oxides cobalt, praseodymium, iron, or neodymium. The latter creates delicate shades ranging from pure violet through wine-red and warm grey. Enamel can be transparent, opaque or opalescent (translucent). Different enamel colours can be mixed to make a new colour, in the manner of paint.

There are various types of frit, which may be applied in sequence. A ground coat is applied first; it usually contains smelted-in transition metal oxides such as cobalt, nickel, copper, manganese, and iron that facilitate adhesion to the metal. Next, clear and semi-opaque frits that contain material for producing colours are applied.

Techniques of artistic enameling

 
Medallion of the Death of the Virgin, with basse-taille enamel, partly fallen away
 
The Dunstable Swan Jewel, a livery badge in ronde bosse enamel, about 1400. British Museum

The three main historical techniques for enamelling metal are:

  • Cloisonné, French for "cell", where thin wires are applied to form raised barriers, which contain different areas of (subsequently applied) enamel. Widely practiced in Europe, the Middle East and East Asia.[27]
  • Champlevé, French for "raised field", where the surface is carved out to form pits in which enamel is fired, leaving the original metal exposed; the Romanesque Stavelot Triptych is an example.[28]
  • Painted enamel, a design in enamel is painted onto a smooth metal surface. Limoges enamel is the best known type of painted enamel, using this from the 16th century onwards.[29] Most traditional painting on glass, and some on ceramics, uses what is technically enamel, but is often described by terms such as "painted in enamels", reserving "painted enamel" and "enamel" as a term for the whole object for works with a metal base.[30]

Variants, and less common techniques are:

  • Basse-taille, from the French word meaning "low-cut". The surface of the metal is decorated with a low relief design which can be seen through translucent and transparent enamels. The 14th century Royal Gold Cup is an outstanding example.[31]
  • Plique-à-jour, French for "open to daylight" where the enamel is applied in cells, similar to cloisonné, but with no backing, so light can shine through the transparent or translucent enamel. It has a stained-glass like appearance; the Mérode Cup is the surviving medieval example.[32]
  • Ronde bosse, French for "in the round", also known as "encrusted enamel". A 3D type of enamelling where a sculptural form or wire framework is completely or partly enamelled, as in the 15th century Holy Thorn Reliquary.[33]
  • Grisaille, version of painted enamel, French term meaning "in grey", where a dark, often blue or black background is applied, then a palescent (translucent) enamel is painted on top, building up designs in a monochrome gradient, paler as the thickness of the layer of light colour increases.[34]
  • En résille (Émail en résille sur verre, French for 'enamel in a network on glass,') where enamelled metal is suspended in glass. The technique was briefly popular in seventeenth-century France and was re-discovered by Margret Craver in 1953. Craver spent 13 years re-creating the technique.[35]

Other types:

  • Enamelled glass, in which a glass surface is enamelled, and fired to fuse the glasses.
  • Stenciling, where a stencil is placed over the work and the powdered enamel is sifted over the top. The stencil is removed before firing, the enamel staying in a pattern, slightly raised.
  • Sgraffito, where an unfired layer of enamel is applied over a previously fired layer of enamel of a contrasting colour, and then partly removed with a tool to create the design.
  • Serigraph, where a silkscreen is used with 60–70in grade mesh.
  • Surrey enamel, a 17th-century type for brass objects such as candlesticks; effectively champlevé.[36]
  • Counter-enamelling, not strictly a technique, but a necessary step in many techniques, especially painted enamel on thin plaques; introduced in 15th-century Europe. Enamel is applied to the back of a piece as well – sandwiching the metal – to equalize the rates of expansion under heat, and so create less tension on the glass so it does not crack.[37]
  • Safed chalwan, where jewels are set in white enamel

See also Japanese shipōyaki techniques.

Industrial enamel application

 
Old German enamel street sign

On sheet steel, a ground coat layer is applied to create adhesion. The only surface preparation required for modern ground coats is degreasing of the steel with a mildly alkaline solution. White and coloured second "cover" coats of enamel are applied over the fired ground coat. For electrostatic enamels, the coloured enamel powder can be applied directly over a thin unfired ground coat "base coat" layer that is co-fired with the cover coat in a very efficient two-coat/one-fire process.

