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Mixed-anion compounds

January 01, 1970

Mixed-anion compounds, heteroanionic materials or mixed-anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture.[1][2]

Use in materials science edit

By having more than one anion, many more compounds can be made, and properties tuned to desirable values.[3] In terms of optics, properties include phosphorescence, photocatalysis,[4] laser damage threshold, refractive index, birefringence, absorption particularly in the ultraviolet or near infrared, non-linearity.[5] Mechanical properties can include ability to grow a large crystal, ability to form a thin layer, strength, or brittleness.

Thermal properties can include melting point, thermal stability, phase transition temperatures, thermal expansion coefficient.

For electrical properties, electric conductivity, band gap, superconducting transition temperature piezoelectricity, pyroelectricity, ferromagnetism, dielectric constant, charge-density wave transition can be adjusted.

Production edit

Many of the non-metals that could make mixed-anion compounds may have greatly varying volatilities. This makes it more difficult to combine the elements together. Compounds may be produced in a solid state reaction, by heating solids together, either in a vacuum or a gas. Common gases used include, oxygen, hydrogen, ammonia, chlorine, fluorine, hydrogen sulfide, or carbon disulfide. Soft chemical approaches to manufacture include solvothermal synthesis, or substituting atoms in a structure by others, including by water, oxygen, fluorine, or nitrogen. Teflon pouches can be used to separate different formulations. Thin film deposits can yield strained layers. High pressures can be used to prevent evaporation of volatiles. High pressure can result in different crystal forms, perhaps with higher coordination number.[1]

Kinds edit

Elemental edit

H
B BH B
C CH CB C
N NH NB NC N
O OH OB OC ON O
F FH FB FC FN FO F
Si SiH SiB SiC SiN SiO SiF Si
P PH PB PC PN PO PF PSi P
S SH SB SC SN SO SF SSi SP S
Cl ClH ClB ClC ClN ClO ClF ClSi ClP ClS Cl
Ge GeH GeB GeC GeN GeO GeF GeSi GeP GeS GeCl Ge
As AsH AsB AsC AsN AsO AsF AsSi AsP AsS AsCl AsGe As
Se SeH SeB SeC SeN SeO SeF SeSi SeP SeS SeCl SeGe SeAs Se
Br BrH BrB BrC BrN BrO BrF BrSi BrP BrS BrCl BrGe BrAs BrSe Br
Sb SbH SbB SbC SbN SbO SbF SbSi SbP SbS SbCl SbGe SbAs SbSe SbBr Sb
Te TeH TeB TeC TeN TeO TeF TeSi TeP TeS TeCl TeGe TeAs TeSe TeBr TeSb Te
I IH IB IC IN IO IF ISi IP IS ICl IGe IAs ISe IBr ISb ITe I
Bi BiH BiB BiC BiN BiO BiF BiSi BiP BiS BiCl BiGe BiAs BiSe BiBr BiSb BiTe BiI

Molecular anions edit

  • borohydride-chloride[8]
  • disulfide dithioorthovanadate[9]

Oxyanions edit

Fluoroanions edit

Mixed valency and oligomers edit

Some elements can form several kinds of anions, and compounds may exist with more than one. Examples include the iodate periodates,[10] sulfite sulfates, selenate selenites, tellurite tellurates, nitrate nitrites, phosphate phosphites, and arsenate arsenites.

These kinds also include different oligomeric forms such as phosphates or fluorotitanates, such as [Ti4F20]4- and [TiF5]−.[11]

