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Ladder operator

In linear algebra (and its application to quantum mechanics), a raising or lowering operator (collectively known as ladder operators) is an operator that increases or decreases the eigenvalue of another operator. In quantum mechanics, the raising operator is sometimes called the creation operator, and the lowering operator the annihilation operator. Well-known applications of ladder operators in quantum mechanics are in the formalisms of the quantum harmonic oscillator and angular momentum.

Terminology edit

There is a relationship between the raising and lowering ladder operators and the creation and annihilation operators commonly used in quantum field theory which lies in representation theory. The creation operator ai increments the number of particles in state i, while the corresponding annihilation operator ai decrements the number of particles in state i. This clearly satisfies the requirements of the above definition of a ladder operator: the incrementing or decrementing of the eigenvalue of another operator (in this case the particle number operator).

Confusion arises because the term ladder operator is typically used to describe an operator that acts to increment or decrement a quantum number describing the state of a system. To change the state of a particle with the creation/annihilation operators of QFT requires the use of both annihilation and creation operators. An annihilation operator is used to remove a particle from the initial state and a creation operator is used to add a particle to the final state.

The term "ladder operator" or "raising and lowering operators" is also sometimes used in mathematics, in the context of the theory of Lie algebras and in particular the affine Lie algebras. For example to describe the su(2) subalgebras, the root system and the highest weight modules can be constructed by means of the ladder operators.[1] In particular, the highest weight is annihilated by the raising operators; the rest of the positive root space is obtained by repeatedly applying the lowering operators (one set of ladder operators per subalgebra).

Motivation from mathematics edit

From a representation theory standpoint a linear representation of a semi-simple Lie group in continuous real parameters induces a set of generators for the Lie algebra. A complex linear combination of those are the ladder operators.[clarification needed] For each parameter there is a set of ladder operators; these are then a standardized way to navigate one dimension of the root system and root lattice.[2] The ladder operators of the quantum harmonic oscillator or the "number representation" of second quantization are just special cases of this fact. Ladder operators then become ubiquitous in quantum mechanics from the angular momentum operator, to coherent states and to discrete magnetic translation operators.

General formulation edit

Suppose that two operators X and N have the commutation relation

 
for some scalar c. If   is an eigenstate of N with eigenvalue equation
 
then the operator X acts on   in such a way as to shift the eigenvalue by c:
 

In other words, if   is an eigenstate of N with eigenvalue n, then   is an eigenstate of N with eigenvalue n + c or is zero. The operator X is a raising operator for N if c is real and positive, and a lowering operator for N if c is real and negative.

If N is a Hermitian operator, then c must be real, and the Hermitian adjoint of X obeys the commutation relation

 

In particular, if X is a lowering operator for N, then X is a raising operator for N and conversely.[dubious ]

Angular momentum edit

A particular application of the ladder operator concept is found in the quantum-mechanical treatment of angular momentum. For a general angular momentum vector J with components Jx, Jy and Jz one defines the two ladder operators[3]

 
where i is the imaginary unit.

The commutation relation between the cartesian components of any angular momentum operator is given by

 
where εijk is the Levi-Civita symbol, and each of i, j and k can take any of the values x, y and z.

From this, the commutation relations among the ladder operators and Jz are obtained:

 
(technically, this is the Lie algebra of  ).

The properties of the ladder operators can be determined by observing how they modify the action of the Jz operator on a given state:

 

Compare this result with

 

Thus, one concludes that   is some scalar multiplied by  :

 

This illustrates the defining feature of ladder operators in quantum mechanics: the incrementing (or decrementing) of a quantum number, thus mapping one quantum state onto another. This is the reason that they are often known as raising and lowering operators.

To obtain the values of α and β, first take the norm of each operator, recognizing that J+ and J are a Hermitian conjugate pair ( ):

 

The product of the ladder operators can be expressed in terms of the commuting pair J2 and Jz:

 

Thus, one may express the values of |α|2 and |β|2 in terms of the eigenvalues of J2 and Jz:

 

The phases of α and β are not physically significant, thus they can be chosen to be positive and real (Condon–Shortley phase convention). We then have[4]

 

Confirming that m is bounded by the value of j ( ), one has

 

The above demonstration is effectively the construction of the Clebsch–Gordan coefficients.

Applications in atomic and molecular physics edit

Many terms in the Hamiltonians of atomic or molecular systems involve the scalar product of angular momentum operators. An example is the magnetic dipole term in the hyperfine Hamiltonian:[5]

 
where I is the nuclear spin.

