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Phosphanide

May 02, 2024

Phosphanides are chemicals containing the [PH2]− anion. This is also known as the phosphino anion or phosphido ligand. The IUPAC name can also be dihydridophosphate(1−).[1]

Phosphanide
Identifiers
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:29938
ChemSpider
  • 56490
284
  • 62746
  • InChI=1S/H2P/h1H2/q-1
    Key: JZWFHNVJSWEXLH-UHFFFAOYSA-N
  • [H][P-][H]
Properties
H2P−
Molar mass 32.990 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

It can occur as a group phosphanyl -PH2 in organic compounds or ligand called phosphanido, or dihydridophosphato(1−). A related substance has PH2−. Phosphinidene (PH) has phosphorus in a −1 oxidation state.[2]

As a ligand PH2 can either bond to one atom or be in a μ2-bridged ligand across two metal atoms.[3] With transition metals and actinides, bridging is likely unless the metal atom is mostly enclosed in a ligand.

In phosphanides, phosphorus is in the −3 oxidation state. When phosphanide is oxidised, the first step is phosphinite ([H2PO]−). Further oxidation yields phosphonite ([HPO2]2−)and phosphite ([PO3]3−).[4]

The study of phosphine derivatives is unpopular, because they are unstable, poisonous and malodorous.[5]

Formation edit

Alkali metal phosphanides can be made from phosphine and the metal dissolved in liquid ammonia. Sodium phosphanide can also be made from phosphine and triphenylmethyl sodium. Lithium phospahnide can be made from phosphine and butyl lithium or phenyl lithium.[3]

Another way to produce -PH2 complexes is by hydrolysis of a -P(SiMe3)2 compound with an alcohol, such as methanol.[3]

Yet another way is to remove a hydrogen atom from the phosphine in a phosphine complex by using a strong base.[3]

Properties edit

When calcium phosphanide is heated, it decomposes by releasing phosphine and yielding the phosphanediide: CaPH. With further heating a binary calcium phosphide is formed.[4] Other compounds may also lose hydrogen as well as phosphine.[6]


Phosphanides can react with CCl4 to substitute Cl for H giving a -PCl2 compound. Similarly CBr4 can produce -PBr2. Also AgBF4 can react to yield -PF2.[7]

Sodium phosphanide can react with ethyl alcohol in a diethyl carbonate solution to yield sodium 2-phosphaethynolate (NaOCP). Na(DME)2OCP is also formed from NaPH2 when reacted with CO in a dimethoxyethane (DME) solution under pressure.[8]

