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Magnesium chromate

Magnesium chromate is a chemical compound, with the formula MgCrO4. It is a yellow, odorless, water-soluble solid with several important industrial uses. This chromate can be manufactured as a powder.

Magnesium chromate
Names
Other names
Magnesium chromate(VI)
Magnesium monochromate
Magnesium monochromate(VI)
Identifiers
  • 13423-61-5
3D model (JSmol)
  • Interactive image
ChemSpider
  • 55507
ECHA InfoCard 100.033.204
  • 61599
  • DTXSID50893929
  • InChI=1S/Cr.Mg.4O/q;+2;;;2*-1
    Key: CRGGPIWCSGOBDN-UHFFFAOYSA-N
  • InChI=1/Cr.Mg.4O/q;+2;;;2*-1/rCrO4.Mg/c2-1(3,4)5;/q-2;+2
    Key: CRGGPIWCSGOBDN-OVNOGNLDAB
  • [O-][Cr](=O)(=O)[O-].[Mg+2]
Properties
MgCrO4
Molar mass 140.297 g·mol−1
Appearance Yellow solid
soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

History

Before 1940, the literature about magnesium chromate and its hydrates was sparse, but studies starting in that year looked at its properties and solubility.[1]

Uses

It is available commercially in a variety of powders, from nanoscale to micron-sized, either as an anhydrous or hydrated form.[2][3]

As a hydrate, it is useful as a corrosion inhibitor and pigment,[4] or as an ingredient in cosmetics.[5] In 2011, an undecahydrate (containing 11 molecules of water) of this compound was discovered by scientists at the University College London.[6]

Hazards

Magnesium chromate hydrate should be stored at room temperature, and there is no current therapeutic use.[7] It is a confirmed carcinogen, and can cause acute and dermititis, and possibly kidney and liver damage if inhaled, so it should be treated as a hazardous waste.[8]

References

  1. ^ Hill, Arthur E.; Soth, Glenn C.; Ricci, John E. (1940). "The Systems Magnesium Chromate—Water and Ammonium Chromate—Water from 0 to 75 °C". Journal of the American Chemical Society. 62 (8): 2131. doi:10.1021/ja01865a059.
  2. ^ . American Elements. Archived from the original on 2013-07-22. Retrieved 2013-07-16.
  3. ^ Li, Su Ping; Jia, Xiao Lin; Qi, Ya Fang (2011). "Synthesis of Nano-Crystalline Magnesium Chromate Spinel by Citrate Sol-Gel Method". Advanced Materials Research. 284–286: 730. doi:10.4028/www.scientific.net/AMR.284-286.730. S2CID 137408833.
  4. ^ "Magnesium chromate hydrate, 99.8% (metals basis)". Us.vwr.com. Retrieved 2013-07-16.
  5. ^ "Item # MG-401, Heavy Magnesium Chromate Powder On Atlantic Equipment Engineers, A Division Of Micron Metals, Inc". Metal-powders-compounds.micronmetals.com. Retrieved 2013-07-16.
  6. ^ Fortes, A. Dominic; Wood, Ian G. (March 2012). "X-ray powder diffraction analysis of a new magnesium chromate hydrate, MgCrO4·11H2O". Powder Diffraction. 27 (1): 8–11. doi:10.1017/S088571561200005X.
  7. ^ "Magnesium chromate hydrate | CAS 23371-94-0 | Santa Cruz Biotech". Santa Cruz Biotechnology, Inc. Retrieved 2013-07-16.
  8. ^ (PDF). McGean-Rohco, Inc. Archived from the original (PDF) on 2013-07-09. Retrieved 2013-07-16.

magnesium, chromate, chemical, compound, with, formula, mgcro4, yellow, odorless, water, soluble, solid, with, several, important, industrial, uses, this, chromate, manufactured, powder, namesother, names, magnesium, monochromatemagnesium, monochromate, identi. Magnesium chromate is a chemical compound with the formula MgCrO4 It is a yellow odorless water soluble solid with several important industrial uses This chromate can be manufactured as a powder Magnesium chromate NamesOther names Magnesium chromate VI Magnesium monochromateMagnesium monochromate VI IdentifiersCAS Number 13423 61 53D model JSmol Interactive imageChemSpider 55507ECHA InfoCard 100 033 204PubChem CID 61599CompTox Dashboard EPA DTXSID50893929InChI InChI 1S Cr Mg 4O q 2 2 1Key CRGGPIWCSGOBDN UHFFFAOYSA NInChI 1 Cr Mg 4O q 2 2 1 rCrO4 Mg c2 1 3 4 5 q 2 2Key CRGGPIWCSGOBDN OVNOGNLDABSMILES O Cr O O O Mg 2 PropertiesChemical formula MgCrO4Molar mass 140 297 g mol 1Appearance Yellow solidSolubility in water solubleExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references Contents 1 History 2 Uses 3 Hazards 4 ReferencesHistory EditBefore 1940 the literature about magnesium chromate and its hydrates was sparse but studies starting in that year looked at its properties and solubility 1 Uses EditIt is available commercially in a variety of powders from nanoscale to micron sized either as an anhydrous or hydrated form 2 3 As a hydrate it is useful as a corrosion inhibitor and pigment 4 or as an ingredient in cosmetics 5 In 2011 an undecahydrate containing 11 molecules of water of this compound was discovered by scientists at the University College London 6 Hazards EditMagnesium chromate hydrate should be stored at room temperature and there is no current therapeutic use 7 It is a confirmed carcinogen and can cause acute and dermititis and possibly kidney and liver damage if inhaled so it should be treated as a hazardous waste 8 References Edit Hill Arthur E Soth Glenn C Ricci John E 1940 The Systems Magnesium Chromate Water and Ammonium Chromate Water from 0 to 75 C Journal of the American Chemical Society 62 8 2131 doi 10 1021 ja01865a059 Magnesium Chromate American Elements Archived from the original on 2013 07 22 Retrieved 2013 07 16 Li Su Ping Jia Xiao Lin Qi Ya Fang 2011 Synthesis of Nano Crystalline Magnesium Chromate Spinel by Citrate Sol Gel Method Advanced Materials Research 284 286 730 doi 10 4028 www scientific net AMR 284 286 730 S2CID 137408833 Magnesium chromate hydrate 99 8 metals basis Us vwr com Retrieved 2013 07 16 Item MG 401 Heavy Magnesium Chromate Powder On Atlantic Equipment Engineers A Division Of Micron Metals Inc Metal powders compounds micronmetals com Retrieved 2013 07 16 Fortes A Dominic Wood Ian G March 2012 X ray powder diffraction analysis of a new magnesium chromate hydrate MgCrO4 11H2O Powder Diffraction 27 1 8 11 doi 10 1017 S088571561200005X Magnesium chromate hydrate CAS 23371 94 0 Santa Cruz Biotech Santa Cruz Biotechnology Inc Retrieved 2013 07 16 Material Data Sheet PDF McGean Rohco Inc Archived from the original PDF on 2013 07 09 Retrieved 2013 07 16 Retrieved from https en wikipedia org w index php title Magnesium chromate amp oldid 1015117979, wikipedia, wiki, book, books, library,

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