The frit in the ground coat contains smelted-in cobalt and/or nickel oxide as well as other transition metal oxides to catalyse the enamel-steel bonding reactions. During firing of the enamel at between 760 to 895 °C (1,400 to 1,643 °F), iron oxide scale first forms on the steel. The molten enamel dissolves the iron oxide and precipitates cobalt and nickel. The iron acts as the anode in an electrogalvanic reaction in which the iron is again oxidised, dissolved by the glass, and oxidised again with the available cobalt and nickel limiting the reaction. Finally, the surface becomes roughened with the glass anchored into the holes.[38]

Building cladding

Enamel coatings applied to steel panels offer protection to the core material whether cladding road tunnels, underground stations, building superstructures or other applications. It can also be specified as a curtain walling. Qualities of this structural material include:[39]

  • Durable
  • Withstands extreme temperatures and is non-flammable
  • Long lasting UV, climate and corrosion resistance
  • Dirt-repellent and graffiti-proof
  • Resistant to abrasion and chemicals
  • Easy cleaning and maintenance

Gallery

See also

Notes

  1. ^ Campbell, 6
  2. ^ Chisholm, Hugh, ed. (1911). "Enamel" . Encyclopædia Britannica (11th ed.). Cambridge University Press.
  3. ^ a b c d Osborne, 331
  4. ^ Ogden, 166
  5. ^ a b Sullivan, Michael, The arts of China, 4th edn, p. 239, University of California Press, 1999, ISBN 0-520-21877-9, ISBN 978-0-520-21877-2, Google books
  6. ^ a b c d e f g h i j Impey, Oliver; Fairley, Malcolm (2009). "Enamel in Japan". In Williams, Haydn (ed.). Enamels of the world, 1700-2000: the Khalili collections. London: Khalili Family Trust. pp. 149–156. ISBN 978-1-874780-17-5.
  7. ^ a b c d Earle, Joe (1999). Splendors of Meiji : treasures of imperial Japan : masterpieces from the Khalili Collection. St. Petersburg, Fla.: Broughton International Inc. pp. 252–254. ISBN 1874780137. OCLC 42476594.
  8. ^ Harada, Jiro (1911). "Japanese Art & Artists of To-day VI. Cloisonné Enamels". The Studio. 53: 271 – via Internet Archive.
  9. ^ a b "Polished to Perfection". Asian Art Newspaper. 5 November 2017. ISSN 1475-1372. Retrieved 16 July 2020.
  10. ^ "Kawade Shibatarō | Imperial Presentation Vase with Maple Branches and Imperial Chrysanthemum Crest (one of a pair)". www.metmuseum.org. Metropolitan Museum of Art. Retrieved 16 July 2020.
  11. ^ Irvine, Gregory (2013). Japonisme and the rise of the modern art movement : the arts of the Meiji period : the Khalili collection. New York: Thames & Hudson. p. 181. ISBN 978-0-500-23913-1. OCLC 853452453.
  12. ^ a b Leonard, Loryn (2012-06-26). "How It's Made: Japanese Cloisonné". Dallas Museum of Art Uncrated. Retrieved 2020-10-16.
  13. ^ "Ashmolean − Eastern Art Online, Yousef Jameel Centre for Islamic and Asian Art". jameelcentre.ashmolean.org. Ashmolean Museum, University of Oxford. Retrieved 16 July 2020.
  14. ^ "Japanese Art Enamels". The Decorator and Furnisher. 21 (5): 170. 1893. ISSN 2150-6256. JSTOR 25582341. We doubt if any form of the enameller's art can equal the work executed in Japan, which is distinguished by great freedom of design, and the most exquisite gradations of color.
  15. ^ Toyoro Hida, Gregory Irvine, Kana Ooki, Tomoko Hana and Yukari Muro. Namikawa Yasuyuki and Japanese Cloisonné The Allure of Meiji Cloisonné: The Aesthetic of Translucent Black, pp.182-188, The Mainichi Newspapers Co, Ltd, 2017
  16. ^ a b c Moura Carvalho, Pedro (2009). "Enamel in the Islamic Lands". In Williams, Haydn (ed.). Enamels of the world, 1700-2000: the Khalili collections. London: Khalili Family Trust. pp. 187–196. ISBN 978-1-874780-17-5.
  17. ^ "The Art of Minakari". iranreview.org.
  18. ^ "What is Vitreous Enamel?". vea.org.uk.
  19. ^ database and e-research tool for art and design researchers. "Bernard Hesling :: biography at :: at Design and Art Australia Online". Daao.org.au. Retrieved 2013-12-25.
  20. ^ a b Andrews, Andrew Irving, Porcelain enamels: the preparation, application, and properties of enamels, Garrard Press, 1961
  21. ^ Judd, Donald, “Porcelain Enameling Aluminum: An Overview,” Proceedings of the 59th Porcelain Enamel Institute Technical Forum, 45-51 (1997).
  22. ^ Sullivan, J.D. and Nelson, F.W., "Stainless Steel Requires Special Enameling Procedures", Proceedings of the Porcelain Enamel Institute Technical Forum," 150-155 (1970).
  23. ^ Pew, Steve, "The Who, What, Why, Where, and When of Cast Iron Enameling," Advances in Porcelain Enamel Technology, 177-186, (2010).
  24. ^ Fedak, David and Baldwin, Charles, "A Comparison of Enameled and Stainless Steel Surfaces," Proceedings of the 67th Porcelain Enamel Institute Technical Forum, 45-54 (2005).
  25. ^ Gavlenski, Jim and Baldwin, Charles, "Advanced Porcelain Enamel Coatings with Novel Properties," Proceedings of the 69th Porcelain Enamel Institute Technical Forum, 53-58, (2007).
  26. ^ Andrews, A.I. Porcelain Enamels, The Garrard Press: Champaign, IL, 1961 p. 321-2.
  27. ^ Campbell, 6, 10-17
  28. ^ Campbell, 7, 17-32
  29. ^ Campbell, 7
  30. ^ British Museum collection database, "Scope note" for the term "enamelled"; other sources use different categories.
  31. ^ Campbell, 7, 33-41
  32. ^ Campbell, 38-42
  33. ^ Campbell, 7, 42
  34. ^ Lucie-Smith, 83
  35. ^ . Luce Foundation Center for American Art. Smithsonian American Art Museum. Archived from the original on 13 July 2009. Retrieved 29 March 2013.
  36. ^ Lucie-Smith, 84
  37. ^ Lucie-Smith, 83
  38. ^ Feldman, Sid and Baldwin, Charles, "Surface Tension and Fusion Properties of Porcelain Enamels," Proceedings of the 69th Porcelain Enamel Institute Technical Forum, 1-10 (2008)
  39. ^ Vitreous and porcelain enamels — Characteristics of enamel coatings applied to steel panels intended for architecture. Standards Policy and Strategy Committee. 2008. ISBN 978-0-580-72284-4.

