Lead picrate is an organicpicrate salt.[3] It is a sensitive and highly explosive compound that is typically found as a hydrate.[2] Dry lead picrate is incredibly dangerous and cannot be handled without explosive decomposition occurring.
Lead picrate was first discovered in the early 1900s. It was investigated by numerous militaries during the First World War as a potential primary explosive, most notably Germany for using it in blasting caps.[2]
Preparation
Numerous lead precursors can be used to create lead picrate. Two of the simplest examples of lead picrate synthesis are the addition of lead(II) oxide or lead carbonate with picric acid.[2]
References
^ abcYang, Li; Pei, Qin; Zhang, Tonglai; Zhang, Jianguo; Cao, Yunling (2007). "Solubilities and enthalpies of solution of picric acid and picrates at 298.15K in DMF, EtOH and acetic acid". Thermochimica Acta. 463 (1–2): 13–14. doi:10.1016/j.tca.2007.04.013.
^ abcdeMatsukakwa, Makoto; Matsunaga, Takehiro; Yoshida, Masatake; Fujiwara, Shuzo (2004). "Synthesis and properties of lead picrates". Science and Technology of Energetic Materials. 65 (1): 7–13.
^Jai Prakash Agrawal (2015). High Energy Materials: Propellants, Explosives and Pyrotechnics. John Wiley & Sons.
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lead, picrate, organic, picrate, salt, sensitive, highly, explosive, compound, that, typically, found, hydrate, lead, picrate, incredibly, dangerous, cannot, handled, without, explosive, decomposition, occurring, namesiupac, name, lead, trinitrophenolateother,. Lead picrate is an organic picrate salt 3 It is a sensitive and highly explosive compound that is typically found as a hydrate 2 Dry lead picrate is incredibly dangerous and cannot be handled without explosive decomposition occurring Lead picrate NamesIUPAC name Lead II 2 4 6 trinitrophenolateOther names Lead dipicrateIdentifiersCAS Number 25721 38 46477 64 13D model JSmol Interactive imageECHA InfoCard 100 210 303EC Number 229 335 2PubChem CID 3045289162344796CompTox Dashboard EPA DTXSID80215079InChI InChI 1S 2C6H3N3O7 Pb c2 10 6 4 8 13 14 1 3 7 11 12 2 5 6 9 15 16 h2 1 2 10H q 2 p 2Key MHVVRZIRWITSIP UHFFFAOYSA LSMILES C1 C C C C C1 N O O O N O O N O O C1 C C C C C1 N O O O N O O N O O Pb 2 PropertiesChemical formula C 12H 4N 6O 14PbMolar mass 663 4 g mol 1Appearance Orange powderSolubility in water 7 06 g L 1 Solubility Soluble in ethanol acetic acid 1 Very soluble in DMF 1 dichloromethane 2 HazardsGHS labelling PictogramsSignal word DangerHazard statements H201 H302 H332 H360 H373 H410Precautionary statements P260 P261 P264 P270 P271 P273 P280 P304 P340 P330 P391 P405 P501Autoignitiontemperature 270 75 327 15 C 519 7 621 0 F 600 3 543 9 K 2 Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesHistory EditLead picrate was first discovered in the early 1900s It was investigated by numerous militaries during the First World War as a potential primary explosive most notably Germany for using it in blasting caps 2 Preparation EditNumerous lead precursors can be used to create lead picrate Two of the simplest examples of lead picrate synthesis are the addition of lead II oxide or lead carbonate with picric acid 2 References Edit a b c Yang Li Pei Qin Zhang Tonglai Zhang Jianguo Cao Yunling 2007 Solubilities and enthalpies of solution of picric acid and picrates at 298 15K in DMF EtOH and acetic acid Thermochimica Acta 463 1 2 13 14 doi 10 1016 j tca 2007 04 013 a b c d e Matsukakwa Makoto Matsunaga Takehiro Yoshida Masatake Fujiwara Shuzo 2004 Synthesis and properties of lead picrates Science and Technology of Energetic Materials 65 1 7 13 Jai Prakash Agrawal 2015 High Energy Materials Propellants Explosives and Pyrotechnics John Wiley amp Sons This explosives related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Lead picrate amp oldid 1095862650, wikipedia, wiki, book, books, library,
