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Potassium hexafluorocuprate(III)

Potassium hexafluorocuprate(III) is an inorganic compound with the chemical formula K3CuF6. It is a green paramagnetic solid, a relatively rare example of a copper(III) compound.[1]

Synthesis and structure

The compound is prepared by oxidizing the mixture of potassium chloride and cuprous chloride with fluorine:[2]

3 KCl + CuCl + 3 F2 → K3CuF6 + 2 Cl2

A variety of analogues are known.[3] The compound reacts with water easily, producing oxygen and copper(II) products.[1]

See also

References

  1. ^ a b Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, ISBN 0-12-352651-5
  2. ^ Popova, T. V.; Aksenova, N. V. (November 1, 2003). "Complexes of Copper in Unstable Oxidation States". Russian Journal of Coordination Chemistry. 29 (11): 743–765. doi:10.1023/B:RUCO.0000003432.39025.cc. S2CID 93464243.
  3. ^ R. Hoppe, G. Wingefeld "Zur Kenntnis der Hexafluorocuprate(III)" Zeitschrift für anorganische und allgemeine Chemie 1984, Vol. 519, pages 195–203. doi:10.1002/zaac.19845191221

potassium, hexafluorocuprate, inorganic, compound, with, chemical, formula, k3cuf6, green, paramagnetic, solid, relatively, rare, example, copper, compound, synthesis, structure, editthe, compound, prepared, oxidizing, mixture, potassium, chloride, cuprous, ch. Potassium hexafluorocuprate III is an inorganic compound with the chemical formula K3CuF6 It is a green paramagnetic solid a relatively rare example of a copper III compound 1 Synthesis and structure EditThe compound is prepared by oxidizing the mixture of potassium chloride and cuprous chloride with fluorine 2 3 KCl CuCl 3 F2 K3CuF6 2 Cl2A variety of analogues are known 3 The compound reacts with water easily producing oxygen and copper II products 1 See also EditCuprate III caesium hexafluorocuprate IV References Edit a b Holleman Arnold Frederik Wiberg Egon 2001 Wiberg Nils ed Inorganic Chemistry translated by Eagleson Mary Brewer William San Diego Berlin Academic Press De Gruyter ISBN 0 12 352651 5 Popova T V Aksenova N V November 1 2003 Complexes of Copper in Unstable Oxidation States Russian Journal of Coordination Chemistry 29 11 743 765 doi 10 1023 B RUCO 0000003432 39025 cc S2CID 93464243 R Hoppe G Wingefeld Zur Kenntnis der Hexafluorocuprate III Zeitschrift fur anorganische und allgemeine Chemie 1984 Vol 519 pages 195 203 doi 10 1002 zaac 19845191221 This inorganic compound related article is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Potassium hexafluorocuprate III amp oldid 1118577510, wikipedia, wiki, book, books, library,

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