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Perfluorooctane

Perfluorooctane, also known as octadecafluorooctane, is a fluorocarbon liquid—a perfluorinated derivative of the hydrocarbon octane. It can be a good substitute for insulating oil in high voltage electronics. In addition to heat transfer applications, it has also been used as a breathable fluid in partial liquid ventilation.[2]

Perfluorooctane[1]
Names
Preferred IUPAC name
Octadecafluorooctane
Other names
PF5080
Identifiers
  • 307-34-6 N
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:38826 Y
ChemSpider
  • 9018 Y
ECHA InfoCard 100.005.637
EC Number
  • 206-199-2
  • 9387
UNII
  • 6P60ZBK0QL Y
  • DTXSID0059794
  • InChI=1S/C8F18/c9-1(10,3(13,14)5(17,18)7(21,22)23)2(11,12)4(15,16)6(19,20)8(24,25)26 Y
    Key: YVBBRRALBYAZBM-UHFFFAOYSA-N Y
  • InChI=1/C8F18/c9-1(10,3(13,14)5(17,18)7(21,22)23)2(11,12)4(15,16)6(19,20)8(24,25)26
    Key: YVBBRRALBYAZBM-UHFFFAOYAG
  • FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
Properties
C8F18
Molar mass 438.06 g/mol
Appearance Clear, colorless liquid
Density 1.766 g/mL
Melting point −25 °C (−13 °F; 248 K)
Boiling point 103 to 104 °C (217 to 219 °F; 376 to 377 K)
10 ppm
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
None
Flash point None
None
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

Manufacture edit

Perfluorooctane can be manufactured by the Fowler process or by electrochemical fluorination.

Fowler Process edit

The Fowler process involves moderating the action of elemental fluorine with cobalt fluoride in the gas phase from octane.

Electrochemical fluorination edit

Electrolysis in hydrogen fluoride of nonanoic acid will produce both perfluorononanoic acid and perfluorooctane. Perfluorooctane manufactured this way is marketed under the name PF5080 (or FC77) by 3M as part of their Fluorinert range of heat transfer fluids.[3]

Applications edit

Perfluorooctane is chemically inert, but has useful physical properties, leading to its employment in diverse areas:

  • Heat transfer agent[4]
  • Dielectric fluid
  • Tamponade in eye surgery[5]

References edit

  1. ^ Perfluorooctane at Sigma-Aldrich
  2. ^ H. Proquitté; M. Rüdiger; R. R. Wauer & G. Schmalisch (2003). "Breathing gas perfluorocarbon measurements using an absorber filled with zeolites". British Journal of Anaesthesia. 91 (5): 736–8. doi:10.1093/bja/aeg247. PMID 14570799.
  3. ^ "3M Performance Fluid PF-5080". 3M.
  4. ^ . tradelinemedical.net. Archived from the original on 2014-05-20.
  5. ^ Claes C, Worst J, Zivojnovic R (1992). "Retinal detachment surgery following implantation of a keratoprosthesis. A case report". Bulletin de la Société Belge d'Ophtalmologie. 243: 167–169. PMID 1302147.

perfluorooctane, also, known, octadecafluorooctane, fluorocarbon, liquid, perfluorinated, derivative, hydrocarbon, octane, good, substitute, insulating, high, voltage, electronics, addition, heat, transfer, applications, also, been, used, breathable, fluid, pa. Perfluorooctane also known as octadecafluorooctane is a fluorocarbon liquid a perfluorinated derivative of the hydrocarbon octane It can be a good substitute for insulating oil in high voltage electronics In addition to heat transfer applications it has also been used as a breathable fluid in partial liquid ventilation 2 Perfluorooctane 1 Names Preferred IUPAC name Octadecafluorooctane Other names PF5080 Identifiers CAS Number 307 34 6 N 3D model JSmol Interactive image ChEBI CHEBI 38826 Y ChemSpider 9018 Y ECHA InfoCard 100 005 637 EC Number 206 199 2 PubChem CID 9387 UNII 6P60ZBK0QL Y CompTox Dashboard EPA DTXSID0059794 InChI InChI 1S C8F18 c9 1 10 3 13 14 5 17 18 7 21 22 23 2 11 12 4 15 16 6 19 20 8 24 25 26 YKey YVBBRRALBYAZBM UHFFFAOYSA N YInChI 1 C8F18 c9 1 10 3 13 14 5 17 18 7 21 22 23 2 11 12 4 15 16 6 19 20 8 24 25 26Key YVBBRRALBYAZBM UHFFFAOYAG SMILES FC F F C F F C F F C F F C F F C F F C F F C F F F Properties Chemical formula C8F18 Molar mass 438 06 g mol Appearance Clear colorless liquid Density 1 766 g mL Melting point 25 C 13 F 248 K Boiling point 103 to 104 C 217 to 219 F 376 to 377 K Solubility in water 10 ppm Hazards Occupational safety and health OHS OSH Main hazards None Flash point None Autoignitiontemperature None Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references Contents 1 Manufacture 1 1 Fowler Process 1 2 Electrochemical fluorination 2 Applications 3 ReferencesManufacture editPerfluorooctane can be manufactured by the Fowler process or by electrochemical fluorination Fowler Process edit The Fowler process involves moderating the action of elemental fluorine with cobalt fluoride in the gas phase from octane Electrochemical fluorination edit Electrolysis in hydrogen fluoride of nonanoic acid will produce both perfluorononanoic acid and perfluorooctane Perfluorooctane manufactured this way is marketed under the name PF5080 or FC77 by 3M as part of their Fluorinert range of heat transfer fluids 3 Applications editPerfluorooctane is chemically inert but has useful physical properties leading to its employment in diverse areas Heat transfer agent 4 Dielectric fluid Tamponade in eye surgery 5 References edit Perfluorooctane at Sigma Aldrich H Proquitte M Rudiger R R Wauer amp G Schmalisch 2003 Breathing gas perfluorocarbon measurements using an absorber filled with zeolites British Journal of Anaesthesia 91 5 736 8 doi 10 1093 bja aeg247 PMID 14570799 3M Performance Fluid PF 5080 3M Tradeline Medical Buy Medical Grade Perfluorooctane tradelinemedical net Archived from the original on 2014 05 20 Claes C Worst J Zivojnovic R 1992 Retinal detachment surgery following implantation of a keratoprosthesis A case report Bulletin de la Societe Belge d Ophtalmologie 243 167 169 PMID 1302147 Retrieved from https en wikipedia org w index php title Perfluorooctane amp oldid 1077919453, wikipedia, wiki, book, books, library,

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