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Tetrabutyltin

Tetrabutyltin is the organotin compound with the molecular formula Sn(CH2CH2CH2CH3)4 or SnBu4, where Bu is butyl −CH2CH2CH2CH3. Sometimes abbreviated TTBT, it is a colorless, lipophilic oil.[3]

Tetrabutyltin
Names
Preferred IUPAC name
Tetrabutylstannane
Other names
Tetra-n-butyltin
Tetra-n-butylstannane
Identifiers
  • 1461-25-2 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 14370 Y
ECHA InfoCard 100.014.510
  • 15098
UNII
  • QJ7Y5V377V Y
  • DTXSID4022153
  • InChI=1S/4C4H9.Sn/c4*1-3-4-2;/h4*1,3-4H2,2H3; Y
    Key: AFCAKJKUYFLYFK-UHFFFAOYSA-N Y
  • InChI=1/4C4H9.Sn/c4*1-3-4-2;/h4*1,3-4H2,2H3;/rC16H36Sn/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h5-16H2,1-4H3
    Key: AFCAKJKUYFLYFK-HBOYHTFSAP
  • CCCC[Sn](CCCC)(CCCC)CCCC
Properties
Sn(CH2CH2CH2CH3)4
Molar mass 347.174 g·mol−1
Appearance Colourless liquid
Density 1.054 g/cm3
Melting point −97 °C (−143 °F; 176 K)
Boiling point 245 °C (473 °F; 518 K)
insoluble
Solubility non-polar solvents such as benzene, ether, or THF[1]
Hazards
GHS labelling:
Danger
H301, H312, H315, H319, H410
P273, P280, P301+P310+P330, P302+P352+P312, P305+P351+P338, P314[2]
Flash point 107 °C (225 °F; 380 K)
Safety data sheet (SDS) Tetrabutyltin
Related compounds
Related tetraalkylstannanes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)

Tetrabutyltin is a precursor to tributyltin and dibutyltin compounds. By the redistribution reaction with tin(IV) chloride it forms tributyltin chloride and dibutyltin chloride. These compounds are starting materials for a wide range of organotin compounds used as stabilizers for PVC and as biocides, fungicides, wood preservatives, and (historically) marine anti-biofouling agents.[4]

References edit

  1. ^ "13Tin - Gelest, Inc" (PDF).
  2. ^ Sigma-Aldrich Co., Tetrabutyltin. Retrieved on 2020-06-28.
  3. ^ Graf, Günter G. (2000). "Tin, Tin Alloys, and Tin Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a27_049.
  4. ^ Hoch, M. (2001). "Organotin compounds in the environment — an overview". Applied Geochemistry. 16 (s 7–8): 719–743. Bibcode:2001ApGC...16..719H. doi:10.1016/S0883-2927(00)00067-6.

tetrabutyltin, organotin, compound, with, molecular, formula, ch2ch2ch2ch3, snbu4, where, butyl, ch2ch2ch2ch3, sometimes, abbreviated, ttbt, colorless, lipophilic, namespreferred, iupac, name, tetrabutylstannaneother, names, tetra, butyltintetra, butylstannane. Tetrabutyltin is the organotin compound with the molecular formula Sn CH2CH2CH2CH3 4 or SnBu4 where Bu is butyl CH2CH2CH2CH3 Sometimes abbreviated TTBT it is a colorless lipophilic oil 3 Tetrabutyltin NamesPreferred IUPAC name TetrabutylstannaneOther names Tetra n butyltinTetra n butylstannaneIdentifiersCAS Number 1461 25 2 Y3D model JSmol Interactive imageChemSpider 14370 YECHA InfoCard 100 014 510PubChem CID 15098UNII QJ7Y5V377V YCompTox Dashboard EPA DTXSID4022153InChI InChI 1S 4C4H9 Sn c4 1 3 4 2 h4 1 3 4H2 2H3 YKey AFCAKJKUYFLYFK UHFFFAOYSA N YInChI 1 4C4H9 Sn c4 1 3 4 2 h4 1 3 4H2 2H3 rC16H36Sn c1 5 9 13 17 14 10 6 2 15 11 7 3 16 12 8 4 h5 16H2 1 4H3Key AFCAKJKUYFLYFK HBOYHTFSAPSMILES CCCC Sn CCCC CCCC CCCCPropertiesChemical formula Sn CH2CH2CH2CH3 4Molar mass 347 174 g mol 1Appearance Colourless liquidDensity 1 054 g cm3Melting point 97 C 143 F 176 K Boiling point 245 C 473 F 518 K Solubility in water insolubleSolubility non polar solvents such as benzene ether or THF 1 HazardsGHS labelling PictogramsSignal word DangerHazard statements H301 H312 H315 H319 H410Precautionary statements P273 P280 P301 P310 P330 P302 P352 P312 P305 P351 P338 P314 2 Flash point 107 C 225 F 380 K Safety data sheet SDS TetrabutyltinRelated compoundsRelated tetraalkylstannanes TetramethyltinTetraethyltinTetrapropyltinExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Y verify what is Y N Infobox references Tetrabutyltin is a precursor to tributyltin and dibutyltin compounds By the redistribution reaction with tin IV chloride it forms tributyltin chloride and dibutyltin chloride These compounds are starting materials for a wide range of organotin compounds used as stabilizers for PVC and as biocides fungicides wood preservatives and historically marine anti biofouling agents 4 References edit 13Tin Gelest Inc PDF Sigma Aldrich Co Tetrabutyltin Retrieved on 2020 06 28 Graf Gunter G 2000 Tin Tin Alloys and Tin Compounds Ullmann s Encyclopedia of Industrial Chemistry Weinheim Wiley VCH doi 10 1002 14356007 a27 049 Hoch M 2001 Organotin compounds in the environment an overview Applied Geochemistry 16 s 7 8 719 743 Bibcode 2001ApGC 16 719H doi 10 1016 S0883 2927 00 00067 6 Retrieved from https en wikipedia org w index php title Tetrabutyltin amp oldid 1169950469, wikipedia, wiki, book, books, library,

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