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Palladium fluoride

Palladium fluoride is the name of a series of binary compounds of palladium and fluorine. These include:

  • Palladium(II) fluoride or palladium difluoride, PdF2
  • Palladium(II,IV) fluoride or palladium trifluoride, PdF3. It is not palladium(III) fluoride (which is unknown), and is often described as palladium(II) hexafluoropalladate(IV), PdII[PdIVF6][1]
  • Palladium(IV) fluoride, or palladium tetrafluoride, PdF4
  • Palladium(VI) fluoride, or palladium hexafluoride, PdF6, which is calculated to be stable[2]

Palladium-fluorine coordination complexes have been developed to catalyse the synthesis of aryl fluorides, which are otherwise difficult to make.[3][4]

References

  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.
  2. ^ Aullón, G.; Alvarez, S. (2007). "On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride". Inorg. Chem. 46 (7): 2700–2703. doi:10.1021/ic0623819. PMID 17326630.
  3. ^ Grushin, V. V. (2002). "Palladium Fluoride Complexes: One More Step toward Metal-Mediated C-F Bond Formation". Chem. Eur. J. 8 (5): 1006–1014. doi:10.1002/1521-3765(20020301)8:5<1006::AID-CHEM1006>3.0.CO;2-M. PMID 11891886.
  4. ^ Watson, D. A.; Su, M.; Teverovskiy, G.; Zhang, Y.; García-Fortanet, J.; Kinzel, T.; Buchwald, S. L. (2009). "Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides". Science. 325 (5948): 1661–1664. Bibcode:2009Sci...325.1661W. doi:10.1126/science.1178239. PMC 3038120. PMID 19679769.

palladium, fluoride, name, series, binary, compounds, palladium, fluorine, these, include, palladium, fluoride, palladium, difluoride, pdf2, palladium, fluoride, palladium, trifluoride, pdf3, palladium, fluoride, which, unknown, often, described, palladium, he. Palladium fluoride is the name of a series of binary compounds of palladium and fluorine These include Palladium II fluoride or palladium difluoride PdF2 Palladium II IV fluoride or palladium trifluoride PdF3 It is not palladium III fluoride which is unknown and is often described as palladium II hexafluoropalladate IV PdII PdIVF6 1 Palladium IV fluoride or palladium tetrafluoride PdF4 Palladium VI fluoride or palladium hexafluoride PdF6 which is calculated to be stable 2 Palladium fluorine coordination complexes have been developed to catalyse the synthesis of aryl fluorides which are otherwise difficult to make 3 4 References Edit Greenwood Norman N Earnshaw Alan 1997 Chemistry of the Elements 2nd ed Butterworth Heinemann pp 1152 1153 ISBN 978 0 08 037941 8 Aullon G Alvarez S 2007 On the Existence of Molecular Palladium VI Compounds Palladium Hexafluoride Inorg Chem 46 7 2700 2703 doi 10 1021 ic0623819 PMID 17326630 Grushin V V 2002 Palladium Fluoride Complexes One More Step toward Metal Mediated C F Bond Formation Chem Eur J 8 5 1006 1014 doi 10 1002 1521 3765 20020301 8 5 lt 1006 AID CHEM1006 gt 3 0 CO 2 M PMID 11891886 Watson D A Su M Teverovskiy G Zhang Y Garcia Fortanet J Kinzel T Buchwald S L 2009 Formation of ArF from LPdAr F Catalytic Conversion of Aryl Triflates to Aryl Fluorides Science 325 5948 1661 1664 Bibcode 2009Sci 325 1661W doi 10 1126 science 1178239 PMC 3038120 PMID 19679769 This set index page lists chemical compounds articles associated with the same name If an internal link led you here you may wish to change the link to point directly to the intended article Retrieved from https en wikipedia org w index php title Palladium fluoride amp oldid 1052866420, wikipedia, wiki, book, books, library,

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