The angular momentum algebra can often be simplified by recasting it in the spherical basis. Using the notation of spherical tensor operators, the "−1", "0" and "+1" components of J(1)J are given by[6]

 

From these definitions, it can be shown that the above scalar product can be expanded as

 

The significance of this expansion is that it clearly indicates which states are coupled by this term in the Hamiltonian, that is those with quantum numbers differing by mi = ±1 and mj = ∓1 only.

Harmonic oscillator edit

Another application of the ladder operator concept is found in the quantum-mechanical treatment of the harmonic oscillator. We can define the lowering and raising operators as

 

They provide a convenient means to extract energy eigenvalues without directly solving the system's differential equation.

Hydrogen-like atom edit

There are two main approaches given in the literature using ladder operators, one using the Laplace–Runge–Lenz vector, another using factorization of the Hamiltonian.

Laplace–Runge–Lenz vector edit

Another application of the ladder operator concept is found in the quantum mechanical treatment of the electronic energy of hydrogen-like atoms and ions. The Laplace–Runge–Lenz vector commutes with the Hamiltonian for an inverse square spherically symmetric potential and can be used to determine ladder operators for this potential.[7][8] We can define the lowering and raising operators (based on the classical Laplace–Runge–Lenz vector)

 
where   is the angular momentum,   is the linear momentum,   is the reduced mass of the system,   is the electronic charge, and   is the atomic number of the nucleus. Analogous to the angular momentum ladder operators, one has   and  .

The commutators needed to proceed are

 
and
 
Therefore,
 
and
 
so
 
where the "?" indicates a nascent quantum number which emerges from the discussion.

Given the Pauli equations[9][10] IV:

 
and III:
 
and starting with the equation
 
and expanding, one obtains (assuming   is the maximum value of the angular momentum quantum number consonant with all other conditions)
 
which leads to the Rydberg formula
 
implying that  , where   is the traditional quantum number.

Factorization of the Hamiltonian edit

The Hamiltonian for a hydrogen-like potential can be written in spherical coordinates as

 
where  , and the radial momentum
 
which is real and self-conjugate.

Suppose   is an eigenvector of the Hamiltonian, where   is the angular momentum, and   represents the energy, so  , and we may label the Hamiltonian as  :

 

The factorization method was developed by Infeld and Hull[11] for differential equations. Newmarch and Golding[12] applied it to spherically symmetric potentials using operator notation.

Suppose we can find a factorization of the Hamiltonian by operators   as

 

(1)

and

 
for scalars   and  . The vector   may be evaluated in two different ways as
 
which can be re-arranged as
 
showing that   is an eigenstate of   with eigenvalue
 
If  , then  , and the states   and   have the same energy.

For the hydrogenic atom, setting

 
with
 
a suitable equation for   is
 
with
 
There is an upper bound to the ladder operator if the energy is negative (so   for some  ), then if follows from equation (1) that
 
and   can be identified with  

Relation to group theory edit

Whenever there is degeneracy in a system, there is usually a related symmetry property and group. The degeneracy of the energy levels for the same value of   but different angular momenta has been identified as the SO(4) symmetry of the spherically symmetric Coulomb potential.[13][14]

3D isotropic harmonic oscillator edit

The 3D isotropic harmonic oscillator has a potential given by

 

It can similarly be managed using the factorization method.

Factorization method edit

A suitable factorization is given by[12]

 
with
 
and
 
Then
 
and continuing this,
 
Now the Hamiltonian only has positive energy levels as can be seen from
 
This means that for some value of   the series must terminate with   and then
 
This is decreasing in energy by   unless   for some value of  . Identifying this value as   gives
 

It then follows the   so that

 
giving a recursion relation on   with solution
 

There is degeneracy caused from angular momentum; there is additional degeneracy caused by the oscillator potential. Consider the states   and apply the lowering operators  :   giving the sequence   with the same energy but with   decreasing by 2. In addition to the angular momentum degeneracy, this gives a total degeneracy of  [15]

Relation to group theory edit

The degeneracies of the 3D isotropic harmonic oscillator are related to the special unitary group SU(3)[15][16]

History edit

Many sources credit Paul Dirac with the invention of ladder operators.[17] Dirac's use of the ladder operators shows that the total angular momentum quantum number   needs to be a non-negative half-integer multiple of ħ.

