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Wikipedia

Glycol distearate

Glycol distearate is the diester of stearic acid and ethylene glycol. It is mostly commonly encountered in personal care products and cosmetics where it is used to produce pearlescent effects as well as a moisturizer.

Glycol distearate
Names
Preferred IUPAC name
Ethane-1,2-diyl di(octadecanoate)
Other names
Ethylene glycol distearate; Ethylene distearate; Ethylene glycol dioctadecanoate
Identifiers
  • 627-83-8 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 55120
ECHA InfoCard 100.010.014
  • 61174
UNII
  • 13W7MDN21W Y
  • DTXSID6027260
  • InChI=1S/C38H74O4/c1-3-5-7-9-11-13-15-17-19-21-23-25-27-29-31-33-37(39)41-35-36-42-38(40)34-32-30-28-26-24-22-20-18-16-14-12-10-8-6-4-2/h3-36H2,1-2H3
    Key: FPVVYTCTZKCSOJ-UHFFFAOYSA-N
  • O=C(OCCOC(=O)CCCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCCC
Properties
C38H74O4
Molar mass 595.006 g·mol−1
Appearance White Flake
Melting point 65 to 73 °C (149 to 163 °F; 338 to 346 K)[1]
Insoluble
Hazards
Lethal dose or concentration (LD, LC):
4,700 mg/kg (rat)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Synthesis edit

Glycol distearate may be produced via the esterification of stearic acid (or its esters) with ethylene glycol. It can also be produced by a reaction of stearic acid with ethylene oxide.[2]

Applications edit

When forced to crystalize as thin platelets glycol distearate can give liquids and gels a pearlescent appearance.[3] This is often used by the producers of personal care products (e.g. shower gel) to increase the visual appeal of their products. It may also act as a skin moisturizer.

Glycol distearate is also commonly used as an embedding agent in microscopy.

See also edit

References edit

  1. ^ Ethylene glycol distearate, chemicalland21.com
  2. ^ Wrigley, A. N.; Smith, F. D.; Stirton, A. J. (January 1959). "Reaction of ethylene oxide or propylene oxide with long-chain fatty acids. Mono- and diester formation". Journal of the American Oil Chemists' Society. 36 (1): 34–36. doi:10.1007/BF02540263.
  3. ^ Bolzinger, M.A.; Cogne, C.; Lafferrere, L.; Salvatori, F.; Ardaud, P.; Zanetti, M.; Puel, F. (May 2007). "Effects of surfactants on crystallization of ethylene glycol distearate in oil-in-water emulsion". Colloids and Surfaces A: Physicochemical and Engineering Aspects. 299 (1–3): 93–100. doi:10.1016/j.colsurfa.2006.11.026.

glycol, distearate, diester, stearic, acid, ethylene, glycol, mostly, commonly, encountered, personal, care, products, cosmetics, where, used, produce, pearlescent, effects, well, moisturizer, namespreferred, iupac, name, ethane, diyl, octadecanoate, other, na. Glycol distearate is the diester of stearic acid and ethylene glycol It is mostly commonly encountered in personal care products and cosmetics where it is used to produce pearlescent effects as well as a moisturizer Glycol distearate NamesPreferred IUPAC name Ethane 1 2 diyl di octadecanoate Other names Ethylene glycol distearate Ethylene distearate Ethylene glycol dioctadecanoateIdentifiersCAS Number 627 83 8 Y3D model JSmol Interactive imageChemSpider 55120ECHA InfoCard 100 010 014PubChem CID 61174UNII 13W7MDN21W YCompTox Dashboard EPA DTXSID6027260InChI InChI 1S C38H74O4 c1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 37 39 41 35 36 42 38 40 34 32 30 28 26 24 22 20 18 16 14 12 10 8 6 4 2 h3 36H2 1 2H3Key FPVVYTCTZKCSOJ UHFFFAOYSA NSMILES O C OCCOC O CCCCCCCCCCCCCCCCC CCCCCCCCCCCCCCCCCPropertiesChemical formula C 38H 74O 4Molar mass 595 006 g mol 1Appearance White FlakeMelting point 65 to 73 C 149 to 163 F 338 to 346 K 1 Solubility in water InsolubleHazardsLethal dose or concentration LD LC LD50 median dose 4 700 mg kg rat Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references Contents 1 Synthesis 2 Applications 3 See also 4 ReferencesSynthesis editGlycol distearate may be produced via the esterification of stearic acid or its esters with ethylene glycol It can also be produced by a reaction of stearic acid with ethylene oxide 2 Applications editWhen forced to crystalize as thin platelets glycol distearate can give liquids and gels a pearlescent appearance 3 This is often used by the producers of personal care products e g shower gel to increase the visual appeal of their products It may also act as a skin moisturizer Glycol distearate is also commonly used as an embedding agent in microscopy See also editGlycol stearate Ethylene bis stearamide References edit Ethylene glycol distearate chemicalland21 com Wrigley A N Smith F D Stirton A J January 1959 Reaction of ethylene oxide or propylene oxide with long chain fatty acids Mono and diester formation Journal of the American Oil Chemists Society 36 1 34 36 doi 10 1007 BF02540263 Bolzinger M A Cogne C Lafferrere L Salvatori F Ardaud P Zanetti M Puel F May 2007 Effects of surfactants on crystallization of ethylene glycol distearate in oil in water emulsion Colloids and Surfaces A Physicochemical and Engineering Aspects 299 1 3 93 100 doi 10 1016 j colsurfa 2006 11 026 Retrieved from https en wikipedia org w index php title Glycol distearate amp oldid 1033510354, wikipedia, wiki, book, books, library,

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