It is prepared by the reaction of molecular iodine with iron pentacarbonyl, following a procedure first reported by Hieber and Wirschung in 1940:[2]
Fe(CO)5 + I2 → FeI2(CO)4 + CO
Iron tetracarbonyl diiodide reacts with a variety of Lewis bases with displacement of one or two CO ligands.[3]
Referencesedit
^Yu. V. Torubayev, A. A. Pasynskii, P. Mathur (2008). Koordinatsionnaya Khimiya. 34: 812–816. {{cite journal}}: Missing or empty |title= (help)CS1 maint: multiple names: authors list (link)
^Hieber, W.; Wirsching, A. (1940). "Über Metallcarbonyle. XXXII. Über Eisencarbonylhalogenide". Z. Anorg. Allg. Chem. 245: 35-58. doi:10.1002/zaac.19402450108.
^Li, Bin; Liu, Tianbiao; Popescu, Codrina V.; Bilko, Andrey; Darensbourg, Marcetta Y. (2009). "Synthesis and Mössbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI2(CO)3L and FeI2(CO)2L2: Developing Models of the [Fe]-H2ase Active Site". Inorg. Chem. 48 (23): 11283–11289. doi:10.1021/ic9017882. PMID 19860458.
January 01, 1970
iron, tetracarbonyl, diiodide, inorganic, compound, with, formula, fei2, molecule, features, four, carbonyl, ligands, iodides, spin, complex, ferrous, iron, confirmed, crystallography, compound, stereochemistry, black, solid, that, soluble, dichloromethane, re. Iron tetracarbonyl diiodide is the inorganic compound with the formula FeI2 CO 4 The molecule features four carbonyl ligands and two iodides It is a low spin complex of ferrous iron As confirmed by X ray crystallography the compound has cis stereochemistry 1 It is a black solid that is soluble in dichloromethane and related organic solvents Iron tetracarbonyl diiodide Identifiers CAS Number 14911 55 8 3D model JSmol Interactive image ChemSpider 452752 PubChem CID 519026 InChI InChI 1S 4CO Fe 2HI c4 1 2 h 2 1H q 2 p 2Key BNIJVXICMSDYLX UHFFFAOYSA L SMILES C O C O C O C O Fe I I Properties Chemical formula C 4Fe I 2O 4 Molar mass 421 694 g mol 1 Appearance black solid Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesPreparation and reactions editIt is prepared by the reaction of molecular iodine with iron pentacarbonyl following a procedure first reported by Hieber and Wirschung in 1940 2 Fe CO 5 I2 FeI2 CO 4 CO Iron tetracarbonyl diiodide reacts with a variety of Lewis bases with displacement of one or two CO ligands 3 References edit Yu V Torubayev A A Pasynskii P Mathur 2008 Koordinatsionnaya Khimiya 34 812 816 a href Template Cite journal html title Template Cite journal cite journal a Missing or empty title help CS1 maint multiple names authors list link Hieber W Wirsching A 1940 Uber Metallcarbonyle XXXII Uber Eisencarbonylhalogenide Z Anorg Allg Chem 245 35 58 doi 10 1002 zaac 19402450108 Li Bin Liu Tianbiao Popescu Codrina V Bilko Andrey Darensbourg Marcetta Y 2009 Synthesis and Mossbauer Characterization of Octahedral Iron II Carbonyl Complexes FeI2 CO 3L and FeI2 CO 2L2 Developing Models of the Fe H2ase Active Site Inorg Chem 48 23 11283 11289 doi 10 1021 ic9017882 PMID 19860458 Retrieved from https en wikipedia org w index php title Iron tetracarbonyl diiodide amp oldid 1166680712, wikipedia, wiki, book, books, library,