Organic edit

  • borate acetate
  • oxalate formate

References edit

  1. ^ a b Kageyama, Hiroshi; Hayashi, Katsuro; Maeda, Kazuhiko; Attfield, J. Paul; Hiroi, Zenji; Rondinelli, James M.; Poeppelmeier, Kenneth R. (22 February 2018). "Expanding frontiers in materials chemistry and physics with multiple anions". Nature Communications. 9 (1): 772. Bibcode:2018NatCo...9..772K. doi:10.1038/s41467-018-02838-4. PMC 5823932. PMID 29472526.
  2. ^ Kageyama, Hiroshi; Ogino, Hiraku; Hasegawa, Tetsuya (26 June 2023). Mixed Anion Compounds. Royal Society of Chemistry. ISBN 978-1839165122.
  3. ^ Takeiri, Fumitaka; Kageyama, Hiroshi (15 December 2018). "Mixed-Anion Compounds: A New Trend in Solid State Chemistry". Nihon Kessho Gakkaishi. 60 (5–6): 240–245. Bibcode:2018NKG....60..240T. doi:10.5940/jcrsj.60.240.
  4. ^ Maeda, Kazuhiko; Takeiri, Fumitaka; Kobayashi, Genki; Matsuishi, Satoru; Ogino, Hiraku; Ida, Shintaro; Mori, Takao; Uchimoto, Yoshiharu; Tanabe, Setsuhisa; Hasegawa, Tetsuya; Imanaka, Nobuhito; Kageyama, Hiroshi (15 January 2022). "Recent Progress on Mixed-Anion Materials for Energy Applications". Bulletin of the Chemical Society of Japan. 95 (1): 26–37. doi:10.1246/bcsj.20210351. S2CID 244141502.
  5. ^ Li, Yan-Yan; Wang, Wen-Jing; Wang, Hui; Lin, Hua; Wu, Li-Ming (7 June 2019). "Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials". Crystal Growth & Design. 19 (7): 4172–4192. doi:10.1021/acs.cgd.9b00358. S2CID 197213596.
  6. ^ a b Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews. 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
  7. ^ Saparov, Bayrammurad; Singh, David J.; Garlea, Vasile O.; Sefat, Athena S. (8 July 2013). "Crystal, magnetic and electronic structures and properties of new BaMnPnF (Pn = As, Sb, Bi)". Scientific Reports. 3 (1): 2154. arXiv:1306.5182. Bibcode:2013NatSR...3E2154S. doi:10.1038/srep02154. PMC 6504822. PMID 23831607.
  8. ^ Ravnsbaek, Dorthe B.; Sørensen, Lise H.; Filinchuk, Yaroslav; Reed, Daniel; Book, David; Jakobsen, Hans J.; Besenbacher, Flemming; Skibsted, Jørgen; Jensen, Torben R. (April 2010). "Mixed-Anion and Mixed-Cation Borohydride KZn(BH4)Cl2: Synthesis, Structure and Thermal Decomposition" (PDF). European Journal of Inorganic Chemistry. 2010 (11): 1608–1612. doi:10.1002/ejic.201000119.
  9. ^ Almoussawi, Batoul; Huvé, Marielle; Dupray, Valérie; Clevers, Simon; Duffort, Victor; Mentré, Olivier; Roussel, Pascal; Arevalo-Lopez, Angel M.; Kabbour, Houria (22 April 2020). "Oxysulfide Ba5(VO2S2)2(S2)2 Combining Disulfide Channels and Mixed-Anion Tetrahedra and Its Third-Harmonic-Generation Properties" (PDF). Inorganic Chemistry. 59 (9): 5907–5917. doi:10.1021/acs.inorgchem.9b03674. PMID 32319754. S2CID 216073355.
  10. ^ Sun, Jun; Abudouwufu, Tushagu; Jin, Congcong; Guo, Zhiyong; Zhang, Min (17 December 2021). "K 6 (IO 6 H 4)(HI 2 O 6)(HIO 3) 2 (IO 3) 4 ·2H 2 O: A Case of Iodate with Coexisting [I 5+ O 3] and [I 7+ O 6] Units". Inorganic Chemistry. 61 (1): 688–692. doi:10.1021/acs.inorgchem.1c03436. PMID 34919392. S2CID 245278633.
  11. ^ Shlyapnikov, Igor M.; Goreshnik, Evgeny A.; Mazej, Zoran (31 December 2018). "Guanidinium Perfluoridotitanate(IV) Compounds: Structural Determination of an Oligomeric [Ti6F27]3– Anion, and an Example of a Mixed-Anion Salt Containing Two Different Fluoridotitanate(IV) Anions". European Journal of Inorganic Chemistry. 2018 (48): 5246–5257. doi:10.1002/ejic.201801207. S2CID 104344701.