See also edit

References edit

  1. ^ Fuchs, Jurgen (1992), Affine Lie Algebras and Quantum Groups, Cambridge University Press, ISBN 0-521-48412-X
  2. ^ Harris, Fulton, Representation Theory pp. 164
  3. ^ de Lange, O. L.; R. E. Raab (1986). "Ladder operators for orbital angular momentum". American Journal of Physics. 54 (4): 372–375. Bibcode:1986AmJPh..54..372D. doi:10.1119/1.14625.
  4. ^ Sakurai, Jun J. (1994). Modern Quantum Mechanics. Delhi, India: Pearson Education, Inc. p. 192. ISBN 81-7808-006-0.
  5. ^ Woodgate, Gordon K. (1983-10-06). Elementary Atomic Structure. ISBN 978-0-19-851156-4. Retrieved 2009-03-03.
  6. ^ "Angular Momentum Operators". Graduate Quantum Mechanics Notes. University of Virginia. Retrieved 2009-04-06.
  7. ^ David, C. W. (1966). "Ladder Operator Solution for the Hydrogen Atom Electronic Energy Levels". American Journal of Physics. 34 (10): 984–985. Bibcode:1966AmJPh..34..984D. doi:10.1119/1.1972354.
  8. ^ Burkhardt, C. E.; Levanthal, J. (2004). "Lenz vector operations on spherical hydrogen atom eigenfunctions". American Journal of Physics. 72 (8): 1013–1016. Bibcode:2004AmJPh..72.1013B. doi:10.1119/1.1758225.
  9. ^ Pauli, Wolfgang (1926). "Über das Wasserstoffspektrum vom Standpunkt der neuen Quantenmechanik". Z. Phys. 36 (5): 336–363. Bibcode:1926ZPhy...36..336P. doi:10.1007/BF01450175. S2CID 128132824.
  10. ^ B. L. Van der Waerden, Sources of Quantum Mechanics, Dover, New York, 1968.
  11. ^ L., Infeld; Hull, T. E. (1951). "The Factorization Method". Rev. Mod. Phys. 23 (1): 21–68. Bibcode:1951RvMP...23...21I. doi:10.1103/RevModPhys.23.21.
  12. ^ a b Newmarch, J. D.; Golding, R. M. (1978). "Ladder operators for some spherically symmetric potentials in quantum". Am. J. Phys. 46: 658–660. doi:10.1119/1.11225.
  13. ^ Weinberg, S. J. (2011). "The SO(4) Symmetry of the Hydrogen Atom" (PDF).
  14. ^ Lahiri, A.; Roy, P. K.; Bagchi, B. (1989). "Supersymmetry and the Ladder Operator Technique in Quantum Mechanics: The Radial Schrödinger Equation". Int. J. Theor. Phys. 28 (2): 183–189. Bibcode:1989IJTP...28..183L. doi:10.1007/BF00669809. S2CID 123255435.
  15. ^ a b Kirson, M. W. (2013). "Introductory Algebra for Physicists: Isotropic harmonic oscillator" (PDF). Weizmann Institute of Science. Retrieved 28 July 2021.
  16. ^ Fradkin, D. M. (1965). "Three-dimensional isotropic harmonic oscillator and SU3". Am. J. Phys. 33 (3): 207–211. Bibcode:1965AmJPh..33..207F. doi:10.1119/1.1971373.
  17. ^ Webb, Stephen. "The Quantum Harmonic Oscillator" (PDF). www.fisica.net. Retrieved 5 November 2023.