References

  • Campbell, Marian. An Introduction to Medieval Enamels, 1983, HMSO for V&A Museum, ISBN 0-11-290385-1
  • Lucie-Smith, Edward, The Thames & Hudson Dictionary of Art Terms, 2003 (2nd edn), Thames & Hudson, World of Art series, ISBN 0500203652
  • Ogden, Jack, "Metal", in Ancient Egyptian Materials and Technology, eds. Paul T. Nicholson, Ian Shaw, 2000, Cambridge University Press, ISBN 0521452570, 9780521452571, google books
  • Osborne, Harold (ed), The Oxford Companion to the Decorative Arts, 1975, OUP, ISBN 0198661134

Further reading

  • "Collection Highlights: Art in the Islamic World". Beaker. Smithsonian Institution: 2013.
  • Dimand, M. S. "An Enameled-Glass Bottle of the Mamluk Period". Metropolitan Museum of Art.
  • Maryon, Herbert (1971). "Enamelling". Metalwork and Enamelling (5th ed.). New York: Dover. ISBN 0-486-22702-2.
  • Papadopoulous, Kiko. "Venetian Eastern Trade: 11th to 14th Centuries" 20 January 2012.

External links

  • Enamels on jewelry – historical
  • Enameling Articles and Tutorials at The Ganoksin Project
  • Mechanical and Physical Properties of Vitreous Enamel
  • Glass on Metal Magazine Online (US)
  • CIDAE Center of Information and Difusion of the Art of Enamelling (ES)
  • EEA European Enamel Authority (EU)
  • Society of Dutch Enamellers (NL)
  • The Enamelist Society (US)
  • Guild of Enamellers, UK
  • International Enamellers Institute
  • Vitreous Enamel Association (UK)

