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Tin(II) 2-ethylhexanoate

Tin(II) 2-ethylhexanoate or tin(II) octoate or stannous octoate (Sn(Oct)2)[1] is a compound of tin. Produced by the reaction of tin(II) oxide and 2-ethylhexanoic acid, it is a clear colorless liquid at room temperature, though often appears yellow due to impurities, likely resulting from oxidation of Sn(II) to Sn(IV).[2]

Tin(II) 2-ethylhexanoate
Names
IUPAC name
Tin(2+) bis(2-ethylhexanoate)
Identifiers
  • 301-10-0 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 8957
ECHA InfoCard 100.005.554
  • 16689712
UNII
  • 519A78R12Y Y
  • DTXSID1027138
  • InChI=1S/2C8H16O2.Sn/c2*1-3-5-6-7(4-2)8(9)10;/h2*7H,3-6H2,1-2H3,(H,9,10);/q;;+2/p-2
  • CCCCC(CC)C(=O)[O-].CCCCC(CC)C(=O)[O-].[Sn+2]
Properties
C16H30O4Sn
Molar mass 405.122 g·mol−1
Appearance Yellow liquid
Density 1.251 g/cm3
Melting point < 0 °C (32 °F; 273 K)
Boiling point ~ 130 to 150 °C (266 to 302 °F; 403 to 423 K) at 30 mTorr
Degrades in water to form Sn(IV)
Hazards
Flash point 113 °C (235 °F; 386 K) closed cup
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

It is sometimes used as a catalyst for ring-opening polymerization, such as for the production of polylactic acid.[3]

References edit

  1. ^ Sometimes misleadingly tin(II) octanoate.
  2. ^ Kumar Suri, Ashok; Banerjee, Srikuman (2006). "Tin". Materials Science and Technology. doi:10.1002/9783527603978.mst0079. ISBN 9783527603978.
  3. ^ Schwach, G.; Coudane, J.; Engel, R.; Vert, M. (1997). "More about the polymerization of lactides in the presence of stannous octoate". Journal of Polymer Science Part A: Polymer Chemistry. 35 (16): 3431–3440. Bibcode:1997JPoSA..35.3431S. doi:10.1002/(SICI)1099-0518(19971130)35:16<3431::AID-POLA10>3.0.CO;2-G.

ethylhexanoate, octoate, stannous, octoate, compound, produced, reaction, oxide, ethylhexanoic, acid, clear, colorless, liquid, room, temperature, though, often, appears, yellow, impurities, likely, resulting, from, oxidation, names, iupac, name, ethylhexanoat. Tin II 2 ethylhexanoate or tin II octoate or stannous octoate Sn Oct 2 1 is a compound of tin Produced by the reaction of tin II oxide and 2 ethylhexanoic acid it is a clear colorless liquid at room temperature though often appears yellow due to impurities likely resulting from oxidation of Sn II to Sn IV 2 Tin II 2 ethylhexanoate Names IUPAC name Tin 2 bis 2 ethylhexanoate Identifiers CAS Number 301 10 0 Y 3D model JSmol Interactive image ChemSpider 8957 ECHA InfoCard 100 005 554 PubChem CID 16689712 UNII 519A78R12Y Y CompTox Dashboard EPA DTXSID1027138 InChI InChI 1S 2C8H16O2 Sn c2 1 3 5 6 7 4 2 8 9 10 h2 7H 3 6H2 1 2H3 H 9 10 q 2 p 2 SMILES CCCCC CC C O O CCCCC CC C O O Sn 2 Properties Chemical formula C 16H 30O 4Sn Molar mass 405 122 g mol 1 Appearance Yellow liquid Density 1 251 g cm3 Melting point lt 0 C 32 F 273 K Boiling point 130 to 150 C 266 to 302 F 403 to 423 K at 30 mTorr Solubility in water Degrades in water to form Sn IV Hazards Flash point 113 C 235 F 386 K closed cup Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references It is sometimes used as a catalyst for ring opening polymerization such as for the production of polylactic acid 3 References edit Sometimes misleadingly tin II octanoate Kumar Suri Ashok Banerjee Srikuman 2006 Tin Materials Science and Technology doi 10 1002 9783527603978 mst0079 ISBN 9783527603978 Schwach G Coudane J Engel R Vert M 1997 More about the polymerization of lactides in the presence of stannous octoate Journal of Polymer Science Part A Polymer Chemistry 35 16 3431 3440 Bibcode 1997JPoSA 35 3431S doi 10 1002 SICI 1099 0518 19971130 35 16 lt 3431 AID POLA10 gt 3 0 CO 2 G Retrieved from https en wikipedia org w index php title Tin II 2 ethylhexanoate amp oldid 1109625971, wikipedia, wiki, book, books, library,

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