Triethylsilane is the organosilicon compound with the formula (C2H5)3SiH. It is a trialkylsilane. The Si-H bond is reactive. This colorless liquid is used in organic synthesis as a reducing agent and as a precursor to silyl ethers.[2] As one of the simplest trialkylsilanes that is a liquid at room temperature, triethylsilane is often used in studies of hydrosilylation catalysis.[3]
Richard T. Beresis, Jason S. Solomon, Michael G. Yang, Nareshkumar F. Jain, and James S. Panek (1998). "Synthesis of Chiral (E)-Crotylsilanes: [3R- AND 3S-]-(4E)-Methyl 3-(Dimethylphenylsilyl)-4-Hexenoate ". Organic Syntheses. 75: 78{{cite journal}}: CS1 maint: multiple names: authors list (link).
Alessandro Dondoni and Daniela Perrone (2000). "Diastereoselective Synthesis of Protected Vicinal Amino Alcohols: (S)-2-[(4S)-N-tert-Butoxycarbonyl-2,2-Dimethyl-1,3,-oxazolidinyl]-2-tert-butyldimethylsiloxyethanal from a Serine-Derived Aldehyde ". Organic Syntheses. 77: 78.
Pape C. (1881). "Über Siliziumpropylverbindungen". Ber. 14: 1873.
Charles A. Kraus & Walter K. Nelson (1934). "The Chemistry of the Triethylsilicyl Group". J. Am. Chem. Soc.56 (1): 195–202. doi:10.1021/ja01316a062.
^Fry, James L.; Rahaim, Ronald J.; Maleczka, Robert E. (2007). "Triethylsilane". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/9780470842898.rt226.pub2. ISBN978-0471936237.
^Brookhart, M.; Grant, B. E. (1993). "Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: Direct evidence for a silyl migration pathway". Journal of the American Chemical Society. 115 (6): 2151–2156. doi:10.1021/ja00059a008.
January 01, 1970
triethylsilane, organosilicon, compound, with, formula, c2h5, 3sih, trialkylsilane, bond, reactive, this, colorless, liquid, used, organic, synthesis, reducing, agent, precursor, silyl, ethers, simplest, trialkylsilanes, that, liquid, room, temperature, trieth. Triethylsilane is the organosilicon compound with the formula C2H5 3SiH It is a trialkylsilane The Si H bond is reactive This colorless liquid is used in organic synthesis as a reducing agent and as a precursor to silyl ethers 2 As one of the simplest trialkylsilanes that is a liquid at room temperature triethylsilane is often used in studies of hydrosilylation catalysis 3 Triethylsilane Names Preferred IUPAC name Triethylsilane Identifiers CAS Number 617 86 7 Y 3D model JSmol Interactive image ChemSpider 11555 ECHA InfoCard 100 009 579 EC Number 210 535 3 PubChem CID 12052 UNII 0F9429873L Y CompTox Dashboard EPA DTXSID20870702 InChI InChI 1S C6H16Si c1 4 7 5 2 6 3 h7H 4 6H2 1 3H3Key AQRLNPVMDITEJU UHFFFAOYSA N SMILES CC SiH CC CC Properties Chemical formula C6H16Si Molar mass 116 28 g mol Appearance colorless liquid Density 0 728 g mL Melting point 156 1 C 249 0 F 117 0 K Boiling point 107 108 C 225 226 F 380 381 K log P 3 08 Vapor pressure 31 hPa at 20 C75 hPa at 38 C126 hPa at 50 C Hazards GHS labelling Pictograms Signal word Danger Hazard statements H225 H412 1 Precautionary statements P210 P273 1 Flash point 2 99 C 26 62 F 270 16 K closed cup 1 Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Y verify what is Y N Infobox referencesAdditional reading editRichard T Beresis Jason S Solomon Michael G Yang Nareshkumar F Jain and James S Panek 1998 Synthesis of Chiral E Crotylsilanes 3R AND 3S 4E Methyl 3 Dimethylphenylsilyl 4 Hexenoate Organic Syntheses 75 78 a href Template Cite journal html title Template Cite journal cite journal a CS1 maint multiple names authors list link Alessandro Dondoni and Daniela Perrone 2000 Diastereoselective Synthesis of Protected Vicinal Amino Alcohols S 2 4S N tert Butoxycarbonyl 2 2 Dimethyl 1 3 oxazolidinyl 2 tert butyldimethylsiloxyethanal from a Serine Derived Aldehyde Organic Syntheses 77 78 Pape C 1881 Uber Siliziumpropylverbindungen Ber 14 1873 Charles A Kraus amp Walter K Nelson 1934 The Chemistry of the Triethylsilicyl Group J Am Chem Soc 56 1 195 202 doi 10 1021 ja01316a062 References edit a b c Sigma Aldrich Co Triethylsilane Retrieved on 2015 01 30 Fry James L Rahaim Ronald J Maleczka Robert E 2007 Triethylsilane Encyclopedia of Reagents for Organic Synthesis doi 10 1002 9780470842898 rt226 pub2 ISBN 978 0471936237 Brookhart M Grant B E 1993 Mechanism of a cobalt III catalyzed olefin hydrosilation reaction Direct evidence for a silyl migration pathway Journal of the American Chemical Society 115 6 2151 2156 doi 10 1021 ja00059a008 Retrieved from https en wikipedia org w index php title Triethylsilane amp oldid 1096741127, wikipedia, wiki, book, books, library,
