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4-Chlorobenzaldehyde

4-Chlorobenzaldehyde is an organic compound with the chemical formula C7H5ClO. It can be produced by the oxidation of 4-chlorobenzyl alcohol.[2][3] It can be further oxidized to 4-chlorobenzoic acid.[4] It will react with malononitrile to form 4-chlorobenzylidenylmalononitrile. [5]4-Chlorobenzaldehyde reacts with benzylamine to produce N-(4-chlorobenzylidenyl)benzylamine。[6]

4-Chlorobenzaldehyde
Identifiers
  • 104-88-1 Y
3D model (JSmol)
  • Interactive image
ChEMBL
  • ChEMBL1474
ECHA InfoCard 100.002.953
EC Number
  • 203-247-4
KEGG
  • C06648
  • 7726
UNII
  • E67727UP9Z
UN number 2811
  • DTXSID2021860
  • InChI=1S/C7H5ClO/c8-7-3-1-6(5-9)2-4-7/h1-5H
    Key: AVPYQKSLYISFPO-UHFFFAOYSA-N
  • C1=CC(=CC=C1C=O)Cl
Properties
C7H5ClO
Molar mass 140.57 g·mol−1
Melting point 47.5 °C (117.5 °F; 320.6 K)
Boiling point 213.5 °C (416.3 °F; 486.6 K)
Hazards
GHS labelling:[1]
Warning
H302, H315, H317, H319, H411
P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P333+P313, P337+P317, P362+P364, P391, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

References edit

  1. ^ "4-Chlorobenzaldehyde". pubchem.ncbi.nlm.nih.gov. Retrieved 3 April 2022.
  2. ^ Yang, Y. X.; An, X. Q.; Kang, M.; Zeng, W.; Yang, Z. W.; Ma, H. C. (2020). "A Simple and Effective Method for Catalytic Oxidation of Alcohols Using the Oxone/Bu4NHSO4 Oxidation System". Russian Journal of Organic Chemistry. 56 (3): 521–523. doi:10.1134/S1070428020030240. ISSN 1070-4280. S2CID 216049138. Retrieved 2021-05-10.
  3. ^ Alegre-Requena, Juan V.; Marqués-López, Eugenia; Herrera, Raquel P. (2018-01-04). "Organocatalyzed Enantioselective Aldol and Henry Reactions Starting from Benzylic Alcohols". Advanced Synthesis & Catalysis. 360 (1): 124–129. doi:10.1002/adsc.201701351. hdl:10261/186549. ISSN 1615-4150. S2CID 102499775. Retrieved 2021-05-10.
  4. ^ Hajimohammadi, Mahdi; Azizi, Naeleh; Tollabimazraeno, Sajjad; Tuna, Ali; Duchoslav, Jiri; Knör, Günther (2021). "Cobalt (II) Phthalocyanine Sulfonate Supported on Reduced Graphene Oxide (RGO) as a Recyclable Photocatalyst for the Oxidation of Aldehydes to Carboxylic Acids". Catalysis Letters. 151 (1): 36–44. doi:10.1007/s10562-020-03287-9. ISSN 1011-372X. S2CID 220312197. Retrieved 2021-05-10.
  5. ^ Gao, Ziyang; Yang, Hongyuan; Liu, Qing (2019). "Natural Seashell Waste as an Efficient and Low-Cost Catalyst for the Synthesis of Arylmethylenemalonitriles". CLEAN – Soil, Air, Water. 47 (10): 1900129. Bibcode:2019CSAW...4700129G. doi:10.1002/clen.201900129. ISSN 1863-0650. S2CID 203946880. Retrieved 2021-05-10.
  6. ^ He, Meixia; Lehn, Jean-Marie (2019-11-20). "Time-Dependent Switching of Constitutional Dynamic Libraries and Networks from Kinetic to Thermodynamic Distributions". Journal of the American Chemical Society. 141 (46): 18560–18569. doi:10.1021/jacs.9b09395. ISSN 0002-7863. PMID 31714075. S2CID 207938797. Retrieved 2021-05-10.

