Bromine monochloride, also called bromine(I) chloride, bromochloride, and bromine chloride, is an interhalogeninorganic compound with chemical formula BrCl. It is a very reactive golden yellow gas with boiling point 5 °C and melting point −66 °C. Its CAS number is 13863-41-7, and its EINECS number is 237-601-4.[1] It is a strong oxidizing agent. Its molecular structure in the gas phase was determined by microwave spectroscopy; the Br-Cl bond has a length of re = 2.1360376(18) Å.[2] Its crystal structure was determined by single crystal X-ray diffraction; the bond length in the solid state is 2.179(2) Å and the shortest intermolecular interaction is r(Cl···Br) = 3.145(2) Å.[3]
Bromine monochloride is used in analytical chemistry in determining low levels of mercury, to quantitatively oxidize mercury in the sample to Hg(II) state.
A common use of bromine monochloride is as an algaecide, fungicide, and disinfectant of industrial recirculating cooling water systems.
Addition of bromine monochloride is used in some types of Li-SO2 batteries to increase voltage and energy density.[4]
^Ogilvie, J. F. (1995). "Electric polarity+BrCl–and rotational g factor from analysis of frequencies of pure rotational and vibration–rotational spectra". J. Chem. Soc., Faraday Trans. 91 (18): 3005–3006. doi:10.1039/ft9959103005. ISSN 0956-5000.
^Drews, Thomas; Seppelt, Konrad (October 2012). "Bromine Monofluoride". Zeitschrift für anorganische und allgemeine Chemie. 638 (12–13): 2106–2110. doi:10.1002/zaac.201200293.
^. GlobalSpec. Archived from the original on 2007-12-23. Retrieved 2008-07-09.
November 24, 2023
bromine, monochloride, also, called, bromine, chloride, bromochloride, bromine, chloride, interhalogen, inorganic, compound, with, chemical, formula, brcl, very, reactive, golden, yellow, with, boiling, point, melting, point, number, 13863, einecs, number, str. Bromine monochloride also called bromine I chloride bromochloride and bromine chloride is an interhalogen inorganic compound with chemical formula BrCl It is a very reactive golden yellow gas with boiling point 5 C and melting point 66 C Its CAS number is 13863 41 7 and its EINECS number is 237 601 4 1 It is a strong oxidizing agent Its molecular structure in the gas phase was determined by microwave spectroscopy the Br Cl bond has a length of re 2 1360376 18 A 2 Its crystal structure was determined by single crystal X ray diffraction the bond length in the solid state is 2 179 2 A and the shortest intermolecular interaction is r Cl Br 3 145 2 A 3 Bromine monochloride NamesOther names bromine I chloridebromochloridebromine chlorideIdentifiersCAS Number 13863 41 7 Y3D model JSmol Interactive imageChemSpider 55600 YECHA InfoCard 100 034 169EC Number 237 601 4PubChem CID 61697RTECS number EF9200000UNII 7G62XY5724UN number 2901CompTox Dashboard EPA DTXSID4035259InChI InChI 1S BrCl c1 2 YKey CODNYICXDISAEA UHFFFAOYSA N YInChI 1 BrCl c1 2Key CODNYICXDISAEA UHFFFAOYAZSMILES BrClPropertiesChemical formula BrClMolar mass 115 357 g molAppearance golden yellow gasDensity 2 172 g cm3Melting point 54 C 65 F 219 K Boiling point 5 C 41 F 278 K Solubility in water 8 5 g LHazardsNFPA 704 fire diamond 302OXExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Y verify what is Y N Infobox referencesUses editBromine monochloride is used in analytical chemistry in determining low levels of mercury to quantitatively oxidize mercury in the sample to Hg II state A common use of bromine monochloride is as an algaecide fungicide and disinfectant of industrial recirculating cooling water systems Addition of bromine monochloride is used in some types of Li SO2 batteries to increase voltage and energy density 4 See also editList of highly toxic gases Interhalogen compoundsReferences edit Gangolli S Royal Society of Chemistry 1999 The Dictionary of Substances and Their Effects p 676 ISBN 0 85404 808 1 Ogilvie J F 1995 Electric polarity BrCl and rotational g factor from analysis of frequencies of pure rotational and vibration rotational spectra J Chem Soc Faraday Trans 91 18 3005 3006 doi 10 1039 ft9959103005 ISSN 0956 5000 Drews Thomas Seppelt Konrad October 2012 Bromine Monofluoride Zeitschrift fur anorganische und allgemeine Chemie 638 12 13 2106 2110 doi 10 1002 zaac 201200293 Battery Chemistry Lithium Thionyl Chloride GlobalSpec Archived from the original on 2007 12 23 Retrieved 2008 07 09 Retrieved from https en wikipedia org w index php title Bromine monochloride amp oldid 1161923313, wikipedia, wiki, book, books, library,