January 01, 1970
mixed, anion, compounds, heteroanionic, materials, mixed, anion, materials, chemical, compounds, containing, cations, more, than, kind, anion, compounds, contain, single, phase, rather, than, just, mixture, contents, materials, science, production, kinds, elem. Mixed anion compounds heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion The compounds contain a single phase rather than just a mixture 1 2 Contents 1 Use in materials science 2 Production 3 Kinds 3 1 Elemental 3 2 Molecular anions 3 3 Oxyanions 3 4 Fluoroanions 3 5 Mixed valency and oligomers 3 6 Organic 4 ReferencesUse in materials science editBy having more than one anion many more compounds can be made and properties tuned to desirable values 3 In terms of optics properties include phosphorescence photocatalysis 4 laser damage threshold refractive index birefringence absorption particularly in the ultraviolet or near infrared non linearity 5 Mechanical properties can include ability to grow a large crystal ability to form a thin layer strength or brittleness Thermal properties can include melting point thermal stability phase transition temperatures thermal expansion coefficient For electrical properties electric conductivity band gap superconducting transition temperature piezoelectricity pyroelectricity ferromagnetism dielectric constant charge density wave transition can be adjusted Production editMany of the non metals that could make mixed anion compounds may have greatly varying volatilities This makes it more difficult to combine the elements together Compounds may be produced in a solid state reaction by heating solids together either in a vacuum or a gas Common gases used include oxygen hydrogen ammonia chlorine fluorine hydrogen sulfide or carbon disulfide Soft chemical approaches to manufacture include solvothermal synthesis or substituting atoms in a structure by others including by water oxygen fluorine or nitrogen Teflon pouches can be used to separate different formulations Thin film deposits can yield strained layers High pressures can be used to prevent evaporation of volatiles High pressure can result in different crystal forms perhaps with higher coordination number 1 Kinds editElemental edit pnictochalcogenides oxypnictides including oxynitrides oxyphosphides oxyarsenides oxyantimonides oxybismuthides chalcohalides or chalcogenide halides 6 oxohalides including oxyfluorides oxychlorides oxybromides oxyiodides fluorosulfides sulfide chlorides selenide chlorides telluride chlorides sulfide bromides selenide bromides telluride bromides sulfide iodides selenide iodides telluride iodides oxysulfides oxyselenides oxyhydrides halopnictides fluoropnictides including fluorophosphides fluoroarsenides fluoroantimonides fluorobismuthides 7 arsenide chlorides H B BH B C CH CB C N NH NB NC N O OH OB OC ON O F FH FB FC FN FO F Si SiH SiB SiC SiN SiO SiF Si P PH PB PC PN PO PF PSi P S SH SB SC SN SO SF SSi SP S Cl ClH ClB ClC ClN ClO ClF ClSi ClP ClS Cl Ge GeH GeB GeC GeN GeO GeF GeSi GeP GeS GeCl Ge As AsH AsB AsC AsN AsO AsF AsSi AsP AsS AsCl AsGe As Se SeH SeB SeC SeN SeO SeF SeSi SeP SeS SeCl SeGe SeAs Se Br BrH BrB BrC BrN BrO BrF BrSi BrP BrS BrCl BrGe BrAs BrSe Br Sb SbH SbB SbC SbN SbO SbF SbSi SbP SbS SbCl SbGe SbAs SbSe SbBr Sb Te TeH TeB TeC TeN TeO TeF TeSi TeP TeS TeCl TeGe TeAs TeSe TeBr TeSb Te I IH IB IC IN IO IF ISi IP IS ICl IGe IAs ISe IBr ISb ITe I Bi BiH BiB BiC BiN BiO BiF BiSi BiP BiS BiCl BiGe BiAs BiSe BiBr BiSb BiTe BiI Molecular anions edit borohydride chloride 8 disulfide dithioorthovanadate 9 Oxyanions edit halocarbonates including carbonate fluorides carbonate chlorides carbonate bromides phosphates including fluoride phosphates chloride phosphate phosphate molybdates phosphate arsenates borates halide borates including fluoride borates borate chlorides borate bromides borate iodides chalcogenide borates including sulfide borates 6 borate carbonates borate nitrates borate sulfates borate phosphates borate acetates Condensed borates borosulfates