List edit

name formula system space group unit cell Å volume density M-P Å comment ref
lithium phosphanide LiPH2
Bis(1,2-dimethoxyethane-O,O′)lithium-phosphanide (dme)2LiPH2 monoclinic a=13.911 b=8.098 c=12.491 β=103.35° 1371.9 1.07 [9]
Li(PH2)(BEt3)2 [10]
LiPH2(BH3)2(THF)2 [10]
sodium dihydrogenphosphide NaPH2 [3]
Na13(PH2)(OtBu)12 [3]
tetraphosphanylsilane Si(PH2)4 [11]
KPH2 [3]
Ca(PH2)2•6NH3 [4]
Ca(PH2)2•2NH3 [4]
Cp2(CO)4Cr2(μ-PH2)(μ-H) [12]
Cp2(CO)4Cr2(μ-PH2)2 [12]
[(CO)4Cr(μ-PH2)]2 orthorhombic Cmca a =12.2545 b =11.5949 c=9.7196 [13]
(CO)4Cr(μ-PH2)2Cr(CO)3(PH3) triclinic P1 a=7.008 b=7.430 c=8.871, α =111.05° β=92.73° γ=114.08° [13]
Mn(PH2)2 · 3 NH3 [14]
K2[Mn(PH2)4] · 2 NH3 [14]
[(CO)4MnPH2]2 triclinic P1 a = 6.804, b = 7.064, c = 9.191, α =110.5°, β = 91.92°, γ =115.65°, Z = 1 [7][15]
(μ-PH2)2 · Mn2(CO8) + (μ-Br)(μ-PH2)Mn2(CO8) monoclinic P21/c a = 9.467, b = 12.181, c = 13.086, β = 109.98° 1418.2 [16]
[(CO)4MnPH2]3 monoclinic P2/n a = 9.052, b = 9.748, c = 12.642, β = 109.1°, Z = 2 [17][15]
(μ-Br)(μ-PH2)Mn2(CO8) [16]
[(CO)3Fe(μ-PH2)]2 monoclinic P21/m a =6.2476 b =12.982 c =7.2193 β =90.14° [13]
Cp(CO)2Fe(μ-PH2)Fe(CO)4 [3]
Co(PH2)3 [3][6]
KCo2(PH2)7 [3][6]
cp(CO)2Fe(μ-PH2)Fe(CO)4 monoclinic P21/c a = 7.336, b = 10.898, c = 17.616, β = 99.65°, Z = 4 2.29, 2.265 [17]
cp(CO)2Fe(μ-PH2)Fe(CO)(NO)2 [18]
cp(CO)2Fe(μ-PH2)Vcp(CO)3 [18]
cp(CO)2Fe(μ-PH2)Crcp(CO)(NO) [18]
cp(CO)2Fe(μ-PH2)Cr(CO)5 [18]
cp(CO)Fe(μ-CO, μ-PH2)Crcp(NO) [18]
cp(CO)2Fe(μ-PH2)MnMecp(CO)2 monoclinic P21 a = 7.501, b = 22.345, c = 9.741, β = 106.23°, Z = 4 [18][19]
cp(CO)2Fe(μ-PH2)Mn(NO)3 [18]
cp(CO)2Fe(μ-PH2)Mncp(CO)2 [18]
cp(CO)Fe(μ-CO, μ-PH2)Mncp(CO) [18]
cp(CO)Fe(μ-CO, μ-PH2)MnMecp(CO) [18]
(μ2-phosphido)-octacarbonyl-iron-manganese FeMn(CO)8(μ-PH2) triclinic P1 a=7.8647 b=9.223 c=9.368, α=90.966° β=91.141° γ=110.032° [20]
Li+[FeMn(CO)8(μ3-PH)Mn(CO)4(μ-PH2)Fe(CO)4]− [20]
Na+[FeMn(CO)8(μ3-PH)Mn(CO)4(μ-PH2)Fe(CO)4]− [20]
K+[FeMn(CO)8(μ3-PH)Mn(CO)4(μ-PH2)Fe(CO)4]− [20]
cp(CO)2Fe(μ-PH2)Co(CO)2(NO) [18]
Ni(PH2)2 [3][21]
[cpNiPH2]2 [22]
[cpNiPH2]3 rhombohedral R3 a = 16.861, c = 5.611 Z = 3 6 member ring [23][15]
K[Ni(PH2)3] orange, green or black [3][21]
cp(CO)2Fe(μ-PH2)Ni(CO)3 [17]
CH{(CMe)(2,6-iPr2C6H3N)}2GeIIPH2 monoclinic P21/c a=14.1380 b=16.3244 c=13.8086 β=116.379 Z=4 2855.1 1.213 orange or red [24]
[CH{(CMe)(2,6-iPr2C6H3N)}2GeIIP(H)]2 triclinic P1 a=10.8175 b=12.0783 c=2.6434 α=91.550 β=108.361 γ=111.339 Z=1 1441.49 1.203 red [24]
