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Trinitroethylorthocarbonate

Trinitroethylorthocarbonate also known as TNEOC is an organic compound with the chemical formula C(OCH2C(NO2)3)4. It is an oxidizer with excellent chemical stability.[citation needed] Its explosion point is 238 °C, and it begins to be decomposed at 200 °C. Its explosion heat is 5.797 J/g and specific volume is 694 L/kg.[1] Its structure is closely related to that of trinitroethylorthoformate (TNEOF). Both are highly explosive and very shock-sensitive, and may be dissolved in nitroalkanes to reduce their shock-sensitivity.[1]

Trinitroethylorthocarbonate
Names
IUPAC name
2,2,2-Trinitroethyl orthocarbonate
Preferred IUPAC name
1,1,1-Trinitro-2-[tris(2,2,2-trinitroethoxy)methoxy]ethane
Other names
  • TNEOC
Identifiers
  • 14548-58-4
3D model (JSmol)
  • Interactive image
ChemSpider
  • 123272
  • 139779
  • InChI=1S/C9H8N12O28/c22-10(23)5(11(24)25,12(26)27)1-46-9(47-2-6(13(28)29,14(30)31)15(32)33,48-3-7(16(34)35,17(36)37)18(38)39)49-4-8(19(40)41,20(42)43)21(44)45/h1-4H2
    Key: JPTHXHQVODRICI-UHFFFAOYSA-N
  • C(C([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-])OC(OCC([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-])(OCC([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-])OCC([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-]
Properties
C(OCH2C(NO2)3)4
Molar mass 732.219 g·mol−1
Appearance Colorless crystals
Melting point 161 °C (322 °F; 434 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Synthesis edit

Trinitroethanol reacts with carbon tetrachloride under a catalyst of FeCl3.

 

References edit

  1. ^ a b Liu, Jiping (2015). Liquid Explosives. Springer. pp. 5, 6, 8, 136, 309. ISBN 9783662458471. Retrieved 26 March 2016.


trinitroethylorthocarbonate, this, article, relies, largely, entirely, single, source, relevant, discussion, found, talk, page, please, help, improve, this, article, introducing, citations, additional, sources, find, sources, news, newspapers, books, scholar, . This article relies largely or entirely on a single source Relevant discussion may be found on the talk page Please help improve this article by introducing citations to additional sources Find sources Trinitroethylorthocarbonate news newspapers books scholar JSTOR May 2017 Trinitroethylorthocarbonate also known as TNEOC is an organic compound with the chemical formula C OCH2C NO2 3 4 It is an oxidizer with excellent chemical stability citation needed Its explosion point is 238 C and it begins to be decomposed at 200 C Its explosion heat is 5 797 J g and specific volume is 694 L kg 1 Its structure is closely related to that of trinitroethylorthoformate TNEOF Both are highly explosive and very shock sensitive and may be dissolved in nitroalkanes to reduce their shock sensitivity 1 Trinitroethylorthocarbonate Names IUPAC name 2 2 2 Trinitroethyl orthocarbonate Preferred IUPAC name 1 1 1 Trinitro 2 tris 2 2 2 trinitroethoxy methoxy ethane Other names TNEOC Identifiers CAS Number 14548 58 4 3D model JSmol Interactive image ChemSpider 123272 PubChem CID 139779 InChI InChI 1S C9H8N12O28 c22 10 23 5 11 24 25 12 26 27 1 46 9 47 2 6 13 28 29 14 30 31 15 32 33 48 3 7 16 34 35 17 36 37 18 38 39 49 4 8 19 40 41 20 42 43 21 44 45 h1 4H2Key JPTHXHQVODRICI UHFFFAOYSA N SMILES C C N O O N O O N O O OC OCC N O O N O O N O O OCC N O O N O O N O O OCC N O O N O O N O O Properties Chemical formula C OCH2C NO2 3 4 Molar mass 732 219 g mol 1 Appearance Colorless crystals Melting point 161 C 322 F 434 K Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesSynthesis editTrinitroethanol reacts with carbon tetrachloride under a catalyst of FeCl3 CCl 4 Carbon tetrachloride 4 HOCH 2 C NO 2 3 Trinitroethanol FeCl 3 TNEOC 4 HCl displaystyle ce underset Carbon tetrachloride CCl4 underset Trinitroethanol 4HOCH2C NO2 3 gt ce FeCl3 TNEOC 4HCl nbsp References edit a b Liu Jiping 2015 Liquid Explosives Springer pp 5 6 8 136 309 ISBN 9783662458471 Retrieved 26 March 2016 nbsp This organic chemistry article is a stub You can help Wikipedia by expanding it vte nbsp This explosives related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Trinitroethylorthocarbonate amp oldid 1216703779, wikipedia, wiki, book, books, library,

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