vitreous, enamel, also, called, porcelain, enamel, material, made, fusing, powdered, glass, substrate, firing, usually, between, powder, melts, flows, then, hardens, smooth, durable, vitreous, coating, word, comes, from, latin, vitreum, meaning, glass, gothic,. Vitreous enamel also called porcelain enamel is a material made by fusing powdered glass to a substrate by firing usually between 750 and 850 C 1 380 and 1 560 F The powder melts flows and then hardens to a smooth durable vitreous coating The word comes from the Latin vitreum meaning glass Gothic chasse 1185 1200 champleve enamel over copper gilded height 17 7 cm width 17 4 cm depth 10 1 cm Enamel can be used on metal glass ceramics stone or any material that will withstand the fusing temperature In technical terms fired enamelware is an integrated layered composite of glass and another material or more glass The term enamel is most often restricted to work on metal which is the subject of this article Essentially the same technique used with other bases is known by different terms on glass as enamelled glass or painted glass and on pottery it is called overglaze decoration overglaze enamels or enamelling The craft is called enamelling the artists enamellers and the objects produced can be called enamels Chinese dish with scalloped rim from the Ming Dynasty early 15th century cloisonne enamel height 2 5 cm diameter 15 2 cm Enamelling is an old and widely adopted technology for most of its history mainly used in jewellery and decorative art Since the 18th century enamels have also been applied to many metal consumer objects such as some cooking vessels steel sinks and cast iron bathtubs It has also been used on some appliances such as dishwashers laundry machines and refrigerators and on marker boards and signage The term enamel has also sometimes been applied to industrial materials other than vitreous enamel such as enamel paint and the polymers coating enameled wire these actually are very different in materials science terms The word enamel comes from the Old High German word smelzan to smelt via the Old French esmail 1 or from a Latin word smaltum first found in a 9th century Life of Leo IV 2 Used as a noun an enamel is usually a small decorative object coated with enamel Enamelled and enamelling are the preferred spellings in British English while enameled and enameling are preferred in American English Contents 1 History 1 1 Ancient 1 2 Medieval and Renaissance Europe 1 3 China 1 4 Japan 1 5 India and Islamic world 1 6 Modern 2 Properties 3 Techniques of artistic enameling 4 Industrial enamel application 5 Building cladding 6 Gallery 7 See also 8 Notes 9 References 10 Further reading 11 External linksHistory Edit Staffordshire Moorlands Pan 2nd century Roman Britain Ancient Edit The earliest enamel all used the cloisonne technique placing the enamel within small cells with gold walls This had been used as a technique to hold pieces of stone and gems tightly in place since the 3rd millennium BC for example in Mesopotamia and then Egypt Enamel seems likely to have developed as a cheaper method of achieving similar results 3 The earliest undisputed objects known to use enamel are a group of Mycenaean rings from Cyprus dated to the 13th century BC 3 Although Egyptian pieces including jewellery from the Tomb of Tutankhamun of c 1325 BC are frequently described as using enamel many scholars doubt the glass paste was sufficiently melted to be properly so described and use terms such as glass paste It seems possible that in Egyptian conditions the melting point of the glass and gold were too close to make enamel a viable technique Nonetheless there appear to be a few actual examples of enamel perhaps from the Third Intermediate Period of Egypt beginning 1070 BC on 4 But it remained rare in both Egypt and Greece The technique appears in the Koban culture of the northern and central Caucasus and was perhaps carried by the Sarmatians to the ancient Celts 3 Red enamel is used in 26 places on the Battersea Shield c 350 50 BC probably as an imitation of the red Mediterranean coral which is used on the Witham Shield 400 300 BC Pliny the Elder mentions the Celts use of the technique on metal which the Romans in his day hardly knew The Staffordshire Moorlands Pan is a 2nd century AD souvenir of Hadrian s Wall made for the Roman military market which has swirling enamel decoration in a Celtic style In Britain probably through preserved Celtic craft skills enamel survived until the hanging bowls of early Anglo Saxon art A problem that adds to the uncertainty over early enamel is artefacts typically excavated that appear to have been prepared for enamel but have now lost whatever filled the cloisons or backing to a champleve piece 3 This occurs in several different regions from ancient Egypt to Anglo Saxon England Once enamel becomes more common as in medieval Europe after about 1000 the assumption that enamel was originally used becomes safer Medieval and Renaissance Europe Edit Detail of painted Limoges enamel dish mid 16th century attributed to Jean de Court In European art history enamel was at its most important in the Middle Ages beginning with the Late Romans and then the Byzantine who began to use cloisonne enamel in imitation of cloisonne inlays of precious stones The Byzantine enamel style was widely adopted by the peoples of Migration Period northern Europe The Byzantines then began to use cloisonne more freely to create images this was also copied in Western Europe Mosan metalwork often included enamel plaques of the highest quality in reliquaries and other large works of goldsmithing Limoges enamel was made in Limoges France the most famous centre of vitreous enamel production in