bisphosphanyl yttriate [(Me3Si)2Cp]2Y(PH2)2[Li(TMEDA)]2Cl [3]
(N,N',N''-[nitrilotri(ethane-2,1-diyl)]tris(t-butyl(dimethyl)silanamino))-phosphanyl-zirconium(iv) Zr(TrenDMBS)(PH2) TrenDMBS=N(CH2CH2NSiMe2But)3 orthorhombic Pbca a=19.978 b=15.4052 c=22.721 Zr−P=2.690 yellow [2]
{Cp(CO)2Mo}2(μ-PH2)(μ-H) [25][26]
Mo2Cp2(μ-PH2)2(CO)2 [27]
cp(CO)2Fe(μ-PH2)Mo(CO)5 [18]
{Cp(CO)2W}2(μ-PH2)(μ-H) [26]
W2Cp2(μ-PH2)2(CO)2 [27]
[(CO)4W(μ-PH2)]2 orthorhombic Cmca a=12.498 b=12.046 c=10.1185 [13]
[(CO)5W(μ-PH2)]2− [3]
(CO)4W(μ-PH2)2W(CO)3(PH3) a=7.008 b=7.430 c=8.871, α =111.05° β =92.73° γ=114.08° [13]
(CO)4W(μ-PH2)2W(CO)2(PH3)2 triclinic P1 a=7.014 b=9.386 c=13.632, α=70.15° β=79.82° γ=68.78° [13]
NMe3•H2BPH2••W(CO)5 [3]
phosphanylalane NMe3•H2AlPH2•W(CO)5 [3]
cp(CO)2Fe(μ-PH2)W(CO)5 [18]
phosphanygallane NMe3•H2GaPH2••W(CO)5 [3]
Re2(μ-PH2)2(CO)8 monoclinic P21/c a=9.808 b=12.326 c=13.299 β=109.08° Z=4 1519.4 2.896 yellow [28]
Re2(μ-H) · (μ-PH2)(CO)8 yellow [28]
Os(η2-O2CCH3)(PH2)(CO)(PPh3)2 [29]
Os(η2-N,N-dimethyldithiocarbamate)(PH2)(CO)(PPh3)2 [29]
Os(η2-acetylacetonate)(PH2)(CO)(PPh3)2 [29]
Os(η2-NO2)(PH2)(CO)(PPh3)2 [29]
OsCl- (PH2)(CO)2(PPh3)2 [30]
OsCl- (PH2)(CO)(PPh3)3 [30]
[Os(μ2-PH2)Cl(CO)(PPh3)2]2 triclinic P1 a 14.101, b 15.091, c 11.708, α 96.68, β 91.71, γ 63.92°, Z = 1 2222.0 [30]
OsH(PH2)(CO)2(PPh3)2 [30]
(μ2-Hydrido)-(μ2-phosphido)-acetonitrilo-henicosacarbonyl-hexa-osmium Os6(μ-H)(CO)21(NCMe)(μ-PH2) monoclinic P21/n a=11.161 b=12.532 c =26.60, β=90.03° [31]
(μ2-Phosphido)-(μ2-hydrido)-bis(undecacarbonyl-tri-osmium) Os6(μ-H)(CO)22(μ-PH2) monoclinic P21/c a =14.328 b =16.658 c =15.258, β =103.79° [31][32]
Os6(μ-H)(CO)21(CNBut)(μ-PH2) [31]
[Os6(μ-H)(CO)20{P(OMe)3}2(μ-PH2)]3 [31]
Ir(CO)ClH(PEt3)2(PH2) [3]
Ir(CO)BrH(PEt3)2(PH2) [3]
(Acetato-O,O')-(μ2-phosphonito)-carbonyl-iodo-bis(triphenylphosphine)-gold-osmium dichloromethane solvate Os(η2-O2CCH3)(PH2AuI)(CO)(PPh3)2 · (CH2Cl2)2 triclinic P1 a=12.320 b=13.962 c=14.122, α=96.76° β=101.93° γ=107.72° [29]
phosphanido-(N'-(triisopropylsilyl)-N,N-bis(2-((triisopropylsilyl)amino)ethyl)ethane-1,2-diaminato)-thorium(iv) Th(TrenTIPS)(PH2) monoclinic P21/n a=18.6189 b=22.6046 c=22.2818 β=113.726° 2.982 colourless [33]
PH2–UH 2.762 in solid argon [34]
TrenTIPS=N(CH2CH2NSiPri3)3 U(TrenTIPS)(PH2) monoclinic P21/n a=12.9994 b=16.2006 c=20.3678 β=91.313 Z=4 4288.3 2.883 yellow [35]