boroselenates borotellurates boroantimonates borophosphates boroselenites sulfates sulfate fluorides sulfate chlorides sulfate arsenate selenite fluorides iodate fluorides Silicates sulfide silicates Fluoroanions edit Mixed valency and oligomers edit Some elements can form several kinds of anions and compounds may exist with more than one Examples include the iodate periodates 10 sulfite sulfates selenate selenites tellurite tellurates nitrate nitrites phosphate phosphites and arsenate arsenites These kinds also include different oligomeric forms such as phosphates or fluorotitanates such as Ti4F20 4 and TiF5 11 Organic edit borate acetate oxalate formateReferences edit a b Kageyama Hiroshi Hayashi Katsuro Maeda Kazuhiko Attfield J Paul Hiroi Zenji Rondinelli James M Poeppelmeier Kenneth R 22 February 2018 Expanding frontiers in materials chemistry and physics with multiple anions Nature Communications 9 1 772 Bibcode 2018NatCo 9 772K doi 10 1038 s41467 018 02838 4 PMC 5823932 PMID 29472526 Kageyama Hiroshi Ogino Hiraku Hasegawa Tetsuya 26 June 2023 Mixed Anion Compounds Royal Society of Chemistry ISBN 978 1839165122 Takeiri Fumitaka Kageyama Hiroshi 15 December 2018 Mixed Anion Compounds A New Trend in Solid State Chemistry Nihon Kessho Gakkaishi 60 5 6 240 245 Bibcode 2018NKG 60 240T doi 10 5940 jcrsj 60 240 Maeda Kazuhiko Takeiri Fumitaka Kobayashi Genki Matsuishi Satoru Ogino Hiraku Ida Shintaro Mori Takao Uchimoto Yoshiharu Tanabe Setsuhisa Hasegawa Tetsuya Imanaka Nobuhito Kageyama Hiroshi 15 January 2022 Recent Progress on Mixed Anion Materials for Energy Applications Bulletin of the Chemical Society of Japan 95 1 26 37 doi 10 1246 bcsj 20210351 S2CID 244141502 Li Yan Yan Wang Wen Jing Wang Hui Lin Hua Wu Li Ming 7 June 2019 Mixed Anion Inorganic Compounds A Favorable Candidate for Infrared Nonlinear Optical Materials Crystal Growth amp Design 19 7 4172 4192 doi 10 1021 acs cgd 9b00358 S2CID 197213596 a b Xiao Jin Rong Yang Si Han Feng Fang Xue Huai Guo Guo Sheng Ping September 2017 A review of the structural chemistry and physical properties of metal chalcogenide halides Coordination Chemistry Reviews 347 23 47 doi 10 1016 j ccr 2017 06 010 Saparov Bayrammurad Singh David J Garlea Vasile O Sefat Athena S 8 July 2013 Crystal magnetic and electronic structures and properties of new BaMnPnF Pn As Sb Bi Scientific Reports 3 1 2154 arXiv 1306 5182 Bibcode 2013NatSR 3E2154S doi 10 1038 srep02154 PMC 6504822 PMID 23831607 Ravnsbaek Dorthe B Sorensen Lise H Filinchuk Yaroslav Reed Daniel Book David Jakobsen Hans J Besenbacher Flemming Skibsted Jorgen Jensen Torben R April 2010 Mixed Anion and Mixed Cation Borohydride KZn BH4 Cl2 Synthesis Structure and Thermal Decomposition PDF European Journal of Inorganic Chemistry 2010 11 1608 1612 doi 10 1002 ejic 201000119 Almoussawi Batoul Huve Marielle Dupray Valerie Clevers Simon Duffort Victor Mentre Olivier Roussel Pascal Arevalo Lopez Angel M Kabbour Houria 22 April 2020 Oxysulfide Ba5 VO2S2 2 S2 2 Combining Disulfide Channels and Mixed Anion Tetrahedra and Its Third Harmonic Generation Properties PDF Inorganic Chemistry 59 9 5907 5917 doi 10 1021 acs inorgchem 9b03674 PMID 32319754 S2CID 216073355 Sun Jun Abudouwufu Tushagu Jin Congcong Guo Zhiyong Zhang Min 17 December 2021 K 6 IO 6 H 4 HI 2 O 6 HIO 3 2 IO 3 4 2H 2 O A Case of Iodate with Coexisting I 5 O 3 and I 7 O 6 Units Inorganic Chemistry 61 1 688 692 doi 10 1021 acs inorgchem 1c03436 PMID 34919392 S2CID 245278633 Shlyapnikov Igor M Goreshnik Evgeny A Mazej Zoran 31 December 2018 Guanidinium Perfluoridotitanate IV Compounds Structural Determination of an Oligomeric Ti6F27 3 Anion and an Example of a Mixed Anion Salt Containing Two Different Fluoridotitanate IV Anions European Journal of Inorganic Chemistry 2018 48 5246 5257 doi 10 1002 ejic 201801207 S2CID 104344701 Retrieved from https en wikipedia org w index php title Mixed anion compounds amp oldid 1193343340, wikipedia, wiki, book, books, library,

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