ladder, operator, linear, algebra, application, quantum, mechanics, raising, lowering, operator, collectively, known, ladder, operators, operator, that, increases, decreases, eigenvalue, another, operator, quantum, mechanics, raising, operator, sometimes, call. In linear algebra and its application to quantum mechanics a raising or lowering operator collectively known as ladder operators is an operator that increases or decreases the eigenvalue of another operator In quantum mechanics the raising operator is sometimes called the creation operator and the lowering operator the annihilation operator Well known applications of ladder operators in quantum mechanics are in the formalisms of the quantum harmonic oscillator and angular momentum Contents 1 Terminology 2 Motivation from mathematics 3 General formulation 4 Angular momentum 4 1 Applications in atomic and molecular physics 5 Harmonic oscillator 6 Hydrogen like atom 6 1 Laplace Runge Lenz vector 6 2 Factorization of the Hamiltonian 6 3 Relation to group theory 7 3D isotropic harmonic oscillator 7 1 Factorization method 7 2 Relation to group theory 8 History 9 See also 10 ReferencesTerminology editMain article Creation and annihilation operators There is a relationship between the raising and lowering ladder operators and the creation and annihilation operators commonly used in quantum field theory which lies in representation theory The creation operator ai increments the number of particles in state i while the corresponding annihilation operator ai decrements the number of particles in state i This clearly satisfies the requirements of the above definition of a ladder operator the incrementing or decrementing of the eigenvalue of another operator in this case the particle number operator Confusion arises because the term ladder operator is typically used to describe an operator that acts to increment or decrement a quantum number describing the state of a system To change the state of a particle with the creation annihilation operators of QFT requires the use of both annihilation and creation operators An annihilation operator is used to remove a particle from the initial state and a creation operator is used to add a particle to the final state The term ladder operator or raising and lowering operators is also sometimes used in mathematics in the context of the theory of Lie algebras and in particular the affine Lie algebras For example to describe the su 2 subalgebras the root system and the highest weight modules can be constructed by means of the ladder operators 1 In particular the highest weight is annihilated by the raising operators the rest of the positive root space is obtained by repeatedly applying the lowering operators one set of ladder operators per subalgebra Motivation from mathematics editFrom a representation theory standpoint a linear representation of a semi simple Lie group in continuous real parameters induces a set of generators for the Lie algebra A complex linear combination of those are the ladder operators clarification needed For each parameter there is a set of ladder operators these are then a standardized way to navigate one dimension of the root system and root lattice 2 The ladder operators of the quantum harmonic oscillator or the number representation of second quantization are just special cases of this fact Ladder operators then become ubiquitous in quantum mechanics from the angular momentum operator to coherent states and to discrete magnetic translation operators General formulation editSuppose that two operators X and N have the commutation relation N X c X displaystyle N X cX nbsp for some scalar c If n displaystyle n rangle nbsp is an eigenstate of N with eigenvalue equation N n n n displaystyle N n rangle n n rangle nbsp then the operator X acts on n displaystyle n rangle nbsp in such a way as to shift the eigenvalue by c N X n X N N X n X N n N X n X n n c X n n c X n displaystyle begin aligned NX n rangle amp XN N X n rangle amp XN n rangle N X n rangle amp Xn n rangle cX n rangle amp n c X n rangle end aligned nbsp In other words if n displaystyle n rangle nbsp is an eigenstate of N with eigenvalue n then X n displaystyle X n rangle nbsp is an eigenstate of N with eigenvalue n c or is zero The operator X is a raising operator for N if c is real and positive and a lowering operator for N if c is real and