Derivatives edit

Some derivatives of phosphanides have also been studied where hydrogen is substituted by another group. They include bis(trimethylsilyl)phosphanide, bis (triisopropylsilyl) phosphanide, bis (trimethylsilyl) phosphanide, diphenyl phosphanide.[36][37]

References edit

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May 02, 2024
phosphanide, chemicals, containing, anion, this, also, known, phosphino, anion, phosphido, ligand, iupac, name, also, dihydridophosphate, identifiers, model, jsmol, interactive, image, chebi, chebi, 29938, chemspider, 56490, gmelin, reference, pubchem, 62746, . Phosphanides are chemicals containing the PH2 anion This is also known as the phosphino anion or phosphido ligand The IUPAC name can also be dihydridophosphate 1 1 Phosphanide Identifiers 3D model JSmol Interactive image ChEBI CHEBI 29938 ChemSpider 56490 Gmelin Reference 284 PubChem CID 62746 InChI InChI 1S H2P h1H2 q 1Key JZWFHNVJSWEXLH UHFFFAOYSA N SMILES H P H Properties Chemical formula H 2P Molar mass 32 990 g mol 1 Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references It can occur as a group phosphanyl PH2 in organic compounds or ligand called phosphanido or dihydridophosphato 1 A related substance has PH2 Phosphinidene PH has phosphorus in a 1 oxidation state 2 As a ligand PH2 can either bond to one atom or be in a m2 bridged ligand across two metal atoms 3 With transition metals and actinides bridging is likely unless the metal atom is mostly enclosed in a ligand In phosphanides phosphorus is in the 3 oxidation state When phosphanide is oxidised the first step is phosphinite H2PO Further oxidation yields phosphonite HPO2 2 and phosphite PO3 3 4 The study of phosphine derivatives is unpopular because they are unstable poisonous and malodorous 5 Contents 1 Formation 2 Properties 3 List 4 Derivatives 5 ReferencesFormation editAlkali metal phosphanides can be made from phosphine and the metal dissolved in liquid ammonia Sodium phosphanide can also be made from phosphine and triphenylmethyl sodium Lithium phospahnide can be made from phosphine and butyl lithium or phenyl lithium 3 Another way to produce PH2 complexes is by hydrolysis of a P SiMe3 2 compound with an alcohol such as methanol 3 Yet another way is to remove a hydrogen atom from the phosphine in a phosphine complex by using a strong base 3 Properties editWhen calcium phosphanide is heated it decomposes by releasing phosphine and yielding the phosphanediide CaPH With further heating a binary calcium phosphide is formed 4 Other compounds may also lose hydrogen as well as phosphine 6 Phosphanides can react with CCl4 to substitute Cl for H giving a PCl2 compound Similarly CBr4 can produce PBr2 Also AgBF4 can react to yield PF2 7 Sodium phosphanide can react with ethyl alcohol in a diethyl carbonate solution to yield sodium 2 phosphaethynolate NaOCP Na DME 2OCP is also formed from NaPH2 when reacted with CO in a dimethoxyethane DME solution under pressure 8 List editname formula system space group unit cell A volume density M P A comment ref lithium phosphanide LiPH2 Bis 1 2 dimethoxyethane O O lithium phosphanide dme 2LiPH2 monoclinic a 13 911 b 8 098 c 12 491 b 103 35 1371 9 1 07 9 Li PH2 BEt3 2 10 LiPH2 BH3 2 THF 2 10 sodium dihydrogenphosphide NaPH2 3 Na13 PH2 OtBu 12 3 tetraphosphanylsilane Si PH2 4 11 KPH2 3 Ca PH2 2 6NH3 4 Ca PH2 2 2NH3 4 Cp2 CO 4Cr2 m PH2 m H 12 Cp2 CO 4Cr2 m PH2 2 12 CO 4Cr m PH2 2 orthorhombic Cmca a 12 2545 b 11 5949 c 9 