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Wikipedia

Benzoyl-CoA

January 08, 2023

Benzoyl-CoA is a molecule implied in the activity of the different enzymes 4-hydroxybenzoyl-CoA reductase, benzoyl-CoA reductase, benzoyl-CoA 3-monooxygenase, benzoate-CoA ligase, 2alpha-hydroxytaxane 2-O-benzoyltransferase, anthranilate N-benzoyltransferase, biphenyl synthase, glycine N-benzoyltransferase, ornithine N-benzoyltransferase and phenylglyoxylate dehydrogenase (acylating).

Benzoyl-Coenzyme A
Names
Other names
benzoyl-S-CoA
S-Benzoate coenzyme A
Identifiers
  • 102185-37-5 Y
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:15515
ChemSpider
  • 7822142 N
  • 25245721
UNII
  • 6ZL6G9S5GY Y
  • DTXSID80585082
  • InChI=1S/C28H40N7O17P3S/c1-28(2,22(38)25(39)31-9-8-18(36)30-10-11-56-27(40)16-6-4-3-5-7-16)13-49-55(46,47)52-54(44,45)48-12-17-21(51-53(41,42)43)20(37)26(50-17)35-15-34-19-23(29)32-14-33-24(19)35/h3-7,14-15,17,20-22,26,37-38H,8-13H2,1-2H3,(H,30,36)(H,31,39)(H,44,45)(H,46,47)(H2,29,32,33)(H2,41,42,43)/t17-,20-,21-,22+,26-/m1/s1 N
    Key: VEVJTUNLALKRNO-TYHXJLICSA-N N
  • InChI=1/C28H40N7O17P3S/c1-28(2,22(38)25(39)31-9-8-18(36)30-10-11-56-27(40)16-6-4-3-5-7-16)13-49-55(46,47)52-54(44,45)48-12-17-21(51-53(41,42)43)20(37)26(50-17)35-15-34-19-23(29)32-14-33-24(19)35/h3-7,14-15,17,20-22,26,37-38H,8-13H2,1-2H3,(H,30,36)(H,31,39)(H,44,45)(H,46,47)(H2,29,32,33)(H2,41,42,43)/t17-,20-,21-,22+,26-/m1/s1
    Key: VEVJTUNLALKRNO-TYHXJLICBE
  • CC(C)(COP(=O)(O)OP(=O)(O)OC[C@@H]1[C@H]([C@H]([C@@H](O1)N2C=NC3=C(N=CN=C32)N)O)OP(=O)(O)O)[C@H](C(=O)NCCC(=O)NCCSC(=O)C4=CC=CC=C4)O
Properties
C28H36N7O17P3S−4
Molar mass 867.60 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

It is a substrate in the formation of xanthonoids in Hypericum androsaemum by benzophenone synthase, condensing a molecule of benzoyl-CoA with three malonyl-CoA, yielding to 2,4,6-trihydroxybenzophenone. This intermediate is subsequently converted by a benzophenone 3′-hydroxylase, a cytochrome P450 monooxygenase, leading to the formation of 2,3′,4,6-tetrahydroxybenzophenone.[1]

Benzoyl-CoA is a substrate of benzoyl-CoA reductase. This enzyme is responsible in part for the reductive dearomatization of aryl compounds mediated by bacteria under anaerobic conditions.[2]

References

  1. ^ Alternative pathways of xanthone biosynthesis in cell cultures of Hypericum androsaemum L. Werner Schmidt and Ludger Beerhues, FEBS Letters, Volume 420, Issues 2-3, 29 December 1997, Pages 143-146, doi:10.1016/S0014-5793(97)01507-X
  2. ^ Matthias Boll , Georg Fuchs , Johann Heider "Anaerobic oxidation of aromatic compounds and hydrocarbons" Current Opinion in Chemical Biology 2002 Volume 6, pp. 604–611. doi:10.1016/S1367-5931(02)00375-7