negative If N is a Hermitian operator then c must be real and the Hermitian adjoint of X obeys the commutation relation N X c X displaystyle N X dagger cX dagger nbsp In particular if X is a lowering operator for N then X is a raising operator for N and conversely dubious discuss Angular momentum editMain article Angular momentum operator A particular application of the ladder operator concept is found in the quantum mechanical treatment of angular momentum For a general angular momentum vector J with components Jx Jy and Jz one defines the two ladder operators 3 J J x i J y J J x i J y displaystyle begin aligned J amp J x iJ y J amp J x iJ y end aligned nbsp where i is the imaginary unit The commutation relation between the cartesian components of any angular momentum operator is given by J i J j i ℏ ϵ i j k J k displaystyle J i J j i hbar epsilon ijk J k nbsp where eijk is the Levi Civita symbol and each of i j and k can take any of the values x y and z From this the commutation relations among the ladder operators and Jz are obtained J z J ℏ J J J 2 ℏ J z displaystyle begin aligned J z J pm amp pm hbar J pm J J amp 2 hbar J z end aligned nbsp technically this is the Lie algebra of s l 2 R displaystyle mathfrak s l 2 mathbb R nbsp The properties of the ladder operators can be determined by observing how they modify the action of the Jz operator on a given state J z J j m J J z J z J j m J J z ℏ J j m ℏ m 1 J j m displaystyle begin aligned J z J pm j m rangle amp big J pm J z J z J pm big j m rangle amp J pm J z pm hbar J pm j m rangle amp hbar m pm 1 J pm j m rangle end aligned nbsp Compare this result withJ z j m 1 ℏ m 1 j m 1 displaystyle J z j m pm 1 rangle hbar m pm 1 j m pm 1 rangle nbsp Thus one concludes that J j m displaystyle J pm j m rangle nbsp is some scalar multiplied by j m 1 displaystyle j m pm 1 rangle nbsp J j m a j m 1 J j m b j m 1 displaystyle begin aligned J j m rangle amp alpha j m 1 rangle J j m rangle amp beta j m 1 rangle end aligned nbsp This illustrates the defining feature of ladder operators in quantum mechanics the incrementing or decrementing of a quantum number thus mapping one quantum state onto another This is the reason that they are often known as raising and lowering operators To obtain the values of a and b first take the norm of each operator recognizing that J and J are a Hermitian conjugate pair J J displaystyle J pm J mp dagger nbsp j m J J j m j m J J j m j m 1 a a j m 1 a 2 j m J J j m j m J J j m j m 1 b b j m 1 b 2 displaystyle begin aligned amp langle j m J dagger J j m rangle langle j m J J j m rangle langle j m 1 alpha alpha j m 1 rangle alpha 2 amp langle j m J dagger J j m rangle langle j m J J j m rangle langle j m 1 beta beta j m 1 rangle beta 2 end aligned nbsp The product of the ladder operators can be expressed in terms of the commuting pair J2 and Jz J J J x i J y J x i J y J x 2 J y 2 i J x J y J 2 J z 2 ℏ J z J J J x i J y J x i J y J x 2 J y 2 i J x J y J 2 J z 2 ℏ J z displaystyle begin aligned J J amp J x iJ y J x iJ y J x 2 J y 2 i J x J y J 2 J z 2 hbar J z J J amp J x iJ y J x iJ y J x 2 J y 2 i J x J y J 2 J z 2 hbar J z end aligned nbsp Thus one may express the values of a 2 and b 2 in terms of the eigenvalues of J2 and Jz a 2 ℏ 2 j j 1 ℏ 2 m 2 ℏ 2 m ℏ 2 j m j m 1 b 2 ℏ 2 j j 1 ℏ 2 m 2 ℏ 2 m ℏ 2 j m j m 1 displaystyle begin aligned alpha 2 amp hbar 2 j j 1 hbar 2 m 2 hbar 2 m hbar 2 j m j m 1 beta 2 amp hbar 2 j j 1 hbar 2 m 2 hbar 2 m hbar 2 j m j m 1 end aligned nbsp The phases of a and b are not physically significant thus they can be chosen to be positive and real Condon Shortley phase convention We then have 4 J j m ℏ j m j m 1 j m 1 ℏ j j 1 m m 1 j m 1 J j m ℏ j m j m 1 j m 1 ℏ j j 1 m m 1 j m 1 displaystyle begin aligned J j m rangle amp hbar sqrt j m j m 1 j m 1 rangle hbar sqrt j j 1 m m 1 j m 1 rangle J j m rangle amp hbar sqrt j m j m 1 j m 1 rangle hbar sqrt j j 1 m m 1 j m 1 rangle end aligned nbsp Confirming that m is bounded by the value of j j m j displaystyle j leq m leq j nbsp one hasJ j j 0 J j j 0 displaystyle begin aligned J j j rangle amp 0 J j j rangle amp 0 end aligned nbsp The above demonstration is effectively the construction of the Clebsch Gordan coefficients Applications in atomic and molecular physics edit Many terms in the Hamiltonians of atomic or molecular systems involve the scalar product of angular momentum