7196 13 CO 4Cr m PH2 2Cr CO 3 PH3 triclinic P1 a 7 008 b 7 430 c 8 871 a 111 05 b 92 73 g 114 08 13 Mn PH2 2 3 NH3 14 K2 Mn PH2 4 2 NH3 14 CO 4MnPH2 2 triclinic P1 a 6 804 b 7 064 c 9 191 a 110 5 b 91 92 g 115 65 Z 1 7 15 m PH2 2 Mn2 CO8 m Br m PH2 Mn2 CO8 monoclinic P21 c a 9 467 b 12 181 c 13 086 b 109 98 1418 2 16 CO 4MnPH2 3 monoclinic P2 n a 9 052 b 9 748 c 12 642 b 109 1 Z 2 17 15 m Br m PH2 Mn2 CO8 16 CO 3Fe m PH2 2 monoclinic P21 m a 6 2476 b 12 982 c 7 2193 b 90 14 13 Cp CO 2Fe m PH2 Fe CO 4 3 Co PH2 3 3 6 KCo2 PH2 7 3 6 cp CO 2Fe m PH2 Fe CO 4 monoclinic P21 c a 7 336 b 10 898 c 17 616 b 99 65 Z 4 2 29 2 265 17 cp CO 2Fe m PH2 Fe CO NO 2 18 cp CO 2Fe m PH2 Vcp CO 3 18 cp CO 2Fe m PH2 Crcp CO NO 18 cp CO 2Fe m PH2 Cr CO 5 18 cp CO Fe m CO m PH2 Crcp NO 18 cp CO 2Fe m PH2 MnMecp CO 2 monoclinic P21 a 7 501 b 22 345 c 9 741 b 106 23 Z 4 18 19 cp CO 2Fe m PH2 Mn NO 3 18 cp CO 2Fe m PH2 Mncp CO 2 18 cp CO Fe m CO m PH2 Mncp CO 18 cp CO Fe m CO m PH2 MnMecp CO 18 m2 phosphido octacarbonyl iron manganese FeMn CO 8 m PH2 triclinic P1 a 7 8647 b 9 223 c 9 368 a 90 966 b 91 141 g 110 032 20 Li FeMn CO 8 m3 PH Mn CO 4 m PH2 Fe CO 4 20 Na FeMn CO 8 m3 PH Mn CO 4 m PH2 Fe CO 4 20 K FeMn CO 8 m3 PH Mn CO 4 m PH2 Fe CO 4 20 cp CO 2Fe m PH2 Co CO 2 NO 18 Ni PH2 2 3 21 cpNiPH2 2 22 cpNiPH2 3 rhombohedral R3 a 16 861 c 5 611 Z 3 6 member ring 23 15 K Ni PH2 3 orange green or black 3 21 cp CO 2Fe m PH2 Ni CO 3 17 CH CMe 2 6 iPr2C6H3N 2GeIIPH2 monoclinic P21 c a 14 1380 b 16 3244 c 13 8086 b 116 379 Z 4 2855 1 1 213 orange or red 24 CH CMe 2 6 iPr2C6H3N 2GeIIP H 2 triclinic P1 a 10 8175 b 12 0783 c 2 6434 a 91 550 b 108 361 g 111 339 Z 1 1441 49 1 203 red 24 bisphosphanyl yttriate Me3Si 2Cp 2Y PH2 2 Li TMEDA 2Cl 3 N N N nitrilotri ethane 2 1 diyl tris t butyl dimethyl silanamino phosphanyl zirconium iv Zr TrenDMBS PH2 TrenDMBS N CH2CH2NSiMe2But 3 orthorhombic Pbca a 19 978 b 15 4052 c 22 721 Zr P 2 690 yellow 2 Cp CO 2Mo 2 m PH2 m H 25 26 Mo2Cp2 m PH2 2 CO 2 27 cp CO 2Fe m PH2 Mo CO 5 18 Cp CO 2W 2 m PH2 m H 26 W2Cp2 m PH2 2 CO 2 27 CO 4W m PH2 2 orthorhombic Cmca a 12 498 b 12 046 c 10 1185 13 CO 5W m PH2 2 3 CO 4W m PH2 2W CO 3 PH3 a 7 008 b 7 430 c 8 871 a 111 05 b 92 73 g 114 08 13 CO 4W m PH2 2W CO 2 PH3 2 triclinic P1 a 7 014 b 9 386 c 13 632 a 70 15 b 79 82 g 68 78 13 NMe3 H2BPH2 W CO 5 3 phosphanylalane NMe3 H2AlPH2 W CO 5 3 cp CO 2Fe m PH2 W CO 5 18 phosphanygallane NMe3 H2GaPH2 W CO 5 3 Re2 m PH2 2 CO 8 monoclinic P21 c a 9 808 b 12 326 c 13 299 b 109 08 Z 4 1519 4 2 896 yellow 28 Re2 m H m PH2 CO 8 yellow 28 Os h2 O2CCH3 PH2 CO PPh3 2 29 Os h2 N N dimethyldithiocarbamate PH2 CO PPh3 2 29 Os h2 acetylacetonate PH2 CO PPh3 2 29 Os h2 NO2 PH2 CO PPh3 2 29 OsCl PH2 CO 2 PPh3 2 30 OsCl PH2 CO PPh3 3 30 Os m2 PH2 Cl CO PPh3 2 2 triclinic P1 a 14 101 b 15 091 c 11 708 a 96 68 b 91 71 g 63 92 Z 1 2222 0 30 OsH PH2 CO 2 PPh3 2 30 m2 Hydrido m2 phosphido acetonitrilo henicosacarbonyl hexa osmium Os6 m H CO 21 NCMe m PH2 monoclinic P21 n a 11 161 b 12 532 c 26 60 b 90 03 31 m2 Phosphido m2 hydrido bis undecacarbonyl tri osmium Os6 m H CO 22 m PH2 monoclinic P21 c a 14 328 b 16 658 c 15 258 b 103 79 31 32 Os6 m H CO 21 CNBut m PH2 31 Os6 m H CO 20 P OMe 3 2 m PH2 3 31 Ir CO ClH PEt3 2 PH2 3 Ir CO BrH PEt3 2 PH2 3 Acetato O O m2 phosphonito carbonyl iodo bis triphenylphosphine gold osmium dichloromethane solvate Os h2 O2CCH3 PH2AuI CO PPh3 2 CH2Cl2 2 triclinic P1 a 12 320 b 13 962 c 14 122 a 96 76 b 101 93 g 107 72 29 phosphanido N