chlorobenzaldehyde, organic, compound, with, chemical, formula, c7h5clo, produced, oxidation, chlorobenzyl, alcohol, further, oxidized, chlorobenzoic, acid, will, react, with, malononitrile, form, chlorobenzylidenylmalononitrile, reacts, with, benzylamine, pro. 4 Chlorobenzaldehyde is an organic compound with the chemical formula C7H5ClO It can be produced by the oxidation of 4 chlorobenzyl alcohol 2 3 It can be further oxidized to 4 chlorobenzoic acid 4 It will react with malononitrile to form 4 chlorobenzylidenylmalononitrile 5 4 Chlorobenzaldehyde reacts with benzylamine to produce N 4 chlorobenzylidenyl benzylamine 6 4 Chlorobenzaldehyde IdentifiersCAS Number 104 88 1 Y3D model JSmol Interactive imageChEMBL ChEMBL1474ECHA InfoCard 100 002 953EC Number 203 247 4KEGG C06648PubChem CID 7726UNII E67727UP9ZUN number 2811CompTox Dashboard EPA DTXSID2021860InChI InChI 1S C7H5ClO c8 7 3 1 6 5 9 2 4 7 h1 5HKey AVPYQKSLYISFPO UHFFFAOYSA NSMILES C1 CC CC C1C O ClPropertiesChemical formula C 7H 5Cl OMolar mass 140 57 g mol 1Melting point 47 5 C 117 5 F 320 6 K Boiling point 213 5 C 416 3 F 486 6 K HazardsGHS labelling 1 PictogramsSignal word WarningHazard statements H302 H315 H317 H319 H411Precautionary statements P261 P264 P264 P265 P270 P271 P272 P273 P280 P301 P317 P302 P352 P304 P340 P305 P351 P338 P319 P321 P330 P332 P317 P333 P313 P337 P317 P362 P364 P391 P403 P233 P405 P501Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesReferences edit 4 Chlorobenzaldehyde pubchem ncbi nlm nih gov Retrieved 3 April 2022 Yang Y X An X Q Kang M Zeng W Yang Z W Ma H C 2020 A Simple and Effective Method for Catalytic Oxidation of Alcohols Using the Oxone Bu4NHSO4 Oxidation System Russian Journal of Organic Chemistry 56 3 521 523 doi 10 1134 S1070428020030240 ISSN 1070 4280 S2CID 216049138 Retrieved 2021 05 10 Alegre Requena Juan V Marques Lopez Eugenia Herrera Raquel P 2018 01 04 Organocatalyzed Enantioselective Aldol and Henry Reactions Starting from Benzylic Alcohols Advanced Synthesis amp Catalysis 360 1 124 129 doi 10 1002 adsc 201701351 hdl 10261 186549 ISSN 1615 4150 S2CID 102499775 Retrieved 2021 05 10 Hajimohammadi Mahdi Azizi Naeleh Tollabimazraeno Sajjad Tuna Ali Duchoslav Jiri Knor Gunther 2021 Cobalt II Phthalocyanine Sulfonate Supported on Reduced Graphene Oxide RGO as a Recyclable Photocatalyst for the Oxidation of Aldehydes to Carboxylic Acids Catalysis Letters 151 1 36 44 doi 10 1007 s10562 020 03287 9 ISSN 1011 372X S2CID 220312197 Retrieved 2021 05 10 Gao Ziyang Yang Hongyuan Liu Qing 2019 Natural Seashell Waste as an Efficient and Low Cost Catalyst for the Synthesis of Arylmethylenemalonitriles CLEAN Soil Air Water 47 10 1900129 Bibcode 2019CSAW 4700129G doi 10 1002 clen 201900129 ISSN 1863 0650 S2CID 203946880 Retrieved 2021 05 10 He Meixia Lehn Jean Marie 2019 11 20 Time Dependent Switching of Constitutional Dynamic Libraries and Networks from Kinetic to Thermodynamic Distributions Journal of the American Chemical Society 141 46 18560 18569 doi 10 1021 jacs 9b09395 ISSN 0002 7863 PMID 31714075 S2CID 207938797 Retrieved 2021 05 10 Retrieved from https en wikipedia org w index php title 4 Chlorobenzaldehyde amp oldid 1210419926, wikipedia, wiki, book, books, library,

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