operators An example is the magnetic dipole term in the hyperfine Hamiltonian 5 H D A I J displaystyle hat H text D hat A mathbf I cdot mathbf J nbsp where I is the nuclear spin The angular momentum algebra can often be simplified by recasting it in the spherical basis Using the notation of spherical tensor operators the 1 0 and 1 components of J 1 J are given by 6 J 1 1 1 2 J x i J y J 2 J 0 1 J z J 1 1 1 2 J x i J y J 2 displaystyle begin aligned J 1 1 amp dfrac 1 sqrt 2 J x iJ y dfrac J sqrt 2 J 0 1 amp J z J 1 1 amp frac 1 sqrt 2 J x iJ y frac J sqrt 2 end aligned nbsp From these definitions it can be shown that the above scalar product can be expanded asI 1 J 1 n 1 1 1 n I n 1 J n 1 I 0 1 J 0 1 I 1 1 J 1 1 I 1 1 J 1 1 displaystyle mathbf I 1 cdot mathbf J 1 sum n 1 1 1 n I n 1 J n 1 I 0 1 J 0 1 I 1 1 J 1 1 I 1 1 J 1 1 nbsp The significance of this expansion is that it clearly indicates which states are coupled by this term in the Hamiltonian that is those with quantum numbers differing by mi 1 and mj 1 only Harmonic oscillator editMain article Quantum harmonic oscillator Another application of the ladder operator concept is found in the quantum mechanical treatment of the harmonic oscillator We can define the lowering and raising operators asa m w 2 ℏ x i m w p a m w 2 ℏ x i m w p displaystyle begin aligned hat a amp sqrt m omega over 2 hbar left hat x i over m omega hat p right hat a dagger amp sqrt m omega over 2 hbar left hat x i over m omega hat p right end aligned nbsp They provide a convenient means to extract energy eigenvalues without directly solving the system s differential equation Hydrogen like atom editMain article Hydrogen like atom There are two main approaches given in the literature using ladder operators one using the Laplace Runge Lenz vector another using factorization of the Hamiltonian Laplace Runge Lenz vector edit Another application of the ladder operator concept is found in the quantum mechanical treatment of the electronic energy of hydrogen like atoms and ions The Laplace Runge Lenz vector commutes with the Hamiltonian for an inverse square spherically symmetric potential and can be used to determine ladder operators for this potential 7 8 We can define the lowering and raising operators based on the classical Laplace Runge Lenz vector A 1 Z e 2 m L p i ℏ p r r displaystyle vec A left frac 1 Ze 2 mu right left vec L times vec p boldsymbol i hbar vec p right frac vec r r nbsp where L displaystyle vec L nbsp is the angular momentum p displaystyle vec p nbsp is the linear momentum m displaystyle mu nbsp is the reduced mass of the system e displaystyle e nbsp is the electronic charge and Z displaystyle Z nbsp is the atomic number of the nucleus Analogous to the angular momentum ladder operators one has A A x i A y displaystyle A A x iA y nbsp and A A x i A y displaystyle A A x iA y nbsp The commutators needed to proceed are A L z i ℏ A displaystyle A pm L z mp boldsymbol i hbar A mp nbsp and A L 2 2 ℏ 2 A 2 ℏ A L z 2 ℏ A z L displaystyle A pm L 2 mp 2 hbar 2 A pm 2 hbar A pm L z pm 2 hbar A z L pm nbsp Therefore A ℓ m ℓ ℓ m ℓ 1 displaystyle A ell m ell rangle rightarrow ell m ell 1 rangle nbsp and L 2 A ℓ ℓ ℏ 2 ℓ 1 ℓ 1 1 A ℓ ℓ displaystyle L 2 left A ell ell rangle right hbar 2 ell 1 ell 1 1 left A ell ell rangle right nbsp so A ℓ ℓ ℓ 1 ℓ 1 displaystyle A ell ell rangle rightarrow ell 1 ell 1 rangle nbsp where the indicates a nascent quantum number which emerges from the discussion Given the Pauli equations 9 10 IV 1 A A 2 E m Z 2 e 4 L 2 ℏ 2 displaystyle 1 A cdot A left frac 2E mu Z 2 e 4 right L 2 hbar 2 nbsp and III A A j 2 i ℏ E m Z 2 e 4 L j displaystyle left A times A right j left frac 2 boldsymbol i hbar E mu Z 2 e 4 right L j nbsp and starting with the equation A A ℓ ℓ 0 displaystyle A A ell ell rangle 0 nbsp and expanding one obtains assuming ℓ displaystyle ell nbsp is the maximum value of the angular momentum quantum number consonant with all other conditions 1 2 E m Z 2 e 4 L 2 ℏ 2 i 2 i ℏ E m Z 2 e 4 L z ℓ ℓ 0 displaystyle left 1 frac 2E mu Z 2 e 4 L 2 hbar 2 i frac 2i hbar E mu Z 2 e 4 L z right ell ell rangle 0 nbsp which leads to the Rydberg formula E n m Z 2 e 4 2 ℏ 2 ℓ 1 2 displaystyle E n frac mu Z 2 e 4 2 hbar 2 ell 1 2 nbsp implying that ℓ 1 n displaystyle ell 1 n nbsp where n displaystyle n nbsp is the traditional quantum number Factorization of the Hamiltonian