triisopropylsilyl N N bis 2 triisopropylsilyl amino ethyl ethane 1 2 diaminato thorium iv Th TrenTIPS PH2 monoclinic P21 n a 18 6189 b 22 6046 c 22 2818 b 113 726 2 982 colourless 33 PH2 UH 2 762 in solid argon 34 TrenTIPS N CH2CH2NSiPri3 3 U TrenTIPS PH2 monoclinic P21 n a 12 9994 b 16 2006 c 20 3678 b 91 313 Z 4 4288 3 2 883 yellow 35 Derivatives editSome derivatives of phosphanides have also been studied where hydrogen is substituted by another group They include bis trimethylsilyl phosphanide bis triisopropylsilyl phosphanide bis trimethylsilyl phosphanide diphenyl phosphanide 36 37 References edit Red Book a b Stafford Hannah Rookes Thomas M Wildman Elizabeth P Balazs Gabor Wooles Ashley J Scheer Manfred Liddle Stephen T 19 June 2017 Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium IV Angewandte Chemie International Edition 56 26 7669 7673 doi 10 1002 anie 201703870 PMC 5575506 PMID 28489308 a b c d e f g h i j k l m n o p q r s Hendrikus Hendriksen Coenradus Johannes 2012 Alkoxide packaged sodium dihydrogenphosphide synthesis and reactivity Thesis ETH Zurich doi 10 3929 ethz a 007333135 hdl 20 500 11850 153552 a href Template Cite thesis html title Template Cite thesis cite thesis a CS1 maint multiple names authors list link a b c d Westerhausen Matthias Krieck Sven Langer Jens Al Shboul Tareq M A Gorls Helmar March 2013 Phosphanides of calcium and their oxidation products Coordination Chemistry Reviews 257 5 6 1049 1066 doi 10 1016 j ccr 2012 06 018 Han Yong Shen 2020 Chemical Transformations of Phosphine and Phosphido Ruthenium Complexes Thesis doi 10 25911 5f6b247b7012f hdl 1885 209941 a b c Mont O Schmitz Du Nagel F Schaal W 1958 02 21 Uber einfache und komplexe Schwermetallphosphine und Polyphosphine Angewandte Chemie in German 70 4 105 doi 10 1002 ange 19580700407 a b Schafer H Zipfel J Gutekunst B Lemmert U October 1985 Ubergangsmetallphosphidokomplexe IX P funktionelle Heterocyclische Mangan Phosphor Vier und Sechsringkomplexe Zeitschrift fur anorganische und allgemeine Chemie in German 529 10 157 172 doi 10 1002 zaac 19855291021 Kosnik Stephanie 2017 Building New Low Valent Phosphorus Molecules by P Transfer Thesis Becker G Eschbach B Mundt O Reti M Niecke E Issberner K Nieger M Thelen V Noth H Waldhor R Schmidt M 1998 Bis 1 2 dimethoxyethan O O lithium phosphanid arsanid und chlorid drei neue Vertreter des Bis 1 2 dimethoxyethan O O lithium bromid Typs Zeitschrift fur Anorganische und Allgemeine Chemie 624 3 469 482 doi 10 1002 SICI 1521 3749 199803 624 3 lt 469 AID ZAAC469 gt 3 0 CO 2 F a b Bhattacharyya Koyel X Dreyfuss Sebastien Saffon Merceron Nathalie Mezailles Nicolas 2016 P 4 functionalization by hydrides direct synthesis of P H bonds Chemical Communications 52 29 5179 5182 doi 10 1039 C6CC01683A PMID 26997653 Mitzel Norbert W 1999 Parent Substances of Inorganic Chemistry Homoleptic Pnictogenyl Compounds of Group 14 E ZR2 4 Angewandte Chemie International Edition 38 1 2 86 88 doi 10 1002 SICI 1521 3773 19990115 38 1 2 lt 86 AID ANIE86 gt 3 0 CO 2 8 a b Umbarkar Shubhangi B Sekar Perumal Scheer Manfred 2001 01 01 Reactivity Study of the P 2 Ligand Complex CpCr CO 2 2 m h 2 P 2 Phosphorus Sulfur and Silicon and the Related Elements 169 1 205 208 doi 10 1080 10426500108546624 S2CID 96952262 a b c d e f Bauer Susanne Hunger Cornelia Bodensteiner Michael Ojo Wilfried Solo Cros Gagneux Arnaud Chaudret Bruno Nayral Celine Delpech Fabien Scheer Manfred 3 November 2014 Transition Metal Complexes