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Vanadium(III) sulfate

Vanadium(III) sulfate is the inorganic compound with the formula V2(SO4)3. It is a pale yellow solid that is stable to air, in contrast to most vanadium(III) compounds. It slowly dissolves in water to give the green aquo complex [V(H2O)6]3+.

Vanadium(III) sulfate[1]
Names
IUPAC name
Vanadium(III) sulfate
Other names
Vanadium trisulfate
Divanadium trisulfate
Identifiers
  • 13701-70-7 Y
ChemSpider
  • 19990317
ECHA InfoCard 100.033.827
EC Number
  • 237-226-6
  • 166888
UNII
  • 1EQF3LAK57 Y
  • DTXSID90890715
Properties
V2(SO4)3
Molar mass 390.074 g/mol
Appearance yellow powder
Melting point 400 °C (752 °F; 673 K) decomposes
slightly soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

The compound is prepared by treating V2O5 in sulfuric acid with elemental sulfur:[2]

V2O5 + S + 3 H2SO4 → V2(SO4)3 + SO2 + 3 H2O

This transformation is a rare example of a reduction by elemental sulfur.

When heated in vacuum at or slightly below 410 °C, it decomposes into vanadyl sulfate (VOSO4) and SO2. Vanadium(III) sulfate is stable in dry air but upon exposure to moist air for several weeks forms a green hydrate form.

Vanadium(III) sulfate is a reducing agent.

References edit

  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–93, ISBN 0-8493-0594-2
  2. ^ Robert T. Claunch, Mark M. Jones "Vanadium(III) Sulfate" Inorganic Syntheses, 1963, Volume 7, pages 92–94. doi:10.1002/9780470132388.ch28


vanadium, sulfate, inorganic, compound, with, formula, pale, yellow, solid, that, stable, contrast, most, vanadium, compounds, slowly, dissolves, water, give, green, aquo, complex, namesiupac, name, other, names, vanadium, trisulfatedivanadium, trisulfateident. Vanadium III sulfate is the inorganic compound with the formula V2 SO4 3 It is a pale yellow solid that is stable to air in contrast to most vanadium III compounds It slowly dissolves in water to give the green aquo complex V H2O 6 3 Vanadium III sulfate 1 NamesIUPAC name Vanadium III sulfateOther names Vanadium trisulfateDivanadium trisulfateIdentifiersCAS Number 13701 70 7 YChemSpider 19990317ECHA InfoCard 100 033 827EC Number 237 226 6PubChem CID 166888UNII 1EQF3LAK57 YCompTox Dashboard EPA DTXSID90890715PropertiesChemical formula V2 SO4 3Molar mass 390 074 g molAppearance yellow powderMelting point 400 C 752 F 673 K decomposesSolubility in water slightly solubleExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references The compound is prepared by treating V2O5 in sulfuric acid with elemental sulfur 2 V2O5 S 3 H2SO4 V2 SO4 3 SO2 3 H2OThis transformation is a rare example of a reduction by elemental sulfur When heated in vacuum at or slightly below 410 C it decomposes into vanadyl sulfate VOSO4 and SO2 Vanadium III sulfate is stable in dry air but upon exposure to moist air for several weeks forms a green hydrate form Vanadium III sulfate is a reducing agent References edit Lide David R 1998 Handbook of Chemistry and Physics 87 ed Boca Raton FL CRC Press pp 4 93 ISBN 0 8493 0594 2 Robert T Claunch Mark M Jones Vanadium III Sulfate Inorganic Syntheses 1963 Volume 7 pages 92 94 doi 10 1002 9780470132388 ch28 nbsp This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Vanadium III sulfate amp oldid 1118575757, wikipedia, wiki, book, books, library,

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