edit The Hamiltonian for a hydrogen like potential can be written in spherical coordinates asH 1 2 m p r 2 1 r 2 L 2 V r displaystyle H frac 1 2 mu left p r 2 frac 1 r 2 L 2 right V r nbsp where V r Z e 2 r displaystyle V r Ze 2 r nbsp and the radial momentum p r x r p x y r p y z r p z displaystyle p r frac x r p x frac y r p y frac z r p z nbsp which is real and self conjugate Suppose n l displaystyle nl rangle nbsp is an eigenvector of the Hamiltonian where l displaystyle l nbsp is the angular momentum and n displaystyle n nbsp represents the energy so L 2 n l l l 1 ℏ 2 n l displaystyle L 2 nl rangle l l 1 hbar 2 nl rangle nbsp and we may label the Hamiltonian as H l displaystyle H l nbsp H l 1 2 m p r 2 1 r 2 l l 1 ℏ 2 V r displaystyle H l frac 1 2 mu left p r 2 frac 1 r 2 l l 1 hbar 2 right V r nbsp The factorization method was developed by Infeld and Hull 11 for differential equations Newmarch and Golding 12 applied it to spherically symmetric potentials using operator notation Suppose we can find a factorization of the Hamiltonian by operators C l displaystyle C l nbsp as C l C l 2 m H l F l displaystyle C l C l 2 mu H l F l nbsp 1 andC l C l 2 m H l 1 G l displaystyle C l C l 2 mu H l 1 G l nbsp for scalars F l displaystyle F l nbsp and G l displaystyle G l nbsp The vector C l C l C l n l displaystyle C l C l C l nl rangle nbsp may be evaluated in two different ways as C l C l C l n l 2 m E l n F l C l n l 2 m H l 1 G l C l n l displaystyle begin aligned C l C l C l nl rangle amp 2 mu E l n F l C l nl rangle amp 2 mu H l 1 G l C l nl rangle end aligned nbsp which can be re arranged as H l 1 C l n l E l n F l G l 2 m C l n l displaystyle H l 1 C l nl rangle E l n F l G l 2 mu C l nl rangle nbsp showing that C l n l displaystyle C l nl rangle nbsp is an eigenstate of H l 1 displaystyle H l 1 nbsp with eigenvalue E l 1 n E l n F l G l 2 m displaystyle E l 1 n E l n F l G l 2 mu nbsp If F l G l displaystyle F l G l nbsp then n n displaystyle n n nbsp and the states n l displaystyle nl rangle nbsp and C l n l displaystyle C l nl rangle nbsp have the same energy For the hydrogenic atom settingV r B ℏ m r displaystyle V r frac B hbar mu r nbsp with B Z m e 2 ℏ displaystyle B frac Z mu e 2 hbar nbsp a suitable equation for C l displaystyle C l nbsp is C l p r i ℏ l 1 r i B l 1 displaystyle C l p r frac i hbar l 1 r frac iB l 1 nbsp with F l G l B 2 l 1 2 displaystyle F l G l frac B 2 l 1 2 nbsp There is an upper bound to the ladder operator if the energy is negative so C l n l max 0 displaystyle C l nl text max rangle 0 nbsp for some l max displaystyle l text max nbsp then if follows from equation 1 that E l n F l 2 m B 2 2 m l max 1 2 m Z 2 e 4 2 ℏ 2 l max 1 2 displaystyle E l n F l 2 mu frac B 2 2 mu l text max 1 2 frac mu Z 2 e 4 2 hbar 2 l text max 1 2 nbsp and n displaystyle n nbsp can be identified with l max 1 displaystyle l text max 1 nbsp Relation to group theory edit Whenever there is degeneracy in a system there is usually a related symmetry property and group The degeneracy of the energy levels for the same value of n displaystyle n nbsp but different angular momenta has been identified as the SO 4 symmetry of the spherically symmetric Coulomb potential 13 14 3D isotropic harmonic oscillator editThe 3D isotropic harmonic oscillator has a potential given byV r 1 2 m w 2 r 2 displaystyle V r tfrac 1 2 mu omega 2 r 2 nbsp It can similarly be managed using the factorization method Factorization method edit A suitable factorization is given by 12 C l p r i ℏ l 1 r i m w r displaystyle C l p r frac i hbar l 1 r i mu omega r nbsp with F l 2 l 3 m w ℏ displaystyle F l 2l 3 mu omega hbar nbsp and G l 2 l 1 m w ℏ displaystyle G l 2l 1 mu omega hbar nbsp Then E l 1 n E l n F l G l 2 m E l n w ℏ displaystyle E l 1 n E l n frac F l G l 2 mu E l n omega hbar nbsp and continuing this E l 2 n E l n 2 w ℏ E l 3 n E l n 3 w ℏ displaystyle begin aligned E l 2 n amp E l n 2 omega hbar E l 3 n amp E l n 3 omega hbar amp vdots end aligned nbsp Now the Hamiltonian only has positive energy levels as can be seen from ps 2 m H l ps ps C l C l ps ps 2 l 3 m w ℏ ps C l ps C l ps 2 l 3 m w ℏ ps ps 0 displaystyle begin aligned langle psi 2 mu H l psi rangle amp langle psi C l C l psi rangle langle psi 2l 3 mu omega hbar psi rangle amp langle C l psi C l psi rangle 2l 3 mu omega hbar langle psi psi rangle amp geq 0 end