Western Europe though Spain also made a good deal Limoges became famous for champleve enamels from the 12th century onwards producing on a large scale and then after a period of reduced production from the 15th century retained its lead by switching to painted enamel on flat metal plaques The champleve technique was considerably easier and very widely practiced in the Romanesque period In Gothic art the finest work is in basse taille and ronde bosse techniques but cheaper champleve works continued to be produced in large numbers for a wider market Painted enamel remained in fashion for over a century and in France developed into a sophisticated Renaissance and the Mannerist style seen on objects such as large display dishes ewers inkwells and in small portraits After it fell from fashion it continued as a medium for portrait miniatures spreading to England and other countries This continued until the early 19th century A Russian school developed which used the technique on other objects as in the Renaissance and for relatively cheap religious pieces such as crosses and small icons China Edit Chinese cloisonne enamel bronze wine pot 18th century From either Byzantium or the Islamic world the cloisonne technique reached China in the 13 14th centuries The first written reference to cloisonne is in a book from 1388 where it is called Dashi Muslim ware 5 No Chinese pieces that are clearly from the 14th century are known the earliest datable pieces are from the reign of the Xuande Emperor 1425 35 which since they show a full use of Chinese styles suggest considerable experience in the technique Cloisonne remained very popular in China until the 19th century and is still produced today The most elaborate and most highly valued Chinese pieces are from the early Ming Dynasty especially the reigns of the Xuande Emperor and Jingtai Emperor 1450 57 although 19th century or modern pieces are far more common 5 Japan Edit Imperial vases by Ando Jubei with the chrysanthemum crests of the Imperial family using moriage to slightly raise the design Khalili Collection of Japanese Art Japanese artists did not make three dimensional enamelled objects until the 1830s but once the technique took hold based on analysis of Chinese objects it developed very rapidly reaching a peak in the Meiji and Taishō eras late 19th early 20th century 6 Enamel had been used as decoration for metalwork since about 1600 7 6 and Japanese cloisonne was already exported to Europe before the start of the Meiji era in 1868 6 Cloisonne is known in Japan as shippo literally seven treasures 8 This refers to richly coloured substances mentioned in Buddhist texts 9 The term was initially used for colourful objects imported from China According to legend in the 1830s Kaji Tsunekichi broke open a Chinese enamel object to examine it then trained many artists starting off Japan s own enamel industry 9 7 Early Japanese enamels were cloudy and opaque with relatively clumsy shapes This changed rapidly from 1870 onwards 6 The Nagoya cloisonne company Nagoya shippo kaisha existed from 1871 to 1884 to sell the output of many small workshops and help them improve their work 6 In 1874 the government created the Kiriu kosho kaisha company to sponsor the creation of a wide range of decorative arts at international exhibitions This was part of a programme to promote Japan as a modern industrial nation 6 Gottfried Wagener was a German scientist brought in by the government to advise Japanese industry and improve production processes Along with Namikawa Yasuyuki he developed a transparent black enamel which was used for backgrounds Translucent enamels in various other colours followed during this period 6 Along with Tsukamoto Kaisuke Wagener transformed the firing processes used by Japanese workshops improving the quality of finishes and extending the variety of colours 6 Kawade Shibatarō introduced a variety of techniques including nagare gusuri drip glaze which produces a rainbow coloured glaze and uchidashi repousse technique in which the metal foundation is hammered outwards to create a relief effect 10 Together with Hattori Tadasaburō he developed the moriage piling up technique which places layers of enamel upon each other to create a three dimensional effect 11 Namikawa Sōsuke developed a pictorial style that imitated paintings He is known for shosen minimised wires and musen wireless cloisonne techniques developed with Wagener in which the wire cloisons are minimised or burned away completely with acid 12 7 This contrasts with the Chinese style which used thick metal cloisons 6 Ando Jubei introduced the shōtai jippō plique a jour technique which burns away the metal substrate to leave translucent enamel producing an effect resembling stained glass 13 The Ando Cloisonne Company which he co founded is one of the few makers from this era still active 6 Distinctively Japanese designs in which flowers birds and insects were used as themes became popular Designs also increasingly used areas of blank space 7 With the greater subtlety these techniques allowed Japanese enamels were regarded as unequalled in the world 14 and won many awards at national and international exhibitions 12 15 India and Islamic world Edit Meenakaari art from Iran Enamel was established in the Mughal Empire by around 1600 for decorating gold and silver objects and became a distinctive feature of Mughal jewellery The Mughal court was known to employ minakar enamelers 16 These craftsmen reached a peak of during the reign of Shah Jahan in the mid 17th century Transparent enamels were popular during this time 16 Both cloissone and champleve were produced in Mughal with champleve used for the finest pieces 16 Modern industrial production