Rhenium(VI) chloride is the inorganic compound with the formula ReCl6. It is a black paramagnetic solid. The molecules adopt an octahedral structure as seen in tungsten(VI) chloride.[1]
Rhenium(VI) chloride was first generated as a mixture by chlorination of Re films.[2] Bulk samples can be prepared by combining rhenium hexafluoride with excess boron trichloride:
rhenium, chloride, inorganic, compound, with, formula, recl6, black, paramagnetic, solid, molecules, adopt, octahedral, structure, seen, tungsten, chloride, names, other, names, rhenium, hexachloride, identifiers, number, 31234, model, jsmol, interactive, imag. Rhenium VI chloride is the inorganic compound with the formula ReCl6 It is a black paramagnetic solid The molecules adopt an octahedral structure as seen in tungsten VI chloride 1 Rhenium VI chloride Names Other names rhenium hexachloride Identifiers CAS Number 31234 26 1 3D model JSmol Interactive image ChemSpider 4321528 PubChem CID 5148054 InChI InChI 1S 6ClH Re h6 1H q 6 p 6Key GSGIQJBJGSKCDZ UHFFFAOYSA H SMILES Cl Re Cl Cl Cl Cl Cl Properties Chemical formula Cl 6Re Molar mass 398 91 g mol 1 Appearance black solid Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesPreparation and reactions editRhenium VI chloride was first generated as a mixture by chlorination of Re films 2 Bulk samples can be prepared by combining rhenium hexafluoride with excess boron trichloride 2 ReF6 6 BCl3 ReCl6 6 BF2Cl It is unstable at room temperature with respect to rhenium V chloride 2 ReCl6 ReCl5 2 Cl2References edit Tamadon Farhad Seppelt K 2012 The Elusive Halides VCl5 MoCl6 and ReCl6 Angewandte Chemie International Edition 52 2 767 769 doi 10 1002 anie 201207552 PMID 23172658 Colton R 1962 Rhenium Hexachloride Nature 194 4826 374 375 Bibcode 1962Natur 194 374C doi 10 1038 194374a0 S2CID 4166446 1 Colton R 1962 Rhenium Hexachloride Nature 194 4826 374 375 Bibcode 1962Natur 194 374C doi 10 1038 194374a0 S2CID 4166446 Retrieved from https en wikipedia org w index php title Rhenium VI chloride amp oldid 1152363643, wikipedia, wiki, book, books, library,
