2,4,6-Tri-tert-butylpyrimidine is the organic compound with the formula HC(ButC)2N2CtBu where tBu = (CH3)3C. It is a substituted derivative of the heterocycle pyrimidine. Known also as TTBP, this compound is of interest as a base that is sufficiently bulky to not bind boron trifluoride but still able to bind protons. It is less expensive that the related bulky derivatives of pyridine such as 2,6-di-tert-butylpyridine, 2,4,6-tri-tert-butylpyridine, and 2,6-di-tert-butyl-4-methylpyridine.[1]
^Crich, David; Smith, Mark; Yao, Qingjia; Picione, John (2001). "2,4,6-Tri-tert-butylpyrimidine (TTBP): A Cost Effective, Readily Available Alternative to the Hindered Base 2,6-Di-tert-butylpyridine and its 4-Substituted Derivatives in Glycosylation and Other Reactions". Synthesis. 2001 (2): 0323–0326. doi:10.1055/s-2001-10798. S2CID 196775791.
January 01, 1970
tert, butylpyrimidine, organic, compound, with, formula, butc, 2n2ctbu, where, substituted, derivative, heterocycle, pyrimidine, known, also, ttbp, this, compound, interest, base, that, sufficiently, bulky, bind, boron, trifluoride, still, able, bind, protons,. 2 4 6 Tri tert butylpyrimidine is the organic compound with the formula HC ButC 2N2CtBu where tBu CH3 3C It is a substituted derivative of the heterocycle pyrimidine Known also as TTBP this compound is of interest as a base that is sufficiently bulky to not bind boron trifluoride but still able to bind protons It is less expensive that the related bulky derivatives of pyridine such as 2 6 di tert butylpyridine 2 4 6 tri tert butylpyridine and 2 6 di tert butyl 4 methylpyridine 1 2 4 6 Tri tert butylpyrimidine Names Preferred IUPAC name 2 4 6 Tri tert butylpyrimidine Identifiers CAS Number 67490 21 5 Y 3D model JSmol Interactive image ChemSpider 2682941 ECHA InfoCard 100 156 924 EC Number 628 674 7 PubChem CID 3440137 CompTox Dashboard EPA DTXSID20392494 InChI InChI 1S C16H28N2 c1 14 2 3 11 10 12 15 4 5 6 18 13 17 11 16 7 8 9 h10H 1 9H3Key VYWSYEDVFVGRGG UHFFFAOYSA N SMILES CC C C C1 CC NC N1 C C C C C C C C Properties Chemical formula C 16H 28N 2 Molar mass 248 414 g mol 1 Appearance White or colorless solid Melting point 77 78 C 171 172 F 350 351 K Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesReferences edit Crich David Smith Mark Yao Qingjia Picione John 2001 2 4 6 Tri tert butylpyrimidine TTBP A Cost Effective Readily Available Alternative to the Hindered Base 2 6 Di tert butylpyridine and its 4 Substituted Derivatives in Glycosylation and Other Reactions Synthesis 2001 2 0323 0326 doi 10 1055 s 2001 10798 S2CID 196775791 Retrieved from https en wikipedia org w index php title 2 4 6 Tri tert butylpyrimidine amp oldid 1195115150, wikipedia, wiki, book, books, library,