began in Calcutta in 1921 with the Bengal Enamel Works Limited Enamel was used in Iran for colouring and ornamenting the surface of metals by fusing over it brilliant colours that are decorated in an intricate design called Meenakari The French traveller Jean Chardin who toured Iran during the Safavid period made a reference to an enamel work of Isfahan which comprised a pattern of birds and animals on a floral background in light blue green yellow and red Gold has been used traditionally for Meenakari jewellery as it holds the enamel better lasts longer and its lustre brings out the colours of the enamels Silver a later introduction is used for artifacts like boxes bowls spoons and art pieces Copper began to be used for handicraft products after the Gold Control Act was enforced in India which compelled the Meenakars to look for an alternative material Initially the work of Meenakari often went unnoticed as this art was traditionally used on the back of pieces of kundan or gem studded jewellery allowing pieces to be reversible 17 Modern Edit Grey clouds typical enamel cooking gear from the Dutch DRU factory popular in the 1950s More recently the bright jewel like colours have made enamel a favoured choice for jewellery designers including the Art Nouveau jewellers for designers of bibelots such as the eggs of Peter Carl Faberge and the enameled copper boxes of the Battersea enamellers 18 and for artists such as George Stubbs and other painters of portrait miniatures A resurgence in enamel based art took place near the end of the 20th century in the Soviet Union led by artists like Alexei Maximov and Leonid Efros In Australia abstract artist Bernard Hesling brought the style into prominence with his variously sized steel plates 19 Enamel was first applied commercially to sheet iron and steel in Austria and Germany in about 1850 20 5 Industrialization increased as the purity of raw materials increased and costs decreased The wet application process started with the discovery of the use of clay to suspend frit in water Developments that followed during the 20th century include enamelling grade steel cleaned only surface preparation automation and ongoing improvements in efficiency performance and quality 20 5 Properties Edit Glass vials with ground vitreous enamel powder in different colors Vitreous enamel can be applied to most metals Most modern industrial enamel is applied to steel in which the carbon content is controlled to prevent unwanted reactions at the firing temperatures Enamel can also be applied to gold silver copper aluminium 21 stainless steel 22 and cast iron 23 Vitreous enamel has many useful properties it is smooth hard chemically resistant durable scratch resistant 5 6 on the Mohs scale has long lasting colour fastness is easy to clean and cannot burn Enamel is glass not paint so it does not fade under ultraviolet light 24 A disadvantage of enamel is a tendency to crack or shatter when the substrate is stressed or bent but modern enamels are relatively chip and impact resistant because of good thickness control and coefficients of thermal expansion well matched to the metal The Buick automobile company was founded by David Dunbar Buick with wealth earned by his development of improved enamelling processes c 1887 for sheet steel and cast iron Such enameled ferrous material had and still has many applications early 20th century and some modern advertising signs interior oven walls cooking pots housing and interior walls of major kitchen appliances housing and drums of clothes washers and dryers sinks and cast iron bathtubs farm storage silos and processing equipment such as chemical reactors and pharmaceutical process tanks Structures such as filling stations bus stations and Lustron Houses had walls ceilings and structural elements made of enamelled steel One of the most widespread modern uses of enamel is in the production of quality chalk boards and marker boards typically called blackboards or whiteboards where the resistance of enamel to wear and chemicals ensures that ghosting or unerasable marks do not occur as happens with polymer boards Since standard enamelling steel is magnetically attractive it may also be used for magnet boards Some new developments in the last ten years include enamel non stick hybrid coatings sol gel functional top coats for enamels enamels with a metallic appearance and easy to clean enamels 25 The key ingredient of vitreous enamel is finely ground glass called frit Frit for enamelling steel is typically an alkali borosilicate glass with a thermal expansion and glass temperature suitable for coating steel Raw materials are smelted together between 2 100 and 2 650 F 1 150 and 1 450 C into a liquid glass that is directed out of the furnace and thermal shocked with either water or steel rollers into frit 26 Colour in enamel is obtained by the addition of various minerals often metal oxides cobalt praseodymium iron or neodymium The latter creates delicate shades ranging from pure violet through wine red and warm grey Enamel can be transparent opaque or opalescent translucent Different enamel colours can be mixed to make a new colour in the manner of paint There are various types of frit which may be applied in sequence A ground coat is applied first it usually contains smelted in transition metal oxides such as cobalt nickel copper manganese and iron that facilitate adhesion to the metal Next clear and semi opaque frits that contain material for producing colours are applied View into a glass lined chemical reactor Turb mixer in a glass lined chemical reactorTechniques of artistic enameling Edit Medallion of the Death of the Virgin with basse taille enamel partly fallen away The Dunstable