January 08, 2023
benzoyl, molecule, implied, activity, different, enzymes, hydroxybenzoyl, reductase, benzoyl, reductase, benzoyl, monooxygenase, benzoate, ligase, 2alpha, hydroxytaxane, benzoyltransferase, anthranilate, benzoyltransferase, biphenyl, synthase, glycine, benzoyl. Benzoyl CoA is a molecule implied in the activity of the different enzymes 4 hydroxybenzoyl CoA reductase benzoyl CoA reductase benzoyl CoA 3 monooxygenase benzoate CoA ligase 2alpha hydroxytaxane 2 O benzoyltransferase anthranilate N benzoyltransferase biphenyl synthase glycine N benzoyltransferase ornithine N benzoyltransferase and phenylglyoxylate dehydrogenase acylating Benzoyl Coenzyme A NamesOther names benzoyl S CoAS Benzoate coenzyme AIdentifiersCAS Number 102185 37 5 Y3D model JSmol Interactive imageChEBI CHEBI 15515ChemSpider 7822142 NPubChem CID 25245721UNII 6ZL6G9S5GY YCompTox Dashboard EPA DTXSID80585082InChI InChI 1S C28H40N7O17P3S c1 28 2 22 38 25 39 31 9 8 18 36 30 10 11 56 27 40 16 6 4 3 5 7 16 13 49 55 46 47 52 54 44 45 48 12 17 21 51 53 41 42 43 20 37 26 50 17 35 15 34 19 23 29 32 14 33 24 19 35 h3 7 14 15 17 20 22 26 37 38H 8 13H2 1 2H3 H 30 36 H 31 39 H 44 45 H 46 47 H2 29 32 33 H2 41 42 43 t17 20 21 22 26 m1 s1 NKey VEVJTUNLALKRNO TYHXJLICSA N NInChI 1 C28H40N7O17P3S c1 28 2 22 38 25 39 31 9 8 18 36 30 10 11 56 27 40 16 6 4 3 5 7 16 13 49 55 46 47 52 54 44 45 48 12 17 21 51 53 41 42 43 20 37 26 50 17 35 15 34 19 23 29 32 14 33 24 19 35 h3 7 14 15 17 20 22 26 37 38H 8 13H2 1 2H3 H 30 36 H 31 39 H 44 45 H 46 47 H2 29 32 33 H2 41 42 43 t17 20 21 22 26 m1 s1Key VEVJTUNLALKRNO TYHXJLICBESMILES CC C COP O O OP O O OC C H 1 C H C H C H O1 N2C NC3 C N CN C32 N O OP O O O C H C O NCCC O NCCSC O C4 CC CC C4 OPropertiesChemical formula C28H36N7O17P3S 4Molar mass 867 60 g molExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references It is a substrate in the formation of xanthonoids in Hypericum androsaemum by benzophenone synthase condensing a molecule of benzoyl CoA with three malonyl CoA yielding to 2 4 6 trihydroxybenzophenone This intermediate is subsequently converted by a benzophenone 3 hydroxylase a cytochrome P450 monooxygenase leading to the formation of 2 3 4 6 tetrahydroxybenzophenone 1 Benzoyl CoA is a substrate of benzoyl CoA reductase This enzyme is responsible in part for the reductive dearomatization of aryl compounds mediated by bacteria under anaerobic conditions 2 References Edit Alternative pathways of xanthone biosynthesis in cell cultures of Hypericum androsaemum L Werner Schmidt and Ludger Beerhues FEBS Letters Volume 420 Issues 2 3 29 December 1997 Pages 143 146 doi 10 1016 S0014 5793 97 01507 X Matthias Boll Georg Fuchs Johann Heider Anaerobic oxidation of aromatic compounds and hydrocarbons Current Opinion in Chemical Biology 2002 Volume 6 pp 604 611 doi 10 1016 S1367 5931 02 00375 7 Retrieved from https en wikipedia org w index php title Benzoyl CoA amp oldid 1106612005, wikipedia, wiki, book, books, library,

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