Containing Parent Phosphine or Phosphinyl Ligands and Their Use as Precursors for Phosphide Nanoparticles Inorganic Chemistry 53 21 11438 11446 doi 10 1021 ic5012082 PMID 25329878 a b Uecker G Schmitz DuMont O December 1969 Dihydrogenphosphide und Dihydrogenphosphidosalze der Ubergangsmetalle II Bildung von Mangan II dihydrogenphosphid und Kalium tetra dihydrogenphosphido manganat II Zeitschrift fur anorganische und allgemeine Chemie in German 371 5 6 318 324 doi 10 1002 zaac 19693710514 a b c Deppisch Bertold Schafer Hans Binder Dieter Leske Werner December 1984 Ubergangsmetallphosphidokomplexe VIII Strukturuntersuchungen an Ubergangsmetallphosphor Vier und Sechsringkomplexen Die Strukturen von CO 4MnPH2 2 CO 4MnPH2 3 und cpNiPH2 3 Zeitschrift fur anorganische und allgemeine Chemie in German 519 12 53 66 doi 10 1002 zaac 19845191206 a b Florke U ed 1996 12 01 m Bromo m phosphido bis tetracarbonylmanganese and di m phosphido bis tetracarbonylmanganese Co crystallization and disorder Zeitschrift fur Kristallographie Crystalline Materials 211 12 908 910 doi 10 1524 zkri 1996 211 12 908 a b c Schafer Hans August 1980 Ubergangsmetallphosphidokomplexe IV Phosphido und Bistrimethylsilylphosphidokomplexe des Eisens Zeitschrift fur anorganische und allgemeine Chemie in German 467 1 105 122 doi 10 1002 zaac 19804670113 a b c d e f g h i j k l m Schafer H Leske W September 1987 Ubergangsmetallphosphido Komplexe XIV P funktionelle phosphidoverbruckte Heterozweikern komplexe mit und ohne Metall Metall Bindung PH2 verbruckte cp CO xFe Derivate Zeitschrift fur anorganische und allgemeine Chemie in German 552 9 50 68 doi 10 1002 zaac 19875520906 Schafer H Leske W Mattern G February 1988 Ubergangsmetallphosphidokomplexe XVI Die Strukturen von zwei offenkettigen PH2 verbruckten Zweikernkomplexen cp CO 2Fe mu PH2 MLn MLn Fe CO 4 MnMecp CO 2 Zeitschrift fur anorganische und allgemeine Chemie in German 557 1 59 68 doi 10 1002 zaac 19885570106 a b c d Colson Adam C Whitmire Kenton H 2010 10 25 Synthesis Characterization and Reactivity of the Heterometallic Dinuclear m PH 2 and m PPhH Complexes FeMn CO 8 m PH 2 and FeMn CO 8 m PPhH Organometallics 29 20 4611 4618 doi 10 1021 om100736m a b Schmitz DuMont O Uecker G Schaal W October 1969 Dihydrogenphosphide und Dihydrogenphosphidosalze der Ubergangsmetalle I Nickel II dihydrogenphosphid und Kalium tris dihydrogen phosphido niccolat II Zeitschrift fur anorganische und allgemeine Chemie in German 370 1 2 67 79 doi 10 1002 zaac 19693700108 Schaffr Hans Zipfel Jurgen Migula Brigitte Binder Dieter June 1983 Ubergangsmetallphosphidokomplexe VII Ringgrosseneffekte bei den NMR Daten von Ubergangsmetallphosphor Vier und Sechsringkomplexen Zeitschrift fur anorganische und allgemeine Chemie in German 501 6 111 120 doi 10 1002 zaac 19835010613 Schafer H December 1979 Ubergangsmetallphosphidokomplexe II Phosphido und Bistrimethylsilylphosphidokomplexe des Nickels Zeitschrift fur anorganische und allgemeine Chemie in German 459 1 157 169 doi 10 1002 zaac 19794590117 a b Yao Shenglai Brym Markus Merz Klaus Driess Matthias 2008 07 01 Facile Access to a Stable Divalent Germanium Compound with a Terminal PH 2 Group and Related PR 2 Derivatives Organometallics 27 14 3601 3607 doi 10 1021 om800269f Vogel Ulf Sekar Perumal Ahlrichs Reinhart Huniar Uwe Scheer Manfred April 2003 An Unusual Bonding Situation in a Novel Au I Phosphido Complex with a Planar Au 3 P 3 Framework European Journal of Inorganic Chemistry 2003 8 