Attempts to synthesise PSI3 by the reaction of lithium iodide with thiophosphoryl bromide lead to the mixed thiophosphoryl halides PSBr2I and PSBrI2 instead.[3]
^Arthur D. F. Toy (1975). The Chemistry of Phosphorus. Permanon Texts in Inorganic Chemistry. Vol. 3. Permanon Press. p. 438. ISBN9781483139593.
^Dillon, K. B.; Craveirinha Dillon, M. G.; Waddington, T. C. (1977). "The identification of some new thiophosphoryl compounds containing P–I bonds by means of 31P N.M.R. spectroscopy". Inorg. Nucl. Chem. Lett.13 (8): 349–353. doi:10.1016/0020-1650(77)80109-8.
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thiophosphoryl, iodide, inorganic, compound, with, formula, psi3, names, other, names, phosphorothioic, triiodidephosphorus, thioiodidethiophosphoryl, triiodide, identifiers, number, 63972, model, jsmol, interactive, image, pubchem, 21517233, comptox, dashboar. Thiophosphoryl iodide is an inorganic compound with the formula PSI3 1 Thiophosphoryl iodide Names Other names Phosphorothioic triiodidePhosphorus thioiodideThiophosphoryl triiodide Identifiers CAS Number 63972 04 3 3D model JSmol Interactive image PubChem CID 21517233 CompTox Dashboard EPA DTXSID00615471 InChI InChI 1S I3PS c1 4 2 3 5Key CVHICNBAVVKDQW UHFFFAOYSA N SMILES S P I I I Properties Chemical formula PSI3 Molar mass 443 75 g mol 1 Appearance red brown solid 1 Melting point 48 C 118 F 321 K Boiling point decomposes Structure Molecular shape Tetrahedral at the P atom Related compounds Related compounds Phosphorus triiodidePhosphoryl iodideThiophosphoryl fluorideThiophosphoryl chlorideThiophosphoryl bromidePhosphorothioic chloride difluoride Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesPreparation editThiophosphoryl iodide can be prepared by reacting phosphorus triiodide with sulfur in carbon disulfide at 10 15 C in the dark for several days 1 2 Attempts to synthesise PSI3 by the reaction of lithium iodide with thiophosphoryl bromide lead to the mixed thiophosphoryl halides PSBr2I and PSBrI2 instead 3 References edit a b c Greenwood Norman N Earnshaw Alan 1997 Chemistry of the Elements 2nd ed Butterworth Heinemann pp 501 503 ISBN 978 0 08 037941 8 Arthur D F Toy 1975 The Chemistry of Phosphorus Permanon Texts in Inorganic Chemistry Vol 3 Permanon Press p 438 ISBN 9781483139593 Dillon K B Craveirinha Dillon M G Waddington T C 1977 The identification of some new thiophosphoryl compounds containing P I bonds by means of 31P N M R spectroscopy Inorg Nucl Chem Lett 13 8 349 353 doi 10 1016 0020 1650 77 80109 8 nbsp This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Thiophosphoryl iodide amp oldid 1177034970, wikipedia, wiki, book, books, library,
