In contrast, the heavier analogues NbCl5 and TaCl5 are stable and not particularly oxidizing.
Referencesedit
^Tamadon, Farhad; Seppelt, K. (2012). "The Elusive Halides VCl5, MoCl6, and ReCl6". Angewandte Chemie International Edition. 52 (2): 767–769. doi:10.1002/anie.201207552. PMID 23172658.
March 14, 2024
vanadium, chloride, inorganic, compound, with, formula, vcl5, black, diamagnetic, solid, molecules, adopt, bioctahedral, structure, similar, that, niobium, chloride, namesother, names, vanadium, pentachlorideidentifierscas, number, 1421358, model, jsmol, inter. Vanadium V chloride is the inorganic compound with the formula VCl5 It is a black diamagnetic solid The molecules adopt a bioctahedral structure similar to that of niobium V chloride 1 Vanadium V chloride NamesOther names vanadium pentachlorideIdentifiersCAS Number 1421358 80 63D model JSmol Interactive imagedimer Interactive imagePubChem CID 13643901InChI InChI 1S 5ClH V h5 1H q 5 p 5Key RPESBQCJGHJMTK UHFFFAOYSA ISMILES Cl V Cl Cl Cl Cldimer Cl V 1 Cl Cl Cl Cl V Cl 1 Cl Cl Cl ClPropertiesChemical formula Cl 10V 2Molar mass 456 38 g mol 1Appearance black solidExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesPreparation and reactions editVanadium V chloride is prepared from the vanadium pentafluoride with excess boron trichloride 2 VF5 10 BCl3 VCl5 2 10 BF2ClIt is unstable at room temperature with respect to vanadium IV chloride VCl5 2 2 VCl4 Cl2In contrast the heavier analogues NbCl5 and TaCl5 are stable and not particularly oxidizing References edit Tamadon Farhad Seppelt K 2012 The Elusive Halides VCl5 MoCl6 and ReCl6 Angewandte Chemie International Edition 52 2 767 769 doi 10 1002 anie 201207552 PMID 23172658 Retrieved from https en wikipedia org w index php title Vanadium V chloride amp oldid 1165481957, wikipedia, wiki, book, books, library,
