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Tetrachloro-m-xylene

Tetrachloro-m-xylene (tetrachlorometaxylene, or TCMX) is the organochlorine compound with the formula C6Cl4(CH3)2. It is the chlorinated derivative of m-xylene in which the four aromatic hydrogen atoms are replaced by chlorine. It is prepared by ferric chloride-catalyzed reaction of the xylene with chlorine.[1]

Tetrachloro-m-xylene
Names
Preferred IUPAC name
1,2,3,5-Tetrachloro-4,6-dimethylbenzene
Other names
Tetrachlorometaxylene
2,4,5,6-Tetrachlorometaxylene
Identifiers
  • 877-09-8 Y
3D model (JSmol)
  • Interactive image
Abbreviations TCMX
ChemSpider
  • 63327 Y
ECHA InfoCard 100.011.715
EC Number
  • 212-886-8
  • 70139
UNII
  • O8XMK3B4S9 Y
  • DTXSID6075433
  • InChI=1S/C8H6Cl4/c1-3-5(9)4(2)7(11)8(12)6(3)10/h1-2H3 Y
    Key: NTUBJKOTTSFEEV-UHFFFAOYSA-N Y
  • InChI=1/C8H6Cl4/c1-3-5(9)4(2)7(11)8(12)6(3)10/h1-2H3
    Key: NTUBJKOTTSFEEV-UHFFFAOYAN
  • Clc1c(c(Cl)c(c(Cl)c1Cl)C)C
Properties
C8H6Cl4
Molar mass 243.94524
Appearance colorless or white solid
Melting point 223 °C (433 °F; 496 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

TCMX is used as an internal standard in the analysis of organochlorides, particularly organochloride pesticides.[2][3]

References

  1. ^ Riegger, Paul; Steffen, Klaus Dieter (1979). "Chlorination of xylenes and secondary Products. I. Chlorination of the nucleus and Side Chains of Xylenes". Chemiker-Zeitung. 103: 1-7.
  2. ^ Organochlorine Pesticides by GCxGC-ECD
  3. ^ Wang, Wentao; Meng, Bingjun; Lu, Xiaoxia; Liu, Yu; Tao, Shu (2007). "Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils: A comparison between Soxhlet extraction, microwave-assisted extraction and accelerated solvent extraction techniques". Analytica Chimica Acta. 602 (2): 211–222. doi:10.1016/j.aca.2007.09.023.

tetrachloro, xylene, tetrachlorometaxylene, tcmx, organochlorine, compound, with, formula, c6cl4, chlorinated, derivative, xylene, which, four, aromatic, hydrogen, atoms, replaced, chlorine, prepared, ferric, chloride, catalyzed, reaction, xylene, with, chlori. Tetrachloro m xylene tetrachlorometaxylene or TCMX is the organochlorine compound with the formula C6Cl4 CH3 2 It is the chlorinated derivative of m xylene in which the four aromatic hydrogen atoms are replaced by chlorine It is prepared by ferric chloride catalyzed reaction of the xylene with chlorine 1 Tetrachloro m xylene NamesPreferred IUPAC name 1 2 3 5 Tetrachloro 4 6 dimethylbenzeneOther names Tetrachlorometaxylene2 4 5 6 TetrachlorometaxyleneIdentifiersCAS Number 877 09 8 Y3D model JSmol Interactive imageAbbreviations TCMXChemSpider 63327 YECHA InfoCard 100 011 715EC Number 212 886 8PubChem CID 70139UNII O8XMK3B4S9 YCompTox Dashboard EPA DTXSID6075433InChI InChI 1S C8H6Cl4 c1 3 5 9 4 2 7 11 8 12 6 3 10 h1 2H3 YKey NTUBJKOTTSFEEV UHFFFAOYSA N YInChI 1 C8H6Cl4 c1 3 5 9 4 2 7 11 8 12 6 3 10 h1 2H3Key NTUBJKOTTSFEEV UHFFFAOYANSMILES Clc1c c Cl c c Cl c1Cl C CPropertiesChemical formula C 8H 6Cl 4Molar mass 243 94524Appearance colorless or white solidMelting point 223 C 433 F 496 K Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references TCMX is used as an internal standard in the analysis of organochlorides particularly organochloride pesticides 2 3 References Edit Riegger Paul Steffen Klaus Dieter 1979 Chlorination of xylenes and secondary Products I Chlorination of the nucleus and Side Chains of Xylenes Chemiker Zeitung 103 1 7 Organochlorine Pesticides by GCxGC ECD Wang Wentao Meng Bingjun Lu Xiaoxia Liu Yu Tao Shu 2007 Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils A comparison between Soxhlet extraction microwave assisted extraction and accelerated solvent extraction techniques Analytica Chimica Acta 602 2 211 222 doi 10 1016 j aca 2007 09 023 This article about an organic halide is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Tetrachloro m xylene amp oldid 1092565108, wikipedia, wiki, book, books, library,

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