aligned nbsp This means that for some value of l displaystyle l nbsp the series must terminate with C l max n l max 0 displaystyle C l text max nl text max rangle 0 nbsp and then E l max n F l max 2 m l max 3 2 w ℏ displaystyle E l text max n frac F l text max 2 mu left l text max frac 3 2 right omega hbar nbsp This is decreasing in energy by w ℏ displaystyle omega hbar nbsp unless C l n l 0 displaystyle C l n l rangle 0 nbsp for some value of l displaystyle l nbsp Identifying this value as n displaystyle n nbsp gives E l n F l n 3 2 w ℏ displaystyle E l n F l left n tfrac 3 2 right omega hbar nbsp It then follows the n n 1 displaystyle n n 1 nbsp so thatC l n l l l n n 1 l 1 displaystyle C l nl rangle lambda l n n 1 l 1 rangle nbsp giving a recursion relation on l displaystyle lambda nbsp with solution l l n m w ℏ 2 n l displaystyle lambda l n mu omega hbar sqrt 2 n l nbsp There is degeneracy caused from angular momentum there is additional degeneracy caused by the oscillator potential Consider the states n n n 1 n 1 n 2 n 2 displaystyle n n rangle n 1 n 1 rangle n 2 n 2 rangle dots nbsp and apply the lowering operators C displaystyle C nbsp C n 2 n 1 n 1 C n 4 C n 3 n 2 n 2 displaystyle C n 2 n 1 n 1 rangle C n 4 C n 3 n 2 n 2 rangle dots nbsp giving the sequence n n n n 2 n n 4 displaystyle n n rangle n n 2 rangle n n 4 rangle dots nbsp with the same energy but with l displaystyle l nbsp decreasing by 2 In addition to the angular momentum degeneracy this gives a total degeneracy of n 1 n 2 2 displaystyle n 1 n 2 2 nbsp 15 Relation to group theory edit The degeneracies of the 3D isotropic harmonic oscillator are related to the special unitary group SU 3 15 16 History editMany sources credit Paul Dirac with the invention of ladder operators 17 Dirac s use of the ladder operators shows that the total angular momentum quantum number j displaystyle j nbsp needs to be a non negative half integer multiple of ħ See also editCreation and annihilation operators Quantum harmonic oscillator Chevalley basisReferences edit Fuchs Jurgen 1992 Affine Lie Algebras and Quantum Groups Cambridge University Press ISBN 0 521 48412 X Harris Fulton Representation Theory pp 164 de Lange O L R E Raab 1986 Ladder operators for orbital angular momentum American Journal of Physics 54 4 372 375 Bibcode 1986AmJPh 54 372D doi 10 1119 1 14625 Sakurai Jun J 1994 Modern Quantum Mechanics Delhi India Pearson Education Inc p 192 ISBN 81 7808 006 0 Woodgate Gordon K 1983 10 06 Elementary Atomic Structure ISBN 978 0 19 851156 4 Retrieved 2009 03 03 Angular Momentum Operators Graduate Quantum Mechanics Notes University of Virginia Retrieved 2009 04 06 David C W 1966 Ladder Operator Solution for the Hydrogen Atom Electronic Energy Levels American Journal of Physics 34 10 984 985 Bibcode 1966AmJPh 34 984D doi 10 1119 1 1972354 Burkhardt C E Levanthal J 2004 Lenz vector operations on spherical hydrogen atom eigenfunctions American Journal of Physics 72 8 1013 1016 Bibcode 2004AmJPh 72 1013B doi 10 1119 1 1758225 Pauli Wolfgang 1926 Uber das Wasserstoffspektrum vom Standpunkt der neuen Quantenmechanik Z Phys 36 5 336 363 Bibcode 1926ZPhy 36 336P doi 10 1007 BF01450175 S2CID 128132824 B L Van der Waerden Sources of Quantum Mechanics Dover New York 1968 L Infeld Hull T E 1951 The Factorization Method Rev Mod Phys 23 1 21 68 Bibcode 1951RvMP 23 21I doi 10 1103 RevModPhys 23 21 a b Newmarch J D Golding R M 1978 Ladder operators for some spherically symmetric potentials in quantum Am J Phys 46 658 660 doi 10 1119 1 11225 Weinberg S J 2011 The SO 4 Symmetry of the Hydrogen Atom PDF Lahiri A Roy P K Bagchi B 1989 Supersymmetry and the Ladder Operator Technique in Quantum Mechanics The Radial Schrodinger Equation Int J Theor Phys 28 2 183 189 Bibcode 1989IJTP 28 183L doi 10 1007 BF00669809 S2CID 123255435 a b Kirson M W 2013 Introductory Algebra for Physicists Isotropic harmonic oscillator PDF Weizmann Institute of Science Retrieved 28 July 2021 Fradkin D M 1965 Three dimensional isotropic harmonic oscillator and SU3 Am J Phys 33 3 207 211 Bibcode 1965AmJPh 33 207F doi 10 1119 1 1971373 Webb Stephen The Quantum Harmonic Oscillator PDF www fisica net Retrieved 5 November 2023 Retrieved from https en wikipedia org w index php title Ladder operator amp oldid 1207470329, wikipedia, wiki, book, books, library,

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