Swan Jewel a livery badge in ronde bosse enamel about 1400 British Museum The three main historical techniques for enamelling metal are Cloisonne French for cell where thin wires are applied to form raised barriers which contain different areas of subsequently applied enamel Widely practiced in Europe the Middle East and East Asia 27 Champleve French for raised field where the surface is carved out to form pits in which enamel is fired leaving the original metal exposed the Romanesque Stavelot Triptych is an example 28 Painted enamel a design in enamel is painted onto a smooth metal surface Limoges enamel is the best known type of painted enamel using this from the 16th century onwards 29 Most traditional painting on glass and some on ceramics uses what is technically enamel but is often described by terms such as painted in enamels reserving painted enamel and enamel as a term for the whole object for works with a metal base 30 Variants and less common techniques are Basse taille from the French word meaning low cut The surface of the metal is decorated with a low relief design which can be seen through translucent and transparent enamels The 14th century Royal Gold Cup is an outstanding example 31 Plique a jour French for open to daylight where the enamel is applied in cells similar to cloisonne but with no backing so light can shine through the transparent or translucent enamel It has a stained glass like appearance the Merode Cup is the surviving medieval example 32 Ronde bosse French for in the round also known as encrusted enamel A 3D type of enamelling where a sculptural form or wire framework is completely or partly enamelled as in the 15th century Holy Thorn Reliquary 33 Grisaille version of painted enamel French term meaning in grey where a dark often blue or black background is applied then a palescent translucent enamel is painted on top building up designs in a monochrome gradient paler as the thickness of the layer of light colour increases 34 En resille Email en resille sur verre French for enamel in a network on glass where enamelled metal is suspended in glass The technique was briefly popular in seventeenth century France and was re discovered by Margret Craver in 1953 Craver spent 13 years re creating the technique 35 Other types Enamelled glass in which a glass surface is enamelled and fired to fuse the glasses Stenciling where a stencil is placed over the work and the powdered enamel is sifted over the top The stencil is removed before firing the enamel staying in a pattern slightly raised Sgraffito where an unfired layer of enamel is applied over a previously fired layer of enamel of a contrasting colour and then partly removed with a tool to create the design Serigraph where a silkscreen is used with 60 70in grade mesh Surrey enamel a 17th century type for brass objects such as candlesticks effectively champleve 36 Counter enamelling not strictly a technique but a necessary step in many techniques especially painted enamel on thin plaques introduced in 15th century Europe Enamel is applied to the back of a piece as well sandwiching the metal to equalize the rates of expansion under heat and so create less tension on the glass so it does not crack 37 Safed chalwan where jewels are set in white enamelSee also Japanese shipōyaki techniques Industrial enamel application Edit Old German enamel street sign Main article Industrial porcelain enamel On sheet steel a ground coat layer is applied to create adhesion The only surface preparation required for modern ground coats is degreasing of the steel with a mildly alkaline solution White and coloured second cover coats of enamel are applied over the fired ground coat For electrostatic enamels the coloured enamel powder can be applied directly over a thin unfired ground coat base coat layer that is co fired with the cover coat in a very efficient two coat one fire process The frit in the ground coat contains smelted in cobalt and or nickel oxide as well as other transition metal oxides to catalyse the enamel steel bonding reactions During firing of the enamel at between 760 to 895 C 1 400 to 1 643 F iron oxide scale first forms on the steel The molten enamel dissolves the iron oxide and precipitates cobalt and nickel The iron acts as the anode in an electrogalvanic reaction in which the iron is again oxidised dissolved by the glass and oxidised again with the available cobalt and nickel limiting the reaction Finally the surface becomes roughened with the glass anchored into the holes 38 Building cladding EditEnamel coatings applied to steel panels offer protection to the core material whether cladding road tunnels underground stations building superstructures or other applications It can also be specified as a curtain walling Qualities of this structural material include 39 Durable Withstands extreme temperatures and is non flammable Long lasting UV climate and corrosion resistance Dirt repellent and graffiti proof Resistant to abrasion and chemicals Easy cleaning and maintenanceGallery Edit Early 13th century Limoges chasse used to hold holy oils most were reliquaries Silver silver gilt and painted enamel beaker Burgundian Netherlands c 1425 1450 The Cloisters nyc The Royal Gold Cup with basse taille enamels weight 1 935 kg British Museum Saint Agnes appears to her friends in a vision Limoges grisaille painted Stations of the Cross Notre Dame des Champs Avranches St Gregory the Great in painted Limoges enamel on a copper plaque by Jacques I Laudin A freehand enameled painting by Einar Hakonarson In the forest 1989 Louis George enamel watch dial Iranian enamelSee also EditFred Uhl Ball American enamellist who created the largest known enamel mural Oskar Schindler Rostov