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Wikipedia

Allyl methyl sulfide

January 01, 1970

Allyl methyl sulfide is an organosulfur compound with the chemical formula CH2=CHCH2SCH3. The molecule features two functional groups, an allyl (CH2=CHCH2) and a sulfide. It is a colourless liquid with a strong odor characteristic of alkyl sulfides. It is a metabolite of garlic, and "garlic breath" is attributed to its presence.[1]

Allyl methyl sulfide
Names
Preferred IUPAC name
3-(Methylsulfanyl)prop-1-ene
Other names
Methyl propenyl sulfide
3-Methylthio-1-propene
Identifiers
  • 10152-76-8 N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 21159856 Y
ECHA InfoCard 100.030.371
EC Number
  • 233-422-0
MeSH allyl+methyl+sulfide
  • 66282
RTECS number
  • UD1015000
UNII
  • V7QI1R316C N
UN number 1993
  • DTXSID9064976
  • InChI=1S/C4H8S/c1-3-4-5-2/h3H,1,4H2,2H3 Y
    Key: NVLPQIPTCCLBEU-UHFFFAOYSA-N Y
  • InChI=1/C4H8S/c1-3-4-5-2/h3H,1,4H2,2H3
    Key: NVLPQIPTCCLBEU-UHFFFAOYAX
  • CSCC=C
Properties
C4H8S
Molar mass 88.17 g·mol−1
Odor Garlic
Density 0.803 g cm−3
Boiling point 92 °C; 197 °F; 365 K
Hazards
GHS labelling:
Danger
H225
P210
Flash point 18.0 °C (64.4 °F; 291.1 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

It is prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol.

CH2=CHCH2Cl + NaOH (aq) + CH3SH → CH2=CHCH2SCH3 + NaCl + H2O

References edit

  1. ^ Eric Block (2010-01-04). Garlic and Other Alliums: The Lore and the Science. Royal Society of Chemistry. ISBN 978-0-85404-190-9.

January 01, 1970
allyl, methyl, sulfide, organosulfur, compound, with, chemical, formula, chch2sch3, molecule, features, functional, groups, allyl, chch2, sulfide, colourless, liquid, with, strong, odor, characteristic, alkyl, sulfides, metabolite, garlic, garlic, breath, attr. Allyl methyl sulfide is an organosulfur compound with the chemical formula CH2 CHCH2SCH3 The molecule features two functional groups an allyl CH2 CHCH2 and a sulfide It is a colourless liquid with a strong odor characteristic of alkyl sulfides It is a metabolite of garlic and garlic breath is attributed to its presence 1 Allyl methyl sulfide Names Preferred IUPAC name 3 Methylsulfanyl prop 1 ene Other names Methyl propenyl sulfide 3 Methylthio 1 propene Identifiers CAS Number 10152 76 8 N 3D model JSmol Interactive image ChemSpider 21159856 Y ECHA InfoCard 100 030 371 EC Number 233 422 0 MeSH allyl methyl sulfide PubChem CID 66282 RTECS number UD1015000 UNII V7QI1R316C N UN number 1993 CompTox Dashboard EPA DTXSID9064976 InChI InChI 1S C4H8S c1 3 4 5 2 h3H 1 4H2 2H3 YKey NVLPQIPTCCLBEU UHFFFAOYSA N YInChI 1 C4H8S c1 3 4 5 2 h3H 1 4H2 2H3Key NVLPQIPTCCLBEU UHFFFAOYAX SMILES CSCC C Properties Chemical formula C 4H 8S Molar mass 88 17 g mol 1 Odor Garlic Density 0 803 g cm 3 Boiling point 92 C 197 F 365 K Hazards GHS labelling Pictograms Signal word Danger Hazard statements H225 Precautionary statements P210 Flash point 18 0 C 64 4 F 291 1 K Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references It is prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol CH2 CHCH2Cl NaOH aq CH3SH CH2 CHCH2SCH3 NaCl H2OReferences edit Eric Block 2010 01 04 Garlic and Other Alliums The Lore and the Science Royal Society of Chemistry ISBN 978 0 85404 190 9 Retrieved from https en wikipedia org w index php title Allyl methyl sulfide amp oldid 1101990319, wikipedia, wiki, book, books, library,

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