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Peroxydisulfate

The peroxydisulfate ion, S
2
O2−
8
, is an oxyanion, the anion of peroxydisulfuric acid. It is commonly referred to as persulfate, but this term also refers to the peroxomonosulfate ion, SO2−
5
. It is also called peroxodisulfate.[2] Approximately 500,000 tons of salts containing this anion are produced annually. Important salts include sodium persulfate (Na2S2O8), potassium persulfate (K2S2O8), and ammonium persulfate ((NH4)2S2O8). These salts are colourless, water-soluble solids that are strong oxidants.[3]

Peroxydisulfate
Names
Other names
  • Peroxodisulfate
  • Persulfate[1]
Identifiers
  • 15092-81-6
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:29267
ChemSpider
  • 97014
  • 107879
UNII
  • 1SQ1481FEQ
  • InChI=1S/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6)/p-2
    Key: JRKICGRDRMAZLK-UHFFFAOYSA-L
  • [O-]S(=O)(=O)OOS([O-])(=O)=O
Properties
O8S2−2
Molar mass 192.11 g·mol−1
Conjugate acid Peroxydisulfuric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Applications edit

Salts of peroxydisulfate are mainly used to initiate the polymerization of various alkenes, including styrene, acrylonitrile, and fluoroalkenes. Polymerization is initiated by the homolysis of the peroxydisulfate:

[O3SO–OSO3]2− ⇌ 2 [SO4]•−

Moreover, sodium peroxydisulfate can be used for soil and groundwater remediation, water and wastewater treatment, and etching of copper on circuit boards.[4][2]

It has also been used to produce hair lighteners and bleaches, medical drugs, cellophane, rubber, soaps, detergents, adhesive papers, dyes for textiles, and in photography.[2]

In addition to its major commercial applications, peroxydisulfate participates in reactions of interest in the laboratory:

Structure edit

Peroxydisulfate is a centrosymmetric anion. The O-O distance is 1.48 Å. The sulfur centers are tetrahedral.[5]

References edit

  1. ^ Ambiguous—see persulfate
  2. ^ a b c Shafiee, Saiful Arifin; Aarons, Jolyon; Hamzah, Hairul Hisham (2018). "Electroreduction of Peroxodisulfate: A Review of a Complicated Reaction". Journal of the Electrochemical Society. 165 (13): H785–H798. doi:10.1149/2.1161811jes. S2CID 106396614.
  3. ^ Harald Jakob, Stefan Leininger, Thomas Lehmann, Sylvia Jacobi, Sven Gutewort. "Peroxo Compounds, Inorganic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_177.pub2. ISBN 978-3527306732.{{cite encyclopedia}}: CS1 maint: multiple names: authors list (link)
  4. ^ Wacławek, Stanisław; Lutze, Holger V.; Grübel, Klaudiusz; Padil, Vinod V.T.; Černík, Miroslav; Dionysiou, Dionysios.D. (2017). "Chemistry of persulfates in water and wastewater treatment: A review". Chemical Engineering Journal. 330: 44–62. doi:10.1016/j.cej.2017.07.132.
  5. ^ Allan, David R. (2006). "Sodium Peroxodisulfate". Acta Crystallographica Section E. 62 (3): i44–i46. doi:10.1107/S1600536806004302.

peroxydisulfate, peroxydisulfate, oxyanion, anion, peroxydisulfuric, acid, commonly, referred, persulfate, this, term, also, refers, peroxomonosulfate, also, called, peroxodisulfate, approximately, tons, salts, containing, this, anion, produced, annually, impo. The peroxydisulfate ion S2 O2 8 is an oxyanion the anion of peroxydisulfuric acid It is commonly referred to as persulfate but this term also refers to the peroxomonosulfate ion SO2 5 It is also called peroxodisulfate 2 Approximately 500 000 tons of salts containing this anion are produced annually Important salts include sodium persulfate Na2S2O8 potassium persulfate K2S2O8 and ammonium persulfate NH4 2S2O8 These salts are colourless water soluble solids that are strong oxidants 3 Peroxydisulfate NamesOther names PeroxodisulfatePersulfate 1 IdentifiersCAS Number 15092 81 63D model JSmol Interactive imageChEBI CHEBI 29267ChemSpider 97014PubChem CID 107879UNII 1SQ1481FEQInChI InChI 1S H2O8S2 c1 9 2 3 7 8 10 4 5 6 h H 1 2 3 H 4 5 6 p 2Key JRKICGRDRMAZLK UHFFFAOYSA LSMILES O S O O OOS O O OPropertiesChemical formula O 8S 2 2Molar mass 192 11 g mol 1Conjugate acid Peroxydisulfuric acidExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesApplications editSalts of peroxydisulfate are mainly used to initiate the polymerization of various alkenes including styrene acrylonitrile and fluoroalkenes Polymerization is initiated by the homolysis of the peroxydisulfate O3SO OSO3 2 2 SO4 Moreover sodium peroxydisulfate can be used for soil and groundwater remediation water and wastewater treatment and etching of copper on circuit boards 4 2 It has also been used to produce hair lighteners and bleaches medical drugs cellophane rubber soaps detergents adhesive papers dyes for textiles and in photography 2 In addition to its major commercial applications peroxydisulfate participates in reactions of interest in the laboratory Elbs persulfate oxidation Oxidation of Ag to Ag2 such as the preparation of tetrakis pyridine silver II peroxydisulfateStructure editPeroxydisulfate is a centrosymmetric anion The O O distance is 1 48 A The sulfur centers are tetrahedral 5 References edit Ambiguous see persulfate a b c Shafiee Saiful Arifin Aarons Jolyon Hamzah Hairul Hisham 2018 Electroreduction of Peroxodisulfate A Review of a Complicated Reaction Journal of the Electrochemical Society 165 13 H785 H798 doi 10 1149 2 1161811jes S2CID 106396614 Harald Jakob Stefan Leininger Thomas Lehmann Sylvia Jacobi Sven Gutewort Peroxo Compounds Inorganic Ullmann s Encyclopedia of Industrial Chemistry Weinheim Wiley VCH doi 10 1002 14356007 a19 177 pub2 ISBN 978 3527306732 a href Template Cite encyclopedia html title Template Cite encyclopedia cite encyclopedia a CS1 maint multiple names authors list link Waclawek Stanislaw Lutze Holger V Grubel Klaudiusz Padil Vinod V T Cernik Miroslav Dionysiou Dionysios D 2017 Chemistry of persulfates in water and wastewater treatment A review Chemical Engineering Journal 330 44 62 doi 10 1016 j cej 2017 07 132 Allan David R 2006 Sodium Peroxodisulfate Acta Crystallographica Section E 62 3 i44 i46 doi 10 1107 S1600536806004302 nbsp This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Peroxydisulfate amp oldid 1211048941, wikipedia, wiki, book, books, library,

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