Dichloro(1,5-cyclooctadiene)palladium is the organopalladium compound with the formula PdCl2(C8H12) where C8H12 is cycloocta-1,5-diene (cod) or abbreviated PdCl2(cod). It is a yellow solid that is soluble in chloroform.[1] According to X-ray crystallography, the Pd center is square planar.[2] This complex can be synthesized by reaction of tetrachloropalladate in hydrochloric acid with cycloocta-1,5-diene.[3]
^Shomir Ghosh; Xiang Wang; Anil Guram (2009). "Dichloro(1,5-cyclooctadiene)palladium(II)". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rd113.pub2. ISBN978-0471936237.
^R. Kumar; A. W. Maverick; F. R. Fronczek; J. R. Doyle; N. C. Baenziger; M. A. M. Howells (1993). "The Pbca polymorph of dichloro(η4-1,5-cyclooctadiene)palladium(II)". Acta Crystallogr. C. 49 (10): 1766–1767. doi:10.1107/S0108270193003889.
^Drew, D.; Doyle, J. R.; Shaver, A. G. (1972). "Cyclic Diolefin Complexes of Platinum and Palladium". Inorganic Syntheses. 13: 47–55. doi:10.1002/9780470132449.ch11.
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dichloro, cyclooctadiene, palladium, organopalladium, compound, with, formula, pdcl2, c8h12, where, c8h12, cycloocta, diene, abbreviated, pdcl2, yellow, solid, that, soluble, chloroform, according, crystallography, center, square, planar, this, complex, synthe. Dichloro 1 5 cyclooctadiene palladium is the organopalladium compound with the formula PdCl2 C8H12 where C8H12 is cycloocta 1 5 diene cod or abbreviated PdCl2 cod It is a yellow solid that is soluble in chloroform 1 According to X ray crystallography the Pd center is square planar 2 This complex can be synthesized by reaction of tetrachloropalladate in hydrochloric acid with cycloocta 1 5 diene 3 Dichloro 1 5 cyclooctadiene palladium IdentifiersCAS Number 12107 56 1 Y3D model JSmol Interactive imageChemSpider 4642864ECHA InfoCard 100 031 953EC Number 235 161 8PubChem CID 5702536CompTox Dashboard EPA DTXSID00923664InChI InChI 1S C8H12 2ClH Pd c1 2 4 6 8 7 5 3 1 h1 2 7 8H 3 6H2 2 1H q 2 p 2 b2 1 8 7 Key RRHPTXZOMDSKRS PHFPKPIQSA LSMILES C1CC CCCC C1 Cl Pd ClPropertiesChemical formula C 8H 12Cl 2PdMolar mass 285 50 g mol 1Appearance yellow solidDensity 2 045 g cm3Melting point 210 C 410 F 483 K HazardsGHS labelling PictogramsSignal word WarningHazard statements H315 H319 H335Precautionary statements P261 P264 P271 P280 P302 P352 P304 P340 P305 P351 P338 P312 P321 P332 P313 P337 P313 P362 P403 P233 P405 P501Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesSee also editDichloro cycloocta 1 5 diene platinum II References edit Shomir Ghosh Xiang Wang Anil Guram 2009 Dichloro 1 5 cyclooctadiene palladium II Encyclopedia of Reagents for Organic Synthesis doi 10 1002 047084289X rd113 pub2 ISBN 978 0471936237 R Kumar A W Maverick F R Fronczek J R Doyle N C Baenziger M A M Howells 1993 The Pbca polymorph of dichloro h4 1 5 cyclooctadiene palladium II Acta Crystallogr C 49 10 1766 1767 doi 10 1107 S0108270193003889 Drew D Doyle J R Shaver A G 1972 Cyclic Diolefin Complexes of Platinum and Palladium Inorganic Syntheses 13 47 55 doi 10 1002 9780470132449 ch11 nbsp This catalysis article is a stub You can help Wikipedia by expanding it vte nbsp This article about chemical compounds is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Dichloro 1 5 cyclooctadiene palladium amp oldid 1182469426, wikipedia, wiki, book, books, library,
