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Triethyl orthoacetate

Triethyl orthoacetate is the organic compound with the formula CH3C(OC2H5)3. It is the ethyl orthoester of acetic acid. It is a colorless oily liquid.

Triethyl orthoacetate
Skeletal formula of Triethylorthoacetate
Ball-and-stick model of the Triethylorthoacetate molecule
Names
Preferred IUPAC name
1,1,1-Triethoxyethane
Identifiers
  • 78-39-7 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 59606 N
ECHA InfoCard 100.001.012
  • 66221
UNII
  • 48352MHC78 Y
  • DTXSID4058815
  • InChI=1S/C8H18O3/c1-5-9-8(4,10-6-2)11-7-3/h5-7H2,1-4H3 N
    Key: NDQXKKFRNOPRDW-UHFFFAOYSA-N N
  • CCOC(C)(OCC)OCC
Properties
C8H18O3
Molar mass 162.229 g·mol−1
Density 0.885 g/mL
Boiling point 142 °C (288 °F; 415 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

Triethyl orthoacetate is used in organic synthesis for acetylation.[1]

It is also used in the Johnson-Claisen rearrangement.[2]

References edit

  1. ^ B. W. Howk, J. C. Sauer (1959). "Phenylpropargylaldehyde Diethyl Acetal". Organic Syntheses. 39: 59. doi:10.15227/orgsyn.039.0059.
  2. ^ Fernandes, Rodney A.; Chowdhury, Asim K.; Kattanguru, Pullaiah (2014). "The Orthoester Johnson-Claisen Rearrangement in the Synthesis of Bioactive Molecules, Natural Products, and Synthetic Intermediates - Recent Advances". European Journal of Organic Chemistry. 2014 (14): 2833–2871. doi:10.1002/ejoc.201301033.

triethyl, orthoacetate, organic, compound, with, formula, ch3c, oc2h5, ethyl, orthoester, acetic, acid, colorless, oily, liquid, skeletal, formula, triethylorthoacetate, ball, stick, model, triethylorthoacetate, molecule, names, preferred, iupac, name, trietho. Triethyl orthoacetate is the organic compound with the formula CH3C OC2H5 3 It is the ethyl orthoester of acetic acid It is a colorless oily liquid Triethyl orthoacetate Skeletal formula of Triethylorthoacetate Ball and stick model of the Triethylorthoacetate molecule Names Preferred IUPAC name 1 1 1 Triethoxyethane Identifiers CAS Number 78 39 7 Y 3D model JSmol Interactive image ChemSpider 59606 N ECHA InfoCard 100 001 012 PubChem CID 66221 UNII 48352MHC78 Y CompTox Dashboard EPA DTXSID4058815 InChI InChI 1S C8H18O3 c1 5 9 8 4 10 6 2 11 7 3 h5 7H2 1 4H3 NKey NDQXKKFRNOPRDW UHFFFAOYSA N N SMILES CCOC C OCC OCC Properties Chemical formula C 8H 18O 3 Molar mass 162 229 g mol 1 Density 0 885 g mL Boiling point 142 C 288 F 415 K Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references Triethyl orthoacetate is used in organic synthesis for acetylation 1 It is also used in the Johnson Claisen rearrangement 2 References edit B W Howk J C Sauer 1959 Phenylpropargylaldehyde Diethyl Acetal Organic Syntheses 39 59 doi 10 15227 orgsyn 039 0059 Fernandes Rodney A Chowdhury Asim K Kattanguru Pullaiah 2014 The Orthoester Johnson Claisen Rearrangement in the Synthesis of Bioactive Molecules Natural Products and Synthetic Intermediates Recent Advances European Journal of Organic Chemistry 2014 14 2833 2871 doi 10 1002 ejoc 201301033 Retrieved from https en wikipedia org w index php title Triethyl orthoacetate amp oldid 1060009050, wikipedia, wiki, book, books, library,

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