in Russia with Moscow a centre of the Russian industryNotes Edit Campbell 6 Chisholm Hugh ed 1911 Enamel Encyclopaedia Britannica 11th ed Cambridge University Press a b c d Osborne 331 Ogden 166 a b Sullivan Michael The arts of China 4th edn p 239 University of California Press 1999 ISBN 0 520 21877 9 ISBN 978 0 520 21877 2 Google books a b c d e f g h i j Impey Oliver Fairley Malcolm 2009 Enamel in Japan In Williams Haydn ed Enamels of the world 1700 2000 the Khalili collections London Khalili Family Trust pp 149 156 ISBN 978 1 874780 17 5 a b c d Earle Joe 1999 Splendors of Meiji treasures of imperial Japan masterpieces from the Khalili Collection St Petersburg Fla Broughton International Inc pp 252 254 ISBN 1874780137 OCLC 42476594 Harada Jiro 1911 Japanese Art amp Artists of To day VI Cloisonne Enamels The Studio 53 271 via Internet Archive a b Polished to Perfection Asian Art Newspaper 5 November 2017 ISSN 1475 1372 Retrieved 16 July 2020 Kawade Shibatarō Imperial Presentation Vase with Maple Branches and Imperial Chrysanthemum Crest one of a pair www metmuseum org Metropolitan Museum of Art Retrieved 16 July 2020 Irvine Gregory 2013 Japonisme and the rise of the modern art movement the arts of the Meiji period the Khalili collection New York Thames amp Hudson p 181 ISBN 978 0 500 23913 1 OCLC 853452453 a b Leonard Loryn 2012 06 26 How It s Made Japanese Cloisonne Dallas Museum of Art Uncrated Retrieved 2020 10 16 Ashmolean Eastern Art Online Yousef Jameel Centre for Islamic and Asian Art jameelcentre ashmolean org Ashmolean Museum University of Oxford Retrieved 16 July 2020 Japanese Art Enamels The Decorator and Furnisher 21 5 170 1893 ISSN 2150 6256 JSTOR 25582341 We doubt if any form of the enameller s art can equal the work executed in Japan which is distinguished by great freedom of design and the most exquisite gradations of color Toyoro Hida Gregory Irvine Kana Ooki Tomoko Hana and Yukari Muro Namikawa Yasuyuki and Japanese Cloisonne The Allure of Meiji Cloisonne The Aesthetic of Translucent Black pp 182 188 The Mainichi Newspapers Co Ltd 2017 a b c Moura Carvalho Pedro 2009 Enamel in the Islamic Lands In Williams Haydn ed Enamels of the world 1700 2000 the Khalili collections London Khalili Family Trust pp 187 196 ISBN 978 1 874780 17 5 The Art of Minakari iranreview org What is Vitreous Enamel vea org uk database and e research tool for art and design researchers Bernard Hesling biography at at Design and Art Australia Online Daao org au Retrieved 2013 12 25 a b Andrews Andrew Irving Porcelain enamels the preparation application and properties of enamels Garrard Press 1961 Judd Donald Porcelain Enameling Aluminum An Overview Proceedings of the 59th Porcelain Enamel Institute Technical Forum 45 51 1997 Sullivan J D and Nelson F W Stainless Steel Requires Special Enameling Procedures Proceedings of the Porcelain Enamel Institute Technical Forum 150 155 1970 Pew Steve The Who What Why Where and When of Cast Iron Enameling Advances in Porcelain Enamel Technology 177 186 2010 Fedak David and Baldwin Charles A Comparison of Enameled and Stainless Steel Surfaces Proceedings of the 67th Porcelain Enamel Institute Technical Forum 45 54 2005 Gavlenski Jim and Baldwin Charles Advanced Porcelain Enamel Coatings with Novel Properties Proceedings of the 69th Porcelain Enamel Institute Technical Forum 53 58 2007 Andrews A I Porcelain Enamels The Garrard Press Champaign IL 1961 p 321 2 Campbell 6 10 17 Campbell 7 17 32 Campbell 7 British Museum collection database Scope note for the term enamelled other sources use different categories Campbell 7 33 41 Campbell 38 42 Campbell 7 42 Lucie Smith 83 Craft Jewelry Brooch Luce Foundation Center for American Art Smithsonian American Art Museum Archived from the original on 13 July 2009 Retrieved 29 March 2013 Lucie Smith 84 Lucie Smith 83 Feldman Sid and Baldwin Charles Surface Tension and Fusion Properties of Porcelain Enamels Proceedings of the 69th Porcelain Enamel Institute Technical Forum 1 10 2008 Vitreous and porcelain enamels Characteristics of enamel coatings applied to steel panels intended for architecture Standards Policy and Strategy Committee 2008 ISBN 978 0 580 72284 4 References EditCampbell Marian An Introduction to Medieval Enamels 1983 HMSO for V amp A Museum ISBN 0 11 290385 1 Lucie Smith Edward The Thames amp Hudson Dictionary of Art Terms 2003 2nd edn Thames amp Hudson World of Art series ISBN 0500203652 Ogden Jack Metal in Ancient Egyptian Materials and Technology eds Paul T Nicholson Ian Shaw 2000 Cambridge University Press ISBN 0521452570 9780521452571 google books Osborne Harold ed The Oxford Companion to the Decorative Arts 1975 OUP ISBN 0198661134Further reading Edit Collection Highlights Art in the Islamic World Beaker Smithsonian Institution 2013 Dimand M S An Enameled Glass Bottle of the Mamluk Period Metropolitan Museum of Art Maryon Herbert 1971 Enamelling Metalwork and Enamelling 5th ed New York Dover ISBN 0 486 22702 2 Papadopoulous Kiko Venetian Eastern Trade 11th to 14th Centuries 20 January 2012 External links Edit Wikimedia Commons has media related to Enamel Enamels on jewelry historical Enameling Articles and Tutorials at The Ganoksin Project Mechanical and Physical Properties of Vitreous Enamel Glass on Metal Magazine Online US CIDAE Center of Information and Difusion of the Art of Enamelling ES EEA European Enamel Authority EU Society of Dutch Enamellers NL The Enamelist Society US Guild of Enamellers UK International Enamellers Institute Vitreous Enamel Association UK Retrieved from https en wikipedia org w index php title Vitreous enamel amp oldid 1120042569, wikipedia, wiki, book, books, library,

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