1518 2522 doi 10 1002 ejic 200390197 a b Ebsworth E A V McIntosh A P Schroder M September 1986 Polynuclear metal complexes incorporating hydrido phosphido ligands Journal of Organometallic Chemistry 312 2 c41 c43 doi 10 1016 0022 328X 86 80309 6 a b Garcia M Esther Riera Victor Ruiz Miguel A Rueda M Teresa Saez David 2002 12 01 Dimolybdenum and Ditungsten Cyclopentadienyl Carbonyls with Electron Rich Phosphido Bridges Synthesis of the Hydrido Phosphido Complexes M 2 Cp 2 m H m PRR CO 4 and Unsaturated Bis phosphido Complexes M 2 Cp 2 m PR 2 m PR R CO x x 1 2 R R R Et Cy t Bu Organometallics 21 25 5515 5525 doi 10 1021 om020573f a b Haupt H J Krampe O Florke U May 1996 Darstellung und Molekulstrukturen von oligofunktionalen Dirheniumcarbonylderivaten aus Dirheniumnonacarbonylphosphan Zeitschrift fur anorganische und allgemeine Chemie in German 622 5 807 812 doi 10 1002 zaac 19966220510 a b c d e Bohle D Scott Clark George R Rickard Clifton E F Roper Warren R August 1990 Organotransition metal substituted primary phosphines osmium phosphido PH2 complexes Journal of Organometallic Chemistry 393 2 243 285 doi 10 1016 0022 328X 90 80204 D a b c d Scott Bohle D Clark George R Rickard Clifton E F Roper Warren R Taylor Michael J July 1988 Phosphine PH3 complexes of ruthenium osmium and iridium as precursors of terminal phosphido PH2 complexes and the crystal structure of Os m2 PH2 Cl CO PPh3 2 2 C2H2Cl4 4 Journal of Organometallic Chemistry 348 3 385 409 doi 10 1016 0022 328X 88 80421 2 a b c d Johnson Brian F G Lewis Jack Nordlander Ebbe Raithby Paul R January 1997 The crystal and molecular structure of Os6 m H CO 21 NCMe m PH2 Polyhedron 16 19 3463 3467 doi 10 1016 S0277 5387 97 00060 0 Johnson Brian F G Lewis Jack Nordlander Ebbe Owen Steven M Raithby Paul R 1996 Systematic synthesis of hexanuclear phosphido bridged osmium clusters crystal and molecular structure of Os 6 µ H CO 22 µ PH 2 J Chem Soc Dalton Trans 8 1567 1571 doi 10 1039 DT9960001567 Wildman Elizabeth P Balazs Gabor Wooles Ashley J Scheer Manfred Liddle Stephen T November 2016 Thorium phosphorus triamidoamine complexes containing Th P single and multiple bond interactions Nature Communications 7 1 12884 doi 10 1038 ncomms12884 PMC 5056418 PMID 27682617 Andrews Lester Cho Han Gook Thanthiriwatte K Sahan Dixon David A 2017 03 06 Thorium and Uranium Hydride Phosphorus and Arsenic Bearing Molecules with Single and Double Actinide Pnictogen and Bridged Agostic Hydrogen Bonds Inorganic Chemistry 56 5 2949 2957 doi 10 1021 acs inorgchem 6b03055 PMID 28195738 Gardner Benedict M Balazs Gabor Scheer Manfred Tuna Floriana McInnes Eric J L McMaster Jonathan Lewis William Blake Alexander J Liddle Stephen T 2014 04 22 Triamidoamine Uranium IV Stabilized Terminal Parent Phosphide and Phosphinidene Complexes PDF Angewandte Chemie International Edition 53 17 4484 4488 doi 10 1002 anie 201400798 PMID 24644135 S2CID 1735535 Driess Matthias Pritzkow Hans Skipinski Markus Winkler Uwe 1 October 1998 Intriguing Tetrasodium Dication Cluster Na 4 2 Stabilized between Two Silyl fluorosilyl phosphanide Shells Journal of the American Chemical Society 120 41 10774 10775 doi 10 1021 ja9822963 A G Sykes 19 April 2000 Main Chemistry Group Advances in Inorganic Chemistry Vol 50 Elsevier p 246 ISBN 978 0 08 049365 7 Retrieved from https en wikipedia org w index php title Phosphanide amp oldid 1141321820